Epitaxial growth, characterization, and phase diagram of HgZnTe
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Smith, E. J.↗
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Defect Clustering and Nano-phase Structure Characterization of Multicomponent Rare Earth-Oxide-Doped Zirconia-Yttria Thermal Barrier Coatings
Advanced thermal barrier coatings (TBCs) have been developed by incorporating multicomponent rare earth oxide dopants into zirconia-based thermal barrier coatings to promote the creation of the thermodynamically stable, immobile oxide defect clusters and/or nanophases within the coating systems. In this paper, the defect clusters, induced by Nd, Gd, and Yb rare earth dopants in the zirconia-yttria thermal barrier coatings, were characterized by high-resolution transmission electron microscopy (TEM). The TEM lattice imaging, selected area diffraction (SAD), and electron energy-loss spectroscopy (EELS) analyses demonstrated that the extensive nanoscale rare earth dopant segregation exists in the plasma-sprayed and electron-physical-vapor-deposited (EB PVD) thermal barrier coatings. The nanoscale concentration heterogeneity and the resulting large lattice distortion promoted the formation of parallel and rotational defective lattice clusters in the coating systems. The presence of the 5-to 100-nm-sized defect clusters and nanophases is believed to be responsible for the significant reduction of thermal conductivity, improved sintering resistance, and long-term high temperature stability of the advanced thermal barrier coating systems.
Zhu, Dongming↗
Interface Consistency Phase I: Characterization and Measurement
See attached document.
Amanda L Smith↗
Optical Spectroscopy of New Materials
Composites are currently used for a rapidly expanding number of applications including aircraft structures, rocket nozzles, thermal protection of spacecraft, high performance ablative surfaces, sports equipment including skis, tennis rackets and bicycles, lightweight automobile components, cutting tools, and optical-grade mirrors. Composites are formed from two or more insoluble materials to produce a material with superior properties to either component. Composites range from dispersion-hardened alloys to advanced fiber-reinforced composites. UV/VIS and FTIR spectroscopy currently is used to evaluate the bonding between the matrix and the fibers, monitor the curing process of a polymer, measure surface contamination, characterize the interphase material, monitor anion transport in polymer phases, characterize the void formation (voids must be minimized because, like cracks in a bulk material, they lead to failure), characterize the surface of the fiber component, and measure the overall optical properties for energy balances.
White, Susan M.↗
Combined Cycle Engine Large-Scale Inlet for Mode Transition Experiments: System Identification Rack Hardware Design
The System Identification (SysID) Rack is a real-time hardware-in-the-loop data acquisition (DAQ) and control instrument rack that was designed and built to support inlet testing in the NASA Glenn Research Center 10- by 10-Foot Supersonic Wind Tunnel. This instrument rack is used to support experiments on the Combined-Cycle Engine Large-Scale Inlet for Mode Transition Experiment (CCE‒ LIMX). The CCE‒LIMX is a testbed for an integrated dual flow-path inlet configuration with the two flow paths in an over-and-under arrangement such that the high-speed flow path is located below the lowspeed flow path. The CCE‒LIMX includes multiple actuators that are designed to redirect airflow from one flow path to the other; this action is referred to as "inlet mode transition." Multiple phases of experiments have been planned to support research that investigates inlet mode transition: inlet characterization (Phase-1) and system identification (Phase-2). The SysID Rack hardware design met the following requirements to support Phase-1 and Phase-2 experiments: safely and effectively move multiple actuators individually or synchronously; sample and save effector control and position sensor feedback signals; automate control of actuator positioning based on a mode transition schedule; sample and save pressure sensor signals; and perform DAQ and control processes operating at 2.5 KHz. This document describes the hardware components used to build the SysID Rack including their function, specifications, and system interface. Furthermore, provided in this document are a SysID Rack effectors signal list (signal flow); system identification experiment setup; illustrations indicating a typical SysID Rack experiment; and a SysID Rack performance overview for Phase-1 and Phase-2 experiments. The SysID Rack described in this document was a useful tool to meet the project objectives.
