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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 37 records · Page 2
All sourcesNASA NTRSDOE OSTI
NASA NTRS2006

Viscosity Measurement for Tellurium Melt

The viscosity of high temperature Te melt was measured using a new technique in which a rotating magnetic field was applied to the melt sealed in a suspended ampoule, and the torque exerted by rotating melt flow on the ampoule wall was measured. Governing equations for the coupled melt flow and ampoule torsional oscillation were solved, and the viscosity was extracted from the experimental data by numerical fitting. The computational result showed good agreement with experimental data. The melt velocity transient initiated by the rotating magnetic field reached a stable condition quickly, allowing the viscosity and electrical conductivity of the melt to be determined in a short period.

Lin, Bochuan↗
NASA NTRS1990

Characterization of medium and high flow series 1500 LARC-TPI

An imidized version of LARC-TPI was developed on NASA's request for use by both aerospace and electronic industries. Two batches of LARC-TPI 1500 Series, consisting of medium-flow and high-flow pellets with different inherent viscosities, are characterized for their dynamic and isothermal melt flow properties at 340 C, mechanical properties of extrudates, extrudate porosity, and degree of crystallinity. The Series shows significantly better melt flow properties than previosly examimed forms of this polymer.

Burks, H. D.↗
DOE OSTI2026

Molten pool dynamics and humping suppression in high-speed laser welding via tailored beam configurations

High-speed laser welding is essential for increasing the production rate of fuel cell fabrication. However, when the welding speed exceeds a critical limit, humping occurs and reduces the weld quality. In this study, two tailored beam configurations, including an adjustable ring mode and a dual-beam configuration, were employed to suppress humping. Computational fluid dynamics simulations were performed to elucidate the underlying suppression mechanisms. Here, the results show that, in the adjustable ring mode, humping mitigation arises from a reduced backward cross-sectional melt flow rate and a more stable molten pool. In the dual-beam configuration, humping suppression is attributed to the deceleration of melt flow, the conduction-mode behavior of the trailing beam, and the widening of the molten pool induced by the trailing laser. Furthermore, because the dual-beam configuration directly modifies the trailing molten pool dynamics, it achieves more effective humping suppression, extending the welding speed limit to 1.50 m/s, compared with 1.00 m/s for the adjustable ring mode.

08 HYDROGEN↗
NASA NTRS2002

Theory and Simulation of A Novel Viscosity Measurement Method for High Temperature Semiconductor

The properties of molten semiconductors are good indicators for material structure transformation and hysteresis under temperature variations. Viscosity, as one of the most important properties, is difficult to measure because of high temperature, high pressure, and vapor toxicity of melts. Recently, a novel method was developed by applying a rotating magnetic field to the melt sealed in a suspended quartz ampoule, and measuring the transient torque exerted by rotating melt flow on the ampoule wall. The method was designed to measure viscosity in short time period, which is essential for evaluating temperature hysteresis. This paper compares the theoretical prediction of melt flow and ampoule oscillation with the experimental data. A theoretical model was established and the coupled fluid flow and ampoule torsional vibration equations were solved numerically. The simulation results showed a good agreement with experimental data. The results also showed that both electrical conductivity and viscosity could be calculated by fitting the theoretical results to the experimental data. The transient velocity of the melt caused by the rotating magnetic field was found reach equilibrium in about half a minute, and the viscosity of melt could be calculated from the altitude of oscillation. This would allow the measurement of viscosity in a minute or so, in contrast to the existing oscillation cup method, which requires about an hour for one measurement.

Lin, Bochuan↗
NASA NTRS1991

Advanced thermoplastic resins, phase 1

Eight thermoplastic polyimide resin systems were evaluated as composite matrix materials. Two resins were selected for more extensive mechanical testing and both were versions of LaRC-TPI (Langley Research Center - Thermoplastic Polyimide). One resin was made with LaRC-TPI and contained 2 weight percent of a di(amic acid) dopant as a melt flow aid. The second system was a 1:1 slurry of semicrystalline LaRC-TPI powder in a polyimidesulfone resin diglyme solution. The LaRC-TPI powder melts during processing and increases the melt flow of the resin. Testing included dynamic mechanical analysis, tension and compression testing, and compression-after-impact testing. The test results demonstrated that the LaRC-TPI resins have very good properties compared to other thermoplastics, and that they are promising matrix materials for advanced composite structures.

