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At least 37 records · Page 2

Subsurface Characterization for Evaluating Geothermal Resource Potential from Existing Oil and Gas Wells in Tuttle, Oklahoma: Preprint

Oil and gas (O&G) wells often encounter co-produced hot water, possibly suitable for geothermal direct-use applications. The City of Tuttle is located on the eastern part of the Anadarko sedimentary basin in Oklahoma with high heat-in-place potential and recovery capability at depth. This study aims at demonstrating the potential of geothermal energy production for direct-use applications in two public schools and 250 nearby houses in Tuttle via repurposing existing O&G wells. In this scope, geochemistry, geology, and borehole log data were collected and incorporated into a 3D conceptual subsurface model. A digital elevation model (DEM) was used to represent the study area topography with four O&G wells. In addition, hydrogeochemical characteristics of the geothermal fluid and scaling potential were analyzed using ternary diagrams and chemical ratios to develop mixing models. The subsurface geology model indicated that the study area primarily consists of Permian to Mississippian Sandstone and Limestone formations, implying a porosity ranging between 12% and 22%, and a permeability up to 3.90E-14 m2 in certain reservoir levels. The reservoir temperature is expected to be ranging between 80 degrees C to 95 degrees C around 3 km depth with an average temperature gradient of 22.8 degrees C/km. Chemical geothermometers also estimated the reservoir temperature as 90 degrees C. Findings of the chemical model demonstrated that the geothermal fluid is Sodium-Potassium-Chloride-Sulfate type and possibly mixed with shallow groundwater resulting in higher Ca and Mg concentrations and lower Na/K ratio implying lower calcite scaling. These results comprehensively characterize the potential of geothermal resources in the study area and imply that geothermal energy production by repurposing existing O&G wells is suitable for low-temperature direct-use applications.

GEOTHERMAL ENERGY↗

Quantification of Methane Emissions from Marginal (Low Production Rate) Oil and Natural Gas Wells

The objective of this research was to measure methane emissions from marginal well sites at various basins across the United States. The goal was to collect and evaluate representative, defensible, and repeatable data and draw quantifiable conclusions on the extent of emissions from marginal wells across oil and gas producing regions of the U.S., and to compare these results to published data on the emissions from nonmarginal wells.

03 NATURAL GAS↗

Techno-economic feasibility of geothermal energy production using inactive oil and gas wells for district heating and cooling systems in Tuttle, Oklahoma

Oil and gas wells have been drilled in the United States and often encounter hot co-produced water possibly suitable for geothermal direct-use applications. Here this study evaluated geothermal resources, heating and cooling demand, and techno-economic potential of four oil and gas wells repurposed for geothermal energy production to serve two public schools and 250 nearby houses in Tuttle, Oklahoma, USA. Subsurface geology in the study area primarily consists of Permian to Mississippian sandstone and limestone formations approximately from 2 km to 3.5 km depth. With a geothermal gradient of 25.3 °C/km, the temperature of geothermal energy production was estimated as 68.2 °C at 2.1 km. The potential of calcite scaling within boreholes and pipes was minimal. Using the characterized reservoir properties, techno-economic analyses were conducted for evaluating levelized costs of geothermal energy production for direct-use heating and cooling and district heating systems with five different production scenarios. Heating and cooling demand in two schools and 250 houses and additional 0.3 MW and 0.6 MW base heating loads for potential geothermal direct-use applications in the study area were also incorporated in the modeling. Results indicated that the levelized cost of heating of geothermal district heating systems utilizing existing wells were significantly lower than those of conventional geothermal energy systems that include well drillings. The geothermal energy production with doublet and quartet configurations was generally sufficient to supply total annual heating demand in the district, while a peaking boiler was used to supply peak loads. Doublet configurations showed higher production temperature with a lower thermal drawdown than the quartet configurations. The doublet system at 2.1 km production depth with 9.3 kg/s flow rate represented the optimal levelized cost of $71/MWh and 91.2% utilization factor. These results imply that the Tuttle geothermal district heating system is techno-economically feasible and comparable to geothermal district heating systems in the United States and the regional natural gas rate for residentials by recycling inactive oil and gas wells with no drillings.

