Search NASA⌕ Search

SEARCH · Search NASA

Results for “minimum sample volume”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 37 records · Page 2
All sourcesNASA NTRSDOE OSTI
NASA NTRS1981

Trends of atmospheric methane in the Southern Hemisphere

Atmospheric observations spanning the past three years show that methane increased at 1.2 (plus or minus 0.3)% per year at Cape Grim in Tasmania (41 deg S). This rate of increase can be compared to the 1.9 (plus or minus 0.4)% per year observed at Cape Meares in Oregon (45 deg N) over the past two years. Over the corresponding period the concentration at Cape Grim increased by 1.4 (plus or minus 0.4)% per year. The Southern Hemisphere data also suggest seasonal variations with minimum concentrations in March and maximum in September. These results are based on 26 large-volume stable air samples collected cryogenically in stainless steel flasks and 75 smaller-volume air samples collected in glass flasks, all analyzed by a gas chromatograph using a flame ionization detector.

Fraser, P. J.↗
NASA NTRS1991

Effects of satellite data resolution on measuring the space/time variations of surfaces and clouds

The correlated distributions of satellite-measured visible and infrared radiances, caused by spatial and temporal variations in clouds and surfaces, have been found to be characteristic of the major climate regimes and can be described by the attributes of bidimensional and monodimensional histograms and time-composite images. Most of the variability of both the surfaces and clouds is found to occur at scales larger than the minimum resolved by satellite imagery. Since satellite imaging data sets are difficult to analyze because of their large volumes, many studies reduce the volume by various sampling or averaging schemes. The effects of data resolution and sampling on the radiance histogram statistics and on the time-composite image characteristics are examined. In particular, the sampling strategy used by the International Satellite Cloud Climatology Project is tested. This sampling strategy is found to preserve the statistics of smaller cloud variations for most regions, with the exception of very rare events, if they are accumulated over large enough areas (at least 500 km in dimension) and long enough time periods (at least one month).

Seze, Genevieve↗
DOE OSTI2020

The impact of mineral reactive surface area variation on simulated mineral reactions and reaction rates

Reactive transport modeling is an essential tool to simulate complex geochemical reactions in porous media that can impact formation properties including porosity and permeability. However, simulating these reactions is challenging due to uncertainties in model parameters, particularly mineral surface areas. Imaging has emerged as a powerful means of estimating model parameters including porosity and mineral abundance, accessibility and accessible surface area. However, these parameters, particularly mineral accessible surface area, vary with image resolution. This work aims to enhance understanding of the impact of image resolution and other means of estimating mineral reactive surface area on simulated mineral reactions and reaction rates. Mineral surface areas calculated from images with resolutions of 0.34 μm and 5.71 μm were used to simulate mineral reactions in the context of geologic CO 2 sequestration in the Paluxy formation at the continuum scale. Additional simulations were carried out using BET surface areas collected from the literature and geometric surface areas. Simulations were run for 7300 days and mineral volume fractions and effluent ion concentrations tracked and compared. Variations in mineral surface areas measured from images are within 1 order of magnitude and yield similar simulation results, indicating the impact of image resolution on simulated reactions and reaction rates is minimum for the resolutions and sample considered. In comparison, surface areas obtained from BET and geometric approaches are 1–4 orders of magnitude higher than image-obtained surface areas and result in greater simulated reaction rates and extents. Minerals with high reaction rates (calcite and siderite) are most impacted by surface area values at short times where simulated mineral volume fractions at longer times agree relatively well, even for simulations with several orders of magnitude variation in surface area. Phases with lower reaction rates, such as K-feldspar and muscovite, are predominantly impacted over longer times where variations in surface areas impact reaction extents and porosity evolution. Overall, variations in surface areas due to image resolution are small and result in little variation in simulated reactions and reaction rates while there are significant variations in simulation results when other surface area estimates are used. These variations, however, depend on the reactivity of the mineral phase where surface areas of fast-reacting phases largely impact simulations at short (hours to days) timescales and surface areas of slower-reactive phases impact longer term simulations (years).

