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NASA NTRS1994

A model for the evolution of CO2 on Mars

We have constructed a model that predicts the evolution of CO2 on Mars from the end of the heavy bombardment period to the present. The model draws on published estimates of the main processes believed to affect the fate of CO2 during this period: chemical weathering, regolith uptake, polar cap formation, and atmospheric escape. Except for escape, the rate at which these processes act is controlled by surface temperatures which we calculate using a modified version of the Gierasch and Toon energy balance model. The modifications account for the change in solar luminosity with time, the greenhouse effect, and a polar and equatorial energy budget. Using published estimates for the main parameters, we find no evolutionary scenario in which CO2 is capable of producing a warm (global mean temperatures greater than 250 K) and wet (surface pressures greater than 30 mbar) early climate, and then evolves to present conditions with approximately 7 mbar in the atmosphere, less than 300 mbar in the regolith, and less than 5 mbar in the caps. Such scenarios would only exist if the early sun were brighter than standard solar models suggest, if greenhouse gases other than CO2 were present in the early atmosphere, or if the polar albedo were significantly lower than 0.75. However, these scenarios generally require the storage of large amounts of CO2 (greater than 1 bar) in the carbonate reservoir. If the warm and wet early Mars constraint is relaxed, then we find best overall agreement with present day reservoirs for initial CO2 inventories of 0.5-1.0 bar. We also find that the polar caps can have a profound effect on how the system evolves. If the initial amount of CO2 is less than some critical value, then there is not enough heating of the poles to prevent permanent caps from forming. Once formed, these caps control how the system evolves, because they set the surface pressure and, hence, the thermal environment. If the initial amount of CO2 is greater than this critical value, then caps do not form initially, but can form later on, when weathering and escape lower the surface pressure to a point at which polar heating is no longer sufficient to prevent cap formation and the collapse of the climate system. Our modeling suggests this critical initial amount of CO2 is between 1 and 2 bar, but its true value will depend on all factors affecting the polar heat budget.

Haberle, Robert M.↗

NASA NTRS1991

Polar stratospheric clouds and the ozone hole

An account is given of physical processes governing the formation of stratospheric particles, in order to dramatize the interactions between polar stratospheric clouds and the Antarctic ozone-destruction mechanism. Attention is given to the successive stages of particle nucleation, condensation/evaporation and sedimentation/coagulation phenomena, and the ways in which polar stratospheric clouds are observed. Considerable evidence exists that polar stratospheric cloud particles are composed of nitric acid. The relatively small Arctic ozone hole depletion is due to the much smaller duration of Arctic stratospheric clouds.

Hamill, Patrick↗

NASA NTRS2016

TPSAS-NF1676L-23432-DND

The POLSTRACC (POlar STRAtosphere in a Changing Climate) field campaign was conducted in the Arctic during December 2015 - March 2016 to investigate the chemical, microphysical, and dynamical processes of the Arctic lowermost stratosphere and upper troposphere. The primary measurement platform for POLSTRACC was the German HALO (High Altitude LOng range) research aircraft carrying a large suite of in situ and remote sensing instruments to measure key chemical species, tracers, as well as aerosol and cloud particles and meteorological parameters. Two primary science objectives of POLSTRACC are to improve our understanding of polar stratospheric cloud (PSC) particle characteristics and formation processes and investigate the impact of Arctic cirrus clouds on radiative forcing and chlorine activation. To complement the more focused measurements from the POLSTRACC field campaign, we have used spaceborne lidar measurements from CALIPSO to characterize PSC occurrence and composition, as well as the occurrence of Arctic cirrus during the 2015-2016 season on vortex-wide scales. In this paper, we present a general overview of the 2015-2016 winter, examine in detail the evolution of PSCs and cirrus during the season, and explore the unique aspects of this season in attempt to understand the underlying physical mechanisms.