15 GEOTHERMAL ENERGY↗

Dynamic Life Cycle Assessment for Evaluating the Global Warming Potential of Geothermal Energy Production Using Inactive Oil and Gas Wells for District Heating in Tuttle, Oklahoma

Repurposing abandoned oil and gas infrastructure for geothermal energy production has great potential to reduce greenhouse gas (GHG) emissions. This study quantified the life cycle global warming potential of geothermal energy production using four inactive oil and gas wells repurposed for district heating in Tuttle, Oklahoma. A cradle-to-grave prospective life cycle assessment was performed to compare GHG emissions between the geothermal district heating system and conventional natural gas-fired heating system from 2020 to 2050. For initial implementation of the geothermal system, we investigated two approaches: 1) repurposing abandoned infrastructure from a nearby oil and gas well site, and 2) production and injection well drillings including new construction of a central heat exchange station. Environmental impacts from the geothermal system were estimated for five scenarios where a natural gas peaking boiler is incorporated to supply peak heat demand. The prospective results indicated that cumulative reduction in GHG emissions from transitioning to the geothermal district heating system increase over time as a function of future renewable resource penetration and technological advancements within electricity, fuel, and steel production. Over 30 years, the global warming potential associated with the district heating demand will have been reduced by up to 24 % with the repurposed system. These results imply that repurposing existing oil and gas infrastructure for geothermal energy systems of district heating will bring future climate benefits.

abandoned oil and gas wells↗

Procedure for locating oil and gas wells in the Appalachian Basin

Locating undocumented (or poorly documented) oil and gas wells for environmental assessment is often difficult. Remnant features that confirm the presence of a well (intact casing/wellhead, well bore, etc.) are typically less than a meter in size and often are obscured from direct observation on the ground or from the air (by dense vegetation, for example). To efficiently find such features, it is useful to first systematically compile publicly available digital data at progressively smaller scales prior to embarking on field campaigns. Further, the information presented here describes the procedure developed and used by the U.S. Department of Energy's National Energy Technology Laboratory to locate potential oil and gas well sites for follow-up field verification and characterization. Digital data are first compiled from national and state resources such as well location/production databases, historical topographic maps, historical aerial photographs, and LiDAR data. Although each data set is likely to be incomplete or inaccurate to some extent, combining the data resources using geographic information system technology can generate potential well site targets with a higher degree of confidence, which improves the efficiency of fieldwork activities. This workflow was developed in the Appalachian Basin region, and although certain aspects may be unique, the general process would be applicable to locating undocumented wells in other regions.

54 ENVIRONMENTAL SCIENCES↗

Environmental risks and opportunities of orphaned oil and gas wells in the United States

Abstract Hundreds of thousands of documented and undocumented orphaned oil and gas wells exist in the United States (U.S.). These wells have the potential to contaminate water supplies, degrade ecosystems, and emit methane and other air pollutants. Thus, orphaned wells present risks to climate stability and to environmental and human health, which can be reduced by plugging. To quantify environmental risks and opportunities of well plugging at the national level, we analyze data on 81 857 documented orphaned wells across the U.S. We find that > 4.6 million people live within 1 km of a documented orphaned well. 35% of the documented orphaned wells are located within 1 km of a domestic groundwater well, yet only 8% of the wells have groundwater quality data within a 1 km radius. Methane emissions from the documented orphaned wells represent approximately 3%–6% of total U.S. methane emissions from abandoned oil and gas wells, but this estimate is based on measurements at < 0.03% of U.S. abandoned wells. 91% of the documented orphaned wells overlie formations favorable for geologic storage of carbon dioxide and hydrogen, meaning that orphaned well plugging can reduce leakage risks from future storage projects. Finally, we estimate plugging costs for documented orphaned wells to exceed the $4.7 billion federal funding by 30%–80%, emphasizing the importance of prioritizing federal spending on wells with large remediation benefits. Overall, environmental monitoring data are not extensive enough to quantify risks, especially those related to air and water quality and human health. Plugging orphaned wells can provide opportunities for geologic storage of carbon dioxide and hydrogen and geothermal energy development, thereby facilitating efforts to transition to net-zero energy systems. Our analysis on environmental risks and opportunities of orphaned wells provides a framework that can be used to manage the millions of documented and undocumented orphaned wells in the U.S. and abroad.

