Search NASA⌕ Search

SEARCH · Search NASA

Results for “salt correction”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 37 records · Page 2

GCM Simulations of the Aerosol Indirect Effect: Sensitivity to Cloud Parameterization and Aerosol Burden

We describe the coupling of the Goddard Institute for Space Studies (GISS) general circulation model (GCM) to an online sulfur chemistry model and source models for organic matter and sea-salt that is used to estimate the aerosol indirect effect. The cloud droplet number concentration is diagnosed empirically from field experiment datasets over land and ocean that observe droplet number and all three aerosol types simultaneously; corrections are made for implied variations in cloud turbulence levels. The resulting cloud droplet number is used to calculate variations in droplet effective radius, which in turn allows us to predict aerosol effects on cloud optical thickness and microphysical process rates. We calculate the aerosol indirect effect by differencing the top-of-the-atmosphere net cloud radiative forcing for simulations with present-day vs. pre-industrial emissions. Both the first (radiative) and second (microphysical) indirect effects are explored. We test the sensitivity of our results to cloud parameterization assumptions that control the vertical distribution of cloud occurrence, the autoconversion rate, and the aerosol scavenging rate, each of which feeds back significantly on the model aerosol burden. The global mean aerosol indirect effect for all three aerosol types ranges from -1.55 to -4.36 W/sq m in our simulations. The results are quite sensitive to the pre-industrial background aerosol burden, with low pre-industrial burdens giving strong indirect effects, and to a lesser extent to the anthropogenic aerosol burden, with large burdens giving somewhat larger indirect effects. Because of this dependence on the background aerosol, model diagnostics such as albedo-particle size correlations and column cloud susceptibility, for which satellite validation products are available, are not good predictors of the resulting indirect effect.

Menon, Surabi↗

GCM Simulations of the Aerosol Indirect Effect: Sensitivity to Cloud Parameterization and Aerosol Burden

We describe the coupling of the Goddard Institute for Space Studies (GISS) general circulation model (GCM) to an online sulfur chemistry model and source models for organic matter and sea-salt that is used to estimate the aerosol indirect effect. The cloud droplet number concentration is diagnosed empirically from field experiment datasets over land and ocean that observe droplet number and all three aerosol types simultaneously; corrections are made for implied variations in cloud turbulence levels. The resulting cloud droplet number is used to calculate variations in droplet effective radius, which in turn allows us to predict aerosol effects on cloud optical thickness and microphysical process rates. We calculate the aerosol indirect effect by differencing the top-of-the-atmosphere net cloud radiative forcing for simulations with present-day vs. pre-industrial emissions. Both the first (radiative) and second (microphysical) indirect effects are explored. We test the sensitivity of our results to cloud parameterization assumptions that control the vertical distribution of cloud occurrence, the autoconversion rate, and the aerosol scavenging rate, each of which feeds back significantly on the model aerosol burden. The global mean aerosol indirect effect for all three aerosol types ranges from -1.55 to -4.36 W m(exp -2) in our simulations. The results are quite sensitive to the pre-industrial background aerosol burden, with low pre-industrial burdens giving strong indirect effects, and to a lesser extent to the anthropogenic aerosol burden, with large burdens giving somewhat larger indirect effects. Because of this dependence on the background aerosol, model diagnostics such as albedo-particle size correlations and column cloud susceptibility, for which satellite validation products are available, are not good predictors of the resulting indirect effect.

Menon, Surabi↗

Remote measurement of salinity in an estuarine environment

The surface salinity of the estuary waters of the Mississippi delta and Mississippi sound was measured using an L-band radiometer at 21 cm wavelength mounted in a P3A Earth Resources Aircraft. The method used for correcting the effects of the atmosphere, cosmic noise, sea surface roughness, and constant radiometer errors is described. The dielectric constant of sea water was taken to be that of NaCl. An accuracy of 3 to 5 parts salt per thousand parts water was obtained for a 5 to 35 part salt per thousand parts water range. Theoretical accuracy is computed to be one part salt per thousand parts water.

