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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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NASA NTRS1995

Airborne spectrograph for the thermal IR: Broadband Array Spectrograph System

Spectroscopic studies in the 'fingerprint' region of the thermal IR from 3 to 14 microns of celestial dust components and the overall energy distribution of the sources are best served by moderate spectral resolution (R = lambda/Delta lambda approximately 30 to 200), high sensitivity observations. Spectral purity and the reproducibility of the spectral shape are critical as well, when using the spectral shape to assign temperatures to dust grains or to gas clouds based on the wavelength and shape of molecular bands. These sensor attributes are also important to the use of wavelengths and ratios of solid state features to derive compositions of dust grains in celestial sources. The advent of high quality linear arrays of blocked impurity band (BIB) detectors of Si:As permitted the development of a state-of-the-art, patented, cooled prism spectrograph. Developed at The Aerospace Corporation largely with in-house funds, the Broadband Array Spectrograph System (BASS) has been used for a variety of remote sensing applications, but especially for IR astronomical studies on the Kuiper Airborne Observatory and at the NASA Infrared Telescope Facility (IRTF). The attributes of the spectrograph, specifically having the pupil imaged onto the 2 linear 58 element detector arrays so that the effects of guiding errors are minimized, being able to maximally exploit the limited observing time by acquiring all 116 spectral channels simultaneously, and having all spectral channels imaged through the same aperture so that spectral mapping is readily and reliably accomplished, afford the scientist with a unique opportunity to conduct both surveys of examples of many different types of sources as well as in-depth studies of a given class of object by thoroughly sampling the class members. This duality was demonstrated with the BASS through a combination of KAO flights where spectral maps were obtained as part of in-depth studies of specific source regions (such as Orion and W3) and flights where up to 21 legs/flight were used to survey many different sources of different types.

Russell, Ray W.↗

NASA NTRS1984

Interstellar Grain Mantles

Techniques for determining the composition of small dust grains in interstellar matter are discussed. The best way to study the composition of interstellar grain mantles is by infrared spectroscopy. The absorption features in a complete infrared spectrum from 2 to 15 microns can be used as fingerprints to identify the absorbing molecule. Ground-based observations around 3 microns confirmed the presence of H2O ice in interstellar grain mantles, through the detection of the 3.08 micron OH stretching vibration. The detection of other molecules, in particular the carbon bearing molecules, is however hampered by atmospheric absorption in the 5-8 micron region and the presence of the strong ice and silicate bands, which dominate the 3 and 10 micron region respectively. Kuiper Airborne Observatory observations of the 5-8 micron region of the spectrum are therefore extremely important to determine the composition of interstellar grain mantles. The 5 to 8 micron spectra of molecular cloud sources was obtained using a 24 detector grating spectrometer. An important characteristic of this spectrometer is that the whole spectrum is obtained simultaneously. It is therefore relatively easy to correct for atmospheric transmission.

Witteborn, F.↗

NASA NTRS2008

Remote Raman Spectroscopy of Minerals at Elevated Temperature Relevant to Venus Exploration

We have used a remote time-resolved telescopic Raman system equipped with 532 nm pulsed laser excitation and a gated intensified CCD (ICCD) detector for measuring Raman spectra of a number of minerals at high temperature to 970 K. Remote Raman measurements were made with samples at 9-meter in side a high-temperature furnace by gating the ICCD detector with 2 micro-sec gate to minimize interference from blackbody emission from mineral surfaces at high temperature as well as interference from ambient light. A comparison of Raman spectra of gypsum (CaSO4.2H2O), dolomite (CaMg(CO3)2), and olivine (Mg2Fe2-xSiO4), as a function of temperature shows that the Raman lines remains sharp and well defined even in the high-temperature spectra. In the case of gypsum, Raman spectral fingerprints of CaSO4.H2O at 518 K were observed due to dehydration of gypsum. In the case of dolomite, partial mineral dissociation was observed at 973 K at ambient pressure indicating that some of the dolomite might survive on Venus surface that is at approximately 750 K and 92 atmospheric pressure. Time-resolved Raman spectra of low clino-enstatite (MgSiO3) measured at 75 mm from the sample in side the high-temperature furnace also show that the Raman lines remains sharp and well defined in the high temperature spectra. These high-temperature remote Raman spectra of minerals show that time-resolved Raman spectroscopy can be used as a potential tool for exploring Venus surface mineralogy at shorter (75 mm) and long (9 m) distances from the samples both during daytime and nighttime. The remote Raman system could also be used for measuring profiles of molecular species in the dense Venus atmosphere during descent as well as on the surface.

Sharma, Shiv K.↗

NASA NTRS2002

Parallel characterization of anaerobic toluene- and ethylbenzene-degrading microbial consortia by PCR-denaturing gradient gel electrophoresis, RNA-DNA membrane hybridization, and DNA microarray technology

A mesophilic toluene-degrading consortium (TDC) and an ethylbenzene-degrading consortium (EDC) were established under sulfate-reducing conditions. These consortia were first characterized by denaturing gradient gel electrophoresis (DGGE) fingerprinting of PCR-amplified 16S rRNA gene fragments, followed by sequencing. The sequences of the major bands (T-1 and E-2) belonging to TDC and EDC, respectively, were affiliated with the family Desulfobacteriaceae. Another major band from EDC (E-1) was related to an uncultured non-sulfate-reducing soil bacterium. Oligonucleotide probes specific for the 16S rRNAs of target organisms corresponding to T-1, E-1, and E-2 were designed, and hybridization conditions were optimized for two analytical formats, membrane and DNA microarray hybridization. Both formats were used to characterize the TDC and EDC, and the results of both were consistent with DGGE analysis. In order to assess the utility of the microarray format for analysis of environmental samples, oil-contaminated sediments from the coast of Kuwait were analyzed. The DNA microarray successfully detected bacterial nucleic acids from these samples, but probes targeting specific groups of sulfate-reducing bacteria did not give positive signals. The results of this study demonstrate the limitations and the potential utility of DNA microarrays for microbial community analysis.

Non-NASA Center↗