54 ENVIRONMENTAL SCIENCES↗

Large reductions in Permian Basin methane intensity shown in multi-year comparison of aerially-visible methane emissions

Spanning the US states of Texas and New Mexico, the Permian Basin has been a hotspot of methane emissions from oil and natural gas activity 1–4, although studies disagree over the magnitude of these emissions. The most comprehensive measurement campaigns published were conducted in 2019 1–5 .There have been large changes in the energy industry since then, including in the prices of oil and gas, both state and federal regulatory environments, investor and activist pressure over methane emissions, and the adoption of new technologies and policies by energy operators. Understanding how any or all of these might influence methane emissions is important for policy makers, oil and gas operators, and other stakeholders. We characterize the time evolution of Permian Basin methane emissions using a series of comprehensive aerial surveys conducted every year from 2020-2023 and compare them to the 2019 results cited above. To maintain comparability, all the data sets are from surveys using Insight M point source methane sensing technology. The scope of these surveys expanded over time: from 33-46% of wells, oil production, and gas production in 2020 to 60-65% in 2021, to 84% of wells and over 90% of both oil and gas production in 2023. These surveys by Insight M also include hundreds of gas processing plants and compressor stations as well as 1000s of km of gathering and transmission pipelines. Considering only the aerially detected portion of emissions (typically the majority of the total in such surveys 4), we find reductions of more than 70% in methane emissions intensity compared to the 2019 New Mexico-only Insight M survey, with variation depending on the year 3,4. Notably, although sources below 100 kg/hr contributed less than 10% of aerially measured emissions the 2019 New Mexico survey 3, these smaller sources constitute a larger proportion of total aerially measured emissions (although not the majority) in 2020-2023. Production facilities and gathering pipelines are responsible for the larges shares of total emissions, followed by compressor stations and gas processing plants. Permian methane emissions were also measured in a comprehensive 2019 Permian-wide survey by the Carbon Mapper team 2. That analysis led to a lower total emissions estimate at the time 4. These new Insight M-based emission rates are still roughly 30-70% lower than the aerially measured portion of the 2019 Carbon Mapper-based estimates 4. Further work is needed to harmonize these surveys in space and time to create the most intercomparable numbers possible 5. Additional analysis is needed to compare our findings to the more spatially constrained 2020, 2021, and 2023 Carbon Mapper surveys in the Permian 4,6. The evidence is strong from these two survey teams that emissions intensity has declined significantly since 2019. Reasons for this trend are currently unclear but point to possible success of emissions control programs. Future work investigating frequency, source, and operator-specific intensities could provide insights into the causes of this promising trend.

methane, oil and gas, data science, remote sensing↗

Integrating the Design of Desalination Technologies into Produced Water Network Optimization

The oil and gas energy sector uses billions of gallons of water for hydraulic fracturing each year to extract oil and gas. The water injected into the ground for fracturing along with naturally occurring formation water from oil wells surfaces back in the form of produced water. Produced water can contain high concentrations of total dissolved solids and is unfit for reuse outside the oil and gas industry without desalination. In semi-arid shale plays, produced water desalination for beneficial reuse could play a crucial role in alleviating water shortages and addressing extreme drought conditions. In this poster we co-optimize the design and operation of desalination technologies along with operational decisions across produced water networks. A multi-period produced water network model with simplified split-fraction-based desalination nodes is developed. Rigorous steady-state desalination mathematical models based on mechanical vapor recompression are developed and embedded at the desalination sites in the network model. An optimal common design across all periods is ensured using global capacity constraints. The solution approach is demonstrated for multi-period planning problems on networks from the PARETO open-source library. Model formulation and challenges associated with scalability are discussed.

