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At least 37 records · Page 2

A pyroloysis technique for determining microamounts of hydrogen in lunar soil using the helium ionization detector

A method has been developed which will determine hydrogen in sub-milligram samples of lunar soil. It consists of heating the sample in a pyroprobe followed by the gas chromatographic determination of hydrogen using the helium ionization detector. Using a 7 foot, 1/8 OD stainless steel column packed with Carbosieve S, 120/140 mesh, hydrogen was well-separated from the other gases released from lunar soil. Standards of hydrogen in helium were used for calibration. The limit to detection under the conditions used was about 2 ng. The method was linear from 2 ng to 270 ng. The method was checked using some actual lunar samples. Results were typical of those obtained for lunar soils using other methods.

Bustin, R.↗

Helium Reservoirs in Iron Nanoparticles on the Lunar Surface

The Moon’s surface is directly exposed to the space environment and subject to alteration by space weathering. One agent of space weathering, the solar wind, enriches the lunar surface with helium. Although we understand how helium is delivered to the Moon, certain aspects of helium concentration processes on the surface remain unknown, such as why impact-generated glass aggregates contain more helium than equally sized soil grains of other types. Here we have analyzed the contents of vesicular iron nanoparticles in lunar impact glasses using aberration-corrected scanning transmission electron microscopy and electron energy loss spectroscopy and show that the nanoparticles contain high concentrations of helium (10-24 atoms/nm3). The widespread occurrence of vesicular iron nanoparticles among lunar samples suggests that they may be an important helium reservoir. These results also suggest that space weathering of iron-rich minerals plays a role in helium sequestration on the Moon and potentially on other airless bodies.

Brittany A. Cymes↗

Helium and hydrogen in the lunar atmosphere

Of the gas species supplied by the solar wind, only helium and hydrogen are light enough to be lost from the moon by Jeans' thermal escape mechanism. To study the behavior of helium and hydrogen, a Monte Carlo technique has been used, in which random ballistic trajectories of individual molecules are traced over a spherical moon. In the computation, a particle is 'created' on the sunlit surface, and the locations of its subsequent encounters with the surface are recorded until it escapes. Global distributions of helium and hydrogen concentrations have been computed, based on the hypothesis that the release of neutral gases from the lunar surface is confined to daytime and is correlated with the solar wind influx. The resulting helium model is in good agreement with the measurements from the Apollo 17 lunar surface mass spectrometer.

Hodges, R. R., Jr.↗

Simulation of Helium-3 Extraction from Lunar Ilmenite

Knowledge of the trapping mechanisms and diffusion characteristics of solar-wind implanted isotopes in the minerals of the lunar regolith will enable the optimization of the processes to extract solar wind gases from regolith particles. Extraction parameters include the temperature and duration of extraction, particle size, and gas yield. Diffusion data will increase the efficiency and profitability of future mining ventures. This data will also assist in optimizing the evaluations of various potential mining sites based on remote sensing data. For instance, if magnesian ilmenite (Mg,Fel.,Ti03) is found to retain He better than stoichiometric ilmenite (FeTi03), remote sensing data for Mg could be considered in addition to Ti and maturity data. The context of the currently discussed work is the mining of helium-3 for potential use as a fuel for fusion energy generation. However, the potential resources deposited by the solar wind include hydrogen (and derived water), helium-4, nitrogen and carbon. Implantation experiments such as those performed for helium isotopes in ilmenite are important for the optimized extraction of these additional resources. These experiments can easily be reproduced for most elements or isotopes of interest.

Kuhlman, K. R.↗

Helium-3 in the lunar regolith

A preliminary assessment of He-3 distribution in lunar soils was completed, including variations with soil location, depth, composition, grain size, and other parameters that might be useful in developing mining scenarios. One of the primary tools was a compilation of available analyses of He-3 in lunar samples. The compilation includes analyses of more than 250 numbered samples (plus duplicates and subsamples in many cases) from the American and Russian lunar programs, reported in nearly 100 publications. In addition, average abundances for soils from each of the Apollo landing sites were computed. These were coupled with models and measurements of other pertinent parameters.

