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All sourcesNASA NTRSDOE OSTI
DOE OSTI2021

Density of Fe-Ni-C Liquids at High Pressures and Implications for Liquid Cores of Earth and the Moon

The presence of light elements in the metallic cores of the Earth, the Moon, and other rocky planetary bodies has been widely proposed. Carbon is among the top candidates in light of its high cosmic abundance, siderophile nature, and ubiquity in iron meteorites. It is, however, still controversial whether carbon-rich core compositional models can account for the seismic velocity observations within the Earth and lunar cores. In this paper we report the density and elasticity of Fe 90 Ni 10 -3 wt.% C and Fe 90 Ni 10 -5 wt.% C liquid alloys using synchrotron-based X-ray absorption experiments and first-principles molecular dynamics simulations. Our results show that alloying of 3 wt.% and 5 wt.% C lowers the density of Fe 90 Ni 10 liquid by ~2.9-3.1% at 2 GPa, and ~3.4-3.6% at 9 GPa. More intriguingly, our experiments and simulations both demonstrate that the bulk moduli of the Fe-Ni-C liquids are similar to or slightly higher than those of Fe-Ni liquids. Thus, the calculated compressional velocity ($v_p$) of Fe-Ni-C liquids are higher than that of pure Fe-Ni alloy, promoting carbon as a possible candidate to explain the elevated v p in the Earth's outer core. However, the values and slopes of both density and v p of the studied two Fe-Ni-C liquids do not match the outer core seismic models, suggesting that carbon may not be the sole principal light element in Earth's outer core. The high $v_p$ of Fe-Ni-C liquids does not match the presumptive $v_p$ of the lunar outer core well, indicating that carbon is less likely to be its dominant light element.

58 GEOSCIENCES↗
NASA NTRS2009

The Moon is a Planet Too: Lunar Science and Robotic Exploration

This slide presentation reviews some of what is known about the moon, and draws parallels between the moon and any other terrestrial planet. The Moon is a cornerstone for all rocky planets The Moon is a terrestrial body, formed and evolved similarly to Earth, Mars, Mercury, Venus, and large asteroids The Moon is a differentiated body, with a layered internal structure (crust, mantle, and core) The Moon is a cratered body, preserving a record of bombardment history in the inner solar system The Moon is an active body, experiencing moonquakes, releasing primordial heat, conducting electricity, sustaining bombardment, and trapping volatile molecules Lunar robotic missions provide early science return to obtain important science and engineering objectives, rebuild a lunar science community, and keep our eyes on the Moon. These lunar missions, both past and future are reviewed.

Cohen, Barbara A.↗
NASA NTRS1993

Composition and Maturity of Apollo 16 Regolith Core 60013/14

Samples from every half-centimeter dissection interval of double drive tube 60013/14 (sections 60013 and 60014) were analyzed by magnetic techniques for Fe concentration and surface maturity parameter I(sub s)/ Fe(O), and by neutron activation for concentrations of 25 lithophile and siderophile elements. Core 60013/14 is one of three regolith cores taken in a triangular array 40-50 m apart on the Cayley plains during Apollo 16 mission to the Moon. The core can be divided into three zones based both on I(sub s)/FeO and composition. Unit A (0-44 cm depth) is compositionally similar to other soils from the surface of the central region of the site and is mature throughout, although maturity decreases with depth. Unit B (44-59 cm) is submature and compositionally more feldspathic than Unit A. Regions of lowest maturity in Unit B are characterized by lower Sm/Sc ratios than any soil obtained from the Cayley plains as a result of some unidentified lithologic component with low surface maturity. The component is probably some type of mafic anorthosite that does not occur in such high abundance in any of the other returned soils. Unit C (59-62 cm) is more mature than Unit B and compositionally equivalent to an 87: 13 mixture of soil such as that from Unit A and plagioclase such as found in ferroan anorthosite. Similar soils, but containing greater abundances of anorthosite (plagioclase), are found at depth in the other two cores of the array. These units of immature to submature soil enriched to varying degrees (compared to the mature surface soil) in ferroan anorthosite consisting of approx. 99% plagioclase are the only compositionally distinct subsurface similarities among the three cores. Each of the cores contains other units that are compositionally dissimilar to any soil unit in the other two cores. These compositionally distinct units probably derive from local subsurface blocks deposited by the event(s) that formed the Cayley plains. The ferroan anorthosite with approx. 99% plagioclase, however, must represent some subsurface lithology that is significant on the scale of tens of meters. The compositional uniformity of the surface soil (0-10 cm depth) over distances of kilometers reflects the large-scale uniformity of the plains deposits; the fine- structure reflects small-scale nonuniformity and the inefficiency of the impact-mixing process at depths as shallow as even one meter.