Michael C Pitts↗

NASA NTRS1996

Stratospheric Heterogeneous Chemistry and Microphysics: Model Development, Validation and Applications

The objectives of this project are to: define the chemical and physical processes leading to stratospheric ozone change that involve polar stratospheric clouds (PSCS) and the reactions occurring on the surfaces of PSC particles; study the formation processes, and the physical and chemical properties of PSCS, that are relevant to atmospheric chemistry and to the interpretation of field measurements taken during polar stratosphere missions; develop quantitative models describing PSC microphysics and heterogeneous chemical processes; assimilate laboratory and field data into these models; and calculate the extent of chemical processing on PSCs and the impact of specific microphysical processes on polar composition and ozone depletion. During the course of the project, a new coupled microphysics/physical-chemistry/ photochemistry model for stratospheric sulfate aerosols and nitric acid and ice PSCs was developed and applied to analyze data collected during NASA's Arctic Airborne Stratospheric Expedition-II (AASE-II) and other missions. In this model, detailed treatments of multicomponent sulfate aerosol physical chemistry, sulfate aerosol microphysics, polar stratospheric cloud microphysics, PSC ice surface chemistry, as well as homogeneous gas-phase chemistry were included for the first time. In recent studies focusing on AASE measurements, the PSC model was used to analyze specific measurements from an aircraft deployment of an aerosol impactor, FSSP, and NO(y) detector. The calculated results are in excellent agreement with observations for particle volumes as well as NO(y) concentrations, thus confirming the importance of supercooled sulfate/nitrate droplets in PSC formation. The same model has been applied to perform a statistical study of PSC properties in the Northern Hemisphere using several hundred high-latitude air parcel trajectories obtained from Goddard. The rates of ozone depletion along trajectories with different meteorological histories are presently being systematically evaluated to identify the principal relationships between ozone loss and aerosol state. Under this project, we formulated a detailed quantitative model that predicts the multicomponent composition of sulfate aerosols under stratospheric conditions, including sulfuric, nitric, hydrochloric, hydrofluoric and hydrobromic acids. This work defined for the first time the behavior of liquid ternary-system type-1b PSCS. The model also allows the compositions and reactivities of sulfate aerosols to be calculated over the entire range of environmental conditions encountered in the stratosphere (and has been incorporated into a trajectory/microphysics model-see above). Important conclusions that derived from this work over the last few years include the following: the HNO3 content of liquid-state aerosols dominate PSCs below about 195 K; the freezing of nitric acid ice from sulfate aerosol solutions is likely to occur within a few degrees K of the water vapor frost point; the uptake and reactions of HCl in liquid aerosols is a critical component of PSC heterogeneous chemistry. In a related application of this work, the inefficiency of chlorine injection into the stratosphere during major volcanic eruptions was explained on the basis of nucleation of sulfuric acid aerosols in rising volcanic plumes leading to the formation of supercooled water droplets on these aerosols, which efficiently scavenges HCl via precipitation.

Turco, Richard P.↗

NASA NTRS2003

An ancient role for nuclear beta-catenin in the evolution of axial polarity and germ layer segregation

The human oncogene beta-catenin is a bifunctional protein with critical roles in both cell adhesion and transcriptional regulation in the Wnt pathway. Wnt/beta-catenin signalling has been implicated in developmental processes as diverse as elaboration of embryonic polarity, formation of germ layers, neural patterning, spindle orientation and gap junction communication, but the ancestral function of beta-catenin remains unclear. In many animal embryos, activation of beta-catenin signalling occurs in blastomeres that mark the site of gastrulation and endomesoderm formation, raising the possibility that asymmetric activation of beta-catenin signalling specified embryonic polarity and segregated germ layers in the common ancestor of bilaterally symmetrical animals. To test whether nuclear translocation of beta-catenin is involved in axial identity and/or germ layer formation in 'pre-bilaterians', we examined the in vivo distribution, stability and function of beta-catenin protein in embryos of the sea anemone Nematostella vectensis (Cnidaria, Anthozoa). Here we show that N. vectensis beta-catenin is differentially stabilized along the oral-aboral axis, translocated into nuclei in cells at the site of gastrulation and used to specify entoderm, indicating an evolutionarily ancient role for this protein in early pattern formation.

NASA Discipline Evolutionary Biology↗

NASA NTRS1993

A model for the evolution of CO2 on Mars

Our MSATT work has focused on the evolution of CO2 on Mars. We have constructed a model that predicts the evolution of CO2 on Mars from a specified initial amount at the end of the heavy bombardment to the present. The model draws on published estimates of the main process believed to affect the fate of CO2 during this period: chemical weathering, regolith uptake, polar cap formation, and atmospheric escape. Except for escape, the rate at which these processes act is controlled by surface temperatures that we calculate using a modified version of the Gierasch and Toon energy balance model. Various aspects of this work are covered.

