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Ultrafiltration by a compacted clay membrane. I - Oxygen and hydrogen isotopic fractionation. II - Sodium ion exclusion at various ionic strengths.

Laboratory experiments were carried out to determine the magnitude of the isotopic fractionation of distilled water and of 0.01N NaCl forced to flow at ambient temperature under a hydraulic pressure drop of 100 bars across a montmorillonite disk compacted to a porosity of 35% by a pressure of 330 bars. The ultrafiltrates in both experiments were depleted in D by 2.5% and in O-18 by 0.8% relative to the residual solution. No additional isotopic fractionation due to a salt-filtering mechanism was observed at NaCl concentrations up to 0.01N. Adsorption is most likely the principal mechanism which produces isotopic fractionation, but molecular diffusion may play a minor role. The results suggest that oxygen and hydrogen isotopic fractionation of ground water during passage through compacted clayey sediments should be a common occurrence, in accord with published interpretations of isotopic data from the Illinois and Alberta basins. It is shown how it is possible to proceed from the ion exchange capacity of clay minerals and, by means of the Donnan membrane equilibrium concept and the Teorell-Meyer-Siever theory, develop a theory to explain why and to what extent ultrafiltration occurs when solutions of known concentration are forced to flow through a clay membrane.

Coplen, T. B.↗

Mass spectrometric analysis of organic compounds, water and volatile constituents in the atmosphere and surface of Mars - The Viking Mars Lander.

An experiment centering around a mass spectrometer is described, which is aimed at the identification of organic substances present in the top 10 cm of the surface of Mars and an analysis of the atmosphere for major and minor constituents as well as isotopic abundances. In addition, an indication of the abundance of water in the surface and some information concerning the mineralogy can be obtained by monitoring the gases produced upon heating the soil sample. The organic material will simply be expelled by heating to 150, 300, and 500 C into the carrier gas stream of a gas chromatograph interfaced to the mass spectrometer or by slowly heating the sample in direct communication with the spectrometer. It is planned to analyze a total of up to nine soil samples in order to study diurnal and seasonal variations. The system is designed to give useful data even for minor constituents if the total of organics should be as low as 5 ppm. The spectrometer covers the mass range of 12-200 with adequate resolution.

Anderson, D. M.↗

Tracer versus trace element diffusion - Diffusional decoupling of Sr concentration from Sr isotope composition

Chemical diffusivities for nonalkali major, minor, and selected trace elements have been measured at 10 kbar, 1300 C during interdiffusion of dacitic and rhyolitic melts. Sr tracer diffusivities were measured at the same conditions in melts of dacitic and rhyolitic composition and in a diffusion couple of these two melts undergoing simultaneous chemical diffusion. Chemical diffusivities of all elements studied are functions of the silica content of the melt, but at any one silica content the chemical diffusivities of all elements studied are within a factor of five of the Si and Al diffusivities. Si diffusivity varies from 2.8 x 10 to the -9th sq cm/s at 65 percent SiO2 to 5.1 x 10 to the -10th sq cm/s at 75 percent SiO2. The diffusivities of minor and trace elements are proposed to be controlled by the ability of the local melt structure to accommodate these elements while maintaining LTE. The measured Sr tracer diffusivities are an order of magnitude above Sr chemical diffusivities.

Baker, Don R.↗

A long-term change of the AR/KR/XE fractionation in the solar corpuscular radiation

Solar noble gases in an ilmenite separate from breccia 79035 (antiquity greater than 1 Ga) were analyzed by closed system stepped etching (CSSE). All five gases show the familiar two-component structure: first solar-wind (SW) gases are released, followed by gases from solar energetic particles (SEP). Element patterns in 79035 are similar to those of 71501 ilmenite. SW-He-Ne were partly lost, but SEP-He-Ne-Ar are retained (nearly) unfractionated. Constant Ar/Kr/Xe ratios indicate that ilmenites contain an unfractionated sample of the heavy SW-SEP noble gases. Ar/Kr/Xe ratios in the solar corpuscular radiation are, however, different from 'solar system' values, whereby the Kr/Xe difference in 79035 is about twice as large as in 71501. We propose that Xe is less fractionated than Kr and Ar, though its first ionization potential (FIP) is higher than the 'cutoff' at approximately 11.5 eV, above which all elements in SEP are usually assumed to be depleted by a roughly constant factor. SW-Ne may be isotopically slightly heavier in the ancient SW trapped by 79035, as proposed earlier. In this work we extend our previous CSSE studies of solar noble gases including Kr and Xe to a lunar sample irradiated at least 1 Ga ago (breccia 79035, ilmenite separate, 42-64 microns). This sample was particularly gently etched in the first steps. Surprisingly, the first three steps, each releasing less than or equal to 0.5% of the total 36-Ar, showed an SEP-like trapped component plus relatively large concentrations of cosmogenic gases. Steps 4ff contain much less cosmogenic and more solar gas with a SW-like isotope pattern. Thus, a very minor easily etchable phase that has completely lost its SW-gases must be responsible for steps 1-3. We will not discuss these steps here and refer to the actual step 4 as the 'initial' etching step.

