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Emergency core cooling system performance criteria for Multi-Layered Silicon Carbide nuclear fuel cladding

Multi-layered Silicon Carbide (SiC) cladding has been proposed to replace the current Zircaloy (Zr) cladding in existing nuclear power plants. Due to its ceramic property, SiC may have a different failure mechanism from that of metallic Zr clad. This characteristic should be considered in designing the plant’s safety system performance, such that the fuel’s integrity is reasonably assured during accident scenarios. This paper aims at optimizing the Emergency Core Cooling System (ECCS) performance criteria in mitigating LBLOCA accidents at a Pressurized Water Reactor (PWR) using the uranium dioxide fuel and duplex or triplex SiC cladding structures. Clad failures by brittle fractures and thermal degradation were modeled in a fuel analysis code. This fuel model was coupled with the RELAP5 plant model by adapting the fuel’s mesh configuration and formulating the effective heat transfer coefficients. A model to quantify the likelihood of clad functional failure as a combination of individual layer fractures at various axial positions was proposed. Updated SiC material properties were gathered from recent reference studies. Clad reliability estimates using the proposed model were compared with the estimates obtained using other models. The results were used to relax the criterion of required actuation timing of ECCS, such that the risk of the new plant design is less or equal to that of the initial plant configuration. Triplex clad was more reliable than duplex clad and Zr, reducing the conditional core damage probability by three orders of magnitude in the reference LBLOCA scenario. Compressive stresses due to irradiation swelling played the determining role in the vulnerabilities of each clad design. The duplex clad was vulnerable to pressure-loading stresses while triplex clad was prone to fail due to thermal shocks experienced during the LOCA reflood phase. Additionally, it was concluded that the most vulnerable axial fuel rod location in the reference LBLOCA scenario was located at the highest axial power peaking location. A sensitivity study on the ECCS timing density was conducted. The results showed that ECCS actuation timing could be extended from the initial technical specification, without increasing the fuel damage likelihood. The time extension was distributed in the order of several hundreds of seconds, which was comparable with time extensions offered by FeCrAl and Cr-coated-Zr clad designs in LBLOCA scenarios. This time extension may potentially reduce the failure probabilities of EDGs and pumps, hence improving the plant safety further.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

Separation of Zirconium from Zircaloy-2 for Spent Nuclear Fuel Cladding Applications using a Chloride Volatility Process

The United States produces a large amount of cladding material from used nuclear fuel, expected to approach 1,000 MT/year for the next 50 years. The recovery of zirconium from the cladding material would represent a ∼50% savings on the geologic waste disposal requirement, and savings of >$40 M/year due to the cost of hafnium-free zirconium. Previous simulation studies have shown that in the irradiated cladding, the major activation products found are {sup 125}Sb, {sup 60}Co, and {sup 93m}Nb, and the major fission product found is {sup 137}Cs. These radioisotopes make it impossible to treat the cladding as low level waste. In a chlorination method, zirconium cladding reacts with Cl{sub 2} at 350-380 deg. C to produce mainly ZrCl{sub 4}. The zirconium tetrachloride has a relatively low boiling point (sublimes at 330 deg. C) which allows its separation from other products, and so it can be treated as low level waste for disposal or recycling. This chlorination approach has been proposed for the reprocessing of zirconium. However, previous work has observed element impurities (Fe, Sn, Cr, Cs, Sb, and Nb) in the recovered ZrCl{sub 4} meaning that additional steps are necessary in a chlorination process previous to the reduction of ZrCl{sub 4} to the metallic form. The chlorination process for zirconium reprocessing has been highly encouraged as it has proven more efficient than previous mechanical processes, redox processes, and other chemical methods such as iodination. The overall goal of this project is to develop the road map for a chlorination process that will yield high purity zirconium. The current study focuses on the recovery of ZrCl{sub 4} from non-irradiated alloys used as nuclear fuel cladding. (authors)

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Deposition of integrated protective material into zirconium cladding for nuclear reactors by high-velocity thermal application

A zirconium alloy nuclear reactor cylindrical cladding has an inner Zr substrate surface, an outer volume of protective material, and an integrated middle volume of zirconium oxide, zirconium and protective material, where the protective material is applied by impaction at a velocity greater than 340 meters/second to provide the integrated middle volume resulting in structural integrity for the cladding.

