Search NASA⌕ Search

SEARCH · Search NASA

Results for “ozonesondes”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 37 records · Page 2
All sourcesNASA NTRSDOE OSTI
NASA NTRS2003

Accuracy and Precision in the Southern Hemisphere Additional Ozonesondes (SHADOZ) Dataset 1998-2000 in Light of the JOSIE-2000 Results

A network of 12 southern hemisphere tropical and subtropical stations in the Southern Hemisphere ADditional OZonesondes (SHADOZ) project has provided over 2000 profiles of stratospheric and tropospheric ozone since 1998. Balloon-borne electrochemical concentration cell (ECC) ozonesondes are used with standard radiosondes for pressure, temperature and relative humidity measurements. The archived data are available at:http: //croc.gsfc.nasa.gov/shadoz. In Thompson et al., accuracies and imprecisions in the SHADOZ 1998- 2000 dataset were examined using ground-based instruments and the TOMS total ozone measurement (version 7) as references. Small variations in ozonesonde technique introduced possible biases from station-to-station. SHADOZ total ozone column amounts are now compared to version 8 TOMS; discrepancies between the two datasets are reduced 2\% on average. An evaluation of ozone variations among the stations is made using the results of a series of chamber simulations of ozone launches (JOSIE-2000, Juelich Ozonesonde Intercomparison Experiment) in which a standard reference ozone instrument was employed with the various sonde techniques used in SHADOZ. A number of variations in SHADOZ ozone data are explained when differences in solution strength, data processing and instrument type (manufacturer) are taken into account.

Witte, J. C.↗
NASA NTRS2004

Insights into Tropospheric Ozone from the INTEX Ozonesonde Network Study (IONS)

Ozone profile data from soundings integrate models, aircraft and other ground-based measurements for better interpretation of atmospheric chemistry and dynamics. A well-designed network of ozonesonde stations, with consistent sampling, can answer questions not possible with short campaigns or current satellite technology. The SHADOZ (Southern Hemisphere Additional Ozonesondes) project, for example, has led to these findings about tropical ozone: definition of the zonal tropospheric wave-one pattern in equatorial ozone, characterization of the "Atlantic ozone paradox" and establishment of a link between tropical Atlantic and Indian Ocean pollution. Building on the SHADOZ concept, a short-term ozone network was formed in July-August 2004 to coordinate ozonesonde launches during the ICARTT/INTEX/NEAQS (International Consortium on Atmospheric Research on Transport and Transformation)/Intercontinental Transport Experiment/New England Air Quality Study. In IONS (INTEX Ozonesonde Network Study), more than 250 soundings, with daily frequency at half the sites, were launched from eleven North American stations and an oceanographic ship in the Gulf of Maine. Although the goal was to examine pollution influences under stable high-pressure systems and transport associated with "warm conveyor belt" flows, the INTEX study region was dominated by a series of weak frontal system that mixed aged pollution with stratospheric ozone in the middle troposphere. Deconvoluting ozone sources provides new insights into ozone in the transition between mid-latitude and polar air.

Thompson, Anne M.↗
NASA NTRS2007

Validation of Aura Microwave Limb Sounder Ozone by Ozonesonde and Lidar Measurements

We present validation studies of MLS version 2.2 upper tropospheric and stratospheric ozone profiles using ozonesonde and lidar data as well as climatological data. Ozone measurements from over 60 ozonesonde stations worldwide and three lidar stations are compared with coincident MLS data. The MLS ozone stratospheric data between 150 and 3 hPa agree well with ozonesonde measurements, within 8% for the global average. MLS values at 215 hPa are biased high compared to ozonesondes by approximately 20% at middle to high latitude, although there is a lot of variability in this altitude region.

validation studies↗
NASA NTRS2018

Evaluation of MERRA-2-Based Ozone Profile Simulations with the Global Ozonesonde Network