Thomann, G. C.↗

Coupled Aerosol-Chemistry-Climate Twentieth-Century Transient Model Investigation: Trends in Short-Lived Species and Climate Responses

The authors simulate transient twentieth-century climate in the Goddard Institute for Space Studies (GISS) GCM, with aerosol and ozone chemistry fully coupled to one another and to climate including a full dynamic ocean. Aerosols include sulfate, black carbon (BC), organic carbon, nitrate, sea salt, and dust. Direct and BC snow-albedo radiative effects are included. Model BC and sulfur trends agree fairly well with records from Greenland and European ice cores and with sulfur deposition in North America; however, the model underestimates the sulfur decline at the end of the century in Greenland. Global BC effects peak early in the century (1940s); afterward the BC effects decrease at high latitudes of the Northern Hemisphere but continue to increase at lower latitudes. The largest increase in aerosol optical depth occurs in the middle of the century (1940s-80s) when sulfate forcing peaks and causes global dimming. After this, aerosols decrease in eastern North America and northern Eurasia leading to regional positive forcing changes and brightening. These surface forcing changes have the correct trend but are too weak. Over the century, the net aerosol direct effect is -0.41 Watts per square meter, the BC-albedo effect is -0.02 Watts per square meter, and the net ozone forcing is +0.24 Watts per square meter. The model polar stratospheric ozone depletion develops, beginning in the 1970s. Concurrently, the sea salt load and negative radiative flux increase over the oceans around Antarctica. Net warming over the century is modeled fairly well; however, the model fails to capture the dynamics of the observedmidcentury cooling followed by the late century warming.Over the century, 20% of Arctic warming and snow ice cover loss is attributed to the BC albedo effect. However, the decrease in this effect at the end of the century contributes to Arctic cooling. To test the climate responses to sulfate and BC pollution, two experiments were branched from 1970 that removed all pollution sulfate or BC. Averaged over 1970-2000, the respective radiative forcings relative to the full experiment were +0.3 and -0.3 Watts per square meter; the average surface air temperature changes were +0.2 degrees and -0.03 C. The small impact of BC reduction on surface temperature resulted from reduced stability and loss of low-level clouds.

Koch, Dorothy↗

Hydrogen Bonding and Vibrational Spectroscopy: A Theoretical Study

Effects of hydrogen bonding on vibrational spectra are studied for several hydrogen-bonded complexes, in which hydrogen bonding ranges from weak (<5 kcal/mol) to very strong (>25 kcal/mol). The systems studied include complexes of inorganic acids and salts with water and ammonia, as well as complexes of several organic molecules (nitriles and amino acids) with water. Since anharmonic effects are very strong in hydrogen-bonded systems, anharmonic vibrational frequencies and infrared intensities are computed using the correlation-corrected vibrational self-consistent field (CC-VSCF) method with ab initio potential surfaces at the MP2 and CCSD(T) levels. The most common spectral effects induced by hydrogen bonding are red shifts of stretching vibrational frequencies ranging from approx.200/cm to over 2000/cm and significant increases of infrared intensities for those bonds that participate in hydrogen bonding. However, some systems (e.g. nitrile-water complexes) exhibit shifts in the opposite direction (to the blue) upon formation of hydrogen bonds.

Chaban, Galina M.↗

Maps Suggest Transport and Source Processes of PM2.5 at 1 km x 1 km for the Whole San Joaquin Valley, Winter 2011 (Generalizations from DISCOVER-AQ)

