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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 37 records · Page 2

PISCES-RF: a liquid-cooled high-power steady-state helicon plasma device

Radio-frequency (RF) driven helicon plasma sources can produce relatively high-density plasmas (n > 1019 m -3 ) at relatively moderate powers (<2 kW) in argon. However, to produce similar high-density plasmas for fusion relevant gases such as hydrogen (H), deuterium (D) and helium (He), much higher RF powers are needed. For very high RF powers, thermal issues of the RF-transparent dielectric window, used in the RF source design, limit the plasma operation timescales. To mitigate this constraint, we have designed, built and tested a novel helicon plasma source assembly with a fully liquid-cooled RF-transparent window which allows steady state operations at high power (up to 20 kW) and successfully produces high-density plasma with both argon and H. Deionized (DI) water, flowing between two concentric dielectric RF windows, is used as the coolant. We show that a full azimuthal blanket of DI water does not prevent high-density plasma production. From calorimetry on the DI water, we measure the net heat removed by the coolant at steady state conditions. Using infra-red imaging, we calculate the constant plasma heat deposition and measure the final steady state temperature distribution patterns on the inner surface of the ceramic layer. The heat deposition pattern follows the helical shape of the antenna. We also show the consistency between the heat absorbed by the DI water, as measured by calorimetry, and the total heat due to the combined effect of the plasma heating and the absorbed RF. These results are being used to answer critical engineering questions for the 200 kW RF device materials plasma exposure experiment being designed at the Oak Ridge National Laboratory as a next generation plasma material interaction device.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Evaluation of the mean excitation energy of liquid argon

Current and future experiments need to know the stopping power of liquid argon. It is used directly in calibration, where commonly the minimum-ionizing portion of muon tracks is used as a standard candle. Similarly, muon range is used as a measure of muon energy. More broadly, the stopping power figures into the simulation of all charged particles, and so uncertainty propagates widely throughout data analysis of all sorts. The main parameter that controls stopping power is the mean excitation energy, or I-value. Experimental information for argon's I-value come primarily from measurements of gaseous argon, with a very limited amount of information from solid argon, and none from liquid argon. These measurements are reviewed, along with a discussion of the difference in central value and uncertainty incurred by the difference of phase. The values newly recommended by this note are $(188 \pm 6)$ eV for gaseous argon and $(197 \pm 8)$ eV for liquid argon (68% C.L. in each case).

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗

Photosynthetically-powered phototactic active nematic liquid crystal fluids and gels

Abstract One of the most ancient forms of life dating to ~3.5 billion years ago, cyanobacteria are highly abundant organisms that convert light into energy and motion, often within conjoined filaments and larger colonies that attract a great deal of interest but their active nematic behavior remained unexplored. Here we demonstrate how light causes a spontaneous self-assembly of two- and three-dimensional active nematic states of cyanobacterial filaments, with a plethora of topological defects. We quantify light-controlled evolutions of orientational and velocity order parameters during the transition between disordered and orientationally ordered states of photosynthetic active matter, as well as the subsequent active nematic’s fluid-gel transformation. Patterned illumination and foreign inclusions with different shapes interact with cyanobacterial active nematics in nontrivial ways while inducing interfacial boundary conditions and fractional boojum defects. Our phototactic model system promises opportunities to systematically explore fundamental properties and technological utility of the liquid crystalline active matter.

Repula, Andrii↗

Development of a silicon carbide ceramic based counter-flow heat exchanger by binder jetting and liquid silicon infiltration for concentrating solar power

A silicon carbide ceramic counter-flow heat exchanger with integrated headers was printed by binder jetting additive manufacturing process. Multiple phenolic binder infiltration cycles (3 or 5) followed by pyrolysis were conducted to increase the net carbon content of the printed SiC specimens. Subsequently, to attain full densification, silicon melt infiltration was used. The microstructure and mechanical properties were comprehensively characterized on the densified material. The chemical compositions and visual distribution of the various regions in the specimens were determined via scanning electron microscopy, while X-ray diffraction and synchrotron µ-computed tomography were used to provide a quantitative assessment of the volume fractions of the identified phase regions. Microhardness measurements showed dependence on the local microstructure. The fracture strength of the material was correlated with the specimen density and agreed with the reported values in the literature. High-temperature exposure at 750 °C for up to 200h did not degrade the strength for the specimens with three phenolic-binder infiltrations; however, the strengths degraded for ones with five phenolic-binder infiltrations. The associated fracture toughnesses of the specimens were ~3.4 MPam 1/2 at room temperature and 750°C, and the thermal conductivities varied from >150 W/mK at room temperature to ~45 W/mK at 750°C. Hence, this study validated the use of the binder-jetting printed SiC ceramic materials for high-temperature heat exchanges. Lastly, we also present in this work the first successful fabrication of a binder-jetting printed one-piece dense SiC ceramic heat exchanger body with unblocked channels that can be used for the flow of heat transfer fluids.