Chemical transport model (CTM) hindcasts of ozone (O3) are useful for filling in observational gaps and providing context for observed O3 variability and trends. We use global networks of ozonesonde stations to evaluate the O3 profiles in two simulations running versions of the NASA Global Modeling Initiative (GMI) chemical mechanism. Both simulations are tied to the NASA Modern-Era Retrospective analysis for Research and Applications, Version 2 (MERRA-2) meteorological reanalysis: 1) The GMI CTM, and 2) The MERRA-2 GMI Replay (M2 GMI). Both simulations start in 1980, and are compared against >50,000 ozonesonde profiles from 37 global stations from the tropics to the poles. The comparisons allow us to evaluate how the Replay technique affects modeled O3 distribution, how an updated chemical mechanism in the GMI CTM affects simulated tropospheric O3 amounts, and how observed O3 distributions compare to the full set of model output. In general, M2 GMI O3 is ~10% higher than in the GMI CTM, and shows global near-surface and tropical upper troposphere/lower stratosphere (UT/LS) high biases. The updated chemical mechanism in the GMI CTM reduces these high biases. Both simulations show similar negative biases in tropical free-tropospheric O3, especially during typical biomass burning seasons. The simulations are highly-correlated with ozonesonde measurements, particularly in the UT/LS (r > 0.8), showing the ability of MERRA-2 to capture tropopause height variations. Both simulations show improved correlations with ozonesonde data and smaller O3 biases in recent years. We expect to use the sonde/model comparisons to diagnose causes of disagreement and to gauge the feasibility of calculating multidecadal O3 trends from the model output.

Stauffer, Ryan↗
NASA NTRS2018

Evaluation of MERRA-2-Based Ozone Profile Simulations with the Global Ozonesonde Network

Chemical transport model (CTM) hindcasts of ozone (O3) are useful for filling in observational gaps and providing context for observed O3 variability and trends. We use global networks of ozonesonde stations to evaluate the O3 profiles in two simulations running versions of the NASA Global Modeling Initiative (GMI) chemical mechanism. Both simulations are tied to the NASA Modern-Era Retrospective analysis for Research and Applications, Version 2 (MERRA-2) meteorological reanalysis: 1) The GMI CTM, and 2) The MERRA-2 GMI Replay (M2 GMI). Both simulations start in 1980, and are compared against >50,000 ozonesonde profiles from 37 global stations from the tropics to the poles. The comparisons allow us to evaluate how the Replay technique affects modeled O3 distribution, how an updated chemical mechanism in the GMI CTM affects simulated tropospheric O3 amounts, and how observed O3 distributions compare to the full set of model output. In general, M2 GMI O3 is ~10% higher than in the GMI CTM, and shows global near-surface and tropical upper troposphere/lower stratosphere (UT/LS) high biases. The updated chemical mechanism in the GMI CTM reduces these high biases. Both simulations show similar negative biases in tropical free-tropospheric O3, especially during typical biomass burning seasons. The simulations are highly-correlated with ozonesonde measurements, particularly in the UT/LS (r > 0.8), showing the ability of MERRA-2 to capture tropopause height variations. Both simulations show improved correlations with ozonesonde data and smaller O3 biases in recent years. We expect to use the sonde/model comparisons to diagnose causes of disagreement and to gauge the feasibility of calculating multidecadal O3 trends from the model output.