Wieler, R.↗

Experimental and Analytical Studies of Solar System Chemistry

The cosmochemistry research funded by this grant resulted in the publications given in the attached Publication List. The research focused in three areas: (1) Experimental studies of trace element partitioning. (2) Studies of the minor element chemistry and O isotopic compositions of MgAlO4 spinels from Ca-Al-Rich Inclusions in carbonaceous chondrite meteorites, and (3) The abundances and chemical fractionations of Th and U in chondritic meteorites.

Burnett, Donald S.↗

Murchison xenoliths

C3 xenoliths in a C2 host (Murchison) are unique among known meteoritic xenolith-host occurrences. They offer an opportunity to determine possible effects on the xenoliths by the hydrated host. Eleven xenoliths were found ranging from 2 to 13 mm. Four of these Murchison Xenoliths (MX1, MX2, MX3 and MX4) have been studied in detail. MX1 and MX2 were large enough for trace element, oxygen isotope, carbon isotope, bulk carbon and bulk nitrogen determinations. All four were studied petrographically and by analytical SEM. The xenoliths cannot be unequivocally identified as C3V or C3O subtypes. MX1 contains some matrix phyllosilicate, indicating reaction with water. MX1, MX2 and MX3 all show extensive alteration by an FeO-rich medium, and some minerals in them contain ferric iron. MX4, however, exhibits very minor alteration by FeO only. Oxygen isotopic and chemical data show that the alteration of these xenoliths did not take place in the Murchison host. The alterations occurred in one or more parent bodies, which were later disrupted to release these xenoliths that ultimately accreted onto the Murchison parent body.

Olsen, Edward J.↗

The Divnoe meteorite: Petrology, chemistry, oxygen isotopes and origin

The Divnoe meteorite is an olivine-rich primitive achondrite with subchondritic chemistry and mineralogy. It has a granoblastic, coarse-grained, olivine groundmass (CGL: coarse-grained lithology) with relatively large pyroxene-plagioclase poiklitic patches (PP) and small fine-grained domains of an opaque-rich lithology (ORL). Both PP and ORL are inhomogeneously distributed and display reaction boundaries with the groundmass. Major silicates, olivine Fa(20-28) and orthopyroxyene Fs(20-28 Wo(0.5-2.5), display systematic differences in composition between CGL and ORL as well as a complicated pattern of variations within CGL. Accessory plagioclase has low K content and displays regular igneous zoning with core compositions An(40-45) and rims An(32-37). The bulk chemical composition of Divnoe is similar to that of olivine-rich primitive achondrites, except for a depletion of incompatible elements and minor enrichment of refractory siderophiles. Oxygen isotope compositions for whole-rock and separated minerals from Divnoe fall in a narrow range, with mean delta O-18 = +4.91, delta O-17 = +2.24, and Delta O-17 = -0.26 +/- 0.11. The isotopic composition is not within the range of any previously recognized group but is very close to that of the brachinites. To understand the origin of Divnoe lithologies, partial melting and crystallization were modelled using starting compositions equal to that of Divnoe and some chondritic meteorites. It was found that the Divnoe composition could be derived from a chondritic source region by approximately 20 wt% partial melting at Ta approximately 1300 C and log(fO2) = IW-1.8, followed by approximtely 60 wt% crystallization of the partial melt formed, and removal of the still-liquid portion of the partial melt. Removal of the last partial melt resulted in depletion of the Divnoe plagioclase in Na and K. In this scenario, CGL represents the residue of partial melting, and PP is a portion of the partial melt that crystallized in situ. The ORL was formed during the final stages of partial melting by reaction between gaseous sulfur and residual olivine in the source region. A prominent feature of Divnoe is fine micron-scale chemical variations within olivine grains, related to lamellar structures the olivines display. The origin of these structures is not known.