We present interpreted data analysis using MAIAC (Multiangle implementation of Atmospheric Correction) retrievals and appropriate RAPid Update Cycle (RAP) meteorology to map respirable aerosol (PM2.5) for the period January and February, 2011. The San Joaquin Valley is one of the unhealthiest regions in the USA for PM2.5 and related morbidity. The methodology evaluated can be used for the entire moderate-resolution imaging spectrometer (MODIS, VIIRS) data record. Other difficult areas of the West: Riverside, CA, Salt Lake City, UT, and Doa Ana County, NM share similar difficulties and solutions. The maps of boundary layer depth for 1116 hr local time from RAP allows us to interpret aerosol optical thickness as a concentration of particles in a nearly well-mixed box capped by clean air. That mixing is demonstrated by DISCOVER-AQ data and afternoon samples from the airborne measurements, P3B (on-board) and B200 (HSRL2 lidar). This data and the PM2.5 gathered at the deployment sites allowed us to estimate and then evaluate consistency and daily variation of the AOT to PM2.5 relationship. Mixed-effects modeling allowed a refinement of that relation from day to day; RAP mixed layers explained the success of previous mixed-effects modeling. Compositional, size-distribution, and MODIS angle-of-regard effects seem to describe the need for residual daily correction beyond ML depth.We report on an extension method to the entire San Joaquin Valley for all days with MODIS imagery using the permanent PM2.5 stations, evaluated for representativeness. Resulting map movies show distinct sources, particularly Interstate-5 (at approx. 1km x 1km resolution) and the broader Bakersfield area. Accompanying winds suggest transport effects and variable pathways of pollution cleanout. Such estimates should allow morbiditymortality studies. They should be also useful for actual model assimilations, where composition and sources are uncertain. We conclude with a description of new work to extend these insights to similar regions, e.g. interior valleys of California, the Po Valley, the Mediterranean litoral, and the Ganges Plain.This work show generalizable use of remote sensing, a major goal of DISCOVER-AQ, Deriving Information on Surface Conditions from COlumn and VERtically Resolved Observations Relevant to Air Quality.

Chatfield, R.↗

Recent Advances in Laboratory Infrared Spectroscopy of Polycyclic Aromatic Hydrocarbons: PAHs in the Far Infrared

Over 25 years of observations and laboratory work have shown that the mid-IR spectra of a majority of astronomical sources are dominated by emission features near 3.3, 6.2, 7.7, and 11.2 microns, which originate in free polycyclic aromatic hydrocarbon (PAH) molecules. PAHs dominate the mid-IR emission from many galactic and extragalactic objects. As such, this material tracks a wide variety of astronomical processes, making this spectrum a powerful probe of the cosmos Apart from bands in the mid-IR, PAHs have bands spanning the Far-IR (FIR) and emission from these FIR features should be present in astronomical sources showing the Mid-IR PAH bands. However, with one exception, the FIR spectral characteristics are known only for a few neutral small PAHs trapped in salt pellets or oils at room temperature, data which is not relevant to astrophysics. Furthermore, since most emitting PAHs responsible for the mid-IR astronomical features are ionized, the absence of any experimental or theoretical PAH ion FIR spectra will make it impossible to correctly interpret the FIR data from these objects. In view of the upcoming Herschel space telescope mission and SOFIA's FIR airborne instrumentation, which will pioneer the FIR region, it is now urgent to obtain PAH FIR spectra. This talk will present an overview recent advances in the laboratory spectroscopy of PAHs, Highlighting the FIR spectroscopy along with some quantum calculations.

Mattioda, Andrew L.↗

Remote measurement of salinity in an estuarine environment.

The microwave emission of sea water is dependent upon salinity in the low microwave spectrum, and it appears possible to measure remotely surface salinity at 21-cm wavelength with an accuracy up to one part salt per thousand parts water (.1%) for a .5 to 3.5% salinity range. The dielectric constant of sea water can be represented by that of NaCl, except that the sea water conductivity is retained. The effects of the atmosphere, cosmic noise, sea surface roughness, and constant radiometer errors can be corrected by using surface calibration measurements. In experiments performed in Mississippi and Louisiana coastal waters salinity accuracies of .3 to .5 were obtained. It is believed that the accuracy was limited by the radiometer used.