Mazzoccoli, Jason P.↗

High Temperature Steam Corrosion of Cladding for Nuclear Applications: Experimental

Stability of cladding materials under off-normal conditions is an important issue for the safe operation of light water nuclear reactors. Metals, ceramics, and metal/ceramic composites are being investigated as substitutes for traditional zirconium-based cladding. To support down-selection of these advanced materials and designs, a test apparatus was constructed to study the onset and evolution of cladding oxidation, and deformation behavior of cladding materials, under loss-of-coolant accident scenarios. Preliminary oxidation tests were conducted in dry oxygen and in saturated steam/air environments at 1000OC. Tube samples of Zr-702, Zr-702 reinforced with 1 ply of a ß-SiC CMC overbraid, and sintered a-SiC were tested. Samples were induction heated by coupling to a molybdenum susceptor inside the tubes. The deformation behavior of He-pressurized tubes of Zr-702 and SiC CMC-reinforced Zr-702, heated to rupture, was also examined.

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Aluminum Clad Spent Nuclear Fuel Long Term Dry Storage Technical Issues Action Plan - Technical and Engineering Activities

The DOE Spent Nuclear Fuel Working Group (SNFWG)’s report on technical considerations and challenges for extended dry storage of aluminum-clad spent nuclear fuel (ASNF) entitled, Aluminum-Clad Spent Nuclear Fuel: Technical Consideration and Challenges for Extended (>50 Years) Dry Storage, DOE/ID RPT-1575, June 2017 identified five knowledge gaps and technical data needs. This DOE SNFWG report also made several recommendations including one to develop an action plan to identify needed technical and engineering activities and analyses to address the identified knowledge gaps and technical data needs. A team composed of twenty SNF management experts and appropriate subject matter experts from the Idaho National Laboratory and Savannah River National Laboratory was assembled to develop this action plan. The action plan identifies and recommends six technical and engineering tasks and estimated cost and schedule for task completion. It is estimated that $5M and 18 months will be required to execute the recommended tasks.

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Aluminum Clad Spent Nuclear Fuel Task 1: Oxyhydroxide Layer Behavior and Chemistry Experimental Test Plan

This document presents the test plan for Task 1 of the Aluminum Clad Spent Nuclear Fuel Long Term Dry Storage Technical Issues Action Plan, which covers aluminum clad spent nuclear fuel (ASNF) fuel that is currently or may in the future be held in dry storage for an extended period. The objectives of the Task 1 test plan are to: 1. Understand how ASNF performs over extended dry storage periods. 2. Understand mechanisms that could alter aluminum hydroxide/oxyhydroxide layers during extended storage. 3. Characterize thickness and growth rates of oxyhydroxide layers based on fuel history and provide anticipated H2 gas generation rates based on chemical corrosion. 4. Characterize materials properties for oxides present on ASNF. 5. Interface with canister modeling activity to deliver degradation rates for package performance for both sealed and vented configurations. 6. Understand implications of higher temperature drying (250°C) on stability in dry storage. This test plan lays out the technical activities that will be performed to achieve the test objectives described above. Experiments will be performed at Idaho National Laboratory in-town facilities. Specimens for testing will include those supplied by Savannah River National Laboratory. Activities will include both experiments and modeling and will coordinate with other tasks within the project.

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Structure of the pellet-cladding interaction layer of a high-burnup Zr-Nb-O nuclear fuel cladding

Here, structure of the pellet/cladding-interaction (PCI) layer of a high-burnup nuclear fuel with niobium-bearing cladding was investigated using modern transmission electron microscopy (TEM) techniques. Morphology of the PCI consisted of uniform zirconia layer on the cladding side and finger-like features towards to the ceramic fuel. The PCI layer showed a complex microstructure that constitutes three distinct zirconia layers formed by two zirconia phases. From cladding to fuel, monoclinic, tetragonal, and another tetragonal phase were determined via TEM diffraction patterns and precession electron diffraction (PED) using ASTAR microscopy platform (AMP). Characterizations showed that monoclinic and tetragonal phases close to the cladding were crack-free, but the tetragonal layer adjacent to the fuel contained cracks and pores. Presence of the monoclinic layer suggested that its formation involved the gaseous diffusion of oxygen below threshold dose of fission product damage before the fuel/cladding contact occurred. Furthermore, high-resolution TEM revealed compound phase of (U,Zr)O 2 at fringes of zirconia fingers on the fuel side.