Thomas, Randy↗
Hydrothermal alteration of CM carbonaceous chondrites: Implications of the identification of tochilinite as one type of meteoritic PCP
Poorly characterized phases (PCP's) constitute up to 30 volume percent of some CM carbonaceous chondrites, and are therefore an important key to an understanding of the physico-chemical conditions attending matrix evolution. An iron rich form of the terrestrial phase tochilinite was recently identified as a common type of PCP. Tochilinite has the general formula 6Fe(0.9)S.5(Mg,Fe)(OH)2 and consists of alternating machinawite (FeS) and brucite ((Mg,Fe)(OH)2) sheets, with iron vacancies in the sulfide sheets. In iron rich tochilinite, ferrous hydroxide, called amakinite, replaces brucite. If CM carbonaceous kchondrites have underdone hydrothermal alteration, iron rich tochilinite, at least, probably grew from aqueous solutions characterized by low FO2, high FS2, pH 10 to 12, and at a temperature at or below 170 C.
Zolensky, M. E.↗
Characterizing DebriSat Fragments: So Many Fragments, So Much Data, and So Little Time
To improve prediction accuracy, the DebriSat project was conceived by NASA and DoD to update existing standard break-up models. Updating standard break-up models require detailed fragment characteristics such as physical size, material properties, bulk density, and ballistic coefficient. For the DebriSat project, a representative modern LEO spacecraft was developed and subjected to a laboratory hypervelocity impact test and all generated fragments with at least one dimension greater than 2 mm are collected, characterized and archived. Since the beginning of the characterization phase of the DebriSat project, over 130,000 fragments have been collected and approximately 250,000 fragments are expected to be collected in total, a three-fold increase over the 85,000 fragments predicted by the current break-up model. The challenge throughout the project has been to ensure the integrity and accuracy of the characteristics of each fragment. To this end, the post hypervelocity-impact test activities, which include fragment collection, extraction, and characterization, have been designed to minimize handling of the fragments. The procedures for fragment collection, extraction, and characterization were painstakingly designed and implemented to maintain the post-impact state of the fragments, thus ensuring the integrity and accuracy of the characterization data. Each process is designed to expedite the accumulation of data, however, the need for speed is restrained by the need to protect the fragments. Methods to expedite the process such as parallel processing have been explored and implemented while continuing to maintain the highest integrity and value of the data. To minimize fragment handling, automated systems have been developed and implemented. Errors due to human inputs are also minimized by the use of these automated systems. This paper discusses the processes and challenges involved in the collection, extraction, and characterization of the fragments as well as the time required to complete the processes. The objective is to provide the orbital debris community an understanding of the scale of the effort required to generate and archive high quality data and metadata for each debris fragment 2 mm or larger generated by the DebriSat project.
Shiotani, B.↗
Mars gravity field derived from Viking-1 and Viking-2 - The navigation result
Viking-1 and Viking-2 Doppler tracking data taken during orbit phases characterized by 1500 km subperiapse altitudes have provided a basis for a determination of the Martian gravity field. Navigation results show that the linear combination of short-arc gravity estimates is an acceptable technique for obtaining gravity models over multiple data arcs. An ensemble field composed of Viking data and Mariner-9 a priori retains the inherent local accuracy of its constituent fields. At the same time, the model can be made to be valid globally by careful weighting of a priori Mariner-9 data. The sixth degree and order model presented reduces the error concerning the change in period by more than an order of magnitude during the high altitude (1500 km) phases of the Viking mission. The resulting areoid deviates by no more than 150 m from the areoid produced by the a priori Mariner-9 field.