Petaev, M. I.↗

Sm-Nd and Initial Sr-87/Sr-86 Isotopic Systematics of Asuka 881394 and Cumulate Eucrites Yamato 980318/433 Compared

The Asuka 881394 achondrite contains fossil Al-26 and Mn-53 and has a Pb-206/Pb-207 age of 4566.5 +/- 0.2 Ma, the oldest for an achondrite. Recent re-investigation of A881394 yielded revised initial Sm-146/Sm-144 = (9.1 +/- 1.4) x 10(exp -3), a Sm-147-Nd-143 age of 4525 +/- 58 Ma, a Rb-87-Sr-87 age of 4490 +/- 130 Ma, and initial Sr-87/Sr-86 = 0.698991 +/- 19, respectively. The relatively large uncertainties in the Sm-Nd and Rb-Sr ages are due to disturbances of the isotopic systematics of tridymite and other minor phases. A preliminary value for the Sm-147-Nd-143 age of the Yamato 980318 cumulate eucrite of 4560 +/- 150 Ma was refined in later work to 4567 +/- 24 Ma as reported orally at LPSC 35. Similarly, a preliminary value for Sm-146/Sm-144 = (7.7 +/- 1.2) x 10 (exp -3) was refined to (6.0 +/- 0.3) x 10(exp -3). For Yamato 980433, a Sm-147-Nd-143 age of 4542 +/-42 Ma and Sm-146/Sm-144 = (5.7 +/- 0.5) x 10(exp -3) has been reported. Because these two cumulate eucrites are paired, we consider them to represent one igneous rock and present their combined isotopic data here.

Nyquist, L. E.↗

Pioneer Venus large probe neutral mass spectrometer

The Pioneer Venus large probe neutral mass spectrometer (LNMS) uses a single focusing magnetic sector field mass analyzer with mass range of 1-208 amu, resolution sufficient to separate the mercury isotopes, and sensitivity sufficient to detect minor constituents in the 1 ppm range relative to the CO2 in the Venus atmosphere. A combination of ion and chemical pumping is used to maintain a vacuum in the mass analyzer and to remove the atmosphere gases which enter the ion source chamber through a special leak. A microprocessor controls the operation of the instrument through a highly efficient peak stepping and data compression program, permitting acquisition of a complete mass spectrum roughly once each minute.

Hoffman, J. H.↗

The composition of Saturn's atmosphere at northern temperate latitudes from Voyager IRIS spectra - NH3, PH3, C2H2, C2H6, CH3D, CH4, and the Saturnian D/H isotopic ratio

The vertical distributions and mixing ratios of minor constituents in the northern hemisphere of Saturn are investigated. Results are obtained for NH3, PH3, C2H2, C2H6, CH3D, and CH4; the D/H ratio is obtained from the CH4 and CH3D abundances. The NH3 mixing ratio in the upper atmosphere is found to be compatible with the saturated partial pressure. The inferred PH3/H2 ratio of 1.4 + or - 0.8 x 10 to the -6th is higher than the value derived from the solar P/H ratio. The stratospheric C2H2/H2 and C2H6/H2 ratios are, respectively, 2.1 + or - 1.4 x 10 to the -7th and 3.0 + or - 1.1 x 10 to the -6th; the latter decreases sharply below the 20-50 mbar level. The results for CH3D/H2 and CH4/H2 imply an enrichment of Saturn's upper atmosphere in carbon by a factor of at least three over the solar abundance. The interpretation of two NH3 lines in the five-micron window suggests a NH3/H2 ratio at the two bar level below the solar value.

Courtin, R.↗

Isotopic signatures and distribution of nitrogen and trapped and radiogenic xenon in the Acapulco and FRO90011 meteorites

Acapulco metal and silicate show distinct N isotopic signatures. Trapped heavy noble gases are carried by 'magnetic' opx and radiogenic Xe-129 excesses are observed in phosphate and in minor surficial phases on metal grains. N and Xe isotopic signatures in FRO90011 do not agree with those observed in Acapulco. The Acapulco meteorite is unique in having achondritic texture and chondritic composition. Its mineralogical study shows the record of high temperature (1100 C) recrystallization. However, this meteorite shows abundances of volatile elements close to the levels observed in carbonaceous chondrites and concentrations of heavy noble gases comparable to those observed in type 4 ordinary chondrites, not expected for a presumed highly equilibrated object. Nitrogen measurements in bulk Acapulco revealed two different isotopic signatures, in apparent conflict with evidence for a high degree of recrystallization. N and Xe were studied in separated mineral phases to search for the carriers in order to better understand the formation and thermal history of the Acapulco parent body.