Korotev, Randy T.↗
NASA NTRS2018

Assessment of Volatile Depletion Mechanisms for the Moon - Pre-Cursors, Giant Impact, Core Formation, Post-Impact Loss

The volatile element depletions in the Moon have been recognized for decades. Multiple explanations have been debated, and arguments have become more quantitative, in large part due to new elemental partitioning and isotopic data. Depletions in pre-cursor materials and due to post-accretion degassing have been evaluated using isotopic data. Partitioning of many volatile elements into metallic cores can now be evaluated for many volatile siderophile elements (VSE). Here is presented an evaluation of the role of core formation for 12 volatile siderophile elements for which partitioning data is now available. Examination of all 12 elements at once allows recognition of general trends, without undue focus on one element. Ga, Ge, Zn, Sn, As, Sb, Cd, Ag, Bi, P, In, Cu are all moderately to highly volatile, and will be discussed in their order of volatility as gauged by their 50 percent condensation temperature.

Righter, K.↗
NASA NTRS2012

GRAIL Refinements to Lunar Seismic Structure

A method to enhance and detect subtle seismic arrivals typically used in terrestrial seismology, is to stack seismograms that have been time shifted to the predicted arrival time of a hypothetical phase of interest. We previously applied this array processing approach to the Apollo lunar seismic data, providing the first direct constraint on the size and state of the Moon's core. The method used travel time predictions made from pre-existing estimates of the crust and mantle velocities and densities and assumed that each of the Moons layers ia a uniform shell with no lateral variation or heterogeneity. In reality the structural properties of the Moon are likely inhomogeneous and vary both laterally and with depth.

Weber, Renee C.↗
NASA NTRS1977

Chemical stratigraphy of the Apollo 17 deep drill cores 70009-70007

A description is presented of an analysis of a total of 26 samples from three core segments (70009, 70008, 70007) of the Apollo 17 deep drill string. The deep drill string was taken about 700 m east of the Camelot Crater in the Taurus-Littrow region of the moon. Three core segments have been chemically characterized from the mainly coarse-grained upper portion of the deep drill string. The chemical data suggest that the entire 70007-70009 portion of the deep drill string examined was not deposited as a single unit, but was formed by several events sampling slightly different source materials which may have occurred over a relatively short period of time. According to the data from drill stem 70007, there were at least two phases of deposition. Core segment 70009 is probably derived from somewhat different source material than 70008. It seems to be a very well mixed material.

Ehmann, W. D.↗
NASA NTRS2008

Lunar Science from Laser Ranging - Present and Future

The interior properties of the Moon influence lunar tides and rotation. Three-axis rotation (physical librations) and tides are sensed by tracking lunar landers. The Lunar Laser Ranging (LLR) experiment has acquired 38 yr of increasingly accurate ranges from observatories on the Earth to four corner cube retroreflector arrays on the Moon. Lunar Laser Ranging is reviewed in [1]. Recent lunar science results are in [4,5]. In this abstract present LLR capabilities are described followed by future possibilities.

Lunar Laser Ranging (LLR)↗
NASA NTRS2002

Constraining the Material that Formed the Moon: The Origin of Lunar V, CR, and MN Depletions

The mantles of the Earth and Moon are similarly depleted in V, Cr, and Mn relative to chondritic values. Core formation deep within the Earth was suggested by as the origin of the depletions. Following Earth's core formation, the Moon was proposed to have inherited its mantle from the depleted mantle of the Earth by a giant impact event. This theory implied the Moon was primarily composed of material from the Earth's mantle. Recent systematic metal-silicate experiments of V, Cr, and Mn evaluated the behavior of these elements during different core formation scenarios. The study found that the V, Cr, and Mn depletions in the Earth could indeed be explained by core formation. The conditions of core formation necessary to deplete V, Cr, and Mn in the Earth's mantle were consistent with the deep magma ocean proposed to account for the Earth's mantle abundances of Ni and Co. Using the parameterizations of for the metal-silicate partition coefficients (D) of V, Cr, and Mn, we investigate here the conditions needed to match the depletions in the silicate Moon and determine if such conditions could have been present on the giant impactor.

Chabot, N. L.↗
NASA NTRS1977

The chemical composition of the cores of the terrestrial planets and the moon

Using models of the quasi-chemical theory of solutions, the activity coefficients of silicon are calculated in the melts Fe-Si, Ni-Si, and Fe-Ni-Si. The calculated free energies of solution of liquid nickel and silicon in liquid iron in the interval 0 to 1400 kbar and 1500 to 4000 K, shows that Fe-Ni-Si alloy is stable under the conditions of the outer core of the earth and the cores of the terrestrial planets. The oxidation-reduction conditions are studied, and the fugacity of oxygen in the mantles of the planets and at the core-mantle boundary are calculated. The mechanism of reduction of silicon is analyzed over a broad interval of p and T. The interaction between the matter of the core and mantle is studied, resulting in the extraction of silicon from the mantle and its solution in the material of the core. It is concluded that silicon can enter into the composition of the outer core of the earth and Venus, but probably does not enter into the composition of the cores of Mercury, Mars, and the moon, if in fact the latter possesses one.