58 GEOSCIENCES↗
DOE OSTI2020

Mechanical Characterization of High-Temperature Carbon Fiber-Polyphenylene Sulfide Composites for Large Area Extrusion Deposition Additive Manufacturing

Additive manufacturing (AM) is evolving from rapid prototyping to production of structural components. The widespread application of AM demands a high level of mechanical performance from these components, and it is therefore essential to improve feedstock material in order to meet these mechanical expectations. However, compared to traditional manufacturing techniques, the mechanical properties of AM materials and their resulting components are not well understood. In this study, we investigated the processability, microstructure, and mechanical performance of twin-screw compounded short carbon fiber reinforced polyphenylene sulfide (PPS) pellets as a feedstock material for big area AM (BAAM). The performance of the AM components was compared to that of traditional processing methods, namely injection molding (IM) and extrusion-compression molding (ECM). It was found that the AM composites exhibited 118% lower tensile strength and 55% lower tensile modulus when compared to traditional injection molding composite specimens; however, AM composites exhibited comparable properties to ECM composites. This response was attributed to highly aligned fibers in IM and AM samples. However, the AM composites contained porosity (15.5% volume), which reduced their mechanical properties in comparison to ECM composites. Finally, the IM process showed the maximum amount of fiber attrition with minimum porosity (0.007% volume), while the ECM process exhibited the least fiber attrition with 4.3% volume porosity.

36 MATERIALS SCIENCE↗
NASA NTRS1977

DESAP 1: A structural design program with stress and displacement constraints. Volume 1: Theoretical and user's manual

A finite element program is presented for computer-automated, minimum weight design of elastic structures with constraints on stresses (including local instability criteria) and displacements. Volume 1 of the report contains the theoretical and user's manual of the program. Sample problems and the listing of the program are included in Volumes 2 and 3. The element subroutines are organized so as to facilitate additions and changes by the user. As a result, a relatively minor programming effort would be required to make DESAP 1 into a special purpose program to handle the user's specific design requirements and failure criteria.

Kiusalaas, J.↗
NASA NTRS2006

Optimizing Crystal Volume for Neutron Diffraction

Neutron diffraction is uniquely sensitive to hydrogen positions and protonation state. In that context structural information from neutron data is complementary to that provided through X-ray diffraction. However, there are practical obstacles to overcome in fully exploiting the potential of neutron diffraction, Le. low flux and weak scattering. Several approaches are available to overcome these obstacles and we have investigated the simplest: increasing the diffracting volume of the crystals. Volume is a quantifiable metric that is well suited for experiment design and optimization techniques. By using response surface methods we have optimized xylose isomerase crystal volume, enabling neutron diffraction while we determined the crystallization parameters with the minimum of experiments. Our results suggest a systematic means of enabling neutron diffraction studies for a larger number of samples that require information on hydrogen position and/or protonation state.

Snell, Edward H.↗
DOE OSTI2019

Isotopic evidence for a young lunar magma ocean

Herein, mare basalt sources and ferroan anorthosite suite cumulates define a linear array on a 146 Sm/ 144 Nd versus 142 Nd/ 144 Nd isochron plot demonstrating these materials were derived from a common reservoir at 4336 +31 / –32 Ma. The minimum proportion of the Moon that was in isotopic equilibrium at this time is estimated to be 1-3% of its entire volume based on the geographic extent from which the analyzed samples were collected and the calculated depths from which the samples were derived. Scenarios in which large portions of the Moon were molten to depths of many hundreds of kilometers are required to produce the observed Sm-Nd isotopic equilibrium between the mantle and crustal rocks at 4.34 Ga. This is a consequence of the fact that limited heating of a solid Moon above the blocking temperature of the Sm-Nd isotopic system is insufficient to diffusively homogenize radiogenic Nd throughout the mantle and crust. There are three scenarios that might account for global-scale isotopic equilibrium on the Moon relatively late in Solar System history including: (1) Sm-Nd re-equilibration of a solid Moon resulting from widespread melting in response to mantle overturn or a very large impact, (2) early accretion of the Moon followed by delayed cooling due to the presence of an additional heat source that kept a large portion of the Moon molten until 4.34 Ga, or (3) late accretion of the Moon followed by rapid cooling of the magma ocean late in Solar System history. Neither density-driven overturn of the mantle, nor a large impact, are likely to homogenize the mantle and crust to the extent required by the Sm-Nd isochron. Likewise, secondary heating mechanisms, such as tidal heating or radioactive decay, are not efficient enough to keep the Moon molten to the depth of the mare basalt source regions for many tens to hundreds of millions of years. Instead, the age of equilibrium between such a compositionally diverse set of rocks, produced on a global scale, likely records the time of primordial solidification of the Moon from a magma ocean. This scenario accounts for both the petrogenetic characteristics of lunar rock suites, as well as their Sm-Nd isotopic systematics. It is supported by the preponderance of ~4.35 Ga ages obtained for other hypothetical magma ocean crystallization products, such as ferroan anorthosite suite rocks and K, REE, and P enriched cumulates that are thought to represent flotation cumulates of the magma ocean and the last vestiges of magma ocean solidification, respectively.