Swindle, T.↗

Lunar surface mining for automated acquisition of helium-3: Methods, processes, and equipment

In this paper, several techniques considered for mining and processing the regolith on the lunar surface are presented. These techniques have been proposed and evaluated based primarily on the following criteria: (1) mining operations should be relatively simple; (2) procedures of mineral processing should be few and relatively easy; (3) transferring tonnages of regolith on the Moon should be minimized; (4) operations outside the lunar base should be readily automated; (5) all equipment should be maintainable; and (6) economic benefit should be sufficient for commercial exploitation. The economic benefits are not addressed in this paper; however, the energy benefits have been estimated to be between 250 and 350 times the mining energy. A mobile mining scheme is proposed that meets most of the mining objectives. This concept uses a bucket-wheel excavator for excavating the regolith, several mechanical electrostatic separators for beneficiation of the regolith, a fast-moving fluidized bed reactor to heat the particles, and a palladium diffuser to separate H2 from the other solar wind gases. At the final stage of the miner, the regolith 'tailings' are deposited directly into the ditch behind the miner and cylinders of the valuable solar wind gases are transported to a central gas processing facility. During the production of He-3, large quantities of valuable H2, H2O, CO, CO2, and N2 are produced for utilization at the lunar base. For larger production of He-3 the utilization of multiple-miners is recommended rather than increasing their size. Multiple miners permit operations at more sites and provide redundancy in case of equipment failure.

Li, Y. T.↗

Lunar Magnetic Fields: Implications for Resource Utilization

It is well known that solar-wind-implanted hydrogen and helium-3 in lunar soils are potentially usable resources for future manned activities. For economical mining of these implanted gases, it is desirable that relative concentrations exceed that of typical soils. It has previously been noted that the monthly variation of solar wind flux on the surface due to lunar immersion in the geomagnetic tail may have measurable consequences for resource utilization. It is pointed out that, for a constant external flux, locally strong lunar crustal magnetic fields will exert the dominant influence on solar wind volatile implantation rates. In particular, the strongest lunar crustal magnetic fields will both deflect and focus incident ions in local regions leading to local enhancements of the incident ion flux. Thus, the most economical sites for extraction of solar-wind-implanted volatiles may be within or adjacent to strong crustal magnetic fields. In addition, solar wind ion deflection by crustal magnetic fields must be considered in evaluating the issue of whether remnant cometary ice or water-bearing minerals have survived in permanently shadowed regions near the lunar poles. This is because sputter erosion of water ice by solar wind ions has been suggested to be an important ice loss mechanism within permanently shadowed regions. Thus, permanently shadowed regions that are also shielded from the solar wind by locally strong crustal fields could be the most promising locations for the survival of cometary ice. Additional numerical simulations are employed to show that solar wind ion deflection by strong lunar magnetic anomalies can produce local increases in the implantation rate of solar wind gases such as hydrogen.

Hood, L. L.↗

Light elements in lunar soils revisited - Carbon, nitrogen, hydrogen and helium

Based on combined data from F2-stripping and step-wise heating experiments, it is found that about 30-40% of carbon and nitrogen in submature and mature lunar soils resides in the outermost 0.1 micron of grains, presumably in the amorphous coatings that are known to be present. The remainder of carbon and nitrogen resides in composite particles such as agglutinates and microbreccias, within which C and N are distributed in a roughly uniform way. Helium shows much larger variations in its distribution between grain surfaces and interiors, with helium yield related to ilmenite content of the soil. The depth distribution of solar wind hydrogen is not readily resolvable by the stripping technique.

Becker, R. H.↗

Lunar atmospheric composition experiment

Apollo 17 carried a miniature mass spectrometer, called the Lunar Atmospheric Composition Experiment (LACE), to the moon as part of the Apollo Lunar Surface Experiments Package (ALSEP) to study the composition and variations in the lunar atmosphere. The instrument was successfully deployed in the Taurus-Littrow Valley with its entrance aperture oriented upward to intercept and measure the downward flux of gases at the lunar surface. During the ten lunations that the LACE operated, it produced a large base of data on the lunar atmosphere, mainly collected at night time. It was found that thermal escape is the most rapid loss mechanism for hydrogen and helium. For heavier gases, photoionization followed by acceleration through the solar wind electric field accounted for most of the loss. The dominant gases on the moosn were argon and helium, and models formed for their distribution are described in detail. It is concluded that most of the helium in the lunar atmosphere is of solar wind origin, and that there also exist very small amounts of methane, ammonia, and carbon dioxide.

Hoffman, J. H.↗

Formation of the lunar atmosphere

Measurements of Ar-40 and helium made by the Apollo 17 lunar surface mass-spectrometer are used in the synthesis of atmospheric supply and loss mechanisms. The argon data indicate that about 8% of the Ar-40 produced in the moon due to decay of K-40 is released into the atmosphere and subsequently lost. Variability of the atmospheric abundance of argon requires that the source be localized, probably in an unfractionated, partially molten core. If so, the radiogenic helium released with the argon amounts to 10% of the atmospheric helium supply. The total rate of helium escape from the moon accounts for only 60% of the solar wind particle influx. This seems to require a nonthermal escape mechanism for trapped solar-wind gases, probably involving weathering of exposed soil-grain surfaces by solar-wind protons.