Thomann, G. C.↗

Image-based terrain modeling with thematic mapper applied to resolving the limit of Holocene Lake expansion in the Great Salt Lake Desert, Utah, part 1

The LANDSAT Thematic Mapper (TM) scanner records reflected solar energy from the earth's surface in six wavelength regions, or bands, and one band that records emitted energy in the thermal region, giving a total of seven bands. Useful research was extracted about terrain morphometry from remote sensing measurements and this information is used in an image-based terrain model for selected coastal geomorphic features in the Great Salt Lake Desert (GSLD). Technical developments include the incorporation of Aerial Profiling of Terrain System (APTS) data in satellite image analysis, and the production and use of 3-D surface plots of TM reflectance data. Also included in the technical developments is the analysis of the ground control point spatial distribution and its affects on geometric correction, and the terrain mapping procedure; using satellite data in a way that eliminates the need to degrade the data by resampling. The most common approach for terrain mapping with multispectral scanner data includes the techniques of pattern recognition and image classification, as opposed to direct measurement of radiance for identification of terrain features. The research approach in this investigation was based on an understanding of the characteristics of reflected light resulting from the variations in moisture and geometry related to terrain as described by the physical laws of radiative transfer. The image-based terrain model provides quantitative information about the terrain morphometry based on the physical relationship between TM data, the physical character of the GSLD, and the APTS measurements.

Merola, John A.↗

Heterogeneous reactions of HNO3(g) + NaCl(s) yields HCl(g) + NaNO3(s) and N2O5(g) + NaCl(s) yields ClNO2(g) + NaNO3(s)

The heterogeneous reactions of HNO3(g) + NaCl(s) yields HCl(g) + NaNO3(s) (eq 1) and N2O5(g) + NaCl(s) yields ClNO2(g) + NaNO3(S) (eq 2) were investigated over the temperature range 223-296 K in a flow-tube reactor coupled to a quadrupole mass spectrometer. Either a chemical ionization mass spectrometer (CIMS) or an electron-impact ionization mass spectrometer (EIMS) was used to provide suitable detection sensitivity and selectivity. In order to mimic atmospheric conditions, partial pressures of HNO3 and N2O5 in the range 6 x 10(exp -8) - 2 x 10(exp -6) Torr were used. Granule sizes and surface roughness of the solid NaCl substrates were determined by using a scanning electron microscope. For dry NaCl substrates, decay rates of HNO3 were used to obtain gamma(1) = 0.013 +/- 0.004 (1sigma) at 296 K and > 0.008 at 223 K, respectively. The error quoted is the statistical error. After all corrections were made, the overall error, including systematic error, was estimated to be about a factor of 2. HCl was found to be the sole gas-phase product of reaction 1. The mechanism changed from heterogeneous reaction to predominantly physical adsorption when the reactor was cooled from 296 to 223 K. For reaction 2 using dry salts, gamma(2) was found to be less than 1.0 x 10(exp -4) at both 223 and 296 K. The gas-phase reaction product was identified as ClNO2 in previous studies using an infrared spectrometer. An enhancement in reaction probability was observed if water was not completely removed from salt surfaces, probably due to the reaction of N2O5(g) + H2O(s) yields 2HNO3(g). Our results are compared with previous literature values obtained using different experimental techniques and conditions. The implications of the present results for the enhancement of the hydrogen chloride column density in the lower stratosphere after the El Chichon volcanic eruption and for the chemistry of HCl and HNO3 in the marine troposphere are discussed.

Leu, Ming-Taun↗

Plan for the uniform mapping of earth resources and environmental complexes from Skylab imagery