36 MATERIALS SCIENCE↗

Development of an anti-clogging perforated plate atomizer for a zero liquid discharge humidification-dehumidification desalination system

An anti-clogging perforated plate atomizer is designed for high temperature and salinity applications in a novel solar-powered zero liquid discharge humidification-dehumidification desalination system (US Patent Application US62882953). Herein this paper presents a detailed discussion on its design, and operation. Experiments are performed on seven atomizers to study the effect of design, and operating parameters on spray cone angle, and average droplet diameter. Spray cone angle remains constant with change in air mass flux, and increases with increasing orifice diameter, and manifold diameter. It also increases initially with water mass flow rate, and manifold height, before attaining a constant value. Average droplet diameter increases with increasing water mass flow rate, and decreasing air mass flux, orifice diameter, and manifold diameter. Further, anti-clogging performance of the atomizer is tested with hypersaline water of 100,000 ppm total dissolved solid (NaCl) at elevated temperatures such as air at 175 °C and saline water at 45 °C. Results show no clogging for 2–13 h of operation. Near-complete suppression of atomizer clogging makes our new additively-manufactured perforated plate atomizer an ideal fit for high salinity, and zero liquid discharge humidification-dehumidification desalination systems. Additionally, its open-surface design allows additional surface modifications to further reduce clogging, and enhance self-cleaning characteristics.

47 OTHER INSTRUMENTATION↗

The LIBRA Experiment: Investigating Robust Tritium Accountancy in Molten FLiBe Exposed to a D-T Fusion Neutron Spectrum

The Liquid Immersion Blanket: Robust Accountancy (LIBRA) experiment will be a first-of-a-kind experiment to explore and develop the liquid immersion blanket (LIB) concept. The LIB is a radically simple molten–LiF-BeF2 (FLiBe)–salt tritium breeding blanket for deuterium-tritium (D-T)–fueled fusion power plants (FPPs) achieving a high tritium breeding ratio (TBR) in neutronics models. However, tritium breeding in FLiBe is inherently difficult to study experimentally. As a result, the coupled issues of FLiBe radiochemistry and tritium (T) transport are poorly understood. LIBRA approaches this challenge by simulating an FPP blanket environment using a D-T neutron generator and ≈ 1000 kg of FLiBe. LIBRA will investigate T breeding, containment, and extraction, coupled with FLiBe redox control and radiochemistry. The primary goal of LIBRA is to demonstrate robust T accountancy in blanket prototypical conditions. Here, T accountancy encompasses accurate predictions of T breeding in the FLiBe; detection and measurement of all T bred in LIBRA; and speciation of the T extracted from the FLiBe. Initial neutronics simulations of LIBRA indicate that a global TBR of ~ 1 is possible, where the TBR is defined as the number of tritons bred and extracted from FLiBe relative to the number of neutrons produced by D-T fusion reactions in the neutron generator. In this paper, we present the LIBRA concept and its scientific goals in the context of T breeding experiments. We also consider the potential impact of the LIB on the future fusion power industry, motivating further development of FLiBe-based T breeding research activities such as LIBRA.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Exploring self-healing liquid metal mirrors for high-power laser applications

Here we explore the laser-damage behavior of gallium alloy-based liquid metal mirrors for their potential to provide higher damage-threshold performance. One of the key advantages of using liquid metal mirrors is the self-healing potential following perturbations arising from exposure to high-power laser pulses. In this work, key performance metrics, such as reflectivity and the laser-damage initiation mechanism and initiation threshold, were investigated using fused-silica cells filled with three different Ga liquid metal alloys. The results suggest that irreversible modification (damage) under 355- nm, 6-ns pulses are associated with the formation of gallium oxide, taking place at a fluence significantly higher than that for damage initiation in conventional metal mirrors. This exploratory work is the first of its kind and highlights the strong performance of gallium alloy metal mirrors.