Hodges, R. R., Jr.↗

Lunar Limb Observatory: An Incremental Plan for the Utilization, Exploration, and Settlement of the Moon

This paper proposes a comprehensive incremental program, Lunar Limb Observatory (LLO), for a return to the Moon, beginning with robotic missions and ending with a permanent lunar settlement. Several recent technological developments make such a program both affordable and scientifically valuable: robotic telescopes, the Internet, light-weight telescopes, shared- autonomy/predictive graphics telerobotic devices, and optical interferometry systems. Reasons for focussing new NASA programs on the Moon include public interest, Moon-based astronomy, renewed lunar exploration, lunar resources (especially helium-3), technological stimulus, accessibility of the Moon (compared to any planet), and dispersal of the human species to counter predictable natural catastrophes, asteroidal or cometary impacts in particular. The proposed Lunar Limb Observatory would be located in the crater Riccioli, with auxiliary robotic telescopes in M. Smythii and at the North and South Poles. The first phase of the program, after site certification, would be a series of 5 Delta-launched telerobotic missions to Riccioli (or Grimaldi if Riccioli proves unsuitable), emplacing robotic telescopes and carrying out surface exploration. The next phase would be 7 Delta-launched telerobotic missions to M. Smythii (2 missions), the South Pole (3 missions), and the North Pole (2 missions), emplacing robotic telescopes to provide continuous all-sky coverage. Lunar base establishment would begin with two unmanned Shuttle/Fitan-Centaur missions to Riccioli, for shelter emplacement, followed by the first manned return, also using the Shuttle/Fitan-Centaur mode. The main LLO at Riccioli would then be permanently or periodically inhabited, for surface exploration, telerobotic rover and telescope operation and maintenance, and support of Earth-based student projects. The LLO would evolve into a permanent human settlement, serving, among other functions, as a test area and staging base for the exploration, settlement, and terraforming of Mars.

Lowman, Paul. D., Jr.↗

Composition and physics of the lunar atmosphere.

The existence in the lunar atmosphere of helium, neon, argon, and possibly molecular hydrogen has been confirmed by the Apollo 17 mass spectrometer. The observed helium concentrations and distribution agree closely with model predictions for a non-condensable gas based on a solar wind source, thermal escape and a Monte Carlo random walk calculated longitudinal distribution. Heavier gases are lost by photoionization and subsequent sweeping away by the solar wind electric field. The observed nighttime neon concentration of 80,000 molecules per cu cm is consistent with expected amounts. Argon, however, is adsorbed on the lunar surface late at night when the surface temperature is lowest. It shows the expected predawn enhancement exhibited by condensable gases released into the atmosphere at the sunrise terminator. Hydrogen appears to exist in the molecular rather than atomic state. Its observed concentration is less than a factor of 3 higher than that predicted by a model similar to that used for helium.

Hoffman, J. H.↗

Hydrogen, helium, and other solar-wind components in lunar soil - Abundances and predictions

The lack of a shielding atmosphere on the moon permits solar-wind particles to impinge upon the lunar soil and become implanted into the various phases which comprise the soil. Relatively large quantities of solar-wind implanted hydrogen (50-100 ppm) and helium (10-50 ppm) are present. The measured parameter of I(s)FeO, a direct indicator of maturity and exposure age, can be used as a first approximation to predict the abundances of many solar-wind components in the soils. However, because ilmenite acts as a 'sponge' for the retention of certain elements, the TiO2 content of the soil is a better indicator for hydrogen and helium contents.

Taylor, Lawrence A.↗

A New Sputnik Surprise?

This paper suggests that a new "Sputnik surprise" in the form of a joint Chinese-Russian lunar base program may emerge in this decade. The Moon as a whole has been shown to be territory of strategic value, with discovery of large amounts of hydrogen (probably water ice) at the lunar poles and helium 3 everywhere in the soil, in addition to the Moon's scientific value as an object of study and as a platform for astronomy. There is thus good reason for a return to the Moon, robotically or manned. Relations between China and Russia have thawed since the mid-1990s, and the two countries have a formal space cooperation pact. It is argued here that a manned lunar program would be feasible within 5 years, using modern technology and proven spacecraft and launch vehicles. The combination of Russian lunar hardware with Chinese space technology would permit the two countries together to take the lead in solar system exploration in the 21st century.

Lowman, Paul D., Jr.↗