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Milestone 1.2.16. Reconciling the Impacts of Thermal Pretreatment on Radiation-Induced H2 Generation from Aluminum-Clad Spent Nuclear Fuel Surrogate Materials

To support the technical basis for the extended dry storage of aluminum-clad spent nuclear fuel (ASNF), thermal pretreatment procedures to minimize the radiation-induced generation of molecular hydrogen (H2) have been investigated. The aim of thermal pretreatment is to eliminate the residual adsorbed water content on the ASNF’s corrosion layers, precursors for H2 generation. To date, irradiation studies in this area have found conflicting results for the effectiveness of thermal pretreatment procedures. The aim of this study was to reconcile those differences. However, the presented results, which utilized a modified in situ thermal pretreatment procedure, afforded H2 yield data that further indicates that thermal pretreatment does not significantly reduce the radiation-induced yield of H2 from gamma irradiated ASNF surrogate materials. Assessment of the differences between thermal pretreatment studies suggests that stainless-steel—present in the irradiation setup of studies that demonstrated a reduction in the yield of H2 with thermal pretreatment—may afford not only unanticipated interfacial chemistry, but also the formation and radiolytic contribution of iron oxides to the chemistry underpinning the formation of H2 in these systems. Given the Department of Energy Standard Canister—proposed for the extended dry storage of ASNF—is predominantly composed of stainless-steel, the potential contribution of stainless-steel and its corrosion layers to radiolytic H2 production should be further investigated. This research was funded by the U.S. Department of Environmental Management, Office of Technology Development, under contract DE-AC07-05ID14517.

38 RADIATION CHEMISTRY, RADIOCHEMISTRY, AND NUCLEA↗

Considerations for Defining G-Values for Aluminum-Clad Spent Nuclear Fuel

Sealed-canister dry storage of aluminum-clad spent nuclear fuel (ASNF) generated by research reactors is an alternative to current storage and disposition pathways as directed by the U.S. Department of Energy. The major challenge faced for this storage approach is radiolytic H 2 generation, including from the aluminum (oxy)hydroxide layers on the surface of ASNF. Experimental and modeling activities have been carried out to characterize the radiolytic yield as part of a DOE-sponsored research program to develop the technical basis for ASNF dry storage. The G-value is a commonly way to report results of radiolysis testing and is defined as the radiolytic yield of a species (e.g. molecular hydrogen) per unit radiation energy deposited into the material system. An independent technical review of the ASNF dry storage technical basis performed by Pacific Northwest National Laboratory raised questions about differences in G-value definitions used for experiments on ASNF surrogates consisting of aluminum samples with adherent (oxy)hydroxides compared to G-values reported in prior literature and how the magnitudes compared between different studies. Material systems resembling ASNF pose complications for measuring/defining G-values to predict the evolution of H 2 in a sealed canister, including i) accounting for radiolytic yields potentially arising from multiple sources, i.e., residual free (vapor), physisorbed, and chemisorbed/chemically bound waters; ii) deciding what portions of the multi-material system to include in the absorbed energy (radiation dose) calculation, considering possible energy exchange between materials as well as measurement limitations, and iii) capturing variations in G-value associated with non-linear yield vs. dose curves and/or dependence on the cover gas. This report summarizes previous literature information on radiolytic H 2 generation and associated G-values from mixed-material systems (generally oxides in contact with water or organic compounds) and from (oxy)hydroxides/hydrates to compare with the definitions and values for ASNF surrogate samples containing adherent aluminum (oxy)hydroxides.

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Monitoring the Possible Effects of Corroding Fuel Cladding in Nuclear Ponds: a Modified ROV for Storage Ponds - 20144

Nuclear ponds are used worldwide to store radioactive nuclear material, often for extended periods of time. The pond water conditions need to be closely monitored so that mitigation strategies can be put in place should any leakage of radioactive material occur. This paper describes the selection, development and on-site deployment of a bespoke system whose design was based on of-the-shelf components. The system is able to identify, locate and differentiate the leakage of radioactive material stored in nuclear ponds from the background activity of the water in the pond. The selection of an appropriate detector and monitoring geometry was supported by MCNP modelling which allowed a high degree of confidence in the proposed design. The development of the system allowed a real-time indication of the canister integrity, without incurring the increased operator doses from manual sampling operations that were previously used on site. The benefits of the developed system include the fact that the system is lightweight, easily deployable, retrievable, decontaminable and results in negligible waste products. Moreover, it is able to analyse the samples in-situ, in this way reducing the time needed to manually collect and send the samples to a laboratory for lengthy analysis. (authors)

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Metallographic examinations and hydrogen measurements of high-burnup spent nuclear fuel cladding