79 ASTRONOMY AND ASTROPHYSICS↗
NASA NTRS1975

The Rosiwal Principle and the regolithic distributions of solar-wind elements

In situ accumulation of solar elements is studied for the purpose of determining the extent of applicability of the Rosiwal Principle. The Rosiwal Principle states that the grain exposure area is proportional to the fraction of the unit volume occupied by the grains, and the test involves measurement of the relative concentrations of inert gases and reactive elements across sets of lunar fines samples for which mean grain size, sorting, and minimum radius of surface correlation are known. In some cases, the quantity of an element implanted into the lunar fines from the solar wind is found to be surface correlated, and the implications of this relationship are considered. According to the Rosiwal Principle, coarse soils should retain less inert gas than fine soil. The Principle can also be applied to species volatized or sputtered from the lunar surface and redeposited locally.

Criswell, D. R.↗
NASA NTRS1993

Age and thermochronology of K-feldspars from the Manson Impact Structure

As a contribution to the effort to obtain a precise age for the Manson Impact Structure, we are approaching the problem from a thermo chronological perspective, with the goal of extracting an age from Ar-40/Ar-39 age-spectrum analysis of partially overprinted K-feldspars taken from granitoid clasts. We find that shocked feldspars from Manson generally show a strong overprint in their age spectra, with more than 50 percent of each spectrum being reset. The reset portions of the age spectra correspond to gas lost from very small diffusion domains, and a characteristic of the Manson samples is the very large range in apparent diffusion dimensions that they display, with the smallest domains being some 400 times smaller than the largest domains. It is also noteworthy that the small domains comprise a substantial portion of the volume of the feldspars (50 percent or more). These observations are consistent with the extreme shock experienced by these samples. In detail, the spectra we have measured to date are saddle-shaped and show minimum ages of between 67 and 72 Ma, which we interpret to be maximum estimates for the age of the impact. In the case of one sample (M1-678.3; K-feldspar from a large syenite block located well below the apparent melt-matrix breccia in the M1 borehole), isotope correlation analysis suggests the presence of a non-atmospheric trapped Ar component (Ar-40/Ar-36 of 660 plus or minus 40), and an age of about 65.3 plus or minus 0.5 Ma (2 sigma). Our interpretation of our results is that the shock of impact greatly reduced the diffusion-domain sizes of our samples, making them susceptible to significant Ar loss during heating associated with impact. It appears that while our feldspars were partially open to Ar loss, they equilibrated with a non-atmospheric Ar component, probably related to impact-related degassing of old basement around the impact site.

Zeitler, P. K.↗
NASA NTRS1970

FASTER 3: A generalized-geometry Monte Carlo computer program for the transport of neutrons and gamma rays. Volume 2: Users manual

A description of the FASTER-III program for Monte Carlo Carlo calculation of photon and neutron transport in complex geometries is presented. Major revisions include the capability of calculating minimum weight shield configurations for primary and secondary radiation and optimal importance sampling parameters. The program description includes a users manual describing the preparation of input data cards, the printout from a sample problem including the data card images, definitions of Fortran variables, the program logic, and the control cards required to run on the IBM 7094, IBM 360, UNIVAC 1108 and CDC 6600 computers.

