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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 37 records · Page 2
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NASA NTRS1987

Selection of high temperature thermal energy storage materials for advanced solar dynamic space power systems

Under the direction of NASA's Office of Aeronautics and Technology (OAST), the NASA Lewis Research Center has initiated an in-house thermal energy storage program to identify combinations of phase change thermal energy storage media for use with a Brayton and Stirling Advanced Solar Dynamic (ASD) space power system operating between 1070 and 1400 K. A study has been initiated to determine suitable combinations of thermal energy storage (TES) phase change materials (PCM) that result in the smallest and lightest weight ASD power system possible. To date the heats of fusion of several fluoride salt mixtures with melting points greater than 1025 K have been verified experimentally. The study has indicated that these salt systems produce large ASD systems because of their inherent low thermal conductivity and low density. It is desirable to have PCMs with high densities and high thermal conductivities. Therefore, alternate phase change materials based on metallic alloy systems are also being considered as possible TES candidates for future ASD space power systems.

Lacy, Dovie E.↗
NASA NTRS2015

Phase Change Material Heat Sink for an ISS Flight Experiment

A flight experiment is being constructed to utilize the persistent microgravity environment of the International Space Station (ISS) to prove out operation of a microgravity compatible phase change material (PCM) heat sink. A PCM heat sink can help to reduce the overall mass and volume of future exploration spacecraft thermal control systems (TCS). The program is characterizing a new PCM heat sink that incorporates a novel phase management approach to prevent high pressures and structural deformation that often occur with PCM heat sinks undergoing cyclic operation in microgravity. The PCM unit was made using brazed aluminum construction with paraffin wax as the fusible material. It is designed to be installed into a propylene glycol and water cooling loop, with scaling consistent with the conceptual designs for the Orion Multipurpose Crew Vehicle. This paper reports on the construction of the PCM heat sink and on initial ground test results conducted at UTC Aerospace Systems prior to delivery to NASA. The prototype will be tested later on the ground and in orbit via a self‐contained experiment package developed by NASA Johnson Space Center to operate in an ISS EXPRESS rack.

Quinn, Gregory↗
NASA NTRS2015

Phase Change Material Heat Sink for an ISS Flight Experiment

A flight experiment is being constructed to utilize the persistent microgravity environment of the International Space Station (ISS) to prove out operation of a microgravity compatible phase change material (PCM) heat sink. A PCM heat sink can help to reduce the overall mass and volume of future exploration spacecraft thermal control systems (TCS). The program is characterizing a new PCM heat sink that incorporates a novel phase management approach to prevent high pressures and structural deformation that often occur with PCM heat sinks undergoing cyclic operation in microgravity. The PCM unit was made using brazed aluminum construction with paraffin wax as the fusible material. It is designed to be installed into a propylene glycol and water cooling loop, with scaling consistent with the conceptual designs for the Orion Multipurpose Crew Vehicle. This paper reports on the construction of the PCM heat sink and on initial ground test results conducted at UTC Aerospace Systems prior to delivery to NASA. The prototype will be tested later on the ground and in orbit via a self‐contained experiment package developed by NASA Johnson Space Center to operate in an ISS EXPRESS rack.

Quinn, Gregory↗
NASA NTRS2014

Phase Change Material for Temperature Control of Imager or Sounder on GOES Type Satellites in GEO

This paper uses phase change material (PCM) in the scan cavity of an imager or sounder on satellites in geostationary orbit (GEO) to maintain the telescope temperature stable. When sunlight enters the scan aperture, solar heating causes the PCM to melt. When sunlight stops entering the scan aperture, the PCM releases the thermal energy stored to keep the components in the telescope warm. It has no moving parts or bimetallic springs. It reduces heater power required to make up the heat lost by radiation to space through the aperture. It is an attractive thermal control option to a radiator with a louver and a sunshade.

phase change material↗
NASA NTRS2017

Using Paraffin PCM, Cryogel and TEC to Maintain Comet Surface Sample Cold from Earth Approach Through Retrieval

