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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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NASA NTRS1989

Rotation of the photospheric magnetic fields: A north-south asymmetry

During most of solar cycle 21 the large-scale photospheric field rotated more rapidly in the Northern Hemisphere than in the southern. The large-scale northern field rotated with a 26.9 day period (synodic), was centered at 15 degress N, and covered a latitude zone about 24 degrees wide. The large-scale southern field rotated with a periodicity of 28.1 days, was centered at 26 degrees S, and covered a latitude zone about 32 degrees wide. Our analysis showed rotational power at only a few discrete latitudes and frequencies in each hemisphere. The center of each peak lies near the sunspot differential rotation curve. The largest scale field contributes to the configuration of the coronal and interplanetary magnetic field (IMF). The strength of the first harmonic of the northern field suggests that this structure may be related to the 4-sector pattern observed in the IMF polarity. The southern field had much lower power at the first harmonic of the solar rotation rate and so would contribute only to a 2-sector structure in the IMF. These results were discovered in Fourier analysis of photospheric synoptic charts obtained at the Wilcox Solar Observatory from 1976 to 1986 and confirmed in higher resolution maps from the National Solar Observatory. Mt. Wilson magnetic field measurements from solar cycle 20 show a similar north-south asymmetry.

Antonucci, E.↗

NASA NTRS1990

Rotation of the photospheric magnetic fields - A north-south asymmetry

During most of solar cycle 21 the large-scale photospheric field rotated more rapidly in the Northern Hemisphere than in the southern. The large-scale northern field rotated with a 26.9 day period (synodic), was centered at 15 degrees N, and covered a latitude zone about 24 degrees wide. The large-scale southern field rotated with a periodicity of 28.1 days, was centered at 26 degrees S, and covered a latitude zone about 32 degrees wide. Our analysis showed rotational power at only a few discrete latitudes and frequencies in each hemisphere. The center of each peak lies near to the sunspot differential rotation curve. The largest scale field contributes to the configuration of the coronal and interplanetary magnetic field (IMF). The strength of the first harmonic of the northern field suggests that this structure may be related to the 4-sector pattern observed in the IMF polarity. The southern field had much lower power at the first harmonic of the solar rotation rate and so would contribute only to a 2-sector structure in the IMF. These results were discovered in Fourier analysis of photospheric synoptic charts obtained at the Wilcox Solar Observatory from 1976 to 1986 and confirmed in higher resolution maps from the National Solar Observatory. Mt. Wilson magnetic field measurements from solar cycle 20 show a similar north-south asymmetry.

Antonucci, E.↗

NASA NTRS2016

The Effect of Electrolyte Composition on Lithium Plating During Low Temperature Charging of Li-Ion Cells

In the present work, a number of additives have been investigated for their effect on the charge characteristics of cells containing low temperature, high ester content electrolytes (1.0 M LiPF6 in ethylene carbonate (EC) + ethyl methyl carbonate (EMC) + methyl propionate (MP) 20:20:60 vol % + X additive). These experimental three-electrode cells are composed of graphite anodes, LiNiCoAlO2 cathodes, and a lithium metal reference electrode. Cells were first subjected to electrochemical characterization at various temperatures, consisting of performing Electrochemical Impedance Spectroscopy (EIS), linear micropolarization and Tafel polarization measurement to determine the kinetic parameters for both the anodes and cathodes. Following electrochemical characterization, the cells were subjected to charging at decreasing temperatures using C/5 rates to 4.10V, with a constant potential C/50 current taper. Analysis of the C/20 discharge following the charge at low temperature revealed either the presence or absence of a high voltage plateau during the initial stages of the discharge. This plateau has been linked to the presence of lithium metal on the anode previously and was used as a measure for the extent of lithium plating in the cell. Differential analysis (dV/dQ) was applied as well to more clearly visualize the position of the high voltage plateau and use the peak position (x-axis) in the dV/dQ plot as a gauge for the amount of plating which took place in the cell on the prior charge. Most additives investigated increased the resistance of the anode and decreased the resistance of the cathode, thereby leading to an overall increase in plating observed at low temperature. One additive, LiFSI, was found to be beneficial during low temperature charging, however studies of electrode kinetics from the cell containing LiFSI did not reveal significant improvements compared to the baseline.