Christensen, E. J.↗
Mars Surveyor Program 2001 Mission Overview
The Mars Surveyor 2001 mission to Mars was initially a key element in the Mars sample return sequence of missions. A capable rover, carrying the Cornell Athena instruments would be placed on Mars to roam over several kilometers, select samples, and place them in a cache for return by a subsequent mission. Inevitably, budget constraints forced descopes. At one critical point, the landed payload consisted only of the HEDS (Human Exploration and Development of Space) payloads selected for testing environmental properties of the surface for future human exploration. Then Congress intervened and put back some of the funding that had been deleted. NASA next redefined the payload to include as many of the Athena instruments as possible, to be distributed between the lander deck and a Sojourner class rover. This payload would then be placed on a modified version of the Mars Polar Lander rather than on the much larger, and more expensive, lander that had been originally designed for the mission. With this functionality restored the '01 mission remains an important and pivotal element of the Mars Surveyor program. It completes the Mars Observer objectives with the gamma ray spectrometer mapping. This mission will largely complete the global characterization phase of Mars exploration and mark the beginning of focused surface exploration leading to return of the first samples and the search for evidence of past Martian life. MSP'01 also is the first mission in the combined Mars exploration strategy of the HEDS and Space Science Enterprises of NASA. This mission, and those to follow, will demonstrate technologies and collect environmental data that will provide the basis for a decision to send humans to Mars. The NASA exploration strategy for Mars includes orbiters, landers and rovers launched in 2001 and 2003 and a sample return mission to be launched in 2005, returning a sample by 2008. The purpose of the rovers is to explore and characterize sites on Mars. The 2003 and 2005 missions will select rocks, soil, and atmosphere for return to earth.
Saunders, R. Stephen↗
The Evolution and Fate of Saturn's Stratospheric Vortex: Infrared Spectroscopy from Cassini
The planet-encircling springtime storm in Saturn's troposphere (December 2010-July 2011) produced dramatic perturbations to stratospheric temperatures, winds and composition at mbar pressures that persisted long after the tropospheric disturbance had abated. Observations from the Cassini Composite Infrared Spectrometer (CIRS), supported by ground-based imaging from the VISIR instrument on the Very Large Telescope,is used to track the evolution of a large, hot stratospheric anticyclone between January 2011 and the present day. The evolutionary sequence can be divided into three phases: (I) the formation and intensification of two distinct warm airmasses near 0.5 mbar between 25 and 35N (one residing directly above the convective storm head) between January-April 2011, moving westward with different zonal velocities; (II) the merging of the warm airmasses to form the large single 'stratospheric beacon' near 40N between April and June 2011, dissociated from the storm head and at a higher pressure (2 mbar) than the original beacons; and (III) the mature phase characterized by slow cooling and longitudinal shrinkage of the anticyclone since July 2011, moving west with a near-constant velocity of 2.70+/-0.04 deg/day (-24.5+/-0.4 m/s at 40N). Peak temperatures of 220 K at 2 mbar were measured on May 5th 2011 immediately after the merger, some 80 K warmer than the quiescent surroundings. Thermal winds hear calculations in August 2011 suggest clockwise peripheral velocities of 200400 mls at 2 mbar, defining a peripheral collar with a width of 65 degrees longitude (50,000 km in diameter) and 25 degrees latitude. Stratospheric acetylene (C2H2) was uniformly enhanced by a factor of three within the vortex, whereas ethane (C2H6) remained unaffected. We will discuss the thermal and chemical characteristics of Saturn's beacon in its mature phase, and implications for stratospheric vortices on other giant planets.
Fletcher, Leigh N.↗
Long-Term Trends in Space-Ground Atmospheric Propagation Measurements
Propagation measurement campaigns are critical to characterizing the atmospheric behavior of a location and efficiently designing space-ground links. However, as global climate change affects weather patterns, the long-term trends of propagation data may be impacted over periods of decades or longer. Particularly, at high microwave frequencies (10 GHz and above), rain plays a dominant role in the attenuation statistics, and it has been observed that rain events over the past 50 years have trended toward increased frequency, intensity, and rain height. In the interest of quantifying the impact of these phenomena on long-term trends in propagation data, this paper compares two 20 GHz measurement campaigns both conducted at NASAs White Sands facility in New Mexico. The first is from the Advanced Communications Technology Satellite (ACTS) propagation campaign from 1994 to 1998, while the second is amplitude data recorded during a site test interferometer (STI) phase characterization campaign from 2009 to 2014.
attenuation↗
Long-Term Trends in Space-Ground Atmospheric Propagation Measurements
Propagation measurement campaigns are critical to characterizing the atmospheric behavior of a location and efficiently designing space-ground links. However, as global climate change affects weather patterns, the long-term trends of propagation data may be impacted over periods of decades or longer. Particularly, at high microwave frequencies (10 GHz and above), rain plays a dominant role in the attenuation statistics, and it has been observed that rain events over the past 50 years have trended toward increased frequency, intensity, and rain height. In the interest of quantifying the impact of these phenomena on long-term trends in propagation data, this paper compares two 20 GHz measurement campaigns both conducted at NASA's White Sands facility in New Mexico. The first is from the Advanced Communication Technology Satellite (ACTS) propagation campaign from 1994 - 1998, while the second is amplitude data recorded during a site test interferometer (STI) phase characterization campaign from 2009 - 2014.
