Search NASA⌕ Search

SEARCH · Search NASA

Results for “pullout”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 37 records · Page 2
All sourcesNASA NTRSDOE OSTI
DOE OSTI2025

Concentration-Driven Slowdown of Chain-Exchange Kinetics in Block Copolymer Micelle Solutions

Here, we investigate the dependence of chain-exchange kinetics on polymer concentration for spherical micelles prepared from a polystyrene-b-poly(ethylene-alt-propylene) (SEP) diblock copolymer ( M n = 75 kDa, Ð = 1.05, and f PS = 0.18) in the PEP-selective solvent squalane. Solutions with concentrations of 15 vol% or more adopt a body-centered-cubic (BCC) packing of micelles, or a dense liquid-like packing (LLP), as confirmed by small-angle X-ray scattering. Concurrently, the mean aggregation number of the micelles grows steadily from about 60 in dilute solution to nearly 200 by 50 vol%. Time-resolved small-angle neutron scattering (TR-SANS) analysis reveals a monotonic and substantial (i.e., more than four orders of magnitude) decrease in the rate of chain exchange as the polymer concentration increases from 1 to 50 vol%. The TR-SANS relaxation functions are analyzed, taking into account both changes in contrast (due to chain exchange) and evolution in the structure factor (due to refinement of micelle packing). The activation energy for chain pullout is extracted using an established model and can be expressed as a linear function of polymer concentration, indicating that, in addition to the enthalpic barrier for extracting the core block, the evolution of micelle characteristics with increasing concentration imposes further constraints on chain exchange. Consistent with a theory of Halperin, these results suggest that the dominant factor reflects steric penalties during core block pullout arising from a reduced interfacial area per chain and associated increased corona crowding, due to the increase in aggregation number. The rate of exchange is independent of whether the micelles adopt a BCC or LLP arrangement, confirming that the rate-limiting step is extraction of the core block.

chemical structure↗
DOE OSTI2025

How Does the Rate of Chain Exchange Relate to Stress Relaxation in Triblock Copolymer Networks?

The relationship between macroscopic stress relaxation and molecular-level chain exchange in triblock copolymer micelles has been explored using rheology and time-resolved small-angle neutron scattering (TR-SANS), marking the first measurements of chain exchange in concentrated triblock networks. It has long been assumed in models of transient or thermoreversible networks that the time scales for these two processes are equal. Experimentally, we find that stress relaxation occurs many orders-of-magnitude faster than chain exchange. This difference is quantitatively explained by modest dispersity in the core block that results in a slight asymmetry within any given nominally symmetric triblock. For stress relaxation to occur, only the shorter chain must pull out, while chain exchange is slowed due to the requirement of the eventual pullout of the longer block. The pullout time is extremely sensitive to the length of the core block. This mechanism is supported by measurements with an intentionally asymmetric triblock copolymer, which displays an even larger difference between the stress relaxation and chain exchange rates. These results establish a quantitative molecular-level picture of the chain dynamics associated with stress relaxation in triblock copolymer networks.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2015

Use of polypropylene fibers coated with nano-silica particles into a cementitious mortar

Fiber reinforced cementitious composite (FRCC) materials have been widely used during last decades in order to overcome some of traditional cementitious materials issues: brittle behaviour, fire resistance, cover spalling, impact strength. For composite materials, fiber/matrix bond plays an important role because by increasing fiber/matrix interactions is possible to increase the behaviour of the entire material. In this study, in order to improve fiber to matrix adhesion, two chemical treatments of polypropylene fibers were investigated: alkaline hydrolysis and nano-silica sol-gel particles deposition. Treatmtents effect on fibers morphology and mechanical properties was investigated by scanning electron microscopy (SEM) and tensile tests. SEM investigations report the presence of spherical nano-silica particles on fiber surface, in the case of sol-gel process, while alkaline hydrolysis leads to an increase of fibers roughness. Both treatments have negligible influence on fibers mechanical properties confirming the possibility of their use in a cementitious mortar. Pullout tests were carried out considering three embedded length of fibers in mortar samples (10, 20 and 30 mm, respectively) showing an increase of pullout energy for treated fibers. The influence on fiber reinforced mortar mechanical properties was investigated by three-point flexural tests on prismatic specimens considering two fibers length (15 and 30 mm) and two fibers volume fractions (0.50 and 1.00 %). A general increase of flexural strength over the reference mix was achieved and an overall better behaviour is recognizable for mortars containing treated fibers.