47 OTHER INSTRUMENTATION↗

Deep Electrification Analysis: The Role of the U.S. Power Grid for Sustainable Transportation

This project attempts to quantify the size of electric generation for the entire nation to transition from a fossil fuel based transportation sector to a zero GHG emission-based energy source. The scope of this analysis is limited to decarbonizing the transportation sector, leaving the remaining sectors, such as power (for those that are still fossil based), industry, and building sectors, for later phases of study. The study year for this analysis is 2050, with expected escalation in transportation services and naturally occurring evolutions in the electric power sector and the entire economy. This analysis uses the projections of the Energy Information Administration’s (EIA’s) Annual Energy Outlook (AEO 2020) Reference Case for study year 2050 [EIA/AEO2020] as a base-case. The transportation sector is disaggregated by the following modes and classes: (1) on-road (divided into light-duty, medium-duty, heavy-duty vehicles), (2) aviation, (3) maritime, and (4) rail. The decarbonization case was based on only 2 pathways: (1) electrification of on-road transportation except for 30% of heavy-duty vehicles, and (2) power-to-liquid for the remaining transportation modes. The study estimated for 11 US regions what the additional wind and storage capacities requirements are to replace the fossil-based fuels with renewable wind capacity. Considered were the utilization of the existing idle capacity particularly during the load valley at night and any additional new generation capacity in EIA projections for the reference case. To balance the additional wind capacity required significant energy storage capabilities which were estimated in terms of power capacity (GW) and energy capacity (GWh). The paper further characterizes the energy requirements by a relation of power capacity to duration, allowing the analyst to gain insights into what the best technology portfolio might be to meet the new balancing or flexibility needs.

24 POWER TRANSMISSION AND DISTRIBUTION↗

The Role of Fuels in Transforming Energy End-Use in Buildings and Industrial Processes

This book examines what role fuels have in the transformation of end-use in buildings and industrial processes. Energy efficient technologies are necessary to lower the carbon footprint for a transition towards clean energy in a sustainable manner. Efficient utilization of primary energy resources including renewables to support the current and future energy needs while targeting grid resiliency, energy and environmental security, at an affordable cost is of significant value. Analysis of configurations consisting of heat pumps, fuel driven thermal providers and power systems is presented. Sensitivity of electrical grid's carbon intensity towards carbon footprint in comparison with fuel driven technologies is necessary to recognize the true value proposition of currently available energy solutions for different end consumers. Similarly, the role of low carbon, zero carbon, and carbon negative fuels such as power to gas, power to liquid, hydrogen, biogas, etc. in conjunction with polygeneration technologies are discussed. Transformation of the primary energy resources from conventional fossil fuels to renewable fuels or electricity will have a significant impact on the overall carbon footprint of various end use sectors, including buildings. Hence, this book also examines two different scenarios focused on sensitivity of the pace of decarbonization of electrical grid and fuel supply on operational energy related carbon emissions.

Cheekatamarla, Praveen↗

Moisture-induced autonomous surface potential oscillations for energy harvesting

A variety of autonomous oscillations in nature such as heartbeats and some biochemical reactions have been widely studied and utilized for applications in the fields of bioscience and engineering. Here, we report a unique phenomenon of moisture-induced electrical potential oscillations on polymers, poly([2-(methacryloyloxy)ethyl] dimethyl-(3-sulfopropyl) ammonium hydroxide-co-acrylic acid), during the diffusion of water molecules. Chemical reactions are modeled by kinetic simulations while system dynamic equations and the stability matrix are analyzed to show the chaotic nature of the system which oscillates with hidden attractors to induce the autonomous surface potential oscillation. Using moisture in the ambient environment as the activation source, this self-excited chemoelectrical reaction could have broad influences and usages in surface-reaction based devices and systems. As a proof-of-concept demonstration, an energy harvester is constructed and achieved the continuous energy production for more than 15,000 seconds with an energy density of 16.8 mJ/cm 2 . A 2-Volts output voltage has been produced to power a liquid crystal display toward practical applications with five energy harvesters connected in series.

