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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 37 records · Page 2

Measuring the Absorption Rate of CO 2 in Nonaqueous CO 2 -Binding Organic Liquid Solvents with a Wetted-Wall Apparatus

The kinetics of the absorption of CO 2 into two nonaqueous CO 2 -binding organic liquid (CO 2 BOL) solvents were measured at T=35, 45, and 55 °C with a wetted-wall column. Selected CO 2 loadings were run with a so-called “first-generation” CO 2 BOL, comprising an independent base and alcohol, and a “second-generation” CO 2 BOL, in which the base and alcohol were conjoined. Liquid-film mass-transfer coefficient (k'g) values for both solvents were measured to be comparable to values for monoethanolamine and piperazine aqueous solvents under a comparable driving force, in spite of far higher solution viscosities. An inverse temperature dependence of the k'g value was also observed, which suggests that the physical solubility of CO 2 in organic liquids may be making CO 2 mass transfer faster than expected. Aspen Plus software was used to model the kinetic data and compare the CO 2 absorption behavior of nonaqueous solvents with that of aqueous solvent platforms. This work continues our development of the CO2BOL solvents. Previous work established the thermodynamic properties related to CO 2 capture. The present paper quantitatively studies the kinetics of CO 2 capture and develops a rate-based model.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Simulation of Gas Production from Multilayered Hydrate-Bearing Media with Fully Coupled Flow, Thermal, Chemical and Geomechanical Processes Using TOUGH+Millstone. Part 2: Geomechanical Formulation and Numerical Coupling

The TOUGH+Millstone simulator has been developed for the analysis of coupled flow, thermal and geomechanical processes associated with the formation and/or dissociation of CH 4 hydrates in geological media. It is composed of two constituent codes: (a) a significantly enhanced version of the TOUGH+HYDRATE simulator, v2.0, that accounts for all known flow, physical, thermodynamic and chemical processes associated with the behavior of hydrate-bearing systems undergoing changes and includes the most recent advances in the description of the system properties, coupled seamlessly with (b) Millstone v1.0, a new code that addresses the conceptual, computational and mathematical shortcomings of earlier codes used to describe the geomechanical response of these systems. The capabilities of the TOUGH+Millstone code are demonstrated in the simulation and analysis of the system flow, thermal and geomechanical behavior during gas production from a realistic complex offshore hydrate deposit. In the second part of this series, we describe the Millstone geomechanical simulator. The hydrate-dependent, rate-based poromechanical formulation is presented and solved using a finite element discretization. A novel multimesh coupling scheme is introduced, wherein interpolators are automatically built to transfer data between the finite difference discretization of TOUGH+ and the finite element discretization of Millstone. We provide verification examples against analytic solutions for poroelasticity and a simplified demonstration problem for mechanically induced phase change in a hydrate sediment.

58 GEOSCIENCES↗

Encoding integers and rationals on neuromorphic computers using virtual neuron

Abstract Neuromorphic computers emulate the human brain while being extremely power efficient for computing tasks. In fact, they are poised to be critical for energy-efficient computing in the future. Neuromorphic computers are primarily used in spiking neural network–based machine learning applications. However, they are known to be Turing-complete, and in theory can perform all general-purpose computation. One of the biggest bottlenecks in realizing general-purpose computations on neuromorphic computers today is the inability to efficiently encode data on the neuromorphic computers. To fully realize the potential of neuromorphic computers for energy-efficient general-purpose computing, efficient mechanisms must be devised for encoding numbers. Current encoding mechanisms (e.g., binning, rate-based encoding, and time-based encoding) have limited applicability and are not suited for general-purpose computation. In this paper, we present the virtual neuron abstraction as a mechanism for encoding and adding integers and rational numbers by using spiking neural network primitives. We evaluate the performance of the virtual neuron on physical and simulated neuromorphic hardware. We estimate that the virtual neuron could perform an addition operation using just 23 nJ of energy on average with a mixed-signal, memristor-based neuromorphic processor. We also demonstrate the utility of the virtual neuron by using it in some of the μ -recursive functions, which are the building blocks of general-purpose computation.