The author has identified the following significant results. Below approximately 25% cover visual photointerpretation of vegetation analogs of Skylab 2 Sl9OA color infrared imagery is poor. Correct identifications of vegetation analogs in this category range from 28 to 57%. Good photointerpretation results (64 to 96%) were obtained on vegetation analogs with higher cover values. The four semidesert vegetation analogs (greasewood, saltbush, big sagebrush, and pinyon-juniper) are consistently distinguishable as a group. Photointerpretation accuracy equals 90.1%. When these same types are broken into two sub-groups (salt desert vegetation and shrub steppe/sparse pinyon-juniper vegetation) interpretation success drops to 76% and 85%, respectively. Band ratioing and transmittance differences between two forested analogs as imaged on Skylab 2 S19OA film shows significant differences. In the infrared wavelength both analogs have very similar transmittance characteristics while the visible wavelength shows separation between the two. Relative transmittance values for stands of ponderosa pine forestland and pinyon-juniper woodland are 719.3 + or - 65.9 and 223.6 + or - 48.1, respectively on negative transparencies. In image interpretation along the low-elevation fringe of forested regions these are the two forest analogs most frequently requiring separation.

Poulton, C. E.↗

A New Sea Ice Model: Pancakes to Metrics

We are developing, testing, and validating a new sea ice dynamics model that treats the ice cover as an elastic/decohesive material in the permanent pack and includes the correct frazil/pancake behavior in the marginal zone. Two salient features of present ice dynamics models are that they do not: 1) reproduce the oriented fracture patterns of openings and closings in the pack ice, and 2) accurately model the effects of frazil/pancake ice formation in the ice margin. These poorly modeled areas account for a substantial portion of the ice growth, turbulent heat flux to the atmosphere, salt flux to the ocean, and energy dissipation due to slippage, ridging, and rafting, in the Arctic. Existing sea ice models have shown limited success in predicting the degree to which a lead will open for prescribed or observed forcing conditions. An important aspect of the new model we are developing is that the existence of cracks, along with their orientation, opening, and closing, is predicted. To put this effort in perspective a short history of ice dynamics modeling and data collection is presented. The RGPS data set is used to validate the model. As part of the testing and validation of the model, we are working on a new metric for comparing linear features (leads and ridges) in the data and model to be used in data assimilation for this model. The model framework is presented as well as some results showing the creation and development of leads in a simulation of ice dynamics in the Beaufort Sea. Other presentations by the authors will show other results from this effort.

Coon, M.↗

Chemically frozen multicomponent boundary layer theory of salt and/or ash deposition rates from combustion gases

There is increased interest in, and concern about, deposition and corrosion phenomena in combustion systems containing inorganic condensible vapors and particles (salts, ash). To meet the need for a computationally tractable deposition rate theory general enough to embrace multielement/component situations of current and future gas turbine and magnetogasdynamic interest, a multicomponent chemically 'frozen' boundary layer (CFBL) deposition theory is presented and its applicability to the special case of Na2SO4 deposition from seeded laboratory burner combustion products is demonstrated. The coupled effects of Fick (concentration) diffusion and Soret (thermal) diffusion are included, along with explicit corrections for effects of variable properties and free stream turbulence. The present formulation is sufficiently general to include the transport of particles provided they are small enough to be formally treated as heavy molecules. Quantitative criteria developed to delineate the domain of validity of CFBL-rate theory suggest considerable practical promise for the present framework, which is characterized by relatively modest demands for new input information and computer time.

Rosner, D. E.↗

Composition of Impact Melt Debris from the Eltanin Impact Strewn Field, Bellingshausen Sea

