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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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NASA NTRS2017

Radiation Processing of Polycyclic Aromatic Hydrocarbons (PAHs) in Space: ICEE PoC

Small Polycyclic Aromatic Hydrocarbon molecules or PAHs (<30 carbon atoms) have been identified in comets, meteorites, asteroids, and interplanetary dust particles in our Solar System, while PAHs in the Interstellar Medium (ISM) tend to be much larger, usually between 50 to 100 carbon atoms in size. The cause of the size disparity between PAHs found in the ISM and Solar System as well as their influence on Solar System organics is not yet understood. Two chemical evolutionary paths have been proposed to explain the inventory of solar system organics. In one the prebiotic material was formed from the radiation induced modification of large pre-solar carbon-bearing species (e.g. ISM PAHs). The second path suggests that Solar System prebiotic matter is the result of bottom-up synthesis from small reactive molecules after the Solar System was formed. In this second scenario very few ISM PAHs survived the harsh pre-solar radiation as aromatic structures. ICEE PoC (ICEE Proof of Concept) investigated factors impacting the chemical evolution of large PAHs irradiated under conditions similar to the proto-solar nebula. Likewise ICEE PoC will refine the technical parameters of the proposed ICEE (Institute for Carbon Evolution Experiment) laboratory.

Mattioda, Andrew↗
NASA NTRS1972

Stabilities of nitrogen containing heterocyclic radicals and geometrical influences on non-radiative processes in organic molecules

Stabilities of nitrogen containing heterocyclic radicals were studied to detect radicals of the type R-N-R, and to theoretically rationalize their electronic structure. The computation of simple potential energy surfaces for ground and excited states is discussed along with the photophysical properties of indolizine. Methods of calculation and problems associated with the calculations are presented. Results, tables, diagrams, discussions, and references are included.

Evleth, E. M.↗
NASA NTRS1971

Stabilities of nitrogen containing heterocyclic radicals and geometrical influences on non-radiative processes in organic molecules

Theoretical and experimental work on generating radicals by removal of a hydrogen atom from pyrrole, imidazole, indole, and carbazole is reported. Photophysical studies on indolizine and related aza-derivatives show that materials having large S2-S1 energy gaps might exhibit upper state fluorescence. Photodecomposition quantum yields of a series of sterically hindered p-aminobenzene diazonium cations in water were found structurally and wavelength dependent and unquenched in aqueous sodium bromide solutions. Photodecomposition of diazonium materials did not produce a metastable species with a longer lifetime than 1 msec.

Evleth, E. M.↗
NASA NTRS1976

Radiative processes affecting the abundance of interstellar OH

Photodissociation of OH dominates its destruction for a significant range of density and shielding in H I regions. Although inverse predissociation may provide an observable flux of ultraviolet recombination photons, it can provide only a small fraction of the total observed OH in most H I regions.

Smith, w. H.↗
NASA NTRS1990

Radiative Processes In Air Excited By An ArF Laser

Report describes experimental and theoretical studies of emission spectrum of air excited by light from ArF laser. Purpose of studies to determine conditions under which fluorescence from O2 used to measure temperatures in aerodynamic flows.

Mckenzie, Robert L.↗
NASA NTRS2000

Cosmic Rays and Their Radiative Processes in Numerical Cosmology

A cosmological hydrodynamic code is described, which includes a routine to compute cosmic ray acceleration and transport in a simplified way. The routine was designed to follow explicitly diffusive, acceleration at shocks, and second-order Fermi acceleration and adiabatic loss in smooth flows. Synchrotron cooling of the electron population can also be followed. The updated code is intended to be used to study the properties of nonthermal synchrotron emission and inverse Compton scattering from electron cosmic rays in clusters of galaxies, in addition to the properties of thermal bremsstrahlung emission from hot gas. The results of a test simulation using a grid of 128 (exp 3) cells are presented, where cosmic rays and magnetic field have been treated passively and synchrotron cooling of cosmic ray electrons has not been included.

Ryu, Dongsu↗
NASA NTRS1988

Internal stabilization of polycarbonate resins by two stage radiation process

A new polycarbonate copolymer resin is formed by internal generation of stabilizers bound to the polymer chain. Irradiation of a solid piece or a deoxygenated solution of the resin at a first frequency below 300 nm generates 2 to 8 mol percent of phenyl salicylate groups which are rearranged to dihydroxybenzophenone groups by irradiating the resin under oxygen excluding conditions at a second frequency from 300 to 320 nm.

Gupta, Amitava↗
NASA NTRS2009

Effect of Space Radiation Processing on Lunar Soil Surface Chemistry: X-Ray Photoelectron Spectroscopy Studies

Current understanding of the chemistry and microstructure of the surfaces of lunar soil grains is dominated by a reference frame derived mainly from electron microscopy observations [e.g. 1,2]. These studies have shown that the outermost 10-100 nm of grain surfaces in mature lunar soil finest fractions have been modified by the combined effects of solar wind exposure, surface deposition of vapors and accretion of impact melt products [1,2]. These processes produce surface-correlated nanophase Feo, host grain amorphization, formation of surface patinas and other complex changes [1,2]. What is less well understood is how these changes are reflected directly at the surface, defined as the outermost 1-5 atomic monolayers, a region not easily chemically characterized by TEM. We are currently employing X-ray Photoelectron Spectroscopy (XPS) to study the surface chemistry of lunar soil samples that have been previously studied by TEM. This work includes modification of the grain surfaces by in situ irradiation with ions at solar wind energies to better understand how irradiated surfaces in lunar grains change their chemistry once exposed to ambient conditions on earth.