An innovative thermal design concept to maintain comet surface samples cold (for example, 263 degrees Kelvin, 243 degrees Kelvin or 223 degrees Kelvin) from Earth approach through retrieval is presented. It uses paraffin phase change material (PCM), Cryogel insulation and thermoelectric cooler (TEC), which are commercially available.

comet surface sample return; thermoelectric cooler↗
NASA NTRS1991

Multi-dimensional modeling of a thermal energy storage canister

The Solar Dynamic Power Module being developed for Space Station Freedom uses a eutectic mixture of LiF-CaF2 phase change material (PCM) contained in toroidal canisters for thermal energy storage. Presented are the results from heat transfer analyses of a PCM containment canister. One and two dimensional finite difference computer models are developed to analyze heat transfer in the canister walls, PCM, void, and heat engine working fluid coolant. The modes of heat transfer considered include conduction in canister walls and solid PCM, conduction and pseudo-free convection in liquid PCM, conduction and radiation across PCM vapor filled void regions, and forced convection in the heat engine working fluid. Void shape, location, growth or shrinkage (due to density difference between the solid and liquid PCM phases) are prescribed based on engineering judgment. The PCM phase change process is analyzed using the enthalpy method. The discussion of the results focuses on how canister thermal performance is affected by free convection in the liquid PCM and void heat transfer. Characterizing these effects is important for interpreting the relationship between ground-based canister performance (in 1-g) and expected on-orbit performance (in micro-g). Void regions accentuate canister hot spots and temperature gradients due to their large thermal resistance. Free convection reduces the extent of PCM superheating and lowers canister temperatures during a portion of the PCM thermal charge period. Surprisingly small differences in canister thermal performance result from operation on the ground and operation on-orbit. This lack of a strong gravity dependency is attributed to the large contribution of container walls in overall canister energy redistribution by conduction.

Kerslake, Thomas W.↗
NASA NTRS2015

System Level Analysis of a Water PCM HX Integrated into Orion's Thermal Control System

In a cyclical heat load environment such as low Lunar orbit, a spacecraft's radiators are not sized to reject the full heat load requirement. Traditionally, a supplemental heat rejection device (SHReD) such as an evaporator or sublimator is used to act as a "topper" to meet the additional heat rejection demands. Utilizing a Phase Change Material (PCM) heat exchanger (HX) as a SHReD provides an attractive alternative to evaporators and sublimators as PCM HXs do not use a consumable, thereby leading to reduced launch mass and volume requirements. In continued pursuit of water PCM HX development an Orion system level analysis was performed using Thermal Desktop for a water PCM HX integrated into Orion's thermal control system in a 100km Lunar orbit. The study verified of the thermal model by using a wax PCM and analyzed 1) placing the PCM on the Internal Thermal Control System (ITCS) versus the External Thermal Control System (ETCS) 2) use of 30/70 PGW verses 50/50 PGW and 3) increasing the radiator area in order to reduce PCM freeze times. The analysis showed that for the assumed operating and boundary conditions utilizing a water PCM HX on Orion is not a viable option for any case. Additionally, it was found that the radiator area would have to be increased by at least 40% in order to support a viable water-based PCM HX.

Navarro, Moses↗
NASA NTRS2015

System Level Analysis of a Water PCM HX Integrated Into Orion's Thermal Control System Abstract

In a cyclical heat load environment such as low Lunar orbit, a spacecraft's radiators are not sized to reject the full heat load requirement. Traditionally, a supplemental heat rejection device (SHReD) such as an evaporator or sublimator is used to act as a "topper" to meet the additional heat rejection demands. Utilizing a Phase Change Material (PCM) heat exchanger (HX) as a SHReD provides an attractive alternative to evaporators and sublimators as PCM HXs do not use a consumable, thereby leading to reduced launch mass and volume requirements. In continued pursuit of water PCM HX development an Orion system level analysis was performed using Thermal Desktop for a water PCM HX integrated into Orion's thermal control system and in a 100km Lunar orbit. The study analyzed 1) placing the PCM on the Internal Thermal Control System (ITCS) versus the External Thermal Control System (ETCS) 2) use of 30/70 PGW verses 50/50 PGW and 3) increasing the radiator area in order to reduce PCM freeze times. The analysis showed that for the assumed operating and boundary conditions utilizing a water PCM HX on Orion is not a viable option. Additionally, it was found that the radiator area would have to be increased over 20% in order to have a viable water‐based PCM HX.

