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Review of core characterization with the Illinois State Geologic Survey, with a focus on novel analyses associated with the potential storage formation the St Peter Sandstone.
Flexible sandstone deformation quantitative microstructural study of structure-property relation
Hugoniot equation of state measurements from shock wave loading study of Coconino sandstone
Shock metamorphism of Coconino sandstone at Meteor Crater /Arizona/, examining porosity role in rock compression and in high pressure phases formation
Triplicate dielectric constant and loss tangent measurements on samples of sandstone, shale, coal, and slate were performed. Each of the three necessary configurations of the coal material was sampled to obtain measurements, with each sample machined parallel to the coal layering orientation. The coal samples were machined perpendicular to the coal layering and measured. They were conditioned at 100% humidity and at room temperature and remeasured; then conditioned in an elevated environment, and remeasured for dielectric properties. The coal data appear to remain relatively constant over the microwave frequency region. At the Ghz frequencies, the relative dielectric constant of coal is slightly higher for the E-field parallel to the layers than for the perpendicular case.
The epilithic lichen flora on the Beacon sandstone formation in Victoria Land consists of seven species: Acarospora gwynnii Dodge & Rudolph, Buellia grisea Dodge & Baker, B. pallida Dodge & Baker, Carbonea capsulata (Dodge & Baker) Hale comb. nov., Lecanora fuscobrunnea Dodge & Baker, Lecidea cancriformis Dodge & Baker, and L. siplei Dodge & Baker. The typification of the species is given along with descriptions and distribution in Antarctica.
We have used several non-destructive optical techniques to study the distribution of organic molecules on an Antarctic sandstone sample collected at Battleship Promontory. Cryptoendolithic microorganisms have been found to inhabit rocks in the dry valleys of Antarctica. These dry deserts are an Earth analog to Mars. Future Mars rovers may search for life in the rocks of Mars with similar instrumentation used in this study. Light microscopy was used to determine five distinct regions and to determine textures on the sample. Deep ultraviolet fluorescence spectroscopy was used to scan the rock for the presence of organic molecules. Organic molecules were present in three of the five regions but not in the crust. There were similarities between each region, but each region presented a unique signature. Raman spectroscopy identified the minerals present and also provided more definitive identifications of the organic molecules. X-ray diffraction was also used to definitively identify the minerals present and corroborate the Raman mineral results.
MSL Curiosity investigated the Windjana sandstone outcrop, in the Kimberley area of Gale Crater, and obtained mineralogical analyses with the CheMin XRD instrument. Windjana is remarkable in containing an abundance of potassium feldspar (and thus K in its bulk chemistry) combined with a low abundance of plagioclase (and low Na/K in its chemistry). The source of this enrichment in K is not clear, but has significant implications for the geology of Gale Crater and of Mars. The high K could be intrinsic to the sediment and imply that the sediment source area (Gale Crater rim) includes K-rich basalts and possibly more evolved rocks derived from alkaline magmas. Alternatively, the high K could be diagenetic and imply that the Gale Crater sediments were altered by K-rich aqueous fluids after deposition.
The Windjana drill sample, a sandstone of the Dillinger member (Kimberley formation, Gale Crater, Mars), was analyzed by CheMin X-ray diffraction (XRD) in the MSL Curiosity rover. From Rietveld refinements of its XRD pattern, Windjana contains the following: sanidine (21% weight, approximately Or(sub 95)); augite (20%); magnetite (12%); pigeonite; olivine; plagioclase; amorphous and smectitic material (approximately 25%); and percent levels of others including ilmenite, fluorapatite, and bassanite. From mass balance on the Alpha Proton X-ray Spectrometer (APXS) chemical analysis, the amorphous material is Fe rich with nearly no other cations-like ferrihydrite. The Windjana sample shows little alteration and was likely cemented by its magnetite and ferrihydrite. From ChemCam Laser-Induced Breakdown Spectrometer (LIBS) chemical analyses, Windjana is representative of the Dillinger and Mount Remarkable members of the Kimberley formation. LIBS data suggest that the Kimberley sediments include at least three chemical components. The most K-rich targets have 5.6% K2O, approximately 1.8 times that of Windjana, implying a sediment component with greater than 40% sanidine, e.g., a trachyte. A second component is rich in mafic minerals, with little feldspar (like a shergottite). A third component is richer in plagioclase and in Na2O, and is likely to be basaltic. The K-rich sediment component is consistent with APXS and ChemCam observations of K-rich rocks elsewhere in Gale Crater. The source of this sediment component was likely volcanic. The presence of sediment from many igneous sources, in concert with Curiosity's identifications of other igneous materials (e.g.,mugearite), implies that the northern rim of Gale Crater exposes a diverse igneous complex, at least as diverse as that found in similar-age terranes on Earth.
Manganese has been observed on Mars by the NASA Curiosity rover in a variety of contexts and is an important indicator of redox processes in hydrologic systems on Earth. Within the Murray formation, an ancient primarily fine-grained lacustrine sedimentary deposit in Gale crater, Mars, have observed up to 45× enrichment in manganese and up to 1.5× enrichment in iron within coarser grained bedrock targets compared to the mean Murray sediment composition. This enrichment in manganese coincides with the transition between two stratigraphic units within the Murray: Sutton Island, interpreted as a lake margin environment, and Blunts Point, interpreted as a lake environment. On Earth, lacustrine environments are common locations of manganese precipitation due to highly oxidizing conditions in the lakes. Here, we explore three mechanisms for ferromanganese oxide precipitation at this location: authigenic precipitation from lake water along a lake shore, authigenic precipitation from reduced groundwater discharging through porous sands along a lake shore, and early diagenetic precipitation from groundwater through porous sands. All three scenarios require highly oxidizing conditions and we discuss oxidants that may be responsible for the oxidation and precipitation of manganese oxides. This work has important implications for the habitability of Mars to microbes that could have used Mn redox reactions, owing to its multiple redox states, as an energy source for metabolism.
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Project update presentation for the 2024 AAPG IMAGE Conference
Project presentation at the 2025 Eastern Section American Association of Petroleum Geologists (AAPG)
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