Hendricks, C. L.↗
NASA NTRS2018

Arcjet Ablation of Stony and Iron Meteorites

A test campaign was conducted placing meteorites in the 60 MW plasma Arcjet Interaction Heating Facility at NASA Ames Research Center, with the aim to achieve flight-relevant conditions for asteroid impacts in Earth's atmosphere and to provide insight into how meteoritic materials respond to extreme entry heating environments. The test conditions at heat flux of 4000 W/m2 and 140 kPa stagnation pressure are comparable to those experienced by a 30-meter diameter asteroid moving at 20 km/s velocity at 65 km altitude in the Earth's atmosphere. Test objects were a stony type H5 ordinary chondrite (Tamdakht) and an iron type IAB-MG meteorite (Campo Del Cielo), and included the terrestrial analogs Dense Flood Basalt and Fused Silica. All samples were exposed for only a few seconds in the plasma stream. Significant melt flow and vaporization was observed for both the stony and iron meteorites during exposure. Mass loss from spallation of fragments was also observed. Vapor emitted atomic lines from alkali metals and iron, but did not emit the expected MgO molecular band emissions. The meteoritic melts flowed more rapidly, indicating lower viscosity, than those of Fused Silica. The surface recession was mapped. The effective heat of ablation derived from this showed that ablation under these conditions occurred in the melt-dominated regime. Ablation parameters have an effect on ground damage estimates. A bias in ablation parameters towards the melt-dominated regime would imply that impacting asteroids survive to lower altitude, and therefore could possibly have airbursts with a larger ground damage footprint.

Asteroid↗
NASA NTRS2018

Arcjet Ablation of Stony and Iron Meteorites

A test campaign was conducted placing meteorites in the 60 MW plasma Arcjet Interaction Heating Facility at NASA Ames Research Center, with the aim to achieve flight-relevant conditions for asteroid impacts in Earth's atmosphere and to provide insight into how meteoritic materials respond to extreme entry heating environments. The test conditions at heat flux of 4000 W/m2 and 140 kPa stagnation pressure are comparable to those experienced by a 30-meter diameter asteroid moving at 20 km/s velocity at 65 km altitude in the Earth's atmosphere. Test objects were a stony type H5 ordinary chondrite (Tamdakht) and an iron type IAB-MG meteorite (Campo Del Cielo), and included the terrestrial analogs Dense Flood Basalt and Fused Silica. All samples were exposed for only a few seconds in the plasma stream. Significant melt flow and vaporization was observed for both the stony and iron meteorites during exposure. Mass loss from spallation of fragments was also observed. Vapor emitted atomic lines from alkali metals and iron, but did not emit the expected MgO molecular band emissions. The meteoritic melts flowed more rapidly, indicating lower viscosity, than those of Fused Silica. The surface recession was mapped. The effective heat of ablation derived from this showed that ablation under these conditions occurred in the melt-dominated regime. Ablation parameters have an effect on ground damage estimates. A bias in ablation parameters towards the melt-dominated regime would imply that impacting asteroids survive to lower altitude, and therefore could possibly have airbursts with a larger ground damage footprint.

Arcjet↗
DOE OSTI2025

Large-Scale Compatibilization of Postconsumer Polyolefins in the Presence of Paraffin Wax as a Rheology Modifier

Postconsumer polyolefins (r-POs) are leading plastic waste contributors today. This study reports, for the first time, the compatibilization of r-POs at a 50 kilogram (kg) scale with a styrene block copolymer compatibilizer in the presence of paraffin waxes as rheology modifiers (RMs). The addition of the rheological modifier (RM) and compatibilizer enhances the melt flow indices (MFIs) and mechanical properties, respectively. One aspect of this study is to compare the effectiveness of low-cost paraffin wax to that of specialized and expensive RMs in r-POs. The mechanical and rheological properties such as the melt flow index (MFI) of r-POs were compared in the presence of two types of RMs. Next, the study explores the challenges encountered when scaling the compatibilization of r-POs in the presence of paraffin wax from a 10-g to a 50-kg scale. The mechanical properties were determined and compared for samples at different scales. The study further investigated the effect of the method used for blending paraffin wax with r-PO and its impact on the value of their MFI and mechanical properties. This at-scale validation could pave the way for the commercialization of r-POs.

crystallinity↗
NASA NTRS1990

The effect of thermal damage on the mechanical properties of polymer regrinds

Reprocessed polymers are subjected to high processing temperatures that result in the breakdown of molecular chains and changes in the molecular structures. These phenomena are reflected in the mechanical properties of materials. Practically every regrind is seen as a new material. These experiments deal with the molding, regrinding, and reprocessing of test specimens for the study of their mechanical properties. The comparative test data from each recycled material would give students an insight of the molecular structures and property degradation. Three important rheological and mechanical properties such as melt flow, impact strength, and flexural strength are to be determined. These properties play key roles in the selection of engineering materials. The material selected for demonstration was Makrolon 3000L, a polycarbonate thermoplastic from Bayer AG. The thermal degradation due to repeated processing is reflected in the decrease in molecular weight and breakdown of molecular chains causing increase in melt flow. The Izod-impact resistance and the flexural strength deteriorate gradually.