The impact of the km-sized Eltanin asteroid into the Bellingshausen Sea produced mm- to cm-sized vesicular impact melt-rock particles found in sediment cores across a large area of the ocean floor. These particles are composed mainly of olivine and glass with minor chromite and traces of NiFe-sulfides. Some particles have inclusions of unmelted mineral and rock fragments from the precursor asteroid. Although all samples of melt rock examined have experienced significant alteration since their deposition in the late Pliocene, a significant portion of these particles have interiors that remain pristine and can be used to estimate the bulk composition of the impact melt. The bulk composition of the melt-rock particles is similar to the composition of basaltic meteorites such as howardites or mesosiderite silicates, with a contribution from seawater salts and a siderophile-rich component. There is no evidence that the Eltanin impact melt contains a significant terrestrial silicate component that might have been incorporated by mixing of the projectile with oceanic crust. If terrestrial silicates were incorporated into the melt, then their contribution must be much less than 10 wt%. Since excess K, Na, and CI are not present in seawater proportions, uptake of these elements into the melt must have been greatest for K and least for CI, producing a K/CI ratio about 4 times that in seawater. After correcting for the seawater component, the bulk composition of the Eltanin impact melt provides the best estimate of the bulk composition of the Eltanin asteroid. Excess Fe in the impact melt, relative to that in howardites, must be from a significant metal phase in the parent asteroid. Although the estimated Fe:Ni:Ir ratios (8:1:4 x 10(exp -5)) are similar to those in mesosiderite metal nodules (10:1:6 x 10(exp -5), excess Co and Au by factors of about 2 and 10 times, respectively, imply a metal component distinct from that in typical mesosiderites. An alternative interpretation, that siderophiles have been highly fractionated from a mesosiderite source, would require loss of about 90% of the original metal from the impact melt and the sediments, and is unsupported by any observational data. More likely, the excess Fe in the melt rocks is 'representative of the amount of metal in the impacting asteroid, which is estimated to be 4+/- 1 wt%.

Kyte, Frank T.↗

The Coupling of Solution Chemistry to Plant Nutrient Demand in an on Demand Nutrient Delivery System

The goal of the proposal will be to determine the suitability of the DASI instrument in providing a signal that can be recognized and be utilized as an indicator of plant stress. The method to be utilized for evaluating stress is the presentation of an every increasing level of nutrient deficiency and salinity stress (addition of salt (NACl) or increasing concentration of balanced nutrient) while simultaneously recording spectral reflectance using the DASI instrument and monitoring the traditional processes of gas exchange and nutrient uptake parameters. In this manner, we will be able to directly compare the DASI measurements with known stresses as determined by the traditional gas exchange and nutrient uptake measures of stress. We anticipate that the DASI will provide a sensitive identifier of plant stress; recording signals of the resulting changes in plant metabolism in real time, far before any visible effects of stress could be observed. Thus, there is a potential for very early management intervention to correct a stress condition before damage could develop. The present response time for the observation of visual symptoms of plant stress is considerable and only provides an indication that a stress is present after it has been present for an extended period of time. Thus, the impact of a plant-based life support function will have already been significant. An additional benefit of this research to regenerative life support will be the characterization of a potential recovery scenario from various degrees of stress. The experimental approach to be employed includes the removal of the stress at various points in the stress gradient and the characterization of plant performance and reflectance spectra during recovery from various degrees of stress. Spectral reflectance imaging techniques have been developed and used to measure the biochemical composition of plants and relate these characteristics to the fluxes of biochemical elements within the ecosystem.

Savage, Wayne↗

Electrochemical approaches for chemical and biological analysis on Mars

Obtaining in situ chemical data from planetary bodies such as Mars or Europa can present significant challenges. The one analytical technique that has many of the requisite characteristics to meet such a challenge is electroanalysis. Described here are three electroanalytical devices designed for in situ geochemical and biological analysis on Mars. The Mars Environmental Compatibility Assessment (MECA) was built and flight qualified for the now cancelled NASA Mars 2001 Lander. Part of MECA consisted of four "cells" containing arrays of electrochemical based sensors for measuring the ionic species in soil samples. A next-generation MECA, the Robotic Chemical Analysis Laboratory (RCAL), uses a carousel-type system to allow for greater customization of analytical procedures. A second instrument, proposed as part of the 2007 CryoScout mission, consists of a flow-through inorganic chemical analyzer (MICA). CryoScout is a torpedo-like device designed for subsurface investigation of the stratigraphic climate record embedded in Mars' north polar cap. As the CryoScout melts its way through the ice cap, MICA will collect and analyze the meltwater for a variety of inorganics and chemical parameters. By analyzing the chemistry locked in the layers of dust, salt, and ice, geologists will be able to determine the recent history of climate, water, and atmosphere on Mars and link it to the past. Finally, electroanalysis shows its abilities in the detection of possible microorganism on Mars or elsewhere in the solar system. To identify an unknown microorganism, one that may not even use Earth-type biochemistry, requires a detection scheme which makes minimal assumptions and looks for the most general features. Recent work has demonstrated that the use of an array of electrochemical sensors which monitors the changes in a solution via electrical conductivity, pH, and ion selective electrodes, can be used to detect minute chemical perturbations caused by the growth of bacteria and with the correct methodology provide unamibiguous detection of such life forms.