Jones, John-Paul↗

DOE OSTI2026

Quantitative Analysis and Prediction of Thermal Runaway Metrics of High-Nickel Oxide Cathodes by Machine Learning Models

The pursuit of higher energy density in lithium-ion batteries has made high-nickel (Ni) layered oxides leading cathode candidates for next-generation electric vehicles. However, their poor thermal stability, particularly at Ni contents ≥ 90%, increases the risk of cathode-initiated thermal runaway. Furthermore, we present a data-driven framework combining linear and nonlinear machine learning models to predict key thermal runaway descriptors from a high-throughput differential scanning calorimetry database. With cathode composition and state of charge (SOC) as input features, the ensemble model accurately predicts peak temperature, heat release, and peak heat flow. SHAP analysis identifies Ni content and SOC as the dominant factors controlling thermal runaway temperature, while SOC primarily governs heat release and peak heat flow. Al, Mg, and Mn improve thermal stability by strengthening metal–oxygen bonding and delaying structural transformation, whereas B mainly reduces heat release through surface passivation. Validation with a new cathode composition confirms accurate prediction of SOC-dependent thermal runaway behavior and critical SOC.

25 ENERGY STORAGE↗

NASA NTRS2004

Analysis of He I 1083 nm Imaging Spectroscopy Using a Spectral Standard

We develop a technique. for the analysis of He I 1083 nanometer spectra which addresses several difficulties through determination of a continuum background by comparison with a well calibrated standard and through removal of nearby solar and telluric blends by differential comparison to an average spectrum. The method is compared with earlier analysis of imaging spectroscopy obtained at the National Solar Observatory/Kitt Peak Vacuum Telescope (NSO/KPVT) with the NASA/NSO Spectromagnetograph (SPM). We examine distributions of Doppler velocity and line width as a function of central intensity for an active region, filament, quiet Sun, and coronal hole. For our example, we find that line widths and central intensity are oppositely correlated in a coronal hole and quiet Sun. Line widths are comparable to the quiet sun in the active region, are systematically lower in the filament, and extend to higher values in the coronal hole. Outward velocities of approximately equal to 2 to 4 kilometers per second are typically observed in the coronal hole. The sensitivity of these results to analysis technique is discussed.

Malanushenko, Elena V.↗

NASA NTRS1978

The thermal phase of a large solar flare

EUV and X-ray observations are used to derive the differential emission measures, temperatures, densities, radiative and conductive cooling rates, and thermal energy content of a class 2B flare that occurred on September 7, 1973. The results of the analysis indicate that (1) most of the flare plasma was at temperatures between 3 and 10 million degrees; (2) the peak temperature decreased with time from about 8 million K to 5 million K over a period of 3.5 hours; (3) the differential emission measure steadily decreased with time at nearly all temperatures; (4) both radiation and conduction were important cooling mechanisms for the plasma at temperatures above 100,000 K; and (5) a substantial amount of energy, of the order of 3 x 10 to the 31st power ergs, was deposited in the flare loops after flare maximum. The empirically determined flare parameters are compared with similar parameters derived from a simple theoretical loop model.

