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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 37 records · Page 2

Insight into the epitaxial growth of high optical quality GaAs{sub 1–x}Bi{sub x}

The ternary alloy GaAs{sub 1–x}Bi{sub x} is a potentially important material for infrared light emitting devices, but its use has been limited by poor optical quality. We report on the synthesis of GaAs{sub 1–x}Bi{sub x} epi-layers that exhibit narrow, band edge photoluminescence similar to other ternary GaAs based alloys, e.g., In{sub y}Ga{sub 1–y}As. The measured spectral linewidths are as low as 14 meV and 37 meV at low temperature (6 K) and room temperature, respectively, and are less than half of previously reported values. The improved optical quality is attributed to the use of incident UV irradiation of the epitaxial surface and the presence of a partial surface coverage of bismuth in a surfactant layer during epitaxy. Comparisons of samples grown under illuminated and dark conditions provide insight into possible surface processes that may be altered by the incident UV light. The improved optical quality now opens up possibilities for the practical use of GaAs{sub 1–x}Bi{sub x} in optoelectronic devices.

36 MATERIALS SCIENCE↗

7th Annual NASA/Contractors Conference on Quality and Productivity: "Total Quality Leadership"

More than 750 NASA, government, contractor, and academic representatives attended the Seventh Annual NASA/Contractors Conference on Quality and Productivity on October 12-13, 1990, in Grenelefe, Florida. The panel presentations and keynote speeches revolving around the theme of 'Total Quality Leadership' provided a solid base of understanding of the importance, benefits, and principles of total quality management. The implementation of these strategies is critical if we are to effectively pursue our mission of continuous quality improvement and reliability in our products, processess, and services. The annual NASA/contractors conferences serve as catalysts for achieving success in this mission. The conference was highlighted by the announcement of the first recipients of the George M. Low Trophy: NASA's Quality and Excellence Award. My congratulations go out to all nine finalist organizations and to the two recipients of this prestigious honor: Rockwell Space Systems Division and Marotta Scientific Controls, Inc. (the first small business to achieve this honor). These organizations have demonstrated a commitment to quality that is unsurpassed in the aerospace industry. This report summarizes the presentations and is not intended to be a verbatim proceedings document. You are encouraged to contact the speakers with any requests for further information.

Source record↗

A spatially distributed model for assessment of the effects of changing land use and climate on urban stream quality: Development of a Spatially Distributed Urban Water Quality Model

While the effects of land use change in urban areas have been widely examined, the combined effects of climate and land use change on the quality of urban and urbanizing streams have received much less attention. We describe a modeling framework that is applicable to the evaluation of potential changes in urban water quality and associated hydrologic changes in response to ongoing climate and landscape alteration. The grid-based spatially distributed model, DHSVM-WQ, is an outgrowth of the Distributed Hydrology-Soil-Vegetation Model (DHSVM) that incorporates modules for assessing hydrology and water quality in urbanized watersheds at a high spatial and temporal resolution. DHSVM-WQ simulates surface runoff quality and in-stream processes that control the transport of nonpoint-source (NPS) pollutants into urban streams. We configure DHSVM-WQ for three partially urbanized catchments in the Puget Sound region to evaluate the water quality responses to current conditions and projected changes in climate and/or land use over the next century. Here we focus on total suspended solids (TSS) and total phosphorus (TP) from nonpoint sources (runoff), as well as stream temperature. The projection of future land use is characterized by a combination of densification in existing urban or partially urban areas, and expansion of the urban footprint. The climate change scenarios consist of individual and concurrent changes in temperature and precipitation. Future precipitation is projected to increase in winter and decrease in summer, while future temperature is projected to increase throughout the year. Our results show that urbanization has a much greater effect than climate change on both the magnitude and seasonal variability of streamflow, TSS and TP loads largely due to substantially increased streamflow, and particularly winter flow peaks. Water temperature is more sensitive to climate warming scenarios than to urbanization and precipitation changes. Future urbanization and climate change together are predicted to significantly increase annual mean streamflow (up to 55%), water temperature (up to 1.9 ºC), TSS load (up to 182%), and TP load (up to 74%).