97 MATHEMATICS AND COMPUTING↗

Energy Efficiency and Emissions Intensity Standards

We investigate the role of energy efficiency in rate-based emissions intensity standards, a particularly policy-relevant consideration given that the Environmental Protection Agency's Clean Power Plan allows crediting of electricity savings as a means of complying with state-specific emissions standards. We show that with perfectly inelastic energy services demand, crediting efficiency measures can recover the first-best allocation. However, when demand for energy services exhibits some elasticity, crediting energy efficiency can no longer recover first-best. While crediting removes the relative distortion between energy generation and energy efficiency, it distorts the absolute level of energy services. Building on these results, we derive the conditions determining the second-best intensity standard and crediting rule. Simulations calibrated to the electricity sector in Texas find that while some form of crediting is generally welfare-improving, the proposed one-for-one crediting of energy savings is unlikely to achieve efficient outcomes.

29 ENERGY PLANNING, POLICY, AND ECONOMY↗

Deep unsupervised learning using spike-timing-dependent plasticity

Abstract Spike-timing-dependent plasticity (STDP) is an unsupervised learning mechanism for spiking neural networks that has received significant attention from the neuromorphic hardware community. However, scaling such local learning techniques to deeper networks and large-scale tasks has remained elusive. In this work, we investigate a Deep-STDP framework where a rate-based convolutional network, that can be deployed in a neuromorphic setting, is trained in tandem with pseudo-labels generated by the STDP clustering process on the network outputs. We achieve 24.56% higher accuracy and 3.5 × faster convergence speed at iso-accuracy on a 10-class subset of the Tiny ImageNet dataset in contrast to a k -means clustering approach.

Lu, Sen↗

Genome resequencing reveals demographic history and genetic architecture of seed salinity tolerance in Populus euphratica

Populus euphratica is a dominant tree species in desert riparian forests and possesses extraordinary adaptation to salinity stress. Exploration of its genomic variation and molecular underpinning of salinity tolerance is important for elucidating population evolution and identifying stress-related genes. Here, we identify approximately 3.15 million single nucleotide polymorphisms using whole-genome resequencing. The natural populations of P. euphratica in northwest China are divided into four distinct clades that exhibit strong geographical distribution patterns. Pleistocene climatic fluctuations and tectonic deformation jointly shaped the extant genetic patterns. A seed germination rate-based salinity tolerance index was used to evaluate seed salinity tolerance of P. euphratica and a genome-wide association study was implemented. A total of 38 single nucleotide polymorphisms were associated with seed salinity tolerance and were located within or near 82 genes. Expression profiles showed that most of these genes were regulated under salt stress, revealing the genetic complexity of seed salinity tolerance. Furthermore, DEAD-box ATP-dependent RNA helicase 57 and one undescribed gene (CCG029559) were demonstrated to improve the seed salinity tolerance in transgenic Arabidopsis. These results provide new insights into the demographic history and genetic architecture of seed salinity tolerance in desert poplar.

59 BASIC BIOLOGICAL SCIENCES↗

Modular Adaptive Packing for Integrally Cooled Absorbers

Process intensification is one cornerstone in ION Clean Energy’s (ION) efforts to lowering CO2 capture cost. ION has modeled, designed, and fabricated an innovative gas-liquid contactor known as Modular Adaptive Packing (MAP). During two successful SBIR Phase I and II projects entitled: “Rapid Design and Testing of Novel Gas-Liquid Contacting Devices for Post-Combustion CO2 Capture via 3D-printing”, ION developed and proved this new technology at bench scale. MAP, a 3D-printed lattice-structured packing, combines the absorber gas/liquid contactor with an innovative in-situ heat-exchanger. Thanks to the capabilities of 3D-printing, the lattice structure of MAP contains hollow channels through which coolant water can be pumped to remove the heat of reaction from CO2 absorption. ION refers to this novel method of heat exchange as intracooling. After 25.4 cm (10 in) diameter MAP modules were fabricated, ION built and tested a packing characterization rig at its pilot facility in Boulder, Colorado, U.S.A. To provide baseline results for the characterization rig, ION tested Sulzer’s Mellapak™ 250Y (MP250Y) as a standard structured packing. ION’s MAP was then compared directly to the baseline MP250Y packing to evaluate key indicators including pressure drop, liquid hold-up, and effective area. MAP has a higher pressure drop than MP250Y at the same gas velocities in addition to greater liquid holdup. However, ION found that MAP displays a higher wetting coverage of 93% compared to 65% for MP250Y and reduces shearing forces that result in undesirable droplet formation. Using Optimized Gas Treating’s (OGT) rate-based simulation software ProTreat®, a conceptual evaluation of MAP was modeled for a CO2 absorber using 30 wt% MEA solvent over a range of lean loadings at 90% CO2 capture from a coal-fired power plant. ION modeled a 25-meter column absorber for both the standard MP250Y packing and a hybrid column. The hybrid absorber contained 10 m of MP250Y packing at the top and bottom with the middle 5 meters comprised of MAP. Compared to a traditional intercooled absorber, MAP can remove 22% more heat and increase overall MEA carrying capacity by 4% without increasing overall pressure drop.