Navarro, Moses↗
NASA NTRS2019

Using Paraffin PCM for Thermal Management of BOLAS Planetary CubeSats with Ion Thrusters

The Bi-sat Observations of the Lunar Atmosphere above Swirls (BOLAS) is a NASA planetary CubeSat mission concept in low lunar orbit. The BOLAS lower CubeSat is at a 90 km altitude above the lunar surface during spiraling down from the Evolved Expendable Launch Vehicle (EELV) Secondary Payload Adapter (ESPA) to the Moon. Without phase change material (PCM), the worst hot case temperature prediction for the Command and Data Handling (C&DH) exceeds the 61°C maximum operating limit, and those for the Iris solid state power amplifier (SSPA) and transponder exceed the 50°C maximum operating limit. Miniature n-Tricosane PCM packs on the Iris SSPA and transponder, and miniature n-Hexacosane PCM packs on the C&DH are used to store thermal energy in sunlight and release it in the eclipse. With paraffin PCM, all the temperatures are within the maximum operating limits.

Choi, Michael K.↗
NASA NTRSDate not supplied

Toward High-Endurance Nonvolatile Reconfigurable Metasurfaces

The applications of adaptive optics extend across multiple sectors, encompassing areas such as LiDAR, biological and chemical sensing, and free-space optical communications. The advent of metasurfaces optics with reconfigurability has offered a versatile platform for the design of compact optical components, offering a compelling alternative to their conventional bulky counterparts. In this study, we introduce the PROWESS (Phase change Reconfigurable Optical WavEfront Synthesis System project at NASA LaRC), electrically reconfigurable metasurfaces using low-loss, high-contrast phase change material (PCM), Ge2Sb2Se4Te integrated with IR-transparent silicon microheater for various practical applications. The talk covers a reliable platform for switching large-scale PCM-based devices utilizing a microheater and an architecture for the metasurface switching within an integrated circuit configuration, which is compatible with standard foundry fabrication processes. The utilization of near- to midinfrared transparent silicon microheater in the proposed architecture opens possibilities for the development of reconfigurable transmissive optics such as filters, zoom lenses, and beam steering modules. We demonstrated switching of 140 µm × 140 µm PCM pixel, on a 200 µm × 200 µm silicon microheater for several thousand cycles. Further, we performed an in-depth investigation into the failure mechanism utilizing techniques such as transmission electron microscopy and thermal modeling. Guidelines for device performance improvement are proposed, and an improved design with larger endurance is shown in progress. With further progress, we aim to unlock the full potential of PCM-based devices and advance the field of adaptive optics with demonstrable examples including a reconfigurable beam steerer for ocean surface flash LiDAR and Navigation Doppler LiDAR for precise lunar landing missions.

metasurface optics↗
NASA NTRS2010

Improved OTEC System for a Submarine Robot

An ocean thermal energy conversion (OTEC), now undergoing development, is a less-massive, more-efficient means of exploiting the same basic principle as that of the proposed system described in "Alternative OTEC Scheme for a Submarine Robot" (NPO-43500), NASA Tech Briefs, Vol. 33, No. 1 (January 2009), page 50. The proposed system as described previously would be based on the thawing-expansion/freezing-contraction behavior of a wax or perhaps another suitable phase-change material (PCM). The power generated by the system would be used to recharge the batteries in a battery- powered unmanned underwater vehicle [UUV (essentially, a small exploratory submarine robot)] of a type that has been deployed in large numbers in research pertaining to global warming. A UUV of this type travels between the ocean surface and depths, measuring temperature and salinity. At one phase of its operational cycle, the previously proposed system would utilize the surface ocean temperature (which lies between 15 and 30 C over most of the Earth) to melt a PCM that has a melting/freezing temperature of about 10 C. At the opposite phase of its operational cycle, the system would utilize the lower ocean temperature at depth (e.g., between 4 and 7 C at a depth of 300 m) to freeze the PCM. The melting or freezing would cause the PCM to expand or contract, respectively, by about 9 volume percent. The PCM would be contained in tubes that would be capable of expanding and contracting with the PCM. The PCM-containing tubes would be immersed in a hydraulic fluid. The expansion and contraction would drive a flow of the hydraulic fluid against a piston that, in turn, would push a rack-and-pinion gear system to spin a generator to charge a battery.