Sun, Ning↗

Review of the impacts of leaking CO 2 gas and brine on groundwater quality

This review paper provides a synthetic view of the existing knowledge and summarizes data and findings of the recent literature on the subject of the potential leaking of CO2 from the deep subsurface storage reservoirs and the effects on aquifer quality. New ideas and concepts are developed and insights are also provided. The objectives of this paper are to: 1) present and discuss potential risks for groundwater degradation due to CO2 gas and brine exposure; 2) identify the set of geochemical data required to assess and predict aquifer responses to CO2 and brine leakage. Specifically, this paper will discuss the following issues: 1) Aquifer responses (such as changes in aqueous phase/groundwater chemical composition; changes in solid phase chemistry and mineralogy; changes in the extent and rate of reactions and processes and possible establishment of a new network of reactions and processes affecting or controlling overall mobility of major, minor, and trace elements; development of conceptual and reduced order models (ROMs) to describe and predict aquifer responses); 2) The degree of impact such as significant or insignificant changes in pH and major, minor, and trace element release that depend on the following controlling variables; the effect of leaking plume characteristics (gas composition, pure CO2 and/or CO2 -CH4 -H2S mixtures and brine concentration and composition (trace metals); aquifer properties [such as initial aqueous phase conditions and mineralogy: minerals controlling sediments’ response (e.g., calcite, Si bearing minerals, etc.)]; overview of relevant hydrogeological and geochemical processes related to the impact of CO2 gas and brine on groundwater quality; the fate of the elements released from sediments or transported with brine (such as precipitation/incorporation into minerals (calcite and other minerals), adsorption, electron transfer reactions, the role of natural attenuation; whether or not the release of metals following exposure to CO2 harmful (risk assessment).

Qafoku, Nikolla P.↗

Evaluation of the ride quality of a light twin engine airplane using a ride quality meter

A ride quality meter was used to establish the baseline ride quality of a light twin-engine airplane planned for use as a test bed for an experimental gust alleviation system. The ride quality meter provides estimates of passenger ride discomfort as a function of cabin noise and vibration (acceleration) in five axes (yaw axis omitted). According to the ride quality meter, in smooth air the cabin noise was the dominant source of passenger discomfort, but the total discomfort was approximately the same as that for the smooth-air condition. The researcher's subjective opinion, however, is that the total ride discomfort was much worse in the moderate turbulence than it was in the smooth air. The discrepancy is explained by the lack of measurement of the low-frequency accelerations by the ride quality meter.

Stewart, Eric C.↗

Training, Quality Assurance Factors, and Tools Investigation: a Work Report and Suggestions on Software Quality Assurance

Previously, several research tasks have been conducted, some observations were obtained, and several possible suggestions have been contemplated involving software quality assurance engineering at NASA Johnson. These research tasks are briefly described. Also, a brief discussion is given on the role of software quality assurance in software engineering along with some observations and suggestions. A brief discussion on a training program for software quality assurance engineers is provided. A list of assurance factors as well as quality factors are also included. Finally, a process model which can be used for searching and collecting software quality assurance tools is presented.

Lee, Pen-Nan↗

Realization of high quality production schedules: Structuring quality factors via iteration of user specification processes

This paper describes an architecture for realizing high quality production schedules. Although quality is one of the most important aspects of production scheduling, it is difficult, even for a user, to specify precisely. However, it is also true that the decision as to whether a scheduler is good or bad can only be made by the user. This paper proposes the following: (1) the quality of a schedule can be represented in the form of quality factors, i.e. constraints and objectives of the domain, and their structure; (2) quality factors and their structure can be used for decision making at local decision points during the scheduling process; and (3) that they can be defined via iteration of user specification processes.

Hamazaki, Takashi↗

Pacific Northwest Health & Air Quality - Utilizing NASA Earth Observations to Analyze Air Quality Impacts from Wildfires in the Pacific Northwest

The Pacific Northwest region of the United States and Canada has become more vulnerable to intense wildfire regimes due to years of fire suppression and climatic changes. Smoke from fires exposes communities to hazardous aerosols and pollutants known to trigger asthma symptoms and exacerbate other respiratory and cardiovascular diseases. In partnership with The Nature Conservancy’s Washington Chapter and the Puget Sound Clean Air Agency, NASA DEVELOP investigated the impacts of wildfire smoke on air quality from 2008 to 2020 using NASA Earth observations. To explore the various dimensions of smoke and its relation to air quality, the team looked at the vertical extent of smoke plumes and the resulting changes in air quality. The team evaluated the potential relationship between plume height of wildfire smoke and fire radiative power using the Moderate Resolution Imaging Spectroradiometer (MODIS) aboard the Aqua and Terra satellites and Terra’s Multi-angle Imaging SpectroRadiometer (MISR) using the MISR INteractive eXplorer (MINX). The team determined that there was no regional relationship between fire radiative power and smoke plume height. To investigate changes in air quality resulting from wildfire smoke, the team utilized data from NASA’s Fire Information for Resource Management System, from the European Space Agency’s Sentinel-5P Tropospheric Monitoring Instrument (TROPOMI), and true color imagery from Landsat 8 Operational Land Imager (OLI). The team created a Google Earth Engine-based (GEE) web tool to visualize changes in atmospheric pollutants and aerosol optical depth. Results of case study fires showed varying increases in pollutant concentrations when compared to a baseline map. The end products provided the partners with tools to quantify plume height using MINX and to visualize recent air quality patterns relating to variations in wildfire extent and severity in the Pacific Northwest