20 FOSSIL-FUELED POWER PLANTS↗

Bench-Scale Development of a Non-Aqueous Solvent (NAS) CO 2 Capture Process for Coal-Fired Power Plants

The project aimed to advance RTI’s non-aqueous amine solvent technology by improving the solvent to reduce volatility, demonstrating long-term continuous operation at lab- (0.5 liters solvent) and bench-scale (~120 liters solvent), showing low reboiler heat duty measured during bench-scale testing, evaluating degradation products, building a rate-based process model, and evaluating the techno-economic performance of the process. The project team (RTI, SINTEF, Linde Engineering) and the technology performed well in each area of advancement. The modifications incorporated throughout the project enabled the attainment of target absorber and regenerator conditions for the process. Reboiler duties below 2,000 kJ t /kg CO 2 were observed in a bench-scale test unit operated at RTI.

01 COAL, LIGNITE, AND PEAT↗

Regulatory Incentives and Disincentives for Utility Investments in Grid Modernization

Electric power is America's most capital-intensive industry, with more than $100 billion invested each year in energy infrastructure. Investment needs are likely to grow as electric utilities make power systems more reliable and resilient, deploy advanced digital technologies, and facilitate new services to meet some consumers' expectations for greater choice and control. But do current regulatory approaches provide the appropriate incentives for grid modernization investments? This report presents three perspectives: -Financial analyst Steve Kihm begins by explaining that any major investor-owned electric utility that wants to raise capital today can do so at a reasonable cost. The question is whether utility managers want to raise capital for grid modernization. Specifically, they look for investments that create the most value for their existing shareholders. In cases where grid modernization investments are not the best choice in terms of shareholder value, Kihm describes shareholder incentive mechanisms that regulators could consider to encourage such investments when they are in the public interest. -From an institutional perspective, Dr. Janice Beecher finds that the traditional rate-base/rate of return regulatory model provides powerful incentives for utilities to pursue investments, cost control, efficiency and even innovation, and it is well suited to the policy objectives of grid modernization. Prudence of grid modernization investments (fair returns) depends on careful evaluation of the specific asset, and any special incentives (bonus returns) should be used only if they promote economic efficiency consistent with the core goals of economic regulation. According to Beecher, realizing the promises of grid modernization depends on effective implementation of the traditional regulatory model and ratemaking tools to serve the public interest. -Conversely, former commissioner and clean energy consultant Ron Lehr says that rapid electric industry changes require a better alignment of utility investment incentives with changes challenging the electricity sector, emerging grid modernization options and benefits, and public policies. For example, investor-owned utilities typically have an incentive to make capital investments, but rarely to employ expense-based solutions, since utilities do not earn profits on expenses. Further, Lehr cites a variety of factors that stand in the way of creating well targeted and well aligned utility incentives, including litigated regulatory processes. These may be a poor choice for finding the right balance among competing interests, establishing rules of prospective application, justifying demonstrations of new technologies and approaches to meeting emerging consumer demands, and keeping pace with rapid change.

29 ENERGY PLANNING, POLICY, AND ECONOMY↗

Hybrid Encapsulated Ionic Liquids for Post-Combustion Carbon Dioxide (CO 2 ) Capture