42 ENGINEERING↗

Sustainable Aviation Fuel State-of-Industry Report: Hydroprocessed Esters and Fatty Acids Pathway

Climate change is a pressing issue that requires immediate and decisive action to ensure a sustainable future. To reduce CO 2 emissions and speed up the transition to net-zero aviation, the Biden administration has launched the "Sustainable Aviation Fuels (SAF) Grand Challenge" to scale up production of SAF. The challenge aims to achieve 20% reduction in aviation emissions by producing 3 billion gallons per year (BGPY) of SAF by 2030 and to meet 100% of aviation fuel demand by producing 35 BGPY of SAF by 2050. In this report, we provide an overview of the current state of the hydroprocessed esters and fatty acids (HEFA) SAF industry, guided by the perspectives of the interviewed experts. Currently, the HEFA pathway is the only commercially deployed method to produce significant amounts of SAF. As a result, SAF produced via the HEFA pathway is expected to make the largest contribution to achieving the 2030 production target and play a key role in boosting and establishing the SAF market. Announced SAF's total capacity, including alcohol-to-jet, FT, and power-to-liquid facilities, is expected to reach 2 BGPY by 2030 (1), with the expected from HEFA. Total HEFA capacity, including construction and planned projects, is expected to reach about 9 BGPY by 2030; if completely executed, this would contribute to renewable diesel (RD) and SAF. The production ratio of SAF and RD will depend on market conditions, incentives, and the capabilities of facilities. While some stakeholders believe that the 2030 goal may be achieved solely via HEFA, others believe that overly relying on HEFA may be detrimental to the development of other necessary pathways to meet 2050 goals. Our conclusion is that the HEFA pathway alone will not be sufficient to reach the 2030 target. It is crucial to implement additional pathways to reach the goal. This report conducts a comprehensive analysis and evaluation of the HEFA SAF value chain. Our aim is to provide current status of the industry and to identify potential challenges that could hinder the commercial production and use of SAF produced through the HEFA pathway. We have had extensive discussions, consultations, and collaborative sessions with stakeholders in the HEFA SAF value chain, including HEFA feedstocks, potential volume of HEFA SAF, economic and sustainability metrics when compared to petroleum, and assessment of the HEFA SAF industry's ability to grow and contribute to achieving the "SAF Grand Challenge." Since the HEFA pathway produces both SAF and RD, this report compares both pathways: HEFA to SAF and HEFA to RD.

09 BIOMASS FUELS↗

An Overview of Potential Future Aviation Energy Carriers

Global jet fuel demand is projected to grow to 165 billion gallons by 2050 and there is growing interest in the aviation industry to understand the capabilities of alternative energy carriers. This report considers several potential energy carriers, reviewing their production potential, operational considerations, and economic implications to inform potential next steps in aeronautics research. The following energy carriers (i.e., fuels) were evaluated in this study for future use in aviation: sustainable aviation fuel (SAF) - both biomass-based and power-to-liquids (PtL) - based SAF - cryogenic hydrogen (LH 2 ) - also known as liquid hydrogen - liquefied natural gas (LNG), liquefied ethane (LE), and Jet X. The barriers and opportunities for the evaluated energy carriers vary. SAF is a commercially available drop-in fuel compatible with existing aircraft and infrastructure. SAF is limited by both higher prices and slow commercialization of multiple pathways using different feedstocks necessary to significantly grow supply. Cryogenic fuels, in contrast, have very different thermal, physical, and chemical properties than SAF and Jet A, requiring the construction of new airport storage and dispensing infrastructure and the design of new aircraft energy systems capable of mitigating heat transfer and boil-off. Cryogenic fuels offer an opportunity to diversify aviation fuel carriers from domestic energy relevant for both energy security and resilience. This means cryogenic fuels are more of a longer-term solution for aircraft but are worth exploring for potential future cost savings and emissions benefits. Jet X refers to non-drop-in liquid hydrocarbon fuels in the early stages of investigation seeking favorable properties. There are substantial barriers to non-drop-in liquid aviation fuels that are not compatible with existing aircraft and fuel infrastructure.

33 ADVANCED PROPULSION SYSTEMS↗

Maturation of Next Generation eSAF (CRADA Final Report)

Assessment of current and potential future eSAF production pathways (Power to Liquids, eMethanol to Jet, etc.) against current incumbents (HEFA, Alcohol to Jet) evaluating the overall costs of production, scalability of process, market demand, and policy/ regulatory/ standards for flight.