Withbroe, G. L.↗

DOE OSTI2022

Decay Curve Correction Analysis Report

The decay curve analysis that is done on the short-lived radionuclide gas samples is used to differentiate between gaseous radionuclides that have the same characteristic gamma decay energy, 511 kiloelectron-volts (keV). A sample of stack gas is isolated and the total counts in the 511 keV peak are counted repeatedly in 10-second intervals to evaluate the decay rate of the sample over time. Analysis of this decay data required a series of steps. First, a raw data report is generated by the gamma acquisition system, based on an analysis template within the acquisition software. The data report file was then loaded into Microsoft Word, and a macro was used to perform minor formatting (remove colons and insert tabs between data columns) to allow analysis within Excel. The file is then saved as a text file at this point. The text file is then uploaded into Excel and a series of macros are used to add labels, calculate radioactive decay constants, and analyze the gamma decay data using linear regression techniques. The analysis template has been used since 1998 for stack 53000303 (TA-53, building 0003, exhaust stack 03) and 2000 for stack 53000702. The overall process, including the gamma report format and the macros used in Word and Excel for processing the report, had remained unchanged until 2015. In October of 2015, staff made a change to the report template in the gamma acquisition software which resulted in an error in the calculations later performed by the Excel macro. This error was not caught until a more in-depth review of the analysis took place regarding 2020 data. This report covers a much more complete review of the issue that occurred regarding the decay curve analysis, a review of the calculations completed to correct the issue, a review of the updated decay curve analysis process, and recommendations for moving forward.

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗

DOE OSTI2020

Double-differential inclusive charged-current ν μ cross sections on hydrocarbon in MINERvA at ( E ν ) ~ 3.5 GeV

MINERvA reports inclusive charged-current cross sections for muon neutrinos on hydrocarbon in the NuMI beamline. We measured the double-differential cross section in terms of the longitudinal and transverse muon momenta, as well as the single-differential cross sections in those variables. The data used in this analysis correspond to an exposure of 3.34×10 20 protons on target with a peak neutrino energy of approximately 3.5 GeV. Measurements are compared to the GENIE, NuWro and GiBUU neutrino cross-section predictions, as well as a version of GENIE modified to produce better agreement with prior exclusive MINERvA measurements. None of the models or variants were able to successfully reproduce the data across the entire phase space, which includes areas dominated by each interaction channel.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗

NASA NTRS1991

Nucleation and crystallization of Na2O-2CaO-3SiO2 glass by differential thermal analysis

DTA is presently used to characterize the nucleation and crystallization processes of the Na2O-2CaO-3SiO2 glass. A nucleation rate-temperaturelike curve is obtained by plotting either the reciprocal of the temperature corresponding to the crystallization peak maximum, or the height of the crystallization peak, as a function of nucleation temperature. The nucleation-temperature range for this glass composition, 550-650 C, and the maximum nucleation temperature of 600 + or - 5 C, are found to be in excellent agreement with those associated with the classical nucleation technique, followed by isothermal crystallization. It is noted that when most of the nucleation occurs during the DTA measurements, a modified Kissinger equation must be used to calculate the crystallization energy.

Xu, Xiaojie J.↗

DOE OSTI2022

Conversion of (NH 4 ) 2 [ReF 6 ] into ReO 2 mixed phases: A thermal analysis study

We report the thermal behavior of (NH 4 ) 2 [ReF 6 ] was evaluated in an alumina crucible using simultaneous thermal gravimetric analysis (TGA) and differential scanning calorimetry (DSC) in an argon atmosphere. The TGA of (NH 4 ) 2 [ReF 6 ] is characterized by a single step decomposition while the DSC exhibits two exothermic peaks. Powder X-ray diffraction (PXRD) analyses of the decomposition products show the presence of a mixed ReO 2 phase. The formation of ReO2 is driven by the reaction of (NH 4 ) 2 [ReF 6 ] with Al 2 O 3 at the grain boundary of the alumina crucible. XRD peak broadenings due to the combined effect of crystallite size and lattice strain were evaluated using both Scherrer and Williamson-Hall methods.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