36 MATERIALS SCIENCE↗
DOE OSTI2020

Mechanical and Corrosion Assessment of Friction Self-Piercing Rivet Joint of Carbon Fiber-Reinforced Polymer and Magnesium Alloy AZ31B

In the present work, thermoset carbon fiber–reinforced polymer (CFRP) was spot joined to magnesium alloy AZ31B by a friction self-piercing riveting (F-SPR) process. Lap shear tensile and cross-tension testing were used to evaluate the mechanical joint performance. An average lap shear tensile load of 5.18 kN was achieved, while an average of 2.81 kN was found from cross-tension testing. All F-SPR samples showed a pullout of AZ31B after mechanical testing, indicating good mechanical interlocking between the steel rivet and AZ31B. Corrosion potential was measured for each material to establish the galvanic corrosion characteristics. As expected, AZ31B was found to be the most active, while thermoset CFRP was the most noble. The steel rivet fell between the AZ31B (active) and the thermoset CFRP (noble). Salt fog corrosion testing (ASTM B-117) was performed to evaluate the corrosion performance of the uncoated F-SPR joint. With up to 200 h of exposure, the post-corroded F-SPR joint integrity retained 81.2% of the pre-exposure F-SPR joint strength with AZ31B pullout failure mode. From cross-sectional analysis of the F-SPR joint, extensive corrosion of AZ31B was observed at the joint and other exposure areas. However, steel rivet was not significantly corroded due to sacrificial anode effect by which AZ31B corroded first in the galvanic couple.

36 MATERIALS SCIENCE↗
NASA NTRS1981

Ocular torsion on earth and in weightlessness

Otolith function is studied by means of measurements of ocular torsion under various acceleration environments on earth and in weightlessness. Photographic measurements of ocular torsion as indicated by the rotation of landmarks on the iris with respect to head-fixed fiducial marks were obtained in subjects undergoing horizontal linear acceleration in a ground-based version of the space sled, lateral acceleration from weightlessness during pullout from the free-fall portion of parabolic flight, and optokinetic stimulation about the roll axis in the supine position in the laboratory and during weightlessness. The responses of ocular torsion to horizontal acceleration are in agreement with a simple low-order linear system with a dominant time constant of 0.33 sec, with a transfer function fit by a model with a pure delay of 0 to 400 msec and a first-order lag. In the pullout experiment, torsion was not observed in response to the onset of acceleration in the right-ear-down position, although it was present in response to the lateral stimulus. Results of the roll vection experiments indicate the independence of ocular torsion and visually induced tilt. In addition, an automatic video system using a soft contact lens target is presented which has been developed for ocular torsion measurements.

Young, L. R.↗
NASA NTRS1985

Polymer matrix and graphite fiber interface study

Hercules AS4 graphite fiber, unsized, or with EPON 828, PVA, or polysulfone sizing, was combined with three different polymer matrices. These included Hercules 3501-6 epoxy, Hercules 4001 bismaleimide, and Hexcel F155 rubber toughened epoxy. Unidirectional composites in all twelve combinations were fabricated and tested in transverse tension and axial compression. Quasi-isotropic laminates were tested in axial tension and compression, flexure, interlaminar shear, and tensile impact. All tests were conducted at both room temperature, dry and elevated temperature, and wet conditions. Single fiber pullout testing was also performed. Extensive scanning electron microphotographs of fracture surfaces are included, along with photographs of single fiber pullout failures. Analytical/experimental correlations are presented, based on the results of a finite element micromechanics analysis. Correlations between matrix type, fiber sizing, hygrothermal environment, and loading mode are presented. Results indicate that the various composite properties were only moderately influenced by the fiber sizings utilized.