Kim, Y.↗

IIAB IRON METEORITES: FORMATION AND RELATION TO OTHER METEORITE GROUPS.

The IIAB iron meteorites are one of the largest iron meteorite groups that formed by fractional crystallization [1]. Iron meteorites formed over a range of oxygen fugacities (fO2)[2], most formed relatively reduced at~ IW–4to –2.5 (IABs), where IW= iron-wüstite buffer, to relatively oxidized at IW–1(IVBs) [2,3]. While the IIABs contain reduced mineral phases (daubré elite [1]),the fO2for IIABs is poorly constrained. The fO2of iron meteorites may have become more reducing during cooling, with oxidized phases (i.e., chromite) forming at higher temperatures and daubré elite forming at lower temperatures [4]. The O-and Cr-isotope compositions of silicates and chromite in meteorites, including iron meteorites, can determine potential genetic links to other meteorite sand con-strain if a meteorite is from the non-carbonaceous (NC) or carbonaceous (CC) group [e.g., 5–8]. Iron meteorite groups have been identified as being in the NCor CC group using Mo[9]and Ni [10] isotope compositions of their metallic component. Numerous iron meteorites contain minor amounts of silicates and oxides [e.g., 11], but most have not been analyzed for their Cr or Ti isotope compositions, with some exceptions (e.g., IIIABs [6,7],a IIG, and a IIAB[7]). We analyzed the compositions of silicates and chromite in six IIAB iron meteorites to investigate the relationship between IIABs and known meteorite groups, the fO2of IIABs, and the origin of chromite in the IIABs. *full abstract in document

Meteorite↗

Water-Rock Interactions in Outer Solar System Bodies: Evidence from the Coordinated Analysis of Interplanetary Dust

NASA has an ongoing program of collecting interplanetary dust particles (IDPs) in the stratosphere using high altitude research aircraft. The collected IDPs are derived from asteroids and comets and here we report studies of a subset of hydrated IDPs rich in carbonaceous matter that are proposed to have a cometary origin. Our studies are aimed at understanding the evolution of oxygen reservoirs in the Solar System and their interaction with cometary minerals and organic matter. The small size (<20 μm) and fragility of these IDPs present a number of analytical challenges. We have pioneered techniques for performing chemical, mineralogical, isotopic, and spectroscopic measurements on the same sample in a carefully coordinated sequence. Coordinated analyses of nanogram-size samples is made possible by several delicate sample preparation techniques. To avoid organic contamination, we embed IDPs in elemental sulfur and use ultramicrotomy to partly section the particles (the first few micrometers). Multiple thin sections (50-70 nm thick) are placed on different substrates depending on the analysis technique. We use a JEOL 2500SE scanning, transmission electron microscope (STEM) to determine the mineralogy, microstructure, and elemental compositions of constituent minerals in the thin sections through a combination of high resolution imaging, electron diffraction, quantitative energy-dispersive x-ray mapping, and electron energy-loss spectroscopy. Following the STEM analyses, we use a NanoSIMS 50L for high spatial resolution isotopic measurements of H, C, N, and O to search for presolar grains and to understand the origin of the indigenous organic matter. The isotopic analyses are performed on the same sections analyzed in the STEM in order to correlate isotopic properties with the elemental and mineralogical data. We reserve other thin sections for non-destructive analyses utilizing synchrotron-based techniques including Fourier-transform infrared (FTIR) micro-spectroscopy and X-ray absorption near-edge structure (XANES) analyses, especially for functional group analysis of organic matter in the particles. The remainder of the IDP is extracted from the sulfur bead that was used for microtomy and is pressed into Au foil for quantitative analysis (including light elements) using a JEOL 8530F field emission electron probe microanalyzer (EPMA). After the EPMA measurements, high precision oxygen isotopic analyses are obtained using Cameca IMS1270/1290 instruments at UCLA. The hydrated IDPs in this study are dominated by saponitic clays, with minor magnetite, carbonate and abundant organic matter. The remarkable oxygen isotopic compositions, high carbon contents, and the abundance of isotopically anomalous organic matter, together suggest that the high carbon, hydrated IDPs are derived from primitive sources not yet represented in meteorite collections such as outer main belt P- and D-type asteroids or comets.