DOE OSTI2022

Inclusive and Inelastic Scattering in Neutrino-Nucleus Interactions

Neutrino-nucleus cross section measurements can provide both insights into nuclear physics and important data that can be used to improve model predictions used for neutrino oscillation physics. Two measurements of neutrino-nucleus cross sections were performed using data from the MINERvA experiment, each probing different classes of neutrino interactions. Double and single-differential flux-integrated measurements of inclusive charged current neutrino-nucleus cross sections at a peak neutrino energy of 3.5 GeV are presented as a function of the longitudinal and transverse momentum of the muon produced in the interaction. Additionally, an analysis of charged-current deep inelastic scattering (DIS) of muon neutrinos was performed in carbon, iron, lead and hydrocarbon in a neutrino beam with a peak energy of 6 GeV. Cross sections were measured in each material, and ratios were also taken between the cross sections of each of the materials and hydrocarbon, allowing for examination of nuclear dependencies of the neutrino cross section. Absolute DIS cross sections as a function of neutrino energy and flux integrated differential cross sections as a function of the Bjorken-x scaling variable were both measured.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗

NASA NTRS1995

A Preliminary Investigation of the Cr3Si-Mo Pseudo-Binary Phase Diagram

An investigation was undertaken to study the phase relations in Cr3Si alloyed with Mo varying from 10 to 83.5 wt. % of the material. Specimens were prepared from arc-melted buttons that were subsequently heat treated at 1673 K for 200 h and air quenched to room temperature to structures. Alloys containing more than 20 wt. % MO were primarily two-phase materials of M3Si and M5Si3, where M is (Cr,Mo). Three alloys contained less than 5% of a third phase, which also had the M5Si3 crystal structure. Differential thermal analysis (DTA) was performed on several specimens at temperatures up to 2073 K in order to determine a solidus curve for the M3Si phase. Since only one DTA peak was observed in each alloy, the M5Si3 phase must melt above 2073 K, the maximum temperature examined. A preliminary pseudo-binary phase diagram for (Cr,Mo)3Si and a portion of the 1673 K isothermal section of the Cr-Mo-Si ternary phase diagram are presented.

Dickerson, R. M.↗

NASA NTRS1971

Pyrotechnic hazards classification and evaluation program. Phase 3, segments 1-4: Investigation of sensitivity test methods and procedures for pyrotechnic hazards evaluation and classification, part A

The findings, conclusions, and recommendations relative to the investigations conducted to evaluate tests for classifying pyrotechnic materials and end items as to their hazard potential are presented. Information required to establish an applicable means of determining the potential hazards of pyrotechnics is described. Hazard evaluations are based on the peak overpressure or impulse resulting from the explosion as a function of distance from the source. Other hazard classification tests include dust ignition sensitivity, impact ignition sensitivity, spark ignition sensitivity, and differential thermal analysis.

Source record↗

DOE OSTI2020

Scalability of high-performance PDE solvers

Performance tests and analyses are critical to effective high-performance computing software development and are central components in the design and implementation of computational algorithms for achieving faster simulations on existing and future computing architectures for large-scale application problems. In this article, we explore performance and space-time trade-offs for important compute-intensive kernels of large-scale numerical solvers for partial differential equations (PDEs) that govern a wide range of physical applications. We consider a sequence of PDE-motivated bake-off problems designed to establish best practices for efficient high-order simulations across a variety of codes and platforms. We measure peak performance (degrees of freedom per second) on a fixed number of nodes and identify effective code optimization strategies for each architecture. In addition to peak performance, we identify the minimum time to solution at 80% parallel efficiency. The performance analysis is based on spectral and p-type finite elements but is equally applicable to a broad spectrum of numerical PDE discretizations, including finite difference, finite volume, and h-type finite elements.