Stauffer, Ryan M.↗
NASA NTRS2022

An Examination of the Recent Stability of Ozonesonde Global Network Data

The recent Assessment of Standard Operating Procedures for OzoneSondes (ASOPOS 2.0; WMO/GAW Report #268) addressed questions of homogeneity and long-term stability in global electrochemical concentration cell (ECC) ozone sounding network time series. Among its recommendations was adoption of a standard for evaluating data quality in ozonesonde time series. Total column ozone (TCO) derived from the sondes compared to TCO from Aura’s Ozone Monitoring Instrument (OMI) is a primary quality indicator. Comparisons of sonde ozone with Aura’s Microwave Limb Sounder (MLS) are used to assess the stability of stratospheric ozone. This paper provides a comprehensive examination of global ozonesonde network data stability and accuracy since 2004 in light of the sudden post-2013 TCO “dropoff” of ~3-4% that was reported previously at select stations (Stauffer et al., 2020). Comparisons with Aura OMI TCO averaged across the network of 60 stations are stable within about ±2% over the past 18 years. Sonde TCO has similar stability compared to three other TCO satellite instruments, and the stratospheric ozone measurements average to within ±5% of MLS from 50 to 10 hPa. Thus, sonde data are reliable for trends, but with a caveat applied for a subset of dropoff stations in the tropics and subtropics. The dropoff is associated with only one of two major ECC instrument types. A detailed examination of ECC serial numbers pinpoints the timing of the dropoff. However, we find that overall, ozonesonde data are stable and accurate compared to independent measurements over the past two decades.

Ryan M. Stauffer↗
NASA NTRS2017

Tropospheric Ozonesonde Profiles at Long-Term U.S. Monitoring Sites: 2. Links Between Trinidad Head, CA, Profile Clusters and Inland Surface Ozone Measurements

Much attention has been focused on the transport of ozone (O3) to the western U.S., particularly given the latest revision of the National Ambient Air Quality Standard to 70 parts per billion by volume (ppbv) of O3. This makes quantifying the contributions of stratosphere-to-troposphere exchange, local pollution, and pollution transport to this region essential. To evaluate free-tropospheric and surface O3 in the western U.S., we use self-organizing maps to cluster 18 years of ozonesonde profiles from Trinidad Head, CA. Three of nine O3 mixing ratio profile clusters exhibit thin laminae of high O3 above Trinidad Head. The high O3 layers are located between 1 and 6 km above mean sea level and reside above an inversion associated with a northern location of the Pacific subtropical high. Ancillary data (reanalyses, trajectories, and remotely sensed carbon monoxide) help identify the high O3 sources in one cluster, but distinguishing mixed influences on the elevated O3 in other clusters is difficult. Correlations between the elevated tropospheric O3 and surface O3 at high-altitude monitors at Lassen Volcanic and Yosemite National Parks, and Truckee, CA, are marked and long lasting. The temporal correlations likely result from a combination of transport of baseline O3 and covarying meteorological parameters. Days corresponding to the high O3 clusters exhibit hourly surface O3 anomalies of +5-10 ppbv compared to a climatology; the positive anomalies can last up to 3 days after the ozonesonde profile. The profile and surface O3 links demonstrate the importance of regular ozonesonde profiling at Trinidad Head.

STE↗
NASA NTRS2020

A New Method to Correct the Electrochemical Concentration Cell (ECC) Ozonesonde Time Response and its Implications for "Background Current" and Pump Efficiency

The electrochemical concentration cell (ECC) ozonesonde has been the main instrument for in situ profiling of ozone worldwide; yet, some details of its operation, which contribute to the ozone uncertainty budget, are not well understood. Here, we investigate the time response of the chemical reactions inside the ECC and how corrections can be used to remove some systematic biases. The analysis is based on the understanding that two reaction pathways involving ozone occur inside the ECC that generate electrical currents on two very different timescales. The main fast-reaction pathway with a time constant of about 20 s is due the conversion of iodide to molecular iodine and the generation of two free electrons per ozone molecule. A secondary slow-reaction pathway involving the buffer generates an excess current of about 2 %–10 % with a time constant of about 25 min. This excess current can be interpreted as what has conventionally been considered the “background current”. This contribution can be calculated and removed from the measured current instead of the background current. Here we provide an algorithm to calculate and remove the contribution of the slow-reaction pathway and to correct for the time lag of the fast-reaction pathway. This processing algorithm has been applied to ozonesonde profiles at Costa Rica and during the Central Equatorial Pacific Experiment (CEPEX) as well as to laboratory experiments evaluating the performance of ECC ozonesondes. At Costa Rica, where a 1 % KI, 1/10th buffer solution is used, there is no change in the derived total ozone column; however, in the upper troposphere and lower stratosphere, average reported ozone concentrations increase by up to 7 % and above 30 km decrease by up to 7 %. During CEPEX, where a 1 % KI, full-buffer solution was used, ozone concentrations are increased mostly in the upper troposphere, with no change near the top of the profile. In the laboratory measurements, the processing algorithms have been applied to measurements using the majority of current sensing solutions and using only the stronger pump efficiency correction reported by Johnson et al. (2002). This improves the accuracy of the ECC sonde ozone profiles, especially for low ozone concentrations or large ozone gradients and removes systematic biases relative to the reference instruments. In the surface layer, operational procedures prior to launch, in particular the use of filters, influence how typical gradients above the surface are detected. The correction algorithm may report gradients that are steeper than originally reported, but their uncertainty is strongly influenced by the prelaunch procedures.