Radio Attenuation↗
Electrical Evaluation of RCA MWS5001D Random Access Memory, Volume 1
Electrical characterization and qualification tests were performed on the RCA MWS5001D, 1024 by 1-bit, CMOS, random access memory. Characterization tests were performed on five devices. The tests included functional tests, AC parametric worst case pattern selection test, determination of worst-case transition for setup and hold times and a series of schmoo plots. The qualification tests were performed on 32 devices and included a 2000 hour burn in with electrical tests performed at 0 hours and after 168, 1000, and 2000 hours of burn in. The tests performed included functional tests and AC and DC parametric tests. All of the tests in the characterization phase, with the exception of the worst-case transition test, were performed at ambient temperatures of 25, -55 and 125 C. The worst-case transition test was performed at 25 C. The preburn in electrical tests were performed at 25, -55, and 125 C. All burn in endpoint tests were performed at 25, -40, -55, 85, and 125 C.
Klute, A.↗
Carbonaceous chondrites. I - Characterization and significance of carbonaceous chondrite /CM/ xenoliths in the Jodzie howardite
Mineralogical, chemical, textural, and isotopic studies of the abundant carbonaceous inclusions in the Jodzie howardite which are consistent with carbonaceous chondrite (CM) characteristics are examined. These CM xenoliths show regolith alteration comparable to the Murray and Murchison meteorites but less than Nogoya, flow-oriented development of phyllosilicates and 'poorly characterized phases', and partial oxidation of sulfides. Temperature-programmed pyrolysis mass spectrometry indicates that gas release patterns of volatiles and hydrocarbons, and N, C, and S contents are typical of CM meteorites. The fact that the Ne content is typical for 'solar' values and the isotopic structure of Xe is 'planetary' indicates that these gases were entrapped by different mechanisms, and cosmic ray exposure ages for the xenoliths agree with the reported exposure age for the eucritic host.
Bunch, T. E.↗
A new layered mineral from the Mighei carbonaceous chondrite
The poorly characterized phase (PCP) of the Mighei CM2 carbonaceous chondrite is investigated using high-resolution TEM. Electron-microprobe analyses of samples from both olivine chondrules and the matrix are included in a table. Chondrule PCP is found to have higher concentrations of S and Ni and lower concentrations of Si, Mg, and Al than matrix PCP. TEM shows that PCP in this chondrite is an intergrowth of three phases (in various proportions): a major component containing Fe, S, Ni, and O in wavy rolled layers spaced about 5.4 A apart, an Fe-rich serpentinelike phyllosilicate with 7-A layer spacing, and submicron grains of magnetite, chromite, and phosphate. It is proposed that chondrule PCP contains mainly the 5-A phase with some grains, while matrix PCP consists mostly of the 5-A and 7-A phases.
Tomeoka, K.↗
Gamma-ray transfer and energy deposition in supernovae
Solutions to the energy-independent (gray) radiative transfer equations are compared to results of Monte Carlo simulations of the Ni-56 and Co-56 decay gamma-ray energy deposition in supernovae. The comparison shows that an effective, purely absorptive, gray opacity, kappa(sub gamma) approximately (0. 06 +/- 0.01)Y(sub e) sq cm/g, where Y is the total number of electrons per baryon, accurately describes the interaction of gamma-rays with the cool supernova gas and the local gamma-ray energy deposition within the gas. The nature of the gamma-ray interaction process (dominated by Compton scattering in the relativistic regime) creates a weak dependence of kappa(sub gamma) on the optical thickness of the (spherically symmetric) supernova atmosphere: The maximum value of kappa(sub gamma) applies during optically thick conditions when individual gamma-rays undergo multiple scattering encounters and the lower bound is reached at the phase characterized by a total Thomson optical depth to the center of the atmosphere tau(sub e) approximately less than 1. Gamma-ray deposition for Type Ia supernova models to within 10% for the epoch from maximum light to t = 1200 days. Our results quantitatively confirm that the quick and efficient solution to the gray transfer problem provides an accurate representation of gamma-ray energy deposition for a broad range of supernova conditions.