97 MATHEMATICS AND COMPUTING↗

DOE OSTI2020

Estimation of Sorption Behavior of Europium to Calcium Silicate Hydrate by Thermal Analysis - 20172

High-level radioactive waste generated from reprocessing processes will be disposed in a geological disposal that is deep underground. Calcium silicate hydrate is formed as a secondary mineral in the repository via the reaction of calcium ions leaching from the cement and the silicic acid dissolved from the host rocks. In this study, the sorption behavior of europium, which is also known as a chemical analog of americium, on calcium silicate hydrate was examined. The solid phase was analyzed via thermogravimetry- differential thermal analysis, differential scanning calorimetry, Raman spectroscopy, fluorescence spectroscopy, and fluorescence lifetime analysis. To understand the behavior of calcium silicate hydrate under conditions saturated with groundwater, the study samples were analyzed using the above methods, except for deferential scanning calorimetry, without a drying process. The results of the differential scanning calorimetry analyses showed that the temperatures for the endothermic peaks of calcium silicate hydrate for the lower Ca/Si ratios were larger than those for the higher Ca/Si ratios for coexistent conditions of europium ions. Hence, the relationships of the temperatures of the endothermic peaks and the Ca/Si ratios were reversed by the addition of europium ions. These study results suggest that calcium silicate hydrate can immobilize europium ions, thus preventing the production of colloidal forms. (authors)

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

DOE OSTI2023

Differentiating Between Simultaneous Loss Drivers in Earth's Outer Radiation Belt: Multi‐Dimensional Phase Space Density Analysis

Abstract We analyzed the contribution of electromagnetic ion cyclotron (EMIC) wave driven electron loss to a flux dropout event in September 2017. The evolution of electron phase space density (PSD) through the dropout showed the formation of a radially peaked PSD profile as electrons were lost at high L* , resembling distributions created by magnetopause shadowing. By comparing 2D Fokker Planck simulations of pitch angle diffusion to the observed change in PSD, we found that the μ and K of electron loss aligned with maximum scattering rates at dropout onset. We conclude that, during this dropout event, EMIC waves produced substantial electron loss. Because pitch angle diffusion occurred on closed drift paths near the last closed drift shell, no radial PSD minimum was observed. Therefore, the radial PSD gradients resembled solely magnetopause shadowing loss, even though the local pitch angle scattering produced electron losses of several orders of magnitude of the PSD.

Staples, F. A.↗

DOE OSTI2021

Novel data analysis method for obtaining better performance from a complex 3D-printed collimator

Additively manufactured scattered beam collimators are increasingly being employed to boost the sample to cell peak signal ratio in high pressure neutron diffraction studies because of manufacturing versatility and performance improvements. We study how the measured diffraction pattern is affected by the presence of a collimator downstream of the sample, and develop a novel protocol that provides more effective background rejection. This protocol takes into account critical performance-determinants that were identified in this study, namely: (i) effectively identifying the collimator pattern on the detector; (ii) understanding the dependence of this pattern on sample and cell composition; and (iii) accurately identifying and differentiating the different regions of the pattern on the detector based on the dependency of the cell or sample and finally (iv) resolving the intensities at regions of the detector where neutrons scattered from the sample are preferentially represented, in order to boost the sample to cell peak signal ratio. Application of this novel analysis protocol is shown to increase the collimator performance over the traditional method.

3D printing↗

NASA NTRS1995

Gaussian statistics of the cosmic microwave background: Correlation of temperature extrema in the COBE DMR two-year sky maps

We use the two-point correlation function of the extrema points (peaks and valleys) in the Cosmic Background Explorer (COBE) Differential Microwave Radiometers (DMR) 2 year sky maps as a test for non-Gaussian temperature distribution in the cosmic microwave background anisotropy. A maximum-likelihood analysis compares the DMR data to n = 1 toy models whose random-phase spherical harmonic components a(sub lm) are drawn from either Gaussian, chi-square, or log-normal parent populations. The likelihood of the 53 GHz (A+B)/2 data is greatest for the exact Gaussian model. There is less than 10% chance that the non-Gaussian models tested describe the DMR data, limited primarily by type II errors in the statistical inference. The extrema correlation function is a stronger test for this class of non-Gaussian models than topological statistics such as the genus.

Kogut, A.↗