electrochemical concentration cell (ECC) ozonesond↗
NASA NTRS2020

A Post-2013 Dropoff in Total Ozone at a Third of Global Ozonesonde Stations: Electrochemical Concentration Cell Instrument Artifacts?

An international effort to improve ozonesonde data quality and to reevaluate historical recordshas made significant improvements in the accuracy of global network data. However, between 2014 and2016, ozonesonde total column ozone (TCO; O3) at 14 of 37 regularly reporting stations exhibited a suddendropoff relative to satellite measurements. The ozonesonde TCO drop is 3–7% compared to satellite andground‐based TCO, and 5–10% or more compared to satellite stratospheric O3profiles, compromising theuse of recent data for trends, although they remain reliable for other uses. Hardware changes in theozonesonde instrument are likely a major factor in the O3dropoff, but no single property of the ozonesondeexplains thefindings. The bias remains in recent data. Research to understand the dropoff is in progress; thisletter is intended as a caution to users of the data. Ourfindings underscore the importance of regularozonesonde data evaluation.

ozonesonde TCO drop↗
NASA NTRS2022

Homogenization of the Observatoire de Haute Provence electrochemical concentration cell (ECC) ozonesonde data record: comparison with lidar and satellite observations

The Observatoire de Haute Provence (OHP) weekly Electrochemical Concentration Cell (ECC) ozonesonde data have been homogenized for the period 1991-2021 according to the recommendations of the Ozonesonde Data Quality Assessment (O3S-DQA) panel. The assessment of the ECC homogenization benefit has been carried out using comparisons with other ozone measuring ground based instruments at the same station (lidar, surface measurements) and with collocated satellite observations of the O3vertical profile by Microwave Limb Sounder (MLS). The major differences between uncorrected and5homogenized ECC data are related to a change of ozonesonde type in 1997, removal of the pressure dependency of the ECC background current and correction of internal pump temperature. The original 3-4 ppbv positive bias between ECC and Lidar in the troposphere is corrected with the homogenization. The ECC 30-years trends of the seasonally adjusted ozone concentrations are also significantly improved in both the troposphere and the stratosphere after the ECC homogenization, as shown by the ECC/lidar or ECC/surface ozone trend comparisons. A -0.19% per year negative trend of the normalization factor (NT)10calculated using independent measurements of the total ozone column (TOC) at OHP disappears after homogenization of the ECC data. There is however a remaining -3.7% negative bias in the TOC which is likely related to an underestimate of the ECC concentrations in the stratosphere above 50 hPa. Differences between TOC measured by homogenized ECC and satellite observations show a smaller bias of -1%. Comparisons between homogenized ECC and OHP stratospheric lidar and MLS observations below 26 km are slightly negative (-2%) or positive (+2%), respectively. Both the comparisons with lidar and15satellite observations suggest that homogenization increases the negative bias of the ECC to values lower than -6% above 28km. The reason for this bias is still unclear, but a possible explanation might be related to freezing or evaporation of the sonde solution in the stratosphere.