Ani Matevosian↗

Pacific Northwest Health & Air Quality: Monitoring Trends in Air Quality During a Drought Case Study to Improve Public Health Response to Drought Threats

Recent studies have documented a correlation between air quality and drought in the United States, which has been linked with increased aerosols including airborne particulate matter (PM) during drought conditions. This study partnered with local health departments to evaluate trends in air quality in the Pacific Northwest during the evolution of drought conditions using aerosol optical depth (AOD) observations collected by NASA’s Moderate Resolution Imaging Spectroradiometer (MODIS) sensor aboard the Terra and Aqua satellites. These satellite data were analyzed in conjunction with ground-based PM2.5 and PM10 data sourced from the Environmental Protection Agency (EPA)’s network of ground-based monitors and the Standardized Precipitation Evapotranspiration Index (SPEI) drought index. Based on recommendations by local health departments, this study examined air quality trends between 2015 and 2022 in 12 counties within Oregon and Washington that reflected diversity in population density, drought exposure, rural and urban status, and data availability from EPA monitors. Overall, results indicated variation in relationships among drought, satellite, and ground-based air quality data across the study area. This study did not control for the impact of wildfire events on air quality and also did not investigate shorter SPEI aggregation periods, both of which are avenues for future research. This project supplemented research into links between drought and human health and provided health departments with an objective foundation from which they can communicate public health risks to local communities.

Abby Sgan↗

Quality carbon fibers from fractionated lignin

The application of lignin carbon fibers was hindered by their low quality and mechanical performance. We addressed this challenge by developing a new approach to fractionate and modify lignin to produce quality carbon fibers using an enzyme-mediator system, which derives lignin fractions with different molecular weights, functional groups, and interunitary linkages. The fractionated lignin in general improves the miscibility and spinnability of lignin. In particular, the insoluble lignin fraction renders carbon fibers with a significantly improved turbostratic carbon structure as revealed by XRD and Raman spectroscopy. The improvement in the carbon structure leads to the significantly improved elastic modulus. The results suggest that higher molecular weights, less –OH groups, and more linear structures may contribute to the improved crystallization and mechanical performance of lignin carbon fibers. Finally, the technical breakthrough produces lignin-based carbon fibers with a similar elastic modulus to commercial carbon fibers for the first time, and paves the path for replacing PAN with lignin for producing quality carbon fibers.

Enzymatic fractionation↗

The Role of Gas in Determining Image Quality and Resolution During In Situ Scanning Transmission Electron Microscopy Experiments

As gas-solid heterogeneous catalytic reactions are molecular in nature, a full mechanistic understanding of the process requires atomic scale characterization under realistic operating conditions. While atomic resolution imaging has become a routine in modern high-vacuum (scanning) transmission electron microscopy ((S)TEM), both image quality and resolution nominally degrade when reaction gases are introduced. In this work, we systematically assess the effects of different gases at various pressures on the quality and resolution of images obtained at room temperature in the annular dark field STEM imaging mode using a differentially pumped (DP) gas cell. This imaging mode is largely free from inelastic scattering effects induced by the presence of gases and retains good imaging properties over a wide range of gas mass/pressures. We demonstrate the application of the ESTEM with atomic resolution images of a complex oxide alkane oxidation catalyst MoVNbTeOx (M1) immersed in light and heavy gas environments.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Increased Optoelectronic Quality and Uniformity of Hydrogenated p-InP Thin Films

The thin-film vapor-liquid-solid (TF-VLS) growth technique presents a promising route for high quality, scalable, and cost-effective InP thin films for optoelectronic devices. Toward this goal, careful optimization of material properties and device performance is of utmost interest. Here, we show that exposure of polycrystalline Zn-doped TF-VLS InP to a hydrogen plasma (in the following referred to as hydrogenation) results in improved optoelectronic quality as well as lateral optoelectronic uniformity. A combination of low temperature photoluminescence and transient photocurrent spectroscopy was used to analyze the energy position and relative density of defect states before and after hydrogenation. Notably, hydrogenation reduces the relative intragap defect density by 1 order of magnitude. As a metric to monitor lateral optoelectronic uniformity of polycrystalline TF-VLS InP, photoluminescence and electron beam induced current mapping reveal homogenization of the grain versus grain boundary upon hydrogenation. At the device level, we measured more than 260 TF-VLS InP solar cells before and after hydrogenation to verify the improved optoelectronic properties. Hydrogenation increased the average open-circuit voltage (VOC) of individual TF-VLS InP solar cells by up to 130 mV and reduced the variance in VOC for the analyzed devices.