Jordan, T. M.↗
NASA NTRS1974

Data compression

An approach to data compression is discussed in which the effect achieved by compression is evaluated by the closeness of the approach to the minimum possible volume. An attempt is made to systematize the known results on data compression. The review contains: description of methods of data compression based on statistical coding and information theory; application of methods of interpolation and extrapolation; a specific compression method (related to description of the histogram of a sample); some criteria of effectiveness and methods of service information representation; and discussion of models suggested for theoretical analysis.

Babkin, V. F.↗
NASA NTRS2014

Geostationary Coastal and Air Pollution Events (GeoCAPE) Wide Angle Spectrometer (WAS)

The GeoCAPE Wide Angle Spectrometer (WAS) Study was a revisit of the COEDI Study from 2012. The customer primary goals were to keep mass, volume and cost to a minimum while meeting the science objectives and maximizing flight opportunities by fitting on the largest number of GEO accommodations possible. Riding on a commercial GEO satellite minimizes total mission costs. For this study, it is desired to increase the coverage rate,km2min, while maintaining ground sample size, 375m, and spectral resolution, 0.4-0.5nm native resolution. To be able to do this, the IFOV was significantly increased, hence the wide angle moniker. The field of view for COEDI was +0.6 degrees or (2048) 375m ground pixels. The WAS Threshold (the IDL study baseline design) is +2.4 degrees IDL study baseline design) is +2.4 degrees.

pointing and jitter↗
NASA NTRS1981

Absorption of visible radiation in atmosphere containing mixtures of absorbing and nonabsorbing particles

The presence of a strongly absorbing material, tentatively identified as graphitic carbon, or 'soot', is indicated by measurements of single-scattering albedo of tropospheric aerosols. Although theoretical calculations based on models of the ways in which soot may mix with other aerosol materials yield the single-scattering albedo values of 0.6, accounted for by a minimum 20% soot by volume, in urban regions and 0.8, yielded by 1-5% soot by volume, in rural settings, it is found that these same values can be produced by similar amounts of the iron oxide magnetite. Magnetite is shown to be indistinguishable from soot by optical measurements performed on bulk samples, and calculation of various mixtures of soot indicate the difficulty of determining aerosol composition by optical scattering techniques.

Ackerman, T. P.↗
NASA NTRS1994

HO2 detection by near infrared absorption using tunable diode lasers

The strongest absorption lines are in the v sub 2 vibrational band around 1400/cm; several near-coincident line pairs in this region provide max linestrengths of 1.2 x 10 exp -20 sq. cm/(molecule*cm). High Frequency wavelength modulation coupled with sweep integration were used to minimize noise and maintain spectral discrimination. Reduced pressure sampling was performed using supersonic nozzle and an aerodynamic flow cell to minimize residence time and wall losses of radicals. The astigmatic mirror design provides pathlengths up to 200 m in volume of 3 liters with minimal optical interference fringes; longer pathlengths are possible. The detection limit depends on pathlength and minimum fractional absorptions.

Nelson, David↗
NASA NTRS2014

Geostationary Coastal and Air Pollution Events (GeoCAPE) Filter Radiometer (FR)

The GeoCAPE Filter Radiometer (FR) Study is a different instrument type than all of the previous IDL GeoCape studies. The customer primary goals are to keep mass, volume and cost to a minimum while meeting the science objectives and maximizing flight opportunities by fitting on the largest number of GEO accommodations possible. Minimize total mission costs by riding on a commercial GEO satellite. For this instrument type, the coverage rate, km 2 min, was significantly increased while reducing the nadir ground sample size to 250m. This was accomplished by analyzing a large 2d area for each integration period. The field of view will be imaged on a 4k x 4k detector array of 15 micrometer pixels. Each ground pixel is spread over 2 x 2 detector pixels so the instantaneous field of view (IFOV) is 2048 X 2048 ground pixels. The baseline is, for each field of view 50 sequential snapshot images are taken, each with a different filter, before indexing the scan mirror to the next IFOV. A delta would be to add additional filters.