Chao, Yi↗
NASA NTRS1993

Space Station thermal storage/refrigeration system research and development

Space Station thermal loading conditions represent an order of magnitude increase over current and previous spacecraft such as Skylab, Apollo, Pegasus III, Lunar Rover Vehicle, and Lockheed TRIDENT missiles. Thermal storage units (TSU's) were successfully used on these as well as many applications for ground based solar energy storage applications. It is desirable to store thermal energy during peak loading conditions as an alternative to providing increased radiator surface area which adds to the weight of the system. Basically, TSU's store heat by melting a phase change material (PCM) such as a paraffin. The physical property data for the PCM's used in the design of these TSU's is well defined in the literature. Design techniques are generally well established for the TSU's. However, the Space Station provides a new challenge in the application of these data and techniques because of three factors: the large size of the TSU required, the integration of the TSU for the Space Station thermal management concept with its diverse opportunities for storage application, and the TSU's interface with a two-phase (liquid/vapor) thermal bus/central heat rejection system. The objective in the thermal storage research and development task was to design, fabricate, and test a demonstration unit. One test article was to be a passive thermal storage unit capable of storing frozen food at -20 F for a minimum of 90 days. A second unit was to be capable of storing frozen biological samples at -94 F, again for a minimum of 90 days. The articles developed were compatible with shuttle mission conditions, including safety and handling by astronauts. Further, storage rack concepts were presented so that these units can be integrated into Space Station logistics module storage racks. The extreme sensitivity of spacecraft radiator systems design-to-heat rejection temperature requirements is well known. A large radiator area penalty is incurred if low temperatures are accommodated via a single centralized radiator system. As per the scope of work of this task, the applicability of refrigeration system tailored to meet the specialized requirements of storage of food and biological samples was investigated. The issues addressed were the anticipated power consumption and feasible designs and cycles for meeting specific storage requirements. Further, development issues were assessed related to the operation of vapor compression systems in micro-gravity addressing separation of vapor and liquid phases (via capillary systems).

Dean, W. G.↗
NASA NTRS1971

Phase change materials handbook

This handbook is intended to provide theory and data needed by the thermal design engineer to bridge the gap between research achievements and actual flight systems, within the limits of the current state of the art of phase change materials (PCM) technology. The relationship between PCM and more conventional thermal control techniques is described and numerous space and terrestrial applications of PCM are discussed. Material properties of the most promising PCMs are provided; the purposes and use of metallic filler materials in PCM composites are presented; and material compatibility considerations relevant to PCM design are included. The engineering considerations of PCM design are described, especially those pertaining to the thermodynamic and heat transfer phenomena peculiar to PCM design. Methods of obtaining data not currently available are presented. The special problems encountered in the space environment are described. Computational tools useful to the designer are discussed. In summary, each aspect of the PCM problem important to the design engineer is covered to the extent allowed by the scope of this effort and the state of the art.

Hale, D. V.↗
NASA NTRS1972

Study of structural active cooling and heat sink systems for space shuttle

This technology investigation was conducted to evaluate the feasibility of a number of thermal protection systems (TPS) concepts which are alternate candidates to the space shuttle baseline TPS. Four independent tasks were performed. Task 1 consisted of an in-depth evaluation of active structural cooling of the space shuttle orbiter. In Task 2, heat sink concepts for the booster were studied to identify and postulate solutions for design problems unique to heat sink TPS. Task 3 consisted of a feasibility demonstration test of a phase change material (PCM) incorporated into a reusable surface insulation (RSI) thermal protection system for the shuttle orbiter. In Task 4 the feasibility of heat pipes for stagnation region cooling was studied for the booster and the orbiter. Designs were developed for the orbiter leading edge and used in trade studies of leading edge concepts. At the time this program was initiated, a 2-stage fully reusable shuttle system was envisioned; therefore, the majority of the tasks were focused on the fully reusable system environments. Subsequently, a number of alternate shuttle system approaches, with potential for reduced shuttle system development funding requirements, were proposed. Where practicable, appropriate shifts in emphasis and task scoping were made to reflect these changes.