33 ADVANCED PROPULSION SYSTEMS↗

Zero Liquid Discharge and Water Reuse in Recirculating Cooling Towers at Power Facilities: Review and Case Study Analysis

Zero liquid discharge (ZLD) systems installed at power facilities with the primary purpose of meeting water discharge regulations have the added benefit of providing high quality effluent that can be reused in the facility. This paper provides a review of water use in power sector recirculating cooling towers and a baseline assessment of on-site water reuse at natural gas combined cycle (NGCC) power facilities. Two NGCC facilities with reverse-osmosis (RO) or brine-concentrator processes followed by evaporation ponds were selected as case studies; data from these facilities were used to quantify the water, energy, and cost implications of implementing conventional and emerging ZLD technologies. At one case study facility, model results show that implementation of ZLD would reduce water withdrawals by 18%, which is less than savings associated with implementation of dry cooling but comparable to current efforts to reduce water withdrawals by increasing cycles of concentration. Implementation of ZLD using high-recovery RO resulted in a doubling of the levelized cost of water (LCOW). LCOW increased more when a brine concentrator was used. For both case studies, the ZLD system using high-recovery RO required less than 0.1% of a facilitiy's annual electricity generation and the ZLD system using a brine concentrator process required less than 0.8%. Additionally, increasing the evaporation pond area to minimize required ZLD system recovery rates and reduce system electricity costs does not reduce the LCOW. Instead, the LCOW increases because less water is recovered and more water is lost to evaporation. Furthermore, if water availability decreases or water competition/cost increases, facilities may be incentivized to maximize water recovery from ZLD systems.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

Motility of acoustically powered micro-swimmers in a liquid crystalline environment

Suspensions of microswimmers in liquid crystals demonstrate remarkably complex dynamics and serve as a model system for studying active nematics. So far, experimental realization of microswimmers suspended in liquid crystalline media has relied on biological microorganisms that impose strict limitations on the compatible media and makes it difficult to regulate activity. Here, we demonstrate that acoustically powered bubble microswimmers can efficiently self-propel in a lyotropic liquid crystal. The velocity of the swimmers is controlled by the amplitude of the acoustic field. Histograms of swimming directions with respect to the local nematic field reveal a bimodal distribution: the swimmers tend to either fully align with or swim perpendicular to the director field of the liquid crystal, occasionally switching between these two states. The bubble-induced streaming from a swimmer locally melts the liquid crystal and produces topological defects at the tail of the swimmer. Further, we show that the defect proliferation rate increases with the angle between the swimmer's velocity and the local orientation of the director field.

36 MATERIALS SCIENCE↗

Optimization of laser-induced breakdown spectroscopy for liquid sodium analysis

Next-generation nuclear power reactors based on liquid sodium coolant are in development to improve efficiency and safety. Fast breeder reactors could potentially achieve considerably higher fuel burn-up while producing less nuclear waste compared with current commercial technology. Monitoring of impurities in these types of reactors is important in order to prevent blockage of the cooling system or hazardous reactions due to the high reactivity of sodium with water. In this work, laser-induced breakdown spectroscopy is performed on a liquid sodium sample using a custom-built immersion probe system. The probe provides direct line of sight to the sample vessel in argon atmosphere for laser delivery and signal collection. Signatures of sodium, and impurities such as potassium and oxygen have been obtained. The probe height and immersion have a strong influence on the signal level and stability. Argon flow rates of 2 to 5 liters per minute produce no substantial change in signal, suggesting a steady laminar flowing regime. A high signal-to-noise ratio for impurity elements confirms the suitability of this technique for reliable impurity detection and monitoring in the reactor environment.

Gardette, V. [University of Michigan, Ann Arbor, M↗

Accelerator commissioning and rare isotope identification at the Facility for Rare Isotope Beams

In 2008, Michigan State University was selected to establish the Facility for Rare Isotope Beams (FRIB). Construction of the FRIB accelerator was completed in January 2022. Phased accelerator commissioning with heavy ion beams started in 2017 with the normal-conducting ion source and radio-frequency quadrupole. In April 2021, the full FRIB driver linear accelerator (linac) was commissioned, with heavy ion beams accelerated to energies above 200 MeV/nucleon by 324 superconducting radiofrequency (SRF) resonators operating at 2 K and 4 K with liquid-helium cooling. Further, in preparation for high-power operation, a liquid lithium charge stripper was commissioned with heavy ion beams up to uranium-238, followed by the simultaneous acceleration of multiple-charge-state heavy ion beams to energies above 200 MeV/nucleon. In December 2021, selenium-84 was produced with the FRIB target using a krypton-86 primary beam, demonstrating FRIB’s capability for scientific discovery.

07 ISOTOPE AND RADIATION SOURCES↗