Geo Cape↗
DOE OSTI2020

Design and Characterization of an Extremely-Sensitive, Large-Volume Gamma-Ray Spectrometer for Environmental Samples

A large volume gamma spectrometer was designed and constructed to analyze foodstuffs and environmental samples having low radionuclide concentrations. This system uses eight 11-cm × 42.5-cm × 5.5-cm NaI(Tl) detectors, chosen due to their relatively high sensitivity and availability and arranged in an octagonal configuration. The sensitive volume of the system is ~28 cm in diameter and ~42 cm deep. Shielding consists of an 86-cm × 86-cm square, 64-cm-tall lead brick enclosure with 18-cm-thick lead walls lined by 0.3-cm-thick copper plates. An aluminum top was machined to suspend the detectors within this shield. The shielding reduces background counts by 72% at 100 keV and 42% at 1,000 keV. The positional variability in sensitivity of the well was determined by both simulation and experiment. A 2.1-L volume of nearly uniform sensitivity, varying less than 10%, exists in the well's center. Energy resolutions of 14.6% and 7.8% were measured for 241 Am and 137 Cs, respectively. Energy resolution shows a 0.2% variation for both 241 Am and 137 Cs as a function of position within all regions of the well’s central sensitive volume. Dead time was also determined to be less than 35% for all sources measured in the system, the largest of which had an activity of 1,760 kBq. Simulated results for various source geometries show higher counts for smaller samples, especially at lower energies due to less attenuation of low energy photons. In conclusion, minimum detectable activities were determined for all source energies used, less than 5.1 Bq kg -1 for reasonable background and sample counting times.

47 OTHER INSTRUMENTATION↗
DOE OSTI2020

Survey of Technologies to Meet PAG limits for Detection of Cesium-137 in Water

The goal of this report is to evaluate the process of adding a sorbent to the sampling process to preconcentrate Cs-137 and then analyze the sorbent to provide a rapid assessment of results to guide decisions on drinking water sources and the protection of the public. Multiple unit design variables were considered: sample configuration/geometry, sorbent efficiency, sample volume. Model simulations demonstrated through these unit design efficiencies that 10 L of sample volume processed through a sorbent provides nearly two orders of magnitude improvement in sample counting time to provide results to a decision maker than the current process. Over 60 publications and reports concerning Cs-137 and sorbents were evaluated. The key attributes were readiness of sorbent to be deployed in a mobile laboratory environment, and minimum sample preparation and conditioning. Examples of sorbents not considered further included nanomaterials, which have not been evaluated at a commercial scale and are limited in availability. The recommended sorbents for further consideration include: ferrocyanide salts, zeolite, and chemically modified granular activated carbon.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
NASA NTRS1996

Signal Processing and Calibration of Continuous-Wave Focused CO2 Doppler Lidars for Atmospheric Backscatter Measurement

Two continuous-wave(CW)focused C02 Doppler lidars (9.1 and 10.6 micrometers) were developed for airborne in situ aerosol backscatter measurements. The complex path of reliably calibrating these systems, with different signal processors, for accurate derivation of atmospheric backscatter coefficients is documented. Lidar calibration for absolute backscatter measurement for both lidars is based on range response over the lidar sample volume, not solely at focus. Both lidars were calibrated with a new technique using well-characterized aerosols as radiometric standard targets and related to conventional hard-target calibration. A digital signal processor (DSP), a surface acoustic and spectrum analyzer and manually tuned spectrum analyzer signal analyzers were used. The DSP signals were analyzed with an innovative method of correcting for systematic noise fluctuation; the noise statistics exhibit the chi-square distribution predicted by theory. System parametric studies and detailed calibration improved the accuracy of conversion from the measured signal-to-noise ratio to absolute backscatter. The minimum backscatter sensitivity is approximately 3 x 10(exp -12)/m/sr at 9.1 micrometers and approximately 9 x 10(exp -12)/m/sr at 10.6 micrometers. Sample measurements are shown for a flight over the remote Pacific Ocean in 1990 as part of the NASA Global Backscatter Experiment (GLOBE) survey missions, the first time to our knowledge that 9.1-10.6 micrometer lidar intercomparisons were made. Measurements at 9.1 micrometers, a potential wavelength for space-based lidar remote-sensing applications, are to our knowledge the first based on the rare isotope C-12 O(2)-18 gas.

Rothermel, Jeffry↗