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At least 37 records · Page 2

Dynamic polarizabilities of two-electron atoms, with rigorous upper and lower bounds

Methods are described for calculating rigorous upper and lower bounds to dynamic dipole polarizabilities for frequencies up to and beyond the first excitation threshold, even when (as usual) the field-free problem cannot be solved exactly. These methods were employed to calculate rigorous bounds to the dynamic polarizabilities of the two-electron atoms H(-), He, and Li(+), using well correlated trial wavefunctions up to 135 terms in length. The majority of previous theoretical and experimental results for these atoms can thereby be ruled out, including the highly precise Starkschall-Gordon values, which had heretofore appeared to be the most accurate available.

Glover, R. M.↗

Dynamic polarizabilities of metastable 2/1,3S/ excited states of He and Li/+/, with rigorous upper and lower bounds

Methods previously described for calculating rigorous upper and lower bounds to dynamic dipole polarizabilities are applied to the metastable 2(1S) and 2(2S) excited states of He and Li(+), using highly correlated variational trial functions. For each of these species, the bounds rigorously establish the values of the frequency-dependent dipole polarizability to within about 1% and appear to represent the first determination of this property at frequencies above the first excitation threshold.

Glover, R. M.↗

Lower Bounds to Energy Eigenvalues for the Stark Effect in a Rigid Rotator

Upper and lower bounds have been calculated for the energy levels of a rigid rotator in an electric field, in order to study the problems associated with the use of the partitioning method for bracketing an eigenvalue of the Schrödinger equation. Results of arbitrarily high accuracy are possible in this example.

Choi, Jong H.↗

Analysis of upper and lower bounds of the frame noise in linear detector arrays

This paper estimates the upper and lower bounds of the frame noise of a linear detector array that uses a one-dimensional scan pattern. Using chi-square distribution, it is analytically shown why it is necessary to use the average of the variances and not the average of the standard deviations to estimate these bounds. Also, a criteria for determining whether any excessively noisy lines exist among the detectors is derived from these bounds. Using a Gaussian standard random variable generator, these bounds are demonstrated to be accurate within the specified confidence interval. A silicon detector array is then used for actual dark current measurements. The criterion developed for determination of noisy detectors is checked on the experimentally obtained data.

Jaggi, S.↗