Keller, Lindsay P.↗

Ca-,Al-rich inclusions in the unique chondrite ALH85085 - Petrology, chemistry, and isotopic compositions

A comprehensive study is performed for the Ca-,Al-rich inclusions (CAIs) in the unique chondrite ALH85085. The ALH85085 inclusions are smaller (5-80 microns) and more refractory than their counterparts in carbonaceous chondrites. The study includes 42 inclusions for petrography and mineralogy, 15 for bulk major and minor element chemical composition, six for Mg-Al isotopic systematics, 10 for Ca isotopes, nine for Ti isotopes, and six for trace element abundances. In addition, oxygen-isotopic compositions were determined in minerals from a single inclusion. No correlation is found between mineralogy, major element chemistry, and trace element abundances. It is further shown that the high-temperature geochemical behavior of ultrarefractory trace elements is decoupled from that of the major elements Ca and Ti (Ti is correlated with the relatively volatile elements Nb and Yb) implying that perovskite is of only minor importance as carrier of ultrarefractories.

Kimura, Makoto↗

Crystalline sulfur dioxide: Crystal field splittings, absolute band intensities and complex refractive indices derived from infrared spectra

The infrared absorption spectra of thin crystalline films of sulfur dioxide at 90 K are reported in the 2700 to 450/cm region. The observed multiplicity of the spectral features in the regions of fundamentals is attributed to factor group splittings of the modes in a biaxial crystal lattice and the naturally present minor S-34, S-36, and O-18 isotopic species. Complex refractive indices determined by an iterative Kramers-Kronig analysis of the extinction data, and absolute band strengths derived from them, are also reported in this region.

Khanna, R. K.↗

ALMA Spectral Line and Imaging Survey of a Low and a High Mass-Loss Rate AGB Star Between 335 and 362 GHz

Context. Low and intermediate mass stars are known to power strong stellar winds when evolving through the asymptotic giant branch (AGB) phase. Initial mass, luminosity, temperature, and composition determine the pulsation characteristics of the star and the dust species formed in the pulsating photospheric layers. Radiation pressure on these grains triggers the onset of a stellar wind. However, as of today, we still cannot predict the wind mass-loss rates and wind velocities from first principles neither do we know which species are the first to condense in the upper atmospheric regions. Aims. We aim to characterise the dominant physical, dynamical, and chemical processes in the inner wind region of two archetypical oxygen-rich (C/O<1) AGB stars, that is, the low mass-loss rate AGB star R Dor (M~ 1x10(exp 7) M☉/yr) and the high mass-loss rate AGB star IK Tau (M~5x10(exp 6) M☉/yr). The purpose of this study is to observe the key molecular species contributing to the formation of dust grains and to cross-link the observed line brightnesses of several species to the global and local properties of the star and its wind. Methods. A spectral line and imaging survey of IK Tau and R Dor was made with ALMA between 335 and 362 GHz (band 7) at a spatial resolution of ~150 mas, which corresponds to the locus of the main dust formation region of both targets. Results. Some two hundred spectral features from 15 molecules (and their isotopologues) were observed, including rotational lines in both the ground and vibrationally excited states (up to v=5 for SiO). Detected species include the gaseous precursors of dust grains such as SiO, AlO, AlOH, TiO, and TiO2.We present a spectral atlas for both stars and the parameters of all detected spectral features. A clear dichotomy for the sulphur chemistry is seen: while CS, SiS, SO, and SO2 are abundantly present in IK Tau, only SO and SO2 are detected in R Dor. Also other species such as NaCl, NS, AlO, and AlOH display a completely different behaviour. From some selected species, the minor isotopologues can be used to assess the isotopic ratios. The channel maps of many species prove that both large and small-scale inhomogeneities persist in the inner wind of both stars in the form of blobs, arcs, and/or a disk. The high sensitivity of ALMA allows us to spot the impact of these correlated density structures in the spectral line profiles. The spectral lines often display a half width at zero intensity much larger than expected from the terminal velocity, v1, previously derived for both objects (36 km/s versus v(∞)~17.7 km/s for IK Tau and 23 km/s versus v(∞)~5.5 km/s for R Dor). Both a more complex 3D morphology and a more forceful wind acceleration of the (underlying) isotropic wind can explain this trend. The formation of fractal grains in the region beyond _400 mas can potentially account for the latter scenario. From the continuum map, we deduce a dust mass of ~3.7 x 10(exp 7) M☉ and ~2 x 10(ex0 8) M☉ for IK Tau and R Dor, respectively. Conclusions. The observations presented here provide important constraints on the properties of these two oxygen-dominated AGB stellar winds. In particular, the ALMA data prove that both the dynamical and chemical properties are vastly different for this high mass-loss rate (IK Tau) and low mass-loss rate (R Dor) star.