Naik, Sakshi↗

Integrating the Design of Desalination Technologies into Produced Water Network Optimization

The oil and gas energy sector uses billions of gallons of water for hydraulic fracturing each year to extract oil and gas. The water injected into the ground for fracturing along with naturally occur-ring formation water from the oil wells surfaces back in the form of produced water. Produced water can contain high concentrations of total dissolved solids and is unfit for reuse outside the oil and gas industry without desalination. In semi-arid shale plays, produced water desalination for beneficial reuse could play a crucial role in alleviating water shortages and addressing extreme drought conditions. In this paper we co-optimize the design and operation of desalination technologies along with operational decisions across produced water networks. A multi-period produced water network model with simplified split-fraction-based desalination nodes is developed. Rigorous steady-state desalination mathematical models based on mechanical vapor recompression are developed and embedded at the desalination sites in the network model. An optimal common design is ensured across all periods using global capacity constraints. The solution approach is demonstrated for multi-period planning problems on networks from the PARETO open-source library. Model formulation and challenges associated with scalability are discussed.

Naik, Sakshi↗

Modeling the corrosion of steel casing and the damage of well cement in a borehole system

This work presents the effect of chloride-induced corrosion in an underground borehole system, specifically considering the steel casing and further damage to the surrounding cement. In the past four decades, oil well cement has been successfully used for underground construction. However, high concentrations of chloride ions gradually degrade the functionality and durability of well cement. Gasses and liquids can leak from deterioration caused by chloride ions, and thus motivate this study. The chemo-mechanical coupling diffusion model and a classical fracture mechanics model are applied. The model is validated with OPC concrete corrosion data from literature, and then applied to well cement using experimentally obtained material property data. The time when crack initiation, peak pressure, and complete fracture is reached in the model of the cement sheath provides a quantification of the expected service life of the borehole system.

36 MATERIALS SCIENCE↗

Geothermal Reservoir Simulation Analysis in Support of Electricity Co-Production Feasibility Study at the Blackburn Oil Field, Nevada: Preprint

Geothermal electricity co-production is a viable option for oil reservoirs producing large water cuts with elevated wellhead-observed temperatures. Repurposing existing oil wells significantly reduces initial investment costs historically associated with geothermal resource utilization. The National Renewable Energy Laboratory (NREL), partnering with Gradient Geothermal, Inc. (formerly known as Transitional Energy) and Grant Canyon Oil and Gas, has been tasked to evaluate the feasibility of geothermal electricity co-production at the Blackburn Oil Field with Organic Rankine Cycle (ORC) generators. The Devonian steady-state reservoir has historically been producing high water cuts of 240 degrees F (115.6 degrees C) observed at the wellhead without documented pressure drawdown or thermal breakthrough. An estimated initial reservoir temperature of approx. 260degreesF (126.7 degrees C) has been observed in the field and history-matched in a wellbore production analysis and reservoir simulation. Our objective was to develop a conceptual geological model of the subsurface, simulate a natural-state reservoir, model production scenarios, and complete a technical feasibility analysis to accomplish this task. Through extensive modeling and the use of available proprietary and public data, it was possible simulate three scenarios that indicated minimal thermal decline over the duration of a simulated ten-year production and re-injection scheme.

Blackburn Nevada↗

Geothermal Reservoir Simulation Analysis in Support of Electricity Co-Production Feasibility Study at the Blackburn Oil Field, Nevada

Geothermal electricity co-production is a viable option for oil reservoirs producing large water cuts with elevated wellhead temperatures. Repurposing existing oil wells significantly reduces initial investment costs historically associated with geothermal resource utilization. The National Renewable Energy Laboratory (NREL), partnering with Gradient Geothermal, Inc. (formerly known as Transitional Energy) and Grant Canyon Oil and Gas, has been tasked to evaluate the feasibility of geothermal electricity co-production at the Blackburn Oil Field with Organic Rankine Cycle (ORC) generators. The Devonian steady-state reservoir has historically been producing high water cuts of 240 degrees F (115.6 degrees C) observed at the wellhead without documented pressure drawdown or thermal breakthrough. An estimated initial reservoir temperature of approx. 260 degrees F (126.7 degrees C) has been observed in the field and history-matched in a wellbore production analysis and reservoir simulation. Our objective was to develop a conceptual geological model of the subsurface, simulate a natural-state reservoir, model production scenarios, and complete a technical feasibility analysis to accomplish this task. Through extensive modeling and the use of available proprietary and public data, it was possible simulate three scenarios that indicated minimal thermal decline over the duration of a simulated ten-year production and re-injection scheme.