Adams, D. F.↗
NASA NTRS1992

Piloted simulation study of a balloon-assisted deployment of an aircraft at high altitude

A piloted simulation was used to study the feasibility of a balloon assisted deployment of a research aircraft at high altitude. In the simulation study, an unmanned, modified sailplane was carried to 110,000 ft with a high altitude balloon and released in a nose down attitude. A remote pilot controlled the aircraft through a pullout and then executed a zoom climb to a trimmed, 1 g flight condition. A small parachute was used to limit the Mach number during the pullout to avoid adverse transonic effects. The use of small rocket motor was studied for increasing the maximum attainable altitude. Aerodynamic modifications to the basic sailplane included applying supercritical airfoil gloves over the existing wing and tail surfaces. The aerodynamic model of the simulated aircraft was based on low Reynolds number wind tunnel tests and computational techniques, and included large Mach number and Reynolds number effects at high altitude. Parametric variations were performed to study the effects of launch altitude, gross weight, Mach number limit, and parachute size on the maximum attainable stabilized altitude. A test altitude of approx. 95,000 ft was attained, and altitudes in excess of 100,000 ft was attained.

Murray, James↗
NASA NTRS1993

High-altitude balloon-launched aircraft - A piloted simulation study

A real-time piloted simulation at the NASA Dryden Flight Research Facility was used to study the feasibility of launching a research aircraft from a high-altitude balloon. In the study, the simulated aircraft was launched in a nosedown attitude at zero airspeed from 110,000 ft. After launch, the pilot flew the aircraft through a near-maximum-lift pullout and then through a zoom climb to a trimmed, l-g flight condition at the test altitude. The study included parametric variations to measure the effects of launch altitude, gross weight, Mach number limit, and parachute size on the test altitude attained. The aerodynamic model of the simulated aircraft was based on flight test results, low Reynolds number windtunnel tests, and computational models; the model included significant Mach number and Reynolds number effects at high altitude. A small parachute was included in the simulation to limit Mach number during the pullout to avoid adverse transonic effects and their resultant energy losses. A small rocket motor was included in the simulation and was investigated for boosting the aircraft to a higher test altitude. In the study, a test altitude of approximately 95,000 ft was attained without rocket boost, and a test altitude in excess of 100,000 ft was attained using small rocket boost.

Murray, James E.↗
NASA NTRS1996

Development and testing of airfoils for high-altitude aircraft

Specific tasks included airfoil design; study of airfoil constraints on pullout maneuver; selection of tail airfoils; examination of wing twist; test section instrumentation and layout; and integrated airfoil/heat-exchanger tests. In the course of designing the airfoil, specifically for the APEX test vehicle, extensive studies were made over the Mach and Reynolds number ranges of interest. It is intended to be representative of airfoils required for lightweight aircraft operating at extreme altitudes, which is the primary research objective of the APEX program. Also considered were thickness, pitching moment, and off-design behavior. The maximum ceiling parameter M(exp 2)C(sub L) value achievable by the Apex-16 airfoil was found to be a strong constraint on the pullout maneuver. The NACA 1410 and 2410 airfoils (inverted) were identified as good candidates for the tail, with predictable behavior at low Reynolds numbers and good tolerance to flap deflections. With regards to wing twist, it was decided that a simple flat wing was a reasonable compromise. The test section instrumentation consisted of surface pressure taps, wake rakes, surface-mounted microphones, and skin-friction gauges. Also, a modest wind tunnel test was performed for an integrated airfoil/heat-exchanger configuration, which is currently on Aurora's 'Theseus' aircraft. Although not directly related to the APEX tests, the aerodynamics or heat exchangers has been identified as a crucial aspect of designing high-altitude aircraft and hence is relevant to the ERAST program.