In the US, commercial spent nuclear fuel (SNF) is transferred to interim dry storage casks where it will be stored for decades awaiting transport to a consolidated interim storage facility or a geologic repository. Because the fuel rod cladding is the first barrier against any radioactive material release, understanding the behavior of SNF cladding, particularly at high burnup (HBU), in dry storage conditions is crucial to safely store and transport the spent fuel. In this study, a series of metallographic examinations and cladding hydrogen measurements were conducted on HBU SNF cladding at Oak Ridge National Laboratory as a part of the High Burnup Spent Fuel Data Project, which is sponsored by the US Department of Energy (DOE) Office of Nuclear Energy (NE). Here, t o investigate the effect of simulated drying conditions on the cladding, three as-received fuel rods with different cladding materials—M5, ZIRLO, and Zircaloy-4—were heated to 400°C and then slow-cooled to room temperature. The pellet and cladding were then qualitatively and quantitatively analyzed and compared in terms of pellet crack morphology, HBU rim, waterside oxide, cladding H, and cladding hydride morphologies. This paper presents and discusses the results of these analyses in detail.

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Aluminum Clad Spent Nuclear Fuel Task 3: Sealed and Vented Systems Episodic Breathing and Gas Generation Modeling Plan

This document presents the test plan for Task 3 of the Aluminum Clad Spent Nuclear Fuel Long Term Dry Storage Technical Issues Action Plan, which covers modeling and predictions of the generations of corrosive gases within both sealed and vented, subject to episodic breathing, storage systems. This includes aluminum clad spent nuclear fuel (ASNF) that is currently or may in the future be held in dry storage for an extended period. The overall objectives of the Task 3 modeling plan are to: 1. Comprehensively model the combined effects of episodic breathing in vented storage systems/canisters using INL INTEC CPP-603 facility as an example. Both bulk gas phase radiolysis reactions and aluminum cladding surface gas generation reactions will be included into a 3-dimensional computational fluid dynamics (CFD) model to model and predict long-term evolutions of the temperature and concentrations of corrosive gases within unsealed canisters subjected to episodic breathing. 2. Comprehensively model sealed and inert canister storage system using DOE standard canister as an example. 3. Closely integrate with Task 1 and Task 2 for identification of main gas-generation reactions and kinetics and provide simulation results back to Task 1 and 2 to further refine experimental designs. This test plan lays out the technical activities that will be performed to achieve the test objectives described above. Simulations will be performed using the Idaho National Laboratory super computer Falcon.

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Sensitivity study of coupled chemical-CFD simulations for analyzing aluminum-clad spent nuclear fuel storage in sealed canisters

We report the United States Department of Energy (DOE) manages over 50 Metric Tons Heavy Metal (MTHM) of aluminum-clad spent nuclear fuel. One main source for DOE’s Aluminum-clad spent nuclear fuel (ASNF) inventory is the advanced test reactor (ATR) at the INL site, which makes this fuel of particular interest for storage scenarios. Road-ready and final disposition packaging configurations for the ATR fuel dictates storage within helium-backfilled, sealed DOE standard canisters. The conditions within these sealed canisters for extended (greater than50 year dry) storage is of interest. To further this goal, a three-dimensional (3D) multi-physics computational fluid dynamics (CFD) model is developed of the sealed DOE standard canisters. This 3D CFD model is one-way coupled with bulk gas radiolysis reactions considering sealed canisters with inert gas and possible trace amounts of air and water vapor. This study looks at the evolution of the thermal history of the canisters over a 50 year time period with a coupling to the chemical reactions occurring from radiolytic breakdown of residual water. A sensitivity study is then carried out over the parameters of the model including the fuel decay heat, residual water content, sealed pressure, canister external temperature, and canister emissivity. In pure helium, hydrogen generation rates are low, under 10 ppm, but hydrogen generation rates are affected greatly by the presence of even 1% residual air, increasing by 50-plus-fold, and nitric acid generation with residual air also occurs ranging from 500 to 4000 ppm after 50 years. The fuel decay heat and the residual water content show the most importance in the generation of hydrogen gas in pure air, and for nitric acid with a residual air condition. External temperature, canister emissivity and sealed pressure all show minor sensitivity effects to the generation of potentially harmful species.