It is increasingly clear that carbon dioxide (CO 2 ) capture and sequestration (CCS) must play a critical role in curbing worldwide CO 2 emissions to the atmosphere. Previously, we have developed ionic liquids (ILs) and phase change ionic liquids (PCILs) for post-combustion CO 2 capture. In this project, we synthesized and tested 19 ILs and PCILs and chose one of each for further development. The IL selected for further development was triethyl(octyl)phosphonium 2-cyanopyrrolide ([P 2228 ][2CNPyr]), which has the same anion but a different cation, than used in our previous work. The new cation imparts a lower viscosity than the prior cation. The PCIL selected for further development was tetraethylphosphonium benzimidazolide ([P 2222 ][BnIm]), which was developed in an Advanced Research Projects Agency-Energy (ARPA-E) project. Although we made numerous other candidates, none were better than this original PCIL. Here we showed that the CO 2 absorption by the IL and the PCIL was completely reversible, even when water was present. We determined and quantified the additional chemistry, involving the formation of bicarbonate, when water is present. The IL and PCIL were encapsulated in silicone shells using a microfluidic device. Compatibility between the IL/PCIL and the polymer, viscosity, and surface tension issues, getting sufficiently high IL/PCIL loading and leakage (likely from insufficient cross-linking), were serious challenges. Small quantities (~ 1 g) of microcapsules with good integrity of both the IL and the PCIL were produced. The CO 2 uptake by these capsules was the same as for the free IL and PCIL and the capacity of the capsules decreased only slightly even after five absorption and desorption cycles. As expected, the IL and PCIL (and subsequently the encapsulated IL and PCIL) reacted readily with SO 2 and NO, so, like aqueous amine absorbents, the CO 2 capture unit would have to be located downstream of the flue gas desulfurization and other gas treatment units. Large samples (~70 g and 100 g) of encapsulated PCIL were produced in a parallel microfluidic device and in an in-air device. These capsules were tested in a Laboratory Scale Unit (LSU) to demonstrate uptake capacity in a fluidized bed. We also used the LSU to determine recyclability and mass transfer coefficients. Unfortunately, equivalent experiments with the IL were not possible due to difficulties with producing large samples of the encapsulated IL. This IL encapsulation “scale-up” problem was not solved during the course of this project. Nonetheless, using the PCIL microcapsules we demonstrated that, as expected, the mass transfer is internally controlled. In concert with a new rate-based model of the fluidized bed, we determined that the productivity is increased by a factor of 4.75 in the microcapsule fluidized bed absorber compared to a conventional liquid-gas packed bed absorber. The initial technoeconomic model shows that the capital cost for the microcapsule IL continuous fluidized bed process is similar to that of an aqueous amine process (specifically, the Econamine FG Plus technology). However, the stripping heat requirements are about 35% less for the model IL microcapsule case compared to the monoethanolamine (MEA) case. Thus, encapsulated ILs/PCILs in a continuous fluidized bed absorber for post-combustion CO 2 capture are a significant improvement over the free IL/PCIL case and represent a major reduction in the parasitic energy requirements compared to aqueous amine process.

20 FOSSIL-FUELED POWER PLANTS↗

Solar +: Clean Energy Strategies for the Sunshine State (Final Technical Report (FTR) of the Florida Alliance for Accelerating Solar and Storage Technology Readiness (FAASSTeR))

This reports on a four-year effort to provide foundational research, analysis, strategies and assistance to help Florida, and other states that might learn from this work, to grow solar energy in conjunction with other distributed energy resources by addressing and overcoming existing barriers, and in way that delivers increased value. The start of this effort coincided with an inflection point of sorts into a new dawn for solar energy in Florida, where the Sunshine state’s national ranking in total installed solar, according to the Solar Energy Industries Association (SEIA), has rose from 13th to 4th. Florida has now become the national leader in annual utility-scale solar growth as dozens of large plants have come online. Also, during this time, Florida utilities have expressed a strong and growing interest in understanding the role of energy storage and how to best plan for and deploy this unique resource as part of strategies to grow solar. The utility-scale solar growth experienced has been fueled by the economics of solar cost-parity with natural gas combined cycle plants and Florida Public Service Commission’s (PSC) approval of cost-recovery for the Investor-Owned Utilities (IOU’s), primarily through the Solar Base Rate Adjustment (SoBRA) mechanism. This has led to gigawatts (GW’s) of rate-based solar capacity additions over several years, along with fairly significant amounts of energy storage. Meanwhile, municipal electric utilities, which, collectively, are the third largest source of power in the state, have been increasing solar considerably through power purchase agreements (PPA’s) and are on track to have close to 1 GW of grid-connected solar by 2024. Florida’s municipal utilities and the Florida Municipal Electric Association (FMEA) have been key partners in the Florida Alliance for Accelerating Solar and Storage Technology Readiness (FAASSTeR), formed to carry out this effort. The six largest of these have been Core Team utilities, engaging throughout the project in weekly calls, discussions, and project direction, participating in and hosting workshops and benefiting from technical assistance in several areas.