Drela, Mark↗
NASA NTRS2011

Modifying Matrix Materials to Increase Wetting and Adhesion

In an alternative approach to increasing the degrees of wetting and adhesion between the fiber and matrix components of organic-fiber/polymer matrix composite materials, the matrix resins are modified. Heretofore, it has been common practice to modify the fibers rather than the matrices: The fibers are modified by chemical and/or physical surface treatments prior to combining the fibers with matrix resins - an approach that entails considerable expense and usually results in degradation (typically, weakening) of fibers. The alternative approach of modifying the matrix resins does not entail degradation of fibers, and affords opportunities for improving the mechanical properties of the fiber composites. The alternative approach is more cost-effective, not only because it eliminates expensive fiber-surface treatments but also because it does not entail changes in procedures for manufacturing conventional composite-material structures. The alternative approach is best described by citing an example of its application to a composite of ultra-high-molecular- weight polyethylene (UHMWPE) fibers in an epoxy matrix. The epoxy matrix was modified to a chemically reactive, polarized epoxy nano-matrix to increase the degrees of wetting and adhesion between the fibers and the matrix. The modification was effected by incorporating a small proportion (0.3 weight percent) of reactive graphitic nanofibers produced from functionalized nanofibers into the epoxy matrix resin prior to combining the resin with the UHMWPE fibers. The resulting increase in fiber/matrix adhesion manifested itself in several test results, notably including an increase of 25 percent in the maximum fiber pullout force and an increase of 60-65 percent in fiber pullout energy. In addition, it was conjectured that the functionalized nanofibers became involved in the cross linking reaction of the epoxy resin, with resultant enhancement of the mechanical properties and lower viscosity of the matrix.

Zhong, Katie↗
NASA NTRS2011

Fiber-Reinforced Reactive Nano-Epoxy Composites

An ultra-high-molecular-weight polyethylene/ matrix interface based on the fabrication of a reactive nano-epoxy matrix with lower surface energy has been improved. Enhanced mechanical properties versus pure epoxy on a three-point bend test include: strength (25 percent), modulus (20 percent), and toughness (30 percent). Increased thermal properties include higher Tg (glass transition temperature) and stable CTE (coefficient of thermal expansion). Improved processability for manufacturing composites includes faster wetting rates on macro-fiber surfaces, lower viscosity, better resin infusion rates, and improved rheological properties. Improved interfacial adhesion properties with Spectra fibers by pullout tests include initial debonding force of 35 percent, a maximum pullout force of 25 percent, and energy to debond at 65 percent. Improved mechanical properties of Spectra fiber composites (tensile) aging resistance properties include hygrothermal effects. With this innovation, high-performance composites have been created, including carbon fibers/nano-epoxy, glass fibers/nano-epoxy, aramid fibers/ nano-epoxy, and ultra-high-molecularweight polyethylene fiber (UHMWPE).

Zhong, Wei-Hong↗
NASA NTRS2016

Z-2 Threaded Insert Design and Testing Abstract

The Z-2 Prototype Planetary Extravehicular Space Suit Assembly is a continuation of NASA's Z series of spacesuits. The Z-2 is another step in the NASA's technology development roadmap leading to human exploration of the Martian surface. To meet a more challenging set of requirements than previous suit systems standard design features, such as threaded inserts, have been re-analyzed and improved. NASA's Z-2 prototype space suit contains several components fabricated from an advanced hybrid composite laminate consisting of IM10 carbon fiber and fiber glass. One requirement NASA levied on the suit composites was the ability to have removable, replaceable helicoil inserts to which other suit components would be fastened. An approach utilizing bonded in inserts with helicoils inside of them was implemented. The design of the interface flanges of the composites allowed some of the inserts to be a "T" style insert that was installed through the entire thickness of the laminate. The flange portion of the insert provides a mechanical lock as a redundancy to the adhesive aiding in the pullout load that the insert can withstand. In some locations it was not possible to utilize at "T" style insert and a blind insert was used instead. These inserts rely completely on the bond strength of the adhesive to resist pullout. It was determined during the design of the suit that the inserts did not need to withstand loads induced from pressure cycling but instead tension induced from torqueing the screws to bolt on hardware which creates a much higher stress on them. Bolt tension is determined by dividing the torque on the screw by a k value multiplied by the thread diameter of the bolt. The k value is a factor that accounts for friction in the system. A common value used for k for a non-lubricated screw is 0.2. The k value can go down by as much as 0.1 if the screw is lubricated which means for the same torque, a much larger tension could be placed on the bolt and insert. This paper summarizes testing that was performed to determine a k value for helicoil inserts in the Z2 suit and how the insert design was modified to resist a higher pull out tension.