Kuskov, O. L.↗
NASA NTRS1979

Formation, history and energetics of cores in the terrestrial planets

The size, evolution and energetics of the earth's core and the probable central, metalic cores of Mercury, Venus, the moon and Mars are discussed. The cores of Mercury, Mars and the earth are considered likely to decrease in relative mass and volume with distance from the sun; the moon does not fit this sequence and data from Venus are insufficient. Core formation is concluded to have occurred early (prior to four billion years ago) on the earth and Mercury, while that on the moon would have occurred over a longer interval and the core of Mars would have formed much later. Of the possible energy sources in planetary cores able to maintain a molten state and drive magnetic dynamos, the energy of core formation was probably spent too early in planetary history to provide much present power, and the energy gained from freezing an inner core in the earth and Mercury are considered at best marginally able to match conductive heat loss. Future measurements proposed to improve the quantitative understanding of core properties include a better documentation of the magnetic fields of Venus and Mars and the seismometry of Mars.

Solomon, S. C.↗
NASA NTRS1991

Geochemical stratigraphy of two regolith cores from the Central Highlands of the moon

High-resolution concentration profiles are presented for 20-22 chemical elements in the under 1-mm grain-size fractions of 60001-7 and 60009/10. Emphasis is placed on the stratigraphic features of the cores, and the fresh results are compared with those of previous petrographic and geochemical studies. For elements associated with major mineral phases, the variations in concentration in both cores exceed that observed in some 40 samples of surface and trench soils. Most of the variation in lithophile element concentrations at depths of 18 to 21 cm results from the mixing of two components - oil that is relatively mafic and rich in incompatible trace elements (ITEs), and coarse-grained anorthosite. The linearity of mixing lines on two-element concentration plots argues that the relative abundances of these various subcomponents are sufficiently uniform from sample to sample and from region to region in the core that the mixture behaves effectively as a single component. Soils at depths of 52-55 cm exhibit very low concentrations of ITEs.

Korotev, R. L.↗
NASA NTRS1978

Moon-magnetosphere interaction and estimates of possible lunar core size

It is shown that estimates of the size of a possible lunar core are negligibly affected by currents due to a directed plasma flux toward the moon. A theory for the compression of an induced lunar dipole by an incoming sub-Alfvenic flux of cold plasma is presented for the time-independent case where the external magnetic field, induced dipole moment, and plasma velocity vector are all aligned, and it is demonstrated that, at very long time periods, effects due to the inertia of an incoming flow of cold plasma can be ignored. A theory for time-dependent fluctuations in a stationary plasma is modified to include the effects of incoming flux.

Goldstein, B. E.↗
NASA NTRS1972

Physical structure of the moon.

The moon has a much thicker lithosphere than the earth, as predicted by thermal models and as evidenced by the support of mascons, lack of surface folding, etc. More in question is whether the moon has a core (more properly, asthenosphere) of high temperature, as suggested by the volcanism 1.0-1.3 b.y. after origin and by the large low-degree harmonics in the gravity field. The moon is like the earth in having a large offset of center-of-mass from center-of-volume, apparently the residue of an early convective overturn associated with large-scale differentiation. The moon differs significantly from the earth in its lower iron content, gross homogeneity, much slower rate-of-change, and closer approach to isostatic equilibrium in the sense of stress-difference magnitudes.

Kaula, W. M.↗
NASA NTRS1993

Overturn of magma ocean ilmenite cumulate layer: Implications for lunar magmatic evolution and formation of a lunar core

We explore a model for the chemical evolution of the lunar interior that explains the origin and evolution of lunar magmatism and possibly the existence of a lunar core. A magma ocean formed during accretion differentiates into the anorthositic crust and chemically stratified cumulate mantle. The cumulative mantle is gravitationally unstable with dense ilmenite cumulate layers overlying olivine-orthopyroxene cumulates with Fe/Mg that decreases with depth. The dense ilmenite layer sinks to the center of the moon forming the core. The remainder of the gravitationally unstable cumulate pile also overturns. Any remaining primitive lunar mantle rises to its level of neutral buoyancy in the cumulate pile. Perhaps melting of primitive lunar mantle due to this decompression results in early lunar Mg-rich magmatism. Because of its high concentration of incompatible heat producing elements, the ilmenite core heats the overlying orthopyroxene-bearing cumulates. As a conductively thickening thermal boundary layer becomes unstable, the resulting mantle plumes rise, decompress, and partially melt to generate the mare basalts. This model explains both the timing and chemical characteristics of lunar magmatism.

Hess, P. C.↗