Blackburn Nevada↗

Recent Developments in Hydrogeologic Applications for Strain Tensor Analyses

Changes in fluid pressure deform porous media and this effect occurs in a variety of hydrogeologic processes, from the change in storage during pumping or injection to fluctuations in water levels caused by barometric pressure. We have developed instruments for measuring small strains in porous media, and we have used the resulting strain data to evaluate well testing, hydraulic fracturing, manual loading at the ground surface, and ambient hydrologic processes, like rainfall and evaporation. A particularly important application is the use of strain tensor data measured at shallow depths to analyze well tests or hydraulic fractures conducted at much greater depths. An early demonstration of this technique was conducted at the North Avant Field north of Tulsa, Oklahoma, where Pennsylvanian sandstone creates a confined aquifer and oil reservoir at a depth of 530m. We have showed that the strains caused by injecting into the aquifer could be measured at a depth of 30m and used to evaluate the properties of the aquifer. We recently expanded the array of strainmeters at the North Avant Field by deploying three more instruments at shallow depth (30m) along with a deep instrument at 520m depth in the winter, 2021. The deep instrument is deployed in shale caprock slightly above the aquifer. To our knowledge, the deep strainmeter at the North Avant Field is the deepest strainmeter ever deployed and this required refining methods originally developed for shallow deployments. The instrument was lowered to depth on oil field tubing and cemented in place using techniques and materials developed for use in oil wells. Optical fiber used to communicate with the instrument was cemented in the annulus on the outside of tubing. This is significant because the techniques we used could readily be extended to greater depth, suggesting that strainmeters can be deployed over a wide range of depths for monitoring critical subsurface processes. For example, it suggests that strainmeters could be deployed through the caprock to monitor for leaks from underlying CO2 storage reservoirs. The strainmeter array at the North Avant Field has been used to characterize deformation during a series of injection tests in the spring and summer, 2021. All the new strainmeters respond to pumping, and the strainmeters we installed earlier also responded. To our knowledge, this is the first application of well testing in a deep aquifer that was monitored by an array of strainmeters—our earlier work used strainmeters at a single location. We are currently analyzing the strain data using an analytical solution, a proxy-based Bayesian inversion algorithm, and other methods. Strainmeter data has also been used to characterize periodic pumping tests by us and Riley Blais. A periodically varying pumping rate causes both hydraulic head and strain signals that vary with the same period as the pumping. The peaks and troughs of the head in monitoring wells lag behind the peaks and troughs of the head in the pumping well, and this lag time increases with distance from the pumping well. The lag time of the pressure and the distance to the monitoring well can be used in a simple analysis to estimate the hydraulic diffusivity of the aquifer. The lag time determined from strain data can be used to estimate aquifer properties using the same analysis that works for the pressure only for strain data measured at particular locations. That is because the strain field in a confining unit advances upward, laterally and then downward even though the pressure in the underlying aquifer only advances laterally, according to our recent simulations. We have field data showing that a small periodic signal superimposed on an injection rate at the North Avant Field will create a periodic strain signal at shallow strainmeters. The field data and the recent simulations suggest that including a periodic component to injection or pumping and then monitoring the resulting strain signal could be a way to monitor the subsurface.