Haberle, Robert M.↗

NASA NTRS2003

Analysis of Properties of the North Polar Layered Deposits: THEMIS Data in Context of MGS Data

One of the many questions of Martian exploration is to uncover the history of Mars, through analysis of the polar layered deposits (PLD). Martian polar ice caps hold most of the exposed water on the surface on Mars and yet their history and physical processed involved in their formation are unclear. We will attempt to contribute to our knowledge of the composition and stratigraphy of the polar deposits. In this work we present the latest imaging data acquired by the Mars Odyssey THermal EMission Imaging System (THEMIS) and place it into context of the Mars Global Surveyor (MGS) data. THEMIS provides capabilities for imaging in both thermal IR and visible color wavelengths. These observations are affected by atmospheric scattering and topography. The Mars Orbiter Laser Altimeter (MOLA) and Thermal Emission Spectrometer (TES) instruments on board of the MGS spacecraft can provide context information for THEMIS data. Of particular interest are Mars Orbiter Camera (MOC) images, which provide high resolution data. We are primarily interested in the seasonal evolution of ice cap temperatures during the first northern summer of THEMIS observations. Morphology, stratigraphy and composition of the layered deposits can be addressed by THEMIS VIS color images, along with MOC high resolution data and MOLA Digital Elevation Models (DEM). This work is intentionally descriptive. Based on the knowledge obtained by the orbiting spacecraft and described here, we will attempt to expose major directions for modeling and further understanding of of the physical processes involved in the formation of the polar layered terrain 2 Available data 2.1 THEMIS IR The THEMIS IR camera has 10 bands from 6 to 15 m. Due to to signal-to-noise restrictions the most useful band for polar observations is band 9 (12.57 m ). Band 10 (14.88 m ) data can be used for atmospheric calibration. An example of seasonal evolution observed by the THEMIS IR subsystem is shown in Figure 1. We have projected all IR images, covering a small area near 86N and 90E into a polar stereographic projection and then sampled time dimension in order to look at temperature evolution over the course of the summer. We are plotting averaged temperature data over two 1km2 regions of interest: layered material inside the trough and the surface of the residual ice cap. High resolution THEMIS IR data allows us to distinguish properties of bulk of layered terrain and ice. We were not able yet to distinguish properties of individual layers.

A B Ivanov↗

NASA NTRS2003

Evaluating the Credibility of Transport Processes in the Global Modeling Initiative 3D Model Simulations of Ozone Recovery

The Global Modeling Initiative has integrated two 35-year simulations of an ozone recovery scenario with an offline chemistry and transport model using two different meteorological inputs. Physically based diagnostics, derived from satellite and aircraft data sets, are described and then used to evaluate the realism of temperature and transport processes in the simulations. Processes evaluated include barrier formation in the subtropics and polar regions, and extratropical wave-driven transport. Some diagnostics are especially relevant to simulation of lower stratospheric ozone, but most are applicable to any stratospheric simulation. The temperature evaluation, which is relevant to gas phase chemical reactions, showed that both sets of meteorological fields have near climatological values at all latitudes and seasons at 30 hPa and below. Both simulations showed weakness in upper stratospheric wave driving. The simulation using input from a general circulation model (GMI(sub GCM)) showed a very good residual circulation in the tropics and northern hemisphere. The simulation with input from a data assimilation system (GMI(sub DAS)) performed better in the midlatitudes than at high latitudes. Neither simulation forms a realistic barrier at the vortex edge, leading to uncertainty in the fate of ozone-depleted vortex air. Overall, tracer transport in the offline GMI(sub GCM) has greater fidelity throughout the stratosphere than the GMI(sub DAS).

Strahan, Susan E.↗

NASA NTRS2017

The Formation and Maintenance of the Dominant Southern Polar Crown Cavity of Cycle 24

In this article, we report a study of the longest-lived polar crown cavity of Solar Cycle 24, using an observation from 2013, and propose a physical mechanism to explain its sustained existence. We used high temporal and spatial resolution observations from the Atmospheric Imaging Assembly (AIA) and the Helioseismic Magnetic Imager (HMI) instruments on board the Solar Dynamics Observatory (SDO) to explore the structure and evolution of the cavity. Although it existed for more than a year, we examined the circumpolar cavity in great detail from 2013 March 21 to 2013 October 31. Our study reinforces the existing theory of formation of polar crown filaments that involves two basic processes to form any polar crown cavity as well as the long-lived cavity that we studied here. First, the underlying polarity inversion line (PIL) of the circumpolar cavity is formed between (1) the trailing part of dozens of decayed active regions distributed in different longitudes and (2) the unipolar magnetic field in the polar coronal hole. Second, the long life of the cavity is sustained by the continuing flux cancellation along the PIL. The flux is persistently transported toward the polar region through surface meridional flow and diffusion. The continuing flux cancellation leads to the shrinking of the polar coronal hole.