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A correlation-based approach for evaluating mechanical properties of nuclear fuel cladding tubes

The present work offers and evaluates a correlation-based approach to determine the tensile properties of nuclear fuel cladding tubes. A set of model materials with known properties (i.e., austenitic and ferritic steels, fcc- and hcp-alloys) were tested to build a correlation between conventional tensile tests and ring (hoop) and tube (axial) tests. It was shown that close-to-linear relationships exist for the basic mechanical properties (i.e., yield and ultimate stress, uniform and total elongation) between the uniaxial tensile test data and the ring and tube test data. Using the ring and tube specimen geometries, the feasibility of the approach was demonstrated via manufacturing and testing specimens from irradiated Zr and FeCrAl nuclear fuel cladding tubes. Limitations caused by specific deformation mechanisms (e.g., high ductility of 304L steel) were discussed in detail. The approach can be extended to other tubular products with different geometry and dimensions.

36 MATERIALS SCIENCE↗

Evaluation of Aluminum-clad Spent Nuclear Fuel during Drying and Dry Storage

The DOE SNF Working Group ASNF Subgroup and the U.S. Nuclear Waste Technical Review Board have identified knowledge gaps regarding the management of aluminum-clad spent nuclear fuel (ASNF).[1, 2] The objectives of this research are to observe, sample and analyze the nature of aluminum surface corrosion and corrosion layer chemistry relevant to the ASNF performance over the duration of the dry storage segment of the fuel life cycle. The primary goal is to build an understanding of ASNF behavior, from reactor service and wet storage through drying and dry storage, with parallel testing of surrogate materials. The premise is that residual water affiliated with the aluminum oxide from corrosion during reactor service and wet storage, continues to influence ASNF performance during dry storage, and that even after successful drying the surface conditions of ASNF have yet to be satisfactorily characterized. The initial scope collected and analyzed specimens from irradiated non-fuel components of aluminum-clad Advanced Test Reactor (ATR) fuel elements that are routinely removed at the end of reactor service life. Techniques have been developed for remote material sampling from ATR elements from vented dry storage at the Irradiated Fuel Storage Facility (IFSF). These techniques involve 1) nipping off a small corner of the aluminum near where the end box had been removed and 2) scraping the exterior (non-fueled) plate surface to collect an oxide sample. This second effort targets ATR elements expected to have seen the longest residence in storage, both in the CPP-603 pool (with poor water quality) and in dry storage at IFSF, within the fuel handling scheduled to consolidate ATR at IFSF and receive the remaining inventory at CPP-666. Follow on work has been proposed to nip corners and collect scrapings immediately following ATR fuel drying, before placement in dry storage. Sample analysis will use multiple techniques to understand the chemical composition and morphology of the surface oxides. A simultaneous effort is progressing to develop surrogate materials to enable rigorous controlled experiments. Consistently produced, these surrogate materials can then be used to demonstrate limitations inherent to remote sampling and to validate performance models under relevant constraints. The combined efforts will substantiate ASNF performance and fuel management decisions regarding drying and packaging over a more complete range of life cycle conditions. [1] DOE Spent Nuclear Fuel Working Group, Aluminum-Clad Spent Nuclear Fuel: Technical Considerations and Challenges for Extended (>50 Years) Dry Storage, DOE/ID RPT#: 1575, prepared by Aluminum-Clad SNF Sub Working Group, June 2017. [2] U.S. Nuclear Waste Technical Review Board, Management and Disposal of U.S. Department of Energy Spent Nuclear Fuel, A Report to the United States Congress and the Secretary of Energy, December 2017, p. 143.

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Designing an impedance-based technique for studying corrosion on cladding materials

In nuclear cladding materials, changes in structure and chemistry over the lifetime of claddings can have a significant impact on fuel and reactor performance. Currently, chemical evolution over the lifetime of the fuel and cladding materials can only be inferred using post-irradiation examination. As an alternative to post-irradiation measurements, electrochemical impedance spectroscopy (EIS) can provide an in-pile measurement of changes in chemistry in oxides and hydrides. The objective of this study is to develop an impedance based sensing technology for measuring spatial- and time-resolved in-pile changes in cladding chemistry in order to understand the mechanisms of hydride formation, hydride dealloying and associated cladding corrosion so that a mitigation strategy and technology can be developed for reactor safe operation. Two prototype impedance-based sensors were designed and assembled using Zr-4 as working electrode and Pt as counter and reference electrode. One sensor is tubular type and the other one is plate-type. These sensors will be tested in static autoclave to investigate the effects of various environmental conditions (including temperature, pressure, and water chemistry) on cladding material corrosion mechanisms. These in-situ EIS sensors would provide corrosion-layer parameters in high-temperature water, such as (1) total layer thickness, (2) the evolution of oxide structures as uniform layer dielectric or sublayer(s), and (3) the possible electrochemistry of the volume corrosion process and the solid/liquid interface, such as the cyclic nature of corrosion of Zr alloys in high-temperature water. This work was focused on electrochemical sensor development, targeting cladding oxides/hydrides under thermodynamic equilibria; characterization of samples using Kelvin probe force microscopy (SKPFM), Raman spectroscopy, and scanning electron microscopy (SEM) with energy-dispersive X-ray spectroscopy (EDS) to provide high-resolution co-localized characterization of zirconium oxide and metal/oxide interface.