Murdoch, Larry↗

Recent Developments in Hydrogeologic Applications for Strain Tensor Analyses

Changes in fluid pressure deform porous media and this effect occurs in a variety of hydrogeologic processes, from the change in storage during pumping or injection to fluctuations in water levels caused by barometric pressure. We have developed instruments for measuring small strains in porous media, and we have used the resulting strain data to evaluate well testing, hydraulic fracturing, manual loading at the ground surface, and ambient hydrologic processes, like rainfall and evaporation. A particularly important application is the use of strain tensor data measured at shallow depths to analyze well tests or hydraulic fractures conducted at much greater depths. An early demonstration of this technique was conducted at the North Avant Field north of Tulsa, Oklahoma, where Pennsylvanian sandstone creates a confined aquifer and oil reservoir at a depth of 530m. We have showed that the strains caused by injecting into the aquifer could be measured at a depth of 30m and used to evaluate the properties of the aquifer. We recently expanded the array of strainmeters at the North Avant Field by deploying three more instruments at shallow depth (30m) along with a deep instrument at 520m depth in the winter, 2021. The deep instrument is deployed in shale caprock slightly above the aquifer. To our knowledge, the deep strainmeter at the North Avant Field is the deepest strainmeter ever deployed and this required refining methods originally developed for shallow deployments. The instrument was lowered to depth on oil field tubing and cemented in place using techniques and materials developed for use in oil wells. Optical fiber used to communicate with the instrument was cemented in the annulus on the outside of tubing. This is significant because the techniques we used could readily be extended to greater depth, suggesting that strainmeters can be deployed over a wide range of depths for monitoring critical subsurface processes. For example, it suggests that strainmeters could be deployed through the caprock to monitor for leaks from underlying CO2 storage reservoirs. The strainmeter array at the North Avant Field has been used to characterize deformation during a series of injection tests in the spring and summer, 2021. All the new strainmeters respond to pumping, and the strainmeters we installed earlier also responded. To our knowledge, this is the first application of well testing in a deep aquifer that was monitored by an array of strainmeters—our earlier work used strainmeters at a single location. We are currently analyzing the strain data using an analytical solution, a proxy-based Bayesian inversion algorithm, and other methods. Strainmeter data has also been used to characterize periodic pumping tests by us and Riley Blais. A periodically varying pumping rate causes both hydraulic head and strain signals that vary with the same period as the pumping. The peaks and troughs of the head in monitoring wells lag behind the peaks and troughs of the head in the pumping well, and this lag time increases with distance from the pumping well. The lag time of the pressure and the distance to the monitoring well can be used in a simple analysis to estimate the hydraulic diffusivity of the aquifer. The lag time determined from strain data can be used to estimate aquifer properties using the same analysis that works for the pressure only for strain data measured at particular locations. That is because the strain field in a confining unit advances upward, laterally and then downward even though the pressure in the underlying aquifer only advances laterally, according to our recent simulations. We have field data showing that a small periodic signal superimposed on an injection rate at the North Avant Field will create a periodic strain signal at shallow strainmeters. The field data and the recent simulations suggest that including a periodic component to injection or pumping and then monitoring the resulting strain signal could be a way to monitor the subsurface.

Murdoch, Larry↗

Datasets and U-Net Model for "A Deep Learning Based Framework to Identify Undocumented Orphaned Oil and Gas Wells from Historical Maps: a Case Study for California and Oklahoma"

