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At least 37 records · Page 2

Leveraging Calibration Transfer Techniques for Remote Monitoring of Samarium and Europium in LiCl Using Laser-Induced Florescence Spectroscopy for Radioisotope Production Applications

Radioisotope production relies on complex chemical processes that must be performed in radiological hot cells or glove boxes because of the radioactive and otherwise hazardous materials being used. In these situations, optical sensors can provide real-time monitoring to users, which is unobtainable by more traditional methods. This study explores the use of calibration transfer methods to train a model on one instrument and date and then transfer it to another instrument of the same or different configuration on a different date. By performing laser-induced fluorescence measurements of Eu(III) and Sm(III) in 10 M LiCl over the course of 6 months using two disparate spectrometers and two different training sets, a strategy for calibrating and deploying models for online monitoring was established. Three transfer techniques were compared: direct standardization (DS), piecewise direct standardization (PDS), and external parameter orthogonalization (EPO). DS and PDS outperformed EPO for day-to-day transfers, and EPO was not effective for instrument-to-instrument transfers. Transferring the initial date’s full factorial model provided better prediction performance compared with retraining models the day of measurements using a D-optimal designed calibration set. For both day-to-day and instrument-to-instrument transfers, five Kennard–Stone selected samples were sufficient. Based on this choice, the initial-date, high-resolution spectrometer model was transferred to a lower-resolution, compact spectrometer 6 months later to monitor a simulated, real-time demonstration. Here, the combined predictions of the DS and PDS transferred models were able to accurately track the anticipated concentration profiles, maintaining root-mean-square error of prediction values below 10 ppm.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH

Designing Remote Monitoring for Smart Manufacturing Facilities: Hazard Identification and Classification

This study investigates the process of hazard identification in complex manufacturing environments during the design phase, emphasizing the significance of the design process in developing designs that effectively mitigate hazards in contexts with numerous variables, such as a variety of machines, sensors, actuators, and agents. Through a mixed-methods approach, the objective of this work is to understand how the evolution of design outcomes across various stages might influence a designer’s ability to recognize both standard and novel hazards. To achieve this understanding, an experimental design task was conducted with six designers from a national lab specializing in manufacturing technologies. This approach combined qualitative and quantitative data analysis from a one-hour virtual session with participants. Findings suggest that the complexity of identifying hazards in a high-dimensional design space is challenging within a limited time frame and that the identification of hazards is significantly influenced by the stage of the design task and the initial design decisions, indicating the need for extended time and strategic initial planning in the design process to enhance hazard identification.

Ballestas, Caseysimone

Remote monitoring of soil moisture using airborne microwave radiometers

The current status of microwave radiometry is provided. The fundamentals of the microwave radiometer are reviewed with particular reference to airborne operations, and the interpretative procedures normally used for the modeling of the apparent temperature are presented. Airborne microwave radiometer measurements were made over selected flight lines in Chickasha, Oklahoma and Weslaco, Texas. Extensive ground measurements of soil moisture were made in support of the aircraft mission over the two locations. In addition, laboratory determination of the complex permittivities of soil samples taken from the flight lines were made with varying moisture contents. The data were analyzed to determine the degree of correlation between measured apparent temperatures and soil moisture content.

Kroll, C. L.

Compact telemetry package for remote monitoring of neutron responses in animals

Battery-powered telemeter includes FM transmitter and is light enough to be mounted on animal's head. Animal has complete freedom of movement while its neuron responses are transmitted to receiver in laboratory. Construction may also be applied to monitor blood pressure, body temperature, and different muscular signals.

Baker, C. D.

Remote monitoring of the atmosphere with Raman LIDAR

Some of the Raman LIDAR applications for monitoring the atmosphere are reviewed. Following a definition of Raman scattering, the basic design of a Raman LIDAR system is described and the atmosphere-monitoring potentialities and limitations of the system are discussed, along with the possibilities of further progress.

Melfi, S. H.

Remote monitoring of environmental particulate pollution - A problem in inversion of first-kind integral equations

The determination of the microstructure, chemical nature, and dynamical evolution of scattering particulates in the atmosphere is considered. A description is given of indirect sampling techniques which can circumvent most of the difficulties associated with direct sampling techniques, taking into account methods based on scattering, extinction, and diffraction of an incident light beam. Approaches for reconstructing the particulate size distribution from the direct and the scattered radiation are discussed. A new method is proposed for determining the chemical composition of the particulates and attention is given to the relevance of methods of solution involving first kind Fredholm integral equations.

Fymat, A. L.