Rhodes, RIchard↗
DOE OSTI2019

Characterization of Static Performance and Failure of Resistance Spot Welds of High-Strength and Press-Hardened Steels

The static performances and failure characteristics of resistance spot welds (RSW) of steel sheets were studied in this work. Both similar and dissimilar joints of press-hardened steel grade 22MnB5 and as-rolled high-strength steel grade 1000 were examined. From metallographic analyses and micro-hardness measurements, it was shown that the microstructures of base metal (BM), heat affected zone (HAZ) and fusion zone of steel joints were noticeably different. In particular, the HAZ close to BM or subcritical HAZ (SCHAZ) of 22MnB5 steel exhibited greatly decreased hardness due to occurring tempered martensite, in which carbide precipitation was clearly observed. Furthermore, tensile shear test and cross-tension test of the welded steel sheets were carried out. The determined maximum loads, energy absorbability and corresponding failure mechanisms were analyzed and compared. The RSW samples of similar steel grade 1000 provided the highest load-carrying capacity and absorbed energy in both tests. Due to the large hardness difference and soft zone in weldment of dissimilar steel specimen, failure loads and static absorbed energies were deteriorated up to 17 and 68%, respectively. The observed fracture occurrences of all investigated joints were pullout failure mode, in which BM and HAZ were the crack initiation sites of grades 1000 steel and 22MnB5 steel, respectively. The SCHAZ of welded boron steel considerably caused the failure onset in tension shear test, but seemed to have negligible effect on cross-tension test.

36 MATERIALS SCIENCE↗
DOE OSTI2019

First-principles study, fabrication and characterization of (Zr 0.25 Nb 0.25 Ti 0.25 V 0.25 )C high-entropy ceramics

The formation possibility of a new (Zr 0.25 Nb 0.25 Ti 0.25 V 0.25 )C high-entropy ceramics (ZHC-1) was first analyzed by the first-principles calculations and thermodynamical analysis and then it was successfully fabricated by hot pressing sintering technique. The first-principles calculation results showed that the mixing enthalpy of ZHC-1 was 5.526 kJ/mol and the mixing entropy of ZHC-1 was in the range of 0.693R–1.040R. The thermodynamical analysis results showed that ZHC-1 was thermodynamically stable above 959 K owing to its negative mixing Gibbs free energy. The experimental results showed that the as-prepared ZHC-1 (95.1% relative density) possessed a single rock-salt crystal structure, some interesting nano-plate-like structures, and high compositional uniformity from nanoscale to microscale. By taking advantage of these unique features, compared with the initial metal carbides (ZrC, NbC, TiC and VC), it showed a relatively low thermal conductivity of 15.3 ± 0.3 W/(m·K) at room temperature, which was due to the presence of solid solution effects, nanoplates and porosity. Meanwhile, it exhibited the relatively high nanohardness of 30.3 ± 0.7 GPa and elastic modulus of 460.4 ± 19.2 GPa and the higher fracture toughness of 4.7 ± 0.5 MPam 1/2 , which were attributed to the solid solution strengthening mechanism and nanoplate pullout and microcrack deflection toughening mechanism.

36 MATERIALS SCIENCE↗
DOE OSTI2016

Moisture, anisotropy, stress state, and strain rate effects on bighorn sheep horn keratin mechanical properties

Our paper investigates the effects of moisture, anisotropy, stress state, and strain rate on the mechanical properties of the bighorn sheep (Ovis Canadensis) horn keratin. The horns consist of fibrous keratin tubules extending along the length of the horn and are contained within an amorphous keratin matrix. We tested samples in the rehydrated (35 wt.% water) and ambient dry (10 wt.% water) conditions along the longitudinal and radial directions under tension and compression. Increased moisture content was found to increase ductility and decrease strength, as well as alter the stress state dependent nature of the material. Furthermore, the horn keratin demonstrates a significant strain rate dependence in both tension and compression, and also showed increased energy absorption in the hydrated condition at high strain rates when compared to quasi-static data, with increases of 114% in tension and 192% in compression. Compressive failure occurred by lamellar buckling in the longitudinal orientation followed by shear delamination. Tensile failure in the longitudinal orientation occurred by lamellar delamination combined with tubule pullout and fracture. Finally, the structure-property relationships quantified here for bighorn sheep horn keratin can be used to help validate finite element simulations of ram’s impacting each other as well as being useful for other analysis regarding horn keratin on other animals.