Kundu, Nikhil K.↗
NASA NTRSDate not supplied

Simulating Meteor Ablation at the Hypersonic Materials Environmental Test System

The ablation mechanisms of stony meteorite material and a terrestrial analog were investigated at the Hypersonic Materials Environmental Test System (HyMETS) facility at NASA’s Langley Research Center. The primary analyte (Tamdakht-H5) and arc-jet test conditions were chosen to simulate the entry of an ordinary chondrite through the Earth’s mesosphere. Basalt was selected to compare the meteorite response against material with enhanced polymerization and an elevated concentration of volatile species. The initial ablation process for each material commences with the vaporization of volatile species and germination of a viscous melt layer on the stagnation surface. However, each material exhibited distinct mass loss mechanisms, with basalt recessing at twice the rate of Tamdakht. Inspection of high-speed video and chemical analysis of the post-test melt layer suggests the dominant mode of mass loss of Tamdakht is expressed through the vaporization of volatile compounds. Vaporization rates of Tamdakht are 18x higher than basalt under the most severe test conditions which provides enhanced thermal shielding. Furthermore, Tamdakht produces a relatively stable melt flow, as evidenced by perpetual growth at the sidewall and the exiguous detachment of molten material into the flow. The ablation mechanism of basalt is markedly different from Tamdakht and is governed by volatile species in the virgin material. The dominant mode of mass loss for basalt is attributed to the detachment of large sections of the stagnation surface near the edge radius. An additional but subordinate mode of mass loss is assigned to the removal of melt flow as it passes over the edge radius, where shear forces overcome the rheological properties of the molten matter. Finally, mechanistic details will be discussed in terms of designing future test campaigns, developing meteorite-based materials response models, and impacting the broader scope of the Asteroid Threat Assessment Project (ATAP).

Meteor Ablation↗
NASA NTRS1989

Polyimide matrix composites - Polyimidesulfone/LARC-TPI (1:1) blend

Polyimide matrix composites were fabricated from unidirectional unsized AS-4 carbon fiber and a doped 1:1 blend of two polyimides: PISO2 and LARC-TPI. To enhance melt flow properties, the molecular weight of the PISO2 was controlled by end-capping with phthalic anhydride and addition of 5 percent by weight p-phenylenediamine-phthalic anhydride bisamic acid dopant. Prepreg was drum-wound using a diglyme slurry comprised of the soluble polyamideacid of PISO2, the soluble bisamideacid of the dopant, and the insoluble imidized LARC-TPI powder. Melt flow studies with a rotary rheometer and parallel plate plastometer on neat resin and prepreg helped develop an optimum cure cycle. Composite mechanical properties at room and elevated temperatures, dry and moisture-saturated, were evaluated, including short beam shear strength and flexure, tensile, shear, and compression properties. Two 18 x 24-inch skin-stringer panels were fabricated, one of which was tested in compression to failure.

Johnston, Norman J.↗
NASA NTRS1987

Development of an impact- and solvent-resistant thermoplastic composite matrix, phase 4

Polyimides from BTDA with m-phenylenediamine and three aliphatic diamines were prepared in cresol and characterized. Characterization tests included compression strength and modulus, stressed solvent resistance, and melt-flow tests. Efforts to reduce the molecular weights of these polymers by either stoichiometric imbalance or phthalic anhydride end capping produced opacity in the polymer moldings when the stoichiometry was less than 99 percent. Use of 2,4-diaminotoluene in place of the m-phenylenediamine allowed clear polymer moldings to be obtained at all stoichiometries by end capping or stoichiometric imbalance. After melt-flow/molecular-weight studies, carbon fabric composites were prepared from three polyimide compositions containing BTDA, 2,4-diaminotoluene and two aliphatic diamines. Flexural strengths of two of the resins were in excess of 689 MPa (100 ksi) at both room temperature and 93 C. The polyimide from BTDA was selected for scale-up and neat resin characterization tests. The Tg of this polymer was 233 C.

Delano, C. B.↗
NASA NTRS1989

Polyimide Matrix composites: Polyimidesulfone/LARC-TPI (1:1) blend

Polyimide matrix composites were fabricated from unidirectional unsized AS-4 carbon fiber and a doped 1:1 blend of two polyimides: benzophenone dianhydride-3,3'-diamino diphenylsulfone (PISO2) and benzophenone dianhydride-3,3'-diamino benzophenone (LARC-TPI). To enhance melt flow properties, the molecular weight of the PISO2 was controlled by end-capping with phthalic anhydride and addition of 5 percent by weight p-phenylene diamine-phthalic anhydride bisamic acid dopant. Prepreg was drum-wound using a diglyme slurry comprised of the soluble polyamideacid of PISO2, the soluble bisamideacid of the dopant, and the insoluble imidized LARC-TPI powder. Melt flow studies with a rotary rheometer and parallel plate plastometer on neat resin and prepreg helped develop an optimum cure cycle. Composite mechanical properties at room and elevated temperatures, dry and moisture-saturated, were evaluated, including short beam shear strength and flexure, tensile, shear, and compression properties. Two 18 in. x 24 in. skin-stringer panels were fabricated, one of which was tested in compression to failure.

Johnston, Norman J.↗