Ozonesondes↗
NASA NTRS2022

Validations of Satellite Ozone Profiles in Austral Spring Using Ozonesonde Measurements in the Jang Bogo Station, Antarctica

Using ozonesonde measurements from 2015 to 2018 at the Jang Bogo station located in the southeastern Antarctic region, we evaluate ozone profiles retrieved from the three satellite measurements that are widely used: Ozone Monitoring Instrument (OMI), Microwave Limb Sounder (MLS), and Ozone Mapping Profiler Suite (OMPS) data. For the fair validation, ozonesonde profiles are smoothed using the weighting function of each satellite retrieval algorithm (i.e., convolution process). Compared with limb-viewing MLS and OMPS ozone profiles, the OMI ozone profiles are relatively less qualified: coarser vertical resolution and larger inter-annual variation. Nevertheless, our validation reveals that the quality of all three satellite ozone profiles looks comparable; In general, difference from ozonesonde profile is ∼1 ppm absolutely, and −20 to 30% relatively at maximum. This quantitative range well corresponds to previous work, meaning that our new validation confirms the reliability of satellite ozone profiles in the southeastern Antarctic region where the measurement data for the validation were not enough. Another interesting feature is the role of a priori ozone profile; Nadir-viewing OMI satellite can have qualified ozone profiles by a proper assumption of a priori ozone profile. Since the performance of limb-viewing ozone profiles is better, however, the careful usage of nadir-viewing ozone profile is still required. We think that the simultaneous usage of multiple satellite ozone profiles can contribute to better understanding of Antarctic ozone characteristics.

Antarctica↗
DOE OSTI2023

TRACER-Sonde Ozonesonde and radiosonde data

The TRACER-Sonde campaign used electrochemical cell ozonesondes to measure vertical profiles of ozone, which can be a tracer for convective mixing, in conjunction with meteorological variables measured by a radiosonde. There were 32 days in which TRACER-Sonde had twice-daily ozonesondes from the TRACER M1 site at La Porte at ~11Z and ~15Z (6 am and 10 am LT). The ozonesonde profiles provide an additional method to validate boundary-layer height determinations and test assumptions about vertical mixing in pre-convective environments. There are six additional days with ~15Z radiosonde only (no ozone data) profiles.

54 ENVIRONMENTAL SCIENCES↗
NASA NTRS1977

Performance evaluation of electrochemical concentration cell ozonesondes

Laboratory calibrations of more than a hundred electrochemical concentration cell (ECC) ozonesondes were determined relative to UV-photometry. The average intercept and slope, 0 plus or minus 5 nb and 0.96 plus or minus 0.06, respectively, indicate reasonable agreement with UV photometry, but with considerable variation from one ECC ozonesonde to another. The time required to reach 85% of the final reaction to a step-change in ozone concentration was found to average 51 seconds. Application of the individual calibrations to 20 sets of 1976 flight data reduced the average of the differences between ozonesonde and Dobson spectrophotometric measurements of total ozone from 3.9 to 1.3%. A similar treatment of a set of 10 1977 flight records improved the average ECC-Dobson agreement from -8.5 to -1.4%. Although systematic differences were reduced, no significant effect on the random variations was evident.

Torres, A. L.↗
NASA NTRS1977

Electrochemical concentration cell ozonesonde performance evaluation

A large number of electrochemical concentration cell (EDD) ozonesondes were calibrated relative to ultraviolet photometric absorption (254 nm) to determine their precision and accuracy. The average agreement with UV photometry was found to be good, but with considerable variation from one ECC ozonesonde to another. Applying individual calibrations to vertical ozone profiles reduced the systematic differences between ECC ozonesonde total ozone values and Dobson spectrophotometric determinations of the same quantity, but did not improve random differences.