36 MATERIALS SCIENCE↗
DOE OSTI2018

A discrete-continuum coupled finite element modelling approach for fibre reinforced concrete

Highlights: • An easy-to-implement but effective meso-scale modelling approach is developed for FRC. • It is capable of simulating and interpreting all main failure mechanisms in FRC. • It is critically validated by experiments with single or multiple random fibres under various loading conditions. • It can be used to optimise key design factors of FRC at meso/material scale by parametric studies. - Abstract: Fibre reinforced concrete (FRC) exhibits complicated failure modes such as fibre breakage, mortar cracking, crushing and spalling, fibre-mortar interfacial debonding, depending on many material properties, geometric dimensions, boundary and loading conditions. Most existing numerical models are unable to reproduce these failure modes that may occur simultaneously or sequentially in a specimen, mainly due to difficulties in generating finite element meshes with a large number of randomly-oriented fibres. Herein we develop a discrete-continuum coupled finite element modelling approach for FRC materials capable of effectively simulating all the major failure modes. The continuum damaged plasticity model is used to simulate damage and fracture behaviour of the mortar, while debonding of fibre-mortar interfaces is modelled by nonlinear cohesive interfacial elements. Unique techniques are devised to generate conforming meshes between fibres and the surrounding mortar so that the randomly-oriented fibres are easily modelled. The modelling approach is validated by simulating single fibre pullout tests with different inclination angles, notched and non-notched direct tensile tests and three-point bending beam tests with randomly-distributed multiple fibres.

36 MATERIALS SCIENCE↗
DOE OSTI2016

Effects of process parameters on friction self-piercing riveting of dissimilar materials

In the present work, a recently developed solid state joining technique, Friction self-piercing riveting (F-SPR), has been applied for joining high strength aluminum alloy AA7075-T6 to magnesium alloy AZ31B. The process was performed on a specially designed machine where the spindle can achieve the motion of sudden stop. Effects of rivet rotating rate and punch speed on axial plunge force, torque, joint microstructure and quality have been analyzed systematically. During F-SPR, higher rotating rate and slower punch speed can reduce axial force and torque, which correspondingly results in a slightly smaller interlock between rivet leg and joined materials. Improved local flowability of both aluminum and magnesium alloys under a higher rotating speed results in a thicker aluminum layer surrounding the rivet leg, where formation of Al-Mg intermetallics was observed. Equivalent joint strength obtained in this study are higher than the yield strength of the AZ31 Mg alloy. One of the tensile failure modes is the rivet fracture, which is due to local softening of rivet leg from frictional heat. Lastly, other two failure modes include rivet pullout and shear through of bottom sheet.

36 MATERIALS SCIENCE↗
DOE OSTI2020

Role of Postdeposition Thermal Annealing on Intracrystallite and Intercrystallite Structuring and Charge Transport in Poly(3-hexylthiophene)

The performance of electronic devices comprising conjugated polymers as the active layer depends not only on the intrinsic characteristics of the materials but also on the details of the extrinsic processing conditions. Here, we examine the effect of postdeposition thermal treatments on the microstructure of poly(3-hexylthiophene) (P3HT) thin films and its impact on their electrical properties. Unsurprisingly, we find thermal annealing of P3HT thin films to generally increase their crystallinity and crystallite coherence length while retaining the same crystal structure. Despite such favorable structural improvements of the polymer active layers, however, thermal annealing at high temperatures can lead to a net reduction in the mobility of transistors, implicating structural changes in the intercrystallite amorphous regions of these semicrystalline active layers take place on annealing, and the simplistic picture that crystallinity governs charge transport is not always valid. Our results instead suggest tie-chain pullout, which occurs during crystal growth and perfection upon thermal annealing to govern charge transport, particularly in low-molecular-weight systems in which the tie-chain fraction is low. By demonstrating the interplay between intracrystallite and intercrystallite structuring in determining the macroscopic charge transport, we shed light on how structural evolution and charge-transport properties of nominally the same polymer can vary depending on the details of processing.

36 MATERIALS SCIENCE↗