Source record↗
NASA NTRS1973

Advanced Thermal Control Flight Experiment.

The advanced Thermal Control Flight Experiment on the Applications Technology Satellite (ATS-F) will evaluate, for the first time in a space environment, the performance of a feedback-controlled variable conductance heat pipe and a heat pipe thermal diode. In addition, the temperature control aspects of a phase-change material (PCM) will be demonstrated. The methanol/stainless steel feedback-controlled heat pipe uses helium control gas that is stored in a wicked reservoir. This reservoir is electrically heated through a solid state controller that senses the temperature of the heat source directly. The ammonia/stainless steel diode heat pipe uses excess liquid to block heat transfer in the reverse direction. The PCM is octadecane. Design tradeoffs, fabrication problems, and performance during qualification and flight acceptance tests are discussed.

Kirkpatrick, J. P.↗
NASA NTRS1975

Thermal capacitator design rationale. Part 1: Thermal and mechanical property data for selected materials potentially useful in thermal capacitor design and construction

The thermal properties of paraffin hydrocarbons and hydrocarbon mixtures which may be used as the phase change material (PCM) in thermal capacitors are discussed. The paraffin hydrocarbons selected for consideration are those in the range from C11H24 (n-Undecane) to C20H42 (n-Eicosane). A limited amount of data is included concerning other properties of paraffin hydrocarbons and the thermal and mechanical properties of several aluminum alloys which may find application as constructional materials. Data concerning the melting temperature, transition temperature, latent heat of fusion, heat of transition, specific heat, and thermal conductivity of pure and commercial grades of paraffin hydrocarbons are given. An index of companies capable of producing paraffin hydrocarbons and information concerning the availability of various grades (purity levels) is provided.

Bailey, J. A.↗
NASA NTRS1977

Development of a low temperature phase change material package

Test data obtained for a low temperature phase change material (PCM) canisters are presented. The canister was designed to provide up to 30 w-hrs of storage capacity at approximately -90 C with an overall thermal conductance which is greater than 8 w/deg C. N-heptane which is an n-paraffin and has a -90.6 C freezing point was used as the working fluid. The canister was fabricated from aluminum and has an aluminum honeycomb core. Its void volume permits service temperatures up to 70 C. Results obtained from component and system's tests indicate well defined melting and freezing points which are repeatable and within 1 C of each other. Subcooling effects are less than 0.5 C and are essentially negligible. Measured storage capacities are within 94 to 88% the theoretical.

Brennan, P. J.↗
NASA NTRS1978

High temperature thermal energy storage, including a discussion of TES integrated into power plants

Storage temperatures of 260 C and above are considered. Basic considerations concerning energy thermal storage are discussed, taking into account general aspects of thermal energy storage, thermal energy storage integrated into power plants, thermal storage techniques and technical considerations, and economic considerations. A description of system concepts is provided, giving attention to a survey of proposed concepts, storage in unpressurized fluids, water storage in pressurized containers, the use of an underground lined cavern for water storage, a submerged thin insulated steel shell under the ocean containing pressurized water, gas passage through solid blocks, a rock bed with liquid heat transport fluid, hollow steel ingots, heat storage in concrete or sand, sand in a fluidized bed, sand poured over pipes, a thermal energy storage heat exchanger, pipes or spheres filled with phase change materials (PCM), macroencapsulated PCM with heat pipe concept for transport fluid, solid PCM removed from heat transfer pipes by moving scrapers, and the direct contact between PCM and transport fluid.

Turner, R. H.↗