Karna, N.↗

NASA NTRS1988

Observational results of microwave temperature profile measurements from the airborne Antarctic ozone experiment

The Microwave Temperature Profiler, MTP, is installed on NASA's ER-2 aircraft. MTP measures profiles of air temperature versus altitude. Temperatures are obtained every 13.7 seconds for 15 altitudes in an altitude region that is approximately 5 km thick (at high flight levels). MTP is a passive microwave radiometer, operating at the frequencies 57.3 and 58.8 GHz. Thermal emission from oxygen molecules provides the signal that is converted to air temperature. MTP is unique in that it is the only airborne instrument of its kind. The MTP instrument was used during the Airborne Antarctic Ozone Experiment, AAOE, to enable potential vorticity to be measured along the flight track. Other uses for the MTP data have become apparent. The most intriguing unexpected use is the detection and characterization of mountain waves that were encountered during flights over the Palmer Peninsula. Mountain waves that propagate into the polar vortex may have implications for the formation of the ozone hole. Upward excursions of air parcels lead to a brief cooling. This can begin the process of cloud formation. It is important to determine how much additional formation of polar stratospheric cloud (PSC) material is possible by the passage of air parcels through a mountain wave pattern that endures for long periods. Other mountain wave effects have been suggested, such as a speeding up of the vortex, and a consequent cooling of large air volumes (which in turn might add to PSC production).

Gary, Bruce L.↗

NASA NTRS1987

Is there a weak mixed polarity background field? Theoretical arguments

A number of processes associated with the formation of active regions produce 'U-loops': fluxtubes having two ends at the photosphere but otherwise still embedded in the convection zone. The mass trapped on the field lines of such loops makes them behave in a qualitatively different way from the 'omega-loops' that form active regions. It is shown that U-loops will disperse though the convection zone and form a weak (down to a few gauss) field that covers a significant fraction of the solar surface. This field is tentatively identified with the inner-network fields observed at Kitt Peak and Big Bear. The process by which these fields escape through the surface is described; a remarkable property is that it can make active region fields apparently disappear in situ. The mixed polarity moving magnetic features near sunspots are interpreted as a locally intense form of this disappearance by escape of U-loops.

Spruit, H. C.↗

NASA NTRS1985

Effects of Simulated Weightlessness on Mammalian Development. Part 2: Meiotic Maturation of Mouse Oocytes During Clinostat Rotation

In order to understand the role of gravity in basic cellular processes that are important during development, the effects of a simulated microgravity environment on mammalian gametes and early embryos cultured in vitro are examined. A microgravity environment is simulated by use of a clinostat, which essentially reorients cells relative to the gravity vector. Initial studies have focused on assessing the effects of clinostat rotation on the meiotic progression of mouse oocytes. Modifications centered on providing the unique in vitro culture of the clinostat requirements of mammalian oocytes and embryos: 37 C temperature, constant humidity, and a 5% CO2 in air environment. The oocytes are observed under the dissecting microscope for polar body formation and gross morphological appearance. They are then processed for cytogenetic analysis.

Wolgemuth, D. J.↗

NASA NTRS1991

Infrared polarization images of star-forming regions. I - The ubiquity of bipolar structure

The inefficiency of the stellar formation process leads rather generally to high residual dust densities, and so to the existence of infrared reflection nebulosity (IRN), in regions of star formation. Polarization images of several star-forming regions with mass outflows (GSS 30, S255, GL 5180, GL 2591, GGD 27, and NGC 7538) presented here: (1) establish the universality of bipolarity and of shell or cavity structure in the IRN consistent with that of CO outflow; (2) identify the source of the mass outflow in each case; (3) show that the opening angle near this central source is large; and (4) demonstrate several instances of multiple shells, probably arising from episodic mass loss. Astrometry of 2.2-micron sources with arcsecond accuracy identifies the illuminating source of each IRN uniquely with a compact H II region or a bright IR source. The polarization images provide strong evidence for large-scale dust toroids around each of these sources. The density and mass of these disks are estimated from the extinction through the disk.