Torres, A. L.↗
NASA NTRS1986

A statistical trend analysis of ozonesonde data

A detailed statistical analysis of monthly averages of ozonesond readings is performed to assess trends in ozone in the troposphere and the lower to midstratosphere. Regression time series models, which include seasonal and trend factors, are estimated for 13 stations located mainly in the midlatitudes of the Northern Hemisphere. At each station, trend estimates are calculated for 14 'fractional' Umkehr layers covering the altitude range from 0 to 33 km. For the 1970-1982 period, the main findings indicate an overall negative trend in ozonesonde data in the lower stratosphere (15-21 km) of about -0.5 percent per year, and some evidence of a positive trend in the troposphere (0-5 km) of about 0.8 percent per year. An in-depth sensitivity study of the trend estimates is performed with respect to various correction procedures used to normalize ozonesonde readings to Dobson total ozone measurements. The main results indicate that the negative trend findings in the 15- to 21-km altitude region are robust to the normalization procedures considered.

Tiao, G. C.↗
NASA NTRS1988

The UW digital ozonesonde: Characteristics and flow rate calibration

During the austral springs of 1986 and 1987, a series of balloon soundings were conducted to characterize the temporal and vertical development of Antarctic ozone depletion using the electrochemical concentration cell method (ECC). An important part of this study was to perform correlative studies between ozone and aerosol particles. In order to facilitate these simultaneous measurements, a digital ozonesonde system was developed to interface with aerosol counters. The ozone measurements will be described herein. The ozonesonde modification was accomplished by converting the current output of the sonde to a frequency and adding this digital signal to the serial data stream of a Vaisala Corporation RS-80 radiosonde under microprocessor control. A number of advantages over the standard ozonesonde system currently in use are noted.

Harder, J. W.↗
NASA NTRS2008

An Automated Method for Ozonesonde Calibration: New Insights

An automated method for preparation of the electrochemical concentration cell (ECC) ozonesonde is presented. Development of a computer-controlled system for preparation and calibration of the ECC is an improvement over the manual preparation method, and reduces subjectivity considerably. Preparation measurements in digital form aids analysis of the ECC before release and enhances post-flight data certification. Calibration of ozonesondes over a range of ozone concentrations between 0 mPA and 30 mPA is discussed. This presentation describes the automatic system, gives examples of calibrations. The automated system enables comparison of varying potassium iodide (KI) concentrations that should allow adjustment of earlier ozonesonde data obtained with different KT concentrations used since 1970, i.e., 2, 1.5, 1, and 0.5 percent. Preliminary results indicate ECC accuracy has a strong dependence on the electrolyte concentration and should not be considered linear with altitude.

Schmidlin, F. J.↗
NASA NTRS2020

Estimating Wildfire-Generated Ozone Over North America Using Ozonesonde Profiles and a Differential Back Trajectory Technique

An objective method, employing HYSPLIT back-trajectories and Moderate Resolution Imaging Spectroradiometer (MODIS) fire observations, is developed to estimate ozone enhancement in air transported from regions of active forest fires at 18 ozone sounding sites located across North America. The Differential Back Trajectory (DBT) method compares mean differences between ozone concentrations associated with fire-affected and fire-unaffected parcels. It is applied to more than 1100 ozonesonde profiles collected from these sites during the summer months June to August, 2006, 2008, 2010 and 2011. Layers of high ozone associated with low humidity were first removed from the ozonesonde profiles to minimize the potential effects of stratospheric intrusions on the calculations. No significant influence on average ozone levels by North American fires was found for stations located at Arctic latitudes. The ozone enhancement for stations nearer large fires, such as Trinidad Head and Bratt’s Lake, was up to 324.8% of the TTOC (Total Tropospheric Ozone Column). Fire ozone accounted for up to 8.3% of TTOC at downwind sites such as Yarmouth, Sable Island, Narragansett, and Walsingham. The results are consistent with other studies that have reported an increase in ozone production with the age of the smoke plume.

Moderate Resolution Imaging Spectroradiometer (MOD↗