Dukes, C.↗
NASA NTRS1993

Session on modeling of radiative transfer processes

The session on modeling of radiative transfer processes is reviewed. Six critical issues surfaced in the discussion concerning scale-interactive radiative processes relevent to the mesoscale convective systems (MCS's). These issues are the need to expand basic knowledge of how MCS's influence climate through extensive cloud shields and increased humidity in the upper troposphere; to improve radiation parameterizations used in mesoscale and General Circulation Model (GCM) models; to improve our basic understanding of the influence of radiation on MCS dynamics due to diabatic heating, production of condensate, and vertical and horizontal heat fluxes; to quantify our understanding of radiative impacts of MCS's on the surface and free atmosphere energy budgets; to quantify and identify radiative and microphysical processes important in the evolution of MCS's; and to improve the capability to remotely sense MCS radiative properties from space and ground-based systems.

Flatau, Piotr↗
NASA NTRS2007

Space Plasma Ion Processing of Ilmenite in the Lunar Soil: Insights from In-Situ TEM Ion Irradiation Experiments

Space weathering on the moon and asteroids results largely from the alteration of the outer surfaces of regolith grains by the combined effects of solar ion irradiation and other processes that include deposition of impact or sputter-derived vapors. Although no longer considered the sole driver of space weathering, solar ion irradiation remains a key part of the space weathering puzzle, and quantitative data on its effects on regolith minerals are still in short supply. For the lunar regolith, previous transmission electron microscope (TEM) studies performed by ourselves and others have uncovered altered rims on ilmenite (FeTiO3) grains that point to this phase as a unique "witness plate" for unraveling nanoscale space weathering processes. Most notably, the radiation processed portions of these ilmenite rims consistently have a crystalline structure, in contrast to radiation damaged rims on regolith silicates that are characteristically amorphous. While this has tended to support informal designation of ilmenite as a "radiation resistant" regolith mineral, there are to date no experimental data that directly and quantitatively compare ilmenite s response to ion radiation relative to lunar silicates. Such data are needed because the radiation processed rims on ilmenite grains, although crystalline, are microstructurally and chemically complex, and exhibit changes linked to the formation of nanophase Fe metal, a key space weathering process. We report here the first ion radiation processing study of ilmenite performed by in-situ means using the Intermediate Voltage Electron Microscope- Tandem Irradiation facility (IVEM-Tandem) at Argonne National Laboratory. The capability of this facility for performing real time TEM observations of samples concurrent with ion irradiation makes it uniquely suited for studying the dose-dependence of amorphization and other changes in irradiated samples.

Christoffersen, R.↗
NASA NTRS1983

Apparatus for processing electromagnetic radiation and method

Measuring apparatus including a ruled member having alternate transparent and opaque zones. An optical coupler connecting the ruled member with electromagnetic radiation-conversion apparatus. The conversion apparatus may include a photomultiplier and a discriminator. Radiation impinging on the ruled member will, in part, be converted to electrical pulses which correspond to the intensity of the radiation. A method of processing electromagnetic radiation includes providing a member having alternating dark and light zones, establishing movement of the member through the beam of electromagnetic radiation with the dark zones interrupting passage of radiation through the rule, providing an optical coupler to connect a portion of the radiation with a conversion station where the radiation portion is converted into an electrical pulse which is related to the intensity of the radiation received at the conversion station. The electrical pulses may be counted and the digitized signals stored or permanently recorded to produce positional information.

Gatewood, George D.↗
NASA NTRS1997

Process and Radiation Induced Defects in Electronic Materials and Devices

Process and radiation induced defects are characterized by a variety of electrical techniques, including capacitance-voltage measurements and charge pumping. Separation of defect type into stacking faults, displacement damage, oxide traps, interface states, etc. and their related causes are discussed. The defects are then related to effects on device parameters. Silicon MOS technology is emphasized. Several reviews of radiation effects and silicon processing exist.

Washington, Kenneth↗
NASA NTRS1985

Atmospheric Ozone 1985. Assessment of Our Understanding of the Processes Controlling Its Present Distribution and Change, Volume 1: Global Ozone Research and Monitoring Project - Report No. 16

Topics addressed include: stratospheric chemistry; tropospheric trace gas (sources, distributions, and trends); tropospheric chemistry (processes, controlling the ozone and hydroxyl radicals); stratosphere-troposphere exchange; dynamic processes; and radiative processes (solar and terrestrial).

Source record↗
NASA NTRS1984

The suppression of convective wavebreaking by radiative transfer processes, part 1.3C

Schoeberl et al. (1983) suggested that convective wavebreaking of monochromatic gravity waves might be suppressed by radiative transfer processes if the vertical wavelength waves were sufficiently short. As the vertical wavelength or the gravity wave decreases, radiative transfer between adjacent vertical layers becomes increasingly important. This exchange can increase the radiative relaxation time scale so that the wave will no longer grow with altitude. Thus, very short vertical wavelength waves may dissipate radiatively rather than become convectively unstable. Apruzese and Strobel (1984) have revised the exchange coefficients used in Schoeberl et al. (1983). Also, Chao and Schoeberl (1984) pointed out that the computation made by LINDZEN (1981) of the convective diffusion rate may be a factor of two too low as the convective adjustment processes tends to minimize the thermal transport by the wave. The purpose here is to revise the values given in Schoeberl et al. (1983). These results also suggest that the very thin turbulent layers observed by mesosphere-stratosphere-troposphere (MST) radars (e.g., WOODMAN, 1980) cannot be produced by the convective instability of monochromatic gravity waves with large horizontal scales.

Schoeberl, M. R.↗