14 SOLAR ENERGY↗

Retail Rate Projections for Long-Term Electricity System Models

Electricity prices reported in most electricity-system planning studies leave out many price components and do not translate into retail rates, making it difficult to interpret how projected electricity system changes will impact costs to consumers. Full transmission costs are left out of many studies; distribution and administration costs are similarly excluded or highly simplified. Here, we present a detailed bottom-up accounting method for projecting future retail electricity rates in the United States. Making the simplifying assumption that each state is served by an investor-owned utility (IOU), we translate projected generation and transmission capacity and costs from the Regional Energy Deployment System (ReEDS) capacity-expansion model into IOU balance sheet expenditures, accounting for depreciation, taxes, and the breakdown between operating and capitalized (rate-based) expenses. Distribution, administration, and intra-regional transmission costs are projected forward based on empirical trends over the past decade. Modeled bottom-up electricity rates are compared to historical rates from 2010-2019, and the sensitivity of modeled rates to a range of financing and modeling assumptions is explored. Distribution and administration rate components account for roughly 40% (4.4 ¢/kWh) of the projected national-average retail rate over 2020-2050 under central assumptions.

29 ENERGY PLANNING, POLICY, AND ECONOMY↗

Galileo inflight friction identification for the scan platform control loop

Two types of friction identification algorithms (position-based and rate-based) are investigated in an attempt to better understand cone actuator inflight behavior in the Galileo scan platform pointing system. This investigation involves the measurement of the scan platform position (or rate) with respect to the stator following a platform slew maneuver. Inflight data collection by the spacecraft's sensors and subsequent ground-based data processing comprise the two major steps in the identification experiment. The proposed algorithms were capable of obtaining friction estimates within + or - 10 percent accuracy; hence, it is concluded that this inflight system identification technique can sufficiently tune the Galileo cone controller.

Ianculescu, G. D.↗

A flow-control mechanism for distributed systems

A new approach to the rate-based flow control in store-and-forward networks is evaluated. Existing methods display oscillations in the presence of transport delays. The proposed scheme is based on the explicit use of an embedded dynamic model of a store-and-forward buffer in a controller's feedback loop. It is shown that the use of the model eliminates the oscillations caused by the transport delays. The paper presents simulation examples and assesses the applicability of the scheme in the new generation of high-speed photonic networks where transport delays must be considered.

Maitan, J.↗

An Evaluation of Protocols for UAV Science Applications

This paper identifies data transport needs for current and future science payloads deployed on the NASA Global Hawk Unmanned Aeronautical Vehicle (UAV). The NASA Global Hawk communication system and operational constrains are presented. The Genesis and Rapid Intensification Processes (GRIP) mission is used to provide the baseline communication requirements as a variety of payloads were utilized in this mission. User needs and desires are addressed. Protocols are matched to the payload needs and an evaluation of various techniques and tradeoffs are presented. Such techniques include utilization rate-base selective negative acknowledgement protocols and possible use of protocol enhancing proxies. Tradeoffs of communication architectures that address ease-of-use and security considerations are also presented.

Ivancic, William D.↗

Making Grid-interactive Efficient Buildings a “Win” for Both Customers and Utilities

Buildings account for more than 70% of U.S. electricity use and at least one-third of U.S. economy-wide CO2 emissions. Changing the timing and overall amount of electricity consumption in buildings would significantly reduce energy costs to consumers and facilitate the transition to a decarbonized economy. Grid-interactive efficient buildings (GEBs) incorporate energy efficiency, smart technologies, and active use of distributed energy resources (DERs) to provide these benefits. As the link between the customer and the power system, utilities are central to widespread deployment of GEBs. Yet, despite the significant cost savings and operational benefits of GEBs for utilities, deployment has remained limited. This paper explores emerging models for enabling utilities to facilitate GEB adoption. Building off foundational research conducted to develop the U.S. DOE’s A National Roadmap for Grid-Interactive Efficient Buildings, we describe the most novel recent examples of ways in which utilities and regulators have made demand-side innovation a win for both the customer and the utility. Emerging concepts include: (1) performance incentive mechanisms to align GEB deployment with utility financial motivations, (2) the use of subscription pricing (i.e., fixed monthly bills) to promote load flexibility and energy efficiency, (3) rate-basing utility-controlled behind-the-meter assets, and (4) coupling energy efficiency and load flexibility with electrification proposals to ensure that customer benefits are maximized. The paper concludes with a discussion about prospects for widespread GEB deployment and utilization by utilities, and how to scale efforts.

Satchwell, Andrew↗