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Technology Development for Dry Storage of Aluminum-Clad Spent Nuclear Fuel - 20490

A candidate disposition pathway for the > 13 MTHM of aluminum-clad spent nuclear fuel (ASNF), owned and managed by the U.S. Department of Energy, is the drying and placement of the SNF into sealed-canister dry storage, with the ASNF-in- canisters 'road-ready' for transportation to and final direct disposal in a repository waste package. Technical information gaps in fuel drying, and fuel dry storage behavior, have previously challenged the declaration of technology readiness for drying and placement of this fuel into the DOE Standard Canister design for > 50 years of safe dry storage. The principal technical information gaps included: i) characterization and thermal dehydration behavior of aluminum (oxy)hydroxide films attendant on the cladding due to film formation during reactor operation and during post-discharge up to long-term wet storage histories; and ii) G-value data to enable estimation of the radiolytic gas generation from the cladding with its (oxy)hydroxide films. Thus, the oxide films on the ASNF challenged the safety of a sealed storage canister with thermal and radiolytic decomposition of the waters on the films that can lead to corrosion, pressurization, and flammability issues. These gaps in the technical information base have largely been closed. This paper discusses the investigations at the Idaho National Laboratory (INL) and the Savannah River National laboratory (SRNL), and outlines the pending technology development work for input to an engineering design to enable a road-ready dry storage system for ASNF. The ASNF inventory considered for road-ready dry storage is stored at the Savannah River Site (SRS) and at the Idaho Nuclear Technology and Engineering Center (INTEC) at the INL. The ASNF inventory in the SRS L Basin is from foreign and domestic research reactors (FRR and DRR), and is diverse in terms of design, irradiation, and post-reactor-discharge storage conditions; these factors yield a range of characteristics of cladding oxide films on ASNF. Mixed aluminum (oxy)hydroxide (boehmite and bayerite/gibbsite) films, non-uniform in thicknesses up to a maximum local thickness bounded by 25 μm, were observed on ASNF materials removed from wet storage in the L Basin and in non-sealed dry storage at the SRS following reactor service and a long-term (up to 40+ years) interim storage history. The ASNF inventory at INTEC, in both wet and vented dry storage, is predominantly from the Advanced Test Reactor (ATR), but it also includes DRR and FRR fuel. To address a profound behavior of these films, radiolysis testing of aluminum specimens with mixed type boehmite/bayerite oxide films was performed to develop basic data on G-values for production of radiolytic hydrogen under dry storage conditions with nominal relative humidity, temperature, and cover gas. Modeling and simulation of canister internal environments with postulated inventories of oxide films provides estimation of the evolution of the conditions of the canister loaded with ASNF. Simultaneous Thermal Analysis (TGA/DSC) of hydrated oxide powders, and laboratory-scale aluminum specimens with a bayerite film (∼10 μm) using TGA methods, inform drying time/temperature conditions to be used for the ASNF. A demonstration project is recommended for Verification and Validation of the drying and storage of the ASNF. Remaining major tasks leading up to the hot demonstration include scale-up radiolysis testing and scale-up drying testing. Engineering design with the information from the technology program will establish the safety basis and enable long-term (> 50 years) dry storage compatibility with ASNF in the DOE Standard Canister pending its transportation to and disposal in a repository. This full capability would show the ASNF-in-canister storage system to be road-ready. (authors)

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Aluminum Clad Spent Nuclear Fuel Task 5: Oxide Layer Response to Drying Experiment Test Plan

This document presents a test plan developed to assess the fundamental effectiveness of two widely accepted processes for drying spent nuclear fuel: vacuum drying and helium forced-gas drying. The experimental activities planned for Task 5 follow from the “Aluminum Clad Spent Nuclear Fuel Long Term Dry Storage Technical Issues Action Plan.” The objectives are to evaluate the response of the oxide corrosion layer on aluminum clad spent nuclear fuel (ASNF), processed at temperatures above 100°C, to understand and compare the behavior of oxide corrosion layer compositions resulting from a range of credible procedural variations during the transition of ASNF from wet storage to dry storage.

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