Swartz, Douglas A.↗
The FU Orionis Phenomenon and Solar Nebula Material
We summarize astronomical, meteoritic, and theoretical evidence relating to the FU Orionis phenomenon. This evidence suggests that at early times (the first few 10(exp 5) yr), the solar nebula experienced a hot phase characterized by high accretion rates (the "FU Ori epoch"), punctuated by episodic outbursts of enhanced mass flow through the inner part of the disk (less than or equal to 0.3 AU). Throughout this epoch, disk midplane temperatures exceeded 1000 K at 1 AU. Diminishing infall from the cloud core led to decreasing mass flux throughout the disk. When mass flow de creased below the value critical for outburst (5 x 10(exp -7) solar mass/yr, as suggested by thermal ionization instability models), outbursts ceased and the T Tauri epoch began. Outburst timescales are too long to explain calcium- and aluminum-rich inclusion (CAI) and chondrule formation. Volatility-dependent fractionation patterns seen in meteoritic materials suggest that solids formed beginning during a hot epoch when temperatures exceeded 1400 K, and the presence of volatiles in chondrites argues that this process continued until the nebula had cooled to below 400 K. The thermal ionization instability model for FU Ori outbursts is in quantitative agreement with astronomical observations. Its results imply that the terrestrial region of the nebula reached the hot end of this range only during a time when mass flow through the disk was high enough to trigger outbursts (i.e., the FU Ori epoch) and reached the cool end of this range only during the later T Tauri epoch. According to the models, heating of material in the terrestrial planet region during individual FU Ori outbursts would be limited to surface layers of the nebula, leaving midplane materials (which are at greater than or equal to 1000 K) largely unaffected. Alternative FU Ori models should be developed, particularly if compositional differences among chondrite clans are attributable to episodic heating.
Bell, K. R.↗
Highlights from a Mach 4 Experimental Demonstration of Inlet Mode Transition for Turbine-Based Combined Cycle Hypersonic Propulsion
NASA is focused on technologies for combined cycle, air-breathing propulsion systems to enable reusable launch systems for access to space. Turbine Based Combined Cycle (TBCC) propulsion systems offer specific impulse (Isp) improvements over rocket-based propulsion systems in the subsonic takeoff and return mission segments along with improved safety. Among the most critical TBCC enabling technologies are: 1) mode transition from the low speed propulsion system to the high speed propulsion system, 2) high Mach turbine engine development and 3) innovative turbine based combined cycle integration. To address these challenges, NASA initiated an experimental mode transition task including analytical methods to assess the state-of-the-art of propulsion system performance and design codes. One effort has been the Combined-Cycle Engine Large Scale Inlet Mode Transition Experiment (CCE-LIMX) which is a fully integrated TBCC propulsion system with flowpath sizing consistent with previous NASA and DoD proposed Hypersonic experimental flight test plans. This experiment was tested in the NASA GRC 10 by 10-Foot Supersonic Wind Tunnel (SWT) Facility. The goal of this activity is to address key hypersonic combined-cycle engine issues including: (1) dual integrated inlet operability and performance issues-unstart constraints, distortion constraints, bleed requirements, and controls, (2) mode-transition sequence elements caused by switching between the turbine and the ramjet/scramjet flowpaths (imposed variable geometry requirements), and (3) turbine engine transients (and associated time scales) during transition. Testing of the initial inlet and dynamic characterization phases were completed and smooth mode transition was demonstrated. A database focused on a Mach 4 transition speed with limited off-design elements was developed and will serve to guide future TBCC system studies and to validate higher level analyses.
Foster, Lancert E.↗