14 SOLAR ENERGY↗

Reactive catalytic fast pyrolysis of biomass to produce high-quality bio-crude

Reactive catalytic fast pyrolysis (RCFP) of biomass with atmospheric pressure hydrogen was investigated in a lab-scale fluidized bed reactor with varying reaction conditions (temperature and hydrogen concentration) and catalysts. Presence of atmospheric hydrogen with candidate RCFP catalysts was found to improve the yield and quality of bio-crude and minimize the char and coke formation. Here, a molybdenum-based catalyst was the most effective at hydrodeoxygenating biomass pyrolysis vapors to produce a hydrocarbon-rich bio-crude intermediate with low oxygen content (<10 wt%). Higher hydrogen concentration and moderate reaction temperature (450 °C) favored higher bio-crude yields and quality. A yield of 43.2 C% in the C 4+ organic fraction with as low as 6.2 wt% oxygen in the liquid was obtained under optimized reaction conditions. The resulting bio-crude contained primarily aliphatic and aromatic hydrocarbons, with small amounts of simple ketones, furans, and phenols. Up to 41.5% carbon in the biomass feed was converted into gas and condensable hydrocarbons with 29.7% in the condensable C 4+ fraction. The improved bio-crude quality is expected to be more compatible with existing petroleum refining infrastructure.

09 BIOMASS FUELS↗

Rapid Quality Assessment in Additive Manufacturing: New Procedure Accelerates Build Quality Assessment. White paper

Accelerated growth of the additive manufacturing (AM) industry in recent years is accompanied by a rising need for methods to quickly assess quality at-scale. Current practices for quality inspection include nondestructive test methods and destructive testing of witness coupons, which are artifacts built alongside the actual part. However, these methods can be costly and time-consuming. Recognizing this need, the Additive Manufacturing Center of Excellence (AM CoE) initiated a project led by its partner, Auburn University, to develop rapid testing procedure using asbuilt samples tested in torsion to quantitatively assess build quality. The presented work developed a rapid testing procedure using as-built samples tested in torsion to quantify small variances for assessing build quality.

42 ENGINEERING↗

Project ATLANTA (ATlanta Land-use ANalysis: Temperature and Air quality): A Study of how the Urban Landscape Affects Meteorology and Air Quality Through Time

It is our intent through this investigation to help facilitate measures that can be Project ATLANTA (ATlanta Land-use ANalysis: applied to mitigate climatological or air quality Temperature and Air-quality) is a NASA Earth degradation, or to design alternate measures to sustain Observing System (EOS) Interdisciplinary Science or improve the overall urban environment in the future. investigation that seeks to observe, measure, model, and analyze how the rapid growth of the Atlanta. The primary objectives for this research effort are: 1) To In the last half of the 20th century, Atlanta, investigate and model the relationship between Atlanta Georgia has risen as the premier commercial, urban growth, land cover change, and the development industrial, and transportation urban area of the of the urban heat island phenomenon through time at southeastern United States. The rapid growth of the nested spatial scales from local to regional; 2) To Atlanta area, particularly within the last 25 years, has investigate and model the relationship between Atlanta made Atlanta one of the fastest growing metropolitan urban growth and land cover change on air quality areas in the United States. The population of the through time at nested spatial scales from local to Atlanta metropolitan area increased 27% between 1970 regional; and 3) To model the overall effects of urban and 1980, and 33% between 1980-1990 (Research development on surface energy budget characteristics Atlanta, Inc., 1993). Concomitant with this high rate of across the Atlanta urban landscape through time at population growth, has been an explosive growth in nested spatial scales from local to regional. Our key retail, industrial, commercial, and transportation goal is to derive a better scientific understanding of how services within the Atlanta region. This has resulted in land cover changes associated with urbanization in the tremendous land cover change dynamics within the Atlanta area, principally in transforming forest lands to metropolitan region, wherein urbanization has urban land covers through time, has, and will, effect consumed vast acreas of land adjacent to the city local and regional climate, surface energy flux, and air proper and has pushed the rural/urban fringe farther quality characteristics. Allied with this goal is the and farther away from the original Atlanta urban core. prospect that the results from this research can be An enormous transition of land from forest and applied by urban planners, environmental managers agriculture to urban land uses has occurred in the and other decision-makers, for determining how Atlanta area in the last 25 years, along with subsequent urbanization has impacted the climate and overall

Quattrochi, Dale A.↗