Aircraft versus spacecraft for remote monitoring of water quality in U.S. coastal zones

To provide guidance for conducting future water monitoring missions over U.S. coasts, aircraft and spacecraft approaches were defined and quantitatively compared. Sensors, aircraft and spacecraft were selected from current or developmental types for the hardware concepts and monitoring was assumed to begin in 1981-1983. Comparative data are presented on capabilities and costs to monitor both recognized pollution sites and broad shelf areas. For these mission requirements, a large fleet of light aircraft provided better coverage and at lower costs generally than one spacecraft, assuming a single, multi-spectral sensor on each platform. This result could change, however, should additional useful sensors with low cost penalties be found for the spacecraft.

Darnell, W. L.

Television image compression and small animal remote monitoring

It was shown that a subject can reliably discriminate a difference in video image quality (using a specific commercial product) for image compression levels ranging from 384 kbits per second to 1536 kbits per second. However, their discriminations are significantly influenced by whether or not the TV camera is stable or moving and whether or not the animals are quiescent or active, which is correlated with illumination level (daylight versus night illumination, respectively). The highest video rate used here was 1.54 megabits per second, which is about 18 percent of the so-called normal TV resolution of 8.4MHz. Since this video rate was judged to be acceptable by 27 of the 34 subjects (79 percent), for monitoring the general health and status of small animals within their illuminated (lights on) cages (regardless of whether the camera was stable or moved), it suggests that an immediate Space Station Freedom to ground bandwidth reduction of about 80 percent can be tolerated without a significant loss in general monitoring capability. Another general conclusion is that the present methodology appears to be effective in quantifying visual judgments of video image quality.

Haines, Richard F.

Remote monitoring of agricultural systems using NDVI time series and machine learning methods: a tool for an adaptive agricultural policy

This study aims to provide accurate information about changes in agricultural systems (AS) using phenological metrics derived from the NDVI time series. Use of such information could help land managers optimize land use choices and monitor the status of agricultural lands, under a variety of environmental and socioeconomic conditions. For this purpose, the Moderate Resolution Imaging Spectroradiometer (MODIS) NDVI data were used to derive phenological metrics over the Oum Er-Rbia basin (central Morocco). Random forest (RF), support vector machine (SVM), and K-nearest neighbor (KNN) classifiers were explored and compared on their ability to classify AS classes over the study area. Four main AS classes have been considered: (1) irrigated annual crop (IAC), (2) irrigated perennial crop (IPC), (3) rainfed area (RA), and (4) fallow (FA). By comparing the accuracy of the three classifiers, the RF method showed the best performance with an overall accuracy of 0.97 and kappa coefficient of 0.96.The RF method was then chosen to examine time variations in AS over a 16-year period (2000–2016). The AS main variations were detected and evaluated for the four AS classes. These variations have been found to be linked well with other indicators of local agricultural land management, as well as the historical agricultural drought changes over the study area. Overall, the results present a tool for decision makers to improve agricultural management and provide a different perspective in understanding the spatiotemporal dynamics of agricultural systems.

Youssef Lebrini

Continued Evaluation of the Use of a Raman Spectrometer for H-Canyon Dissolver Monitoring

Remote monitoring of dissolver activities in H-Canyon can help operators avoid delays associated with excessive levels of fuel fragments remaining after a run. SRNL has proposed that effective monitoring can be achieved by using a Raman spectrometer to measure NO 2 concentrations in the offgas stream sampled from the facility stack. Prior work (SRNL-STI-2021-00451) measuring the offgas from one dissolution batch of High Flux Isotope Reactor (HFIR) fuel suggested a relationship between %NO 2 levels and fragment height. Herein, we report the results of monitoring and analysis of the dissolution of four batches of Material Test Reactor (MTR) fuel. A rigorous quantitative relationship between %NO 2 measurements and fragment heights could not be established, due to high uncertainties associated with both measurements. Uncertainties with gas measurements are associated with the %NO 2 levels in the offgas being close to the detection limit for the analyzer. Alternative gas measurement strategies are discussed which could improve sensitivity and reduce uncertainty. Limitations to the precision of the probe measurements are also discussed. It is also noted that the offgas is an average of the products from simultaneous dissolution of elements in multiple wells. Detection of a high fragment height level in an individual well may be hindered by low levels in other wells.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W

Remote water monitoring system

A remote water monitoring system is described that integrates the functions of sampling, sample preservation, sample analysis, data transmission and remote operation. The system employs a floating buoy carrying an antenna connected by lines to one or more sampling units containing several sample chambers. Receipt of a command signal actuates a solenoid to open an intake valve outward from the sampling unit and communicates the water sample to an identifiable sample chamber. Such response to each signal receipt is repeated until all sample chambers are filled in a sample unit. Each sample taken is analyzed by an electrochemical sensor for a specific property and the data obtained is transmitted to a remote sending and receiving station. Thereafter, the samples remain isolated in the sample chambers until the sampling unit is recovered and the samples removed for further laboratory analysis.

Grana, D. C.