Stars: AGB and post-AGB, Stars: mass loss, Stars: ↗

ALMA Spectral Line and Imaging Survey of a Low and a High Mass-Loss Rate AGB Star Between 335 and 362 GHz

Context. Low and intermediate mass stars are known to power strong stellar winds when evolving through the asymptotic giant branch (AGB) phase. Initial mass, luminosity, temperature, and composition determine the pulsation characteristics of the star and the dust species formed in the pulsating photospheric layers. Radiation pressure on these grains triggers the onset of a stellar wind. However, as of today, we still cannot predict the wind mass-loss rates and wind velocities from first principles neither do we know which species are the first to condense in the upper atmospheric regions. Aims. We aim to characterise the dominant physical, dynamical, and chemical processes in the inner wind region of two archetypical oxygen-rich (C/O < 1) AGB stars, that is, the low mass-loss rate AGB star R Dor (M’ ∼ 1 × 10(exp −7) M/yr) and the high mass-loss rate AGB star IK Tau (M’ ∼ 5 × 10(exp −6) M/yr). The purpose of this study is to observe the key molecular species contributing to the formation of dust grains and to cross-link the observed line brightnesses of several species to the global and local properties of the star and its wind. Methods. A spectral line and imaging survey of IK Tau and R Dor was made with ALMA between 335 and 362 GHz (band 7) at a spatial resolution of ∼150 mas, which corresponds to the locus of the main dust formation region of both targets. Results. Some two hundred spectral features from 15 molecules (and their isotopologues) were observed, including rotational lines in both the ground and vibrationally excited states (up to v = 5 for SiO). Detected species include the gaseous precursors of dust grains such as SiO, AlO, AlOH, TiO, and TiO2. We present a spectral atlas for both stars and the parameters of all detected spectral features. A clear dichotomy for the sulphur chemistry is seen: while CS, SiS, SO, and SO2 are abundantly present in IK Tau, only SO and SO2 are detected in R Dor. Also other species such as NaCl, NS, AlO, and AlOH display a completely different behaviour. From some selected species, the minor isotopologues can be used to assess the isotopic ratios. The channel maps of many species prove that both large and small-scale inhomogeneities persist in the inner wind of both stars in the form of blobs, arcs, and/or a disk. The high sensitivity of ALMA allows us to spot the impact of these correlated density structures in the spectral line profiles. The spectral lines often display a half width at zero intensity much larger than expected from the terminal velocity, v∞, previously derived for both objects (36 km/s versus v(∞) ∼ 17.7 km/s for IK Tau and 23 km/s versus v(∞) ∼ 5.5 km/s for R Dor). Both a more complex 3D morphology and a more forceful wind acceleration of the (underlying) isotropic wind can explain this trend. The formation of fractal grains in the region beyond ∼400 mas can potentially account for the latter scenario. From the continuum map, we deduce a dust mass of ∼3.7 × 10(exp −7) Mand ∼2 × 10(exp −8) M for IK Tau and R Dor, respectively. Conclusions. The observations presented here provide important constraints on the properties of these two oxygen-dominated AGB stellar winds. In particular, the ALMA data prove that both the dynamical and chemical properties are vastly different for this high mass-loss rate (IK Tau) and low mass-loss rate (R Dor) star.

L. Decin↗

Isotopic equilibration between dissolved and suspended particulate lead in the Atlantic Ocean - Evidence from Pb-210 and stable Pb isotopes

Vertical profiles of, on one hand, the stable Pb isotopic composition, and on the other, the ratio of total Pb to Pb-210 in suspended particles, are noted to closely track contemporaneous depth variations in these ratios for dissolved Pb throughout the upper 2 km of the Sargasso Sea near Bermuda. A simple flux model suggests that the effect of deep ocean scavenging processes on the flux and isotopic composition of Pb sinking on large particles was minor throughout the preanthropogenic, and most of the anthropogenic era: but it has become more important as surface inputs decrease to preleaded gasoline levels, perhaps exceeding the contribution of surface-derived Pb flux in the next decade.

Sherrell, Robert M.↗