Tamura, M.↗

NASA NTRS2004

Evaluating the Credibility of Transport Processes in Simulations of Ozone Recovery using the Global Modeling Initiative Three-dimensional Model

The Global Modeling Initiative (GMI) has integrated two 36-year simulations of an ozone recovery scenario with an offline chemistry and tra nsport model using two different meteorological inputs. Physically ba sed diagnostics, derived from satellite and aircraft data sets, are d escribed and then used to evaluate the realism of temperature and transport processes in the simulations. Processes evaluated include barri er formation in the subtropics and polar regions, and extratropical w ave-driven transport. Some diagnostics are especially relevant to sim ulation of lower stratospheric ozone, but most are applicable to any stratospheric simulation. The global temperature evaluation, which is relevant to gas phase chemical reactions, showed that both sets of me teorological fields have near climatological values at all latitudes and seasons at 30 hPa and below. Both simulations showed weakness in upper stratospheric wave driving. The simulation using input from a g eneral circulation model (GMI(GCM)) showed a very good residual circulation in the tropics and Northern Hemisphere. The simulation with inp ut from a data assimilation system (GMI(DAS)) performed better in the midlatitudes than it did at high latitudes. Neither simulation forms a realistic barrier at the vortex edge, leading to uncertainty in the fate of ozone-depleted vortex air. Overall, tracer transport in the offline GML(GCM) has greater fidelity throughout the stratosphere tha n it does in the GMI(DAS)

Strahan, Susan E.↗

NASA NTRS2002

Racemic amino acids from the ultraviolet photolysis of interstellar ice analogues

The delivery of extraterrestrial organic molecules to Earth by meteorites may have been important for the origin and early evolution of life. Indigenous amino acids have been found in meteorites-over 70 in the Murchison meteorite alone. Although it has been generally accepted that the meteoritic amino acids formed in liquid water on a parent body, the water in the Murchison meteorite is depleted in deuterium relative to the indigenous organic acids. Moreover, the meteoritical evidence for an excess of laevo-rotatory amino acids is hard to understand in the context of liquid-water reactions on meteorite parent bodies. Here we report a laboratory demonstration that glycine, alanine and serine naturally form from ultraviolet photolysis of the analogues of icy interstellar grains. Such amino acids would naturally have a deuterium excess similar to that seen in interstellar molecular clouds, and the formation process could also result in enantiomeric excesses if the incident radiation is circularly polarized. These results suggest that at least some meteoritic amino acids are the result of interstellar photochemistry, rather than formation in liquid water on an early Solar System body.

Amino Acids/chemistry↗

NASA NTRS2003

Analysis of Properties of the North and South Polar Layered Deposits

Ivanov, A. B.↗

NASA NTRS2017

The Role of Magnetic Helicity in Structuring the Solar Corona

Two of the most widely observed and striking features of the Suns magnetic field are coronal loops, which are smooth and laminar, and prominences or filaments, which are strongly sheared. Loops are puzzling because they show little evidence of tangling or braiding, at least on the quiet Sun, despite the chaotic nature of the solar surface convection. Prominences are mysterious because the origin of their underlying magnetic structure filament channels is poorly understood at best. These two types of features would seem to be quite unrelated and wholly distinct. We argue that, on the contrary, they are inextricably linked and result from a single process: the injection of magnetic helicity into the corona by photospheric motions and the subsequent evolution of this helicity by coronal reconnection. In this paper, we present numerical simulations of the response of a Parker (1972) corona to photospheric driving motions that have varying degrees of helicity preference. We obtain four main conclusions: (1) in agreement with the helicity condensation model of Antiochos (2013), the inverse cascade of helicity by magnetic reconnection in the corona results in the formation of filament channels localized about polarity inversion lines; (2) this same process removes most complex fine structure from the rest of the corona, resulting in smooth and laminar coronal loops; (3) the amount of remnant tangling in coronal loops is inversely dependent on the net helicity injected by the driving motions; and (4) the structure of the solar corona depends only on the helicity preference of the driving motions and not on their detailed time dependence. We discuss the implications of our results for high-resolution observations of the corona.

Knizhnik, K. J.↗

NASA NTRS1990

Ice sublimation and rheology - Implications for the Martian polar layered deposits

If the sublimation and creep of water ice are important processes in the Martian polar layered deposits, ice-rich scenario formation and evolution schemes must invoke a mechanism for the inhibition of sublimation, such as a dust layer derived from the residue of the sublimating deposits. This layer could be of the order of 1 m in thickness. If the deposits are ice-rich, flows of more than 1 km should have occurred. It is noted that the dust particles in question may be cemented by such ice that may be present, but that impurities may also have served to cement dust particles together even in the absence of ice.

Hofstadter, Mark D.↗