Accelerated Testing of the Mechanical and Thermal Integrity of Polymeric Materials
Long time mechanical and thermal stability of polymeric materials predicted from accelerated testing at increased temperature-time relations
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Long time mechanical and thermal stability of polymeric materials predicted from accelerated testing at increased temperature-time relations
Polymeric materials thermal degradation kinetic parameters using combined mass spectrometric and thermogravimetric analysis /MS-TGA/
Calculation of electron energy deposition in thin- film polymeric materials
Stress-strain-time relations in filamentous high polymeric materials - Rheology
Polymeric materials in expulsion bladders for cryogenic liquids, describing fabrication, flexibility, permeability, storage, transfer, control factors, etc
Low outgassing polymeric materials for general service and communication satellite structures
Spacecraft polymeric material interactions during decontamination, sterilization, and thermal vacuum exposures
Two of the major environmental hazards in the Geosynchronous Earth Orbit (GEO) are energetic charged particles and ultraviolet radiation. The charged particles, electrons and protons, range in energy from 0.1 to 4 MeV and each have a flux of 10 to the 8th sq cm/sec. Over a 30 year lifetime, materials in the GEO will have an absorbed dose from this radiation of 10 to the 10th rads. The ultraviolet radiation comes uninhibited from the sun with an irradiance of 1.4 kw/sq m. Radiation is known to initiate chain sission and crosslinking in polymeric materials, both of which affect their structural properties. The 30-year dose level from the combined radiation in the GEO exceeds the threshold for measurable damage in most polymer systems studied. Of further concern is possible synergistic effects from the simultaneous irradiation with charged particles and ultraviolet radiation. Most studies on radiation effects on polymeric materials use either electrons or ultraviolet radiation alone, or in a sequential combination.
Thermal degradation of polymeric materials analyzed by combined mass spectrometric and thermogravimetric technique
Tabulated data on physical and electric properties of polymeric materials after irradiation in vacuum environment
Polymeric materials in expulsion bladders for cryogenic liquids, describing fabrication, flexibility, permeability, storage, transfer, control factors, etc
Partial analytical characterizations are made by four different techniques of three polymeric materials used in conjunction with the Space Telescope for samples flown on mission STS-8. The polymers were Tedlar, Kapton H, and Kapton F. The surfaces of the three polymers were attacked and oxidized by atomic oxygen, and fluorine is lost from the surface of Kapton F, largely due to displacement by atomic oxygen.
The thermomechanical properties of a number of widely used polymeric materials were determined by thermomechanical analysis and dynamic mechanical analysis. A combined profile of the coefficient of thermal expansion and the modulus change over a wide temperature range obtained by the analyses shows clearly the drastic effect of the glass transition on both the CTE and the modulus of a polymer, and the damaging potential due to such effect.
Various polymeric materials were evaluated at different temperatures for relative flammability as defined by the HC value, a measure of the concentration of combustibles related to the concentration representing the lower limit of flammability. Flammability generally decreased with increasing char yield. This appears to support the hypothesis that increasing char yield decreases flammability by reducing the probability of reaching the lower flammable limits.
Aerospace environmental effects on polymeric materials were studied. The polymers under study are being considered for use as structural materials for spacecraft and advanced aircraft. It is necessary to understand the durability of these polymers to the environment in which they are to be used.
High thermal conductivity polymeric materials for spacecraft applications using phenyl compounds
High thermal conductivity polymeric materials for spacecraft electronic equipment use
Relative toxicity data for a large number of natural and synthetic polymeric materials are presented which were obtained by 11 pyrolysis and three flaming-combustion test methods. The materials tested include flexible and rigid polyurethane foams, different kinds of fabrics and woods, and a variety of commodity polymers such as polyethylene. Animal exposure chambers of different volumes containing mice, rats, or rabbits were used in the tests, which were performed over the temperature range from ambient to 800 C with and without air flow or recirculation. The test results are found to be sensitive to such variables as exposure mode, temperature, air flow and dilution, material concentration, and animal species, but relative toxicity rankings appear to be similar for many methods and materials. It is concluded that times to incapacitance and to death provide a more suitable basis for relative toxicity rankings than percent mortality alone, that temperature is the most important variable in the tests reported, and that variables such as chamber volume and animal species may not significantly affect the rankings.