This dataset has results and the model associated with the publication Ciulla et al., (2024). It contains a U-Net semantic segmentation model (unet_model.h5) and associated code implemented in tensorflow 2.0 for the model training and identification of oil and gas well symbols in USGS historical topographic maps (HTMC). Given a quadrangle map (7.5 minutes), downloadable at this url: https://ngmdb.usgs.gov/topoview/, and a list of coordinates of the documented wells present in the area, the model returns the coordinates of oil and gas symbols in the HTMC maps. For reproducibility of our workflow, we provide a sample map in California and the documented well locations for the entire State of California (CalGEM_AllWells_20231128.csv) downloaded from https://www.conservation.ca.gov/calgem/maps/Pages/GISMapping2.aspx. Additionally, the locations of 1,301 potential undocumented orphaned wells identified using our deep learning framework or the counties of Los Angeles and Kern in California, and Osage and Oklahoma in Oklahoma are provided in the file found_potential_UOWs.zip. The results of the visual inspection of satellite imagery in Osage County is in the file visible_potential_UOWs.zip. The dataset also includes a custom tool to validate the detected symbols in the HTMC maps (vetting_tool.py). More details about the methodology can be found in the associated paper: Ciulla, F., Santos, A., Jordan, P., Kneafsey, T., Biraud, S.C., and Varadharajan, C. (2024) A Deep Learning Based Framework to Identify Undocumented Orphaned Oil and Gas Wells from Historical Maps: a Case Study for California and Oklahoma. Accepted for publication in Environmental Science and Technology. The geographical coordinates provided correspond to the locations of potential undocumented orphaned oil and gas wells (UOWs) extracted from historical maps. The actual presence of wells need to be confirmed with on-the-ground investigations. For your safety, do not attempt to visit or investigate these sites without appropriate safety training, proper equipment, and authorization from local authorities. Approaching these well sites without proper personal protective equipment (PPE) may pose significant health and safety risks. Oil and gas wells can emit hazardous gasses including methane, which is flammable, odorless and colorless, as well as hydrogen sulfide, which can be fatal even at low concentrations. Additionally, there may be unstable ground near the wellhead that may collapse around the wellbore. This dataset was prepared as an account of work sponsored by the United States Government. While this document is believed to contain correct information, neither the United States Government nor any agency thereof, nor the Regents of the University of California, nor any of their employees, makes any warranty, express or implied, or assumes any legal responsibility for the accuracy, completeness, or usefulness of any information, apparatus, product, or process disclosed, or represents that its use would not infringe privately owned rights. Reference herein to any specific commercial product, process, or service by its trade name, trademark, manufacturer, or otherwise, does not necessarily constitute or imply its endorsement, recommendation, or favoring by the United States Government or any agency thereof, or the Regents of the University of California. The views and opinions of authors expressed herein do not necessarily state or reflect those of the United States Government or any agency thereof or the Regents of the University of California.

Artificial Intelligence↗

Air quality impacts from the development of unconventional oil and gas well pads: Air toxics and other volatile organic compounds

Unconventional oil and natural gas development (UOGD) has expanded rapidly across the United States in recent decades and raised concerns about associated air quality impacts. While significant effort has been made to quantify methane emissions, relatively few observations have been made of Volatile Organic Compounds (VOCs), especially during drilling and completion of new wells. Extensive air monitoring during development of several large, multi-well pads in Broomfield, Colorado, in the Denver-Julesburg Basin, provides a novel opportunity to examine changes in local air toxics and other VOC concentrations during well drilling and completions and production. These operations offer an especially useful case to study as several management practices were implemented to reduce emissions (e.g., electrified, grid-powered drill rigs and closed loop fluid handling systems to reduce truck traffic and limit fluid handling on the pad). With simultaneous measurements of methane and 50 VOCs from October 2018 to December 2022 at as many as 19 sites near well pads, in adjacent neighborhoods, and at a more distant reference location, we identify impacts from each phase of well development and production. Use of weekly, time-integrated canisters, a Proton Transfer Reaction Mass Spectrometer (PTR-MS), continuous photoionization detectors (PID) to trigger canister collection upon detection of VOC-rich plumes, and an instrumented vehicle, provided a powerful suite of measurements to characterize both transient plumes and longer-term changes in air quality. Prior to the start of well development, VOC gradients were small across Broomfield. Once drilling commenced, concentrations of oil and gas (O&G) related VOCs, including alkanes and aromatics, increased around active well pads. Concentration increases were clearly apparent during certain operations, including drilling, coil tubing/millout operations, and production tubing installation. Emissions of C 8 –C 10 n-alkanes during drilling operations highlighted the importance of VOC emissions from synthetic drilling mud chosen to reduce odor impacts. More than 90 samples were collected of transient plumes. Using composition measurements, meteorological data, and information about well pad activities, these plumes were connected with specific UOGD operations including drilling, flowback, and production equipment maintenance. The chemical signatures of these plumes differed by operation type (e.g., C 8 –C 10 n-alkanes constituted a larger fraction of measured VOCs in drilling-related plumes). Concentrations of individual, oil and gas-related VOCs in these plumes were often several orders of magnitude higher than in background air, with maximum ethane and benzene concentrations of 79,600 and 819 ppbv, respectively. Because these plumes typically impact a monitoring site for just several minutes, they are easily missed by slower-responding instruments. Study measurements highlight future emission mitigation opportunities during UOGD operations, including better control of emissions from shakers that separate drill cuttings from drilling mud, production separator maintenance operations, and periodic emptying of sand cans during flowback operations.