Non-NASA Center↗

Spacecraft Water Impurity Monitor, a System for Water Quality Analysis on Exploration Missions Beyond Low Earth Orbit

Exploration missions beyond low-earth-orbit (LEO) will require advanced instrumentation to monitor water quality. Traveling beyond LEO means the transfer of water samples to an Earth-based laboratory for detailed analysis is not feasible. Detailed analysis of water composition during exploration is still necessary, because having the capability to determine the specific organic chemical causing a change in total organic carbon (TOC) or the specific metal or ionic species causing a change in conductivity has the potential to inform the crew health and system management decisions. On a new vehicle such as a lunar or Mars surface habitat or a Mars transit vehicle, finding “new” impurities not seen on ISS should be expected. The key is to identify the impurity so the correct action can be taken. On ISS we can measure TOC, conductivity, and other physical properties but do not have the capability for detailed analysis using vehicle instrumentation. This is acceptable because ISS can send samples down to Earth for further analysis and obtain the detailed composition. The Spacecraft Water Impurity Monitor (SWIM) will provide detailed water quality analysis for missions in which sample down mass is not available. SWIM is a system comprising organic and inorganic analysis modules. For organic chemicals, a gas chromatograph mass spectrometer (GCMS) detects and identifies organic impurities. For inorganic species, a capillary electrophoresis capacitively coupled contactless conductivity detection (CE-C4D) system as well as ion specific electrodes detect and identify metal ions and other inorganic salts / acids. The SWIM technology demonstration project has completed a System Requirements Review (SRR) to finalize detection requirements and is currently working to refine vehicle interface requirements for a future technology demonstration. The project also has begun preliminary flight design activities for the core analyzers in the instrument suite.

Water Monitoring↗

Spacecraft Water Impurity Monitor, a System for Water Quality Analysis on Exploration Missions Beyond Low Earth Orbit

Exploration missions beyond low-earth-orbit (LEO) will require advanced instrumentation to monitor water quality. Traveling beyond LEO means the transfer of water samples to an Earth-based laboratory for detailed analysis is not feasible. Detailed analysis of water composition during exploration is still necessary, because having the capability to determine the specific organic chemical causing a change in total organic carbon (TOC) or the specific metal or ionic species causing a change in conductivity has the potential to inform the crew health and system management decisions. On a new vehicle such as a lunar or Mars surface habitat or a Mars transit vehicle, finding “new” impurities not seen on ISS should be expected. The key is to identify the impurity so the correct action can be taken. On ISS we can measure TOC, conductivity, and other physical properties but do not have the capability for detailed analysis using vehicle instrumentation. This is acceptable because ISS can send samples down to Earth for further analysis and obtain the detailed composition. The Spacecraft Water Impurity Monitor (SWIM) will provide detailed water quality analysis for missions in which sample down mass is not available. SWIM is a system comprising organic and inorganic analysis modules. For organic chemicals, a gas chromatograph mass spectrometer (GCMS) detects and identifies organic impurities. For inorganic species, a capillary electrophoresis capacitively coupled contactless conductivity detection (CE-C4D) system as well as ion specific electrodes detect and identify metal ions and other inorganic salts / acids. The SWIM technology demonstration project has completed a System Requirements Review (SRR) to finalize detection requirements and is currently working to refine vehicle interface requirements for a future technology demonstration. The project also has begun preliminary flight design activities for the core analyzers in the instrument suite.

Water Monitoring↗