54 ENVIRONMENTAL SCIENCES↗

Distributed electric field sensing using fibre optics in borehole environments

In the past decade, rapid advances in distributed optical fibre sensing technologies have made it possible to record various geophysical data (e.g. strain, temperature and pressure) continuously in both time and space along the fibre, providing an unprecedented quantity and spatial density of data compared to traditional geophysical measurements as well as reducing data acquisition cost. To date, no distributed fibre-based electromagnetic field sensing system has been implemented although electromagnetic sensing could have a broad range of applications to geophysical imaging and monitoring in borehole environments. The goal of this paper is to provide a theoretical feasibility study regarding the design and use of an electromagnetic sensing optical fibre for geophysical applications. First, we present the sensitivity analysis of a ‘hypothetical’ optical fibre coated with polyvinylidene fluoride, a polymer that provides relatively high piezoelectric properties, yet unlike ceramics, is flexible. Next, using a two-dimensional electromagnetic modelling algorithm, we simulate the earth electric-field-to-fibre-strain transfer function and estimate the theoretical sensitivity of the optical fibre to electric fields. Given the state-of-the-art distributed acoustic sensing strain sensitivities in the picometres strain range, our numerical modelling analysis suggests that a perfectly coupled polyvinylidene fluoride–coated optical fibre can measure electric field values in the mV/m to V/m amplitude range. We then apply a cylindrically symmetric modelling algorithm to simulate numerical models demonstrating the applicability of such a fibre in an oilfield environment. Scenarios investigated employ an electric field source and suggest that the measurements can be used to distinguish the oil versus water ratio with a fibre mounted inside a producing steel cased oil well as well as distinguishing between brine and hydrocarbon filled reservoir zones with a fibre located outside of the casing.

58 GEOSCIENCES↗

Orphaned oil and gas well methane emission rates quantified using Gaussian plume inversions of ambient observations

Abstract. Annually, ∼ 3.6 million abandoned oil and gas wells in the US emit a combined ∼ 2.6 Tg methane (CH4), adversely affecting climate and regional air quality. However, these estimates depend on emission factors derived from measuring subpopulations of wells that vary by orders of magnitude due to very limited field sampling and poorly characterized distributions. Currently, US protocols to remediate orphaned wells lacks standardized quantification methods needed to both prioritize plugging and account for emission reductions. Therefore, sensitive, reliable, affordable, and scalable CH4 flux quantification methods are needed. We report the use of a simple Gaussian plume method where the dispersion parameters are constrained by in situ ground measurements of CH4 concentration at four locations 7.5–49 m downwind of the orphan well as well as local winds to estimate the leak rate from an orphan well. We derive a flux of 10.53 ± 1.16 kg CH4 h−1 during a venting procedure in April 2023 that agrees with the directly measured volumetric flow rate of 9.00 ± 0.25 kg CH4 h−1. This is 71 % greater than the 5.3 kg CH4 h−1 flux measured 7 months prior. Additionally, we discovered a secondary leak through the surface casing inferred as 0.43–0.67 kg CH4 h−1 both by our ground Gaussian analysis and by transecting the plume with an uncrewed aerial system (UAS). We show that in situ determination of the dispersion parameters used in our Gaussian inversions allows us to measure methane emissions to 15 % accuracy, significantly reducing errors when compared to the standard practice of assuming stability class. Our results help develop simpler methods and protocols for robust orphan well emission quantification that can be used for reporting.

Follansbee, Emily↗