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NASA NTRS1989

Composition of dust from Comet P/Halley: The mineral fraction

The composition of dust from Comet Halley was investigated in situ during the Vega 1, Vega 2, and Giotto encounters by the PIA/PUMA impact mass spectrometers. More than 5000 meaningful spectra of individual dust particles were obtained, most in a compressed mode. The interpretation of these spectra in terms of elemental and mineralogical composition will be discussed. Accounting for these difficulties, the following conclusions can be derived for the mineral fraction of dust particles: (1) the observed compositions are compatible with the full range of observed meteoritic minerals (in particular mafic silicates, plagioclases, sulfides, oxides); and (2) within each mineralogical class, the spread in composition appears much wider and more uniform than in meteorites. The low overall density and very large excess of light elements will be discussed. These first direct results on cometary dust considerably strengthen the case for a comet sample return mission.

Langevin, Y.↗

NASA NTRS2013

Lessons Learned from the Stardust Sample Return Mission

These are science and mission design and operations lessons learned from the Stardust Mission, which returned grains from comet Wild-2 and fresh interstellar dust to Earth in 2006 [1]. Science Lessons: Major discoveries of the Stardust Wild-2 samples include the presence of numerous chondrules and CAI in a comet, which requires a much more dynamic early solar system than many had envisaged, and verified predictions made by models requiring outward flow of early solar system solids before the early nebular gas had dissipated [1-3]. No evidence has been found for the presence of live Al-26 in the comet, suggesting late accretion [4]. Carbonates and unusual sulfides were found which potentially require activity of liquid water within the comet, but to only a minor degree at best [5-6]. The presence of abundant thermally-metamorphosed silicates in Wild-2 appears to require assembly from an earlier generation of bodies [7]. The abundance of presolar grains in the Wild-2 samples appears to be below what has been found in most chondritic IDPs and primitive chondrites [1]. The bulk mineralogy of Wild-2 grains does not match the mineralogy from any single other known astromaterial [7], and is also strikingly unlike that inferred from Spitzer Telescope spectra of Comet Temple 1 dust [8]. Amino acids and other fragile organics have been detected among the Wild-2 samples [9], which highlights the critical importance of further developing techniques for organic analysis in small samples, and cleaning outbound spacecraft.

Zolensky, M. E.↗

NASA NTRSDate not supplied

PRESOLAR GRAIN ABUNDANCE VARIATION IN THE MILLER RANGE 090019 CO3.1 CHONDRITE

Presolar grains condensed in the outflows of evolved red giant stars and the ejecta of supernovae (SNe) and novae. These grains have greatly anomalous isotopic compositions compared to solar system material, reflecting their stellar origins [1]. They have been identified in primitive meteorites, interplanetary dust particles (IDPs), Antarctic micrometeorites, and comet Wild 2 samples returned by NASA’s Stardust mission. Presolar silicates are one of the most abundant presolar phases and their concentrations extend up to 1.5% in primitive IDPs believed to derive from comets [2]. These grains are highly susceptible to alteration and destruction by secondary processing in the interstellar medium, nebula, and asteroid or comet parent body. Presolarsilicate abundance variations between primitive meteorites and chemical and mineralogical studies provide indications of the extent of secondary hydrothermal alteration [3, 4]. The abundance of presolar SiC grains is generally consistent among chondrites, but lower abundances in some meteorites have been attributed to thermal alteration [5, 6]. Presolar grain abundance variations attributed to localized alteration have also been reported within different regions of a chondrite [e.g., 7].Carbonaceous chondrites from the CO and CR groups have the highest abundances of presolar silicates among meteorites, attesting to their primitive nature. The CO3 chondrite Dominion Range (DOM) 08006 has the highest presolar O-rich grain abundance of ~260 ppm [8, 9]. MillerRange (MIL) 090019 is classified as a CO3.1 chondrite and has affinities to Acfer 094, DOM 08004/6 and Allan Hills (ALH) 77307. These chondrites have high presolar silicate abundances and contain high abundances of various types of refractory inclusions. We previously conducted detailed studies of CAIs in MIL 090019 [10, 11]. Here we evaluate its presolar grain inventory to assess the degree of parent body alteration and compare to other chondrites

A. N. Nguyen↗

NASA NTRS2013

Dust in the Solar System - Properties and Origins

Interplanetary dust pervades the inner Solar System, giving rise to a prominent glow above the horizon at sunrise and sunset known as the zodiacal light. This dust derives from the disintegration of comets as they approach the Sun and from collisions among main-belt asteroids. The Earth accretes roughly 4x10(exp 6) kg/year of 1 - 1,000 micron dust particles as they spiral into the Sun under the influence of Poynting-Robertson drag and solar wind drag. Samples of these grains have been collected from deep sea sediments, Antarctic ice and by high-altitude aircraft and balloon flights. Interplanetary dust particles (IDPs) collected in the stratosphere have been classified by their IR spectra into olivine, pyroxene, and hydrated silicate-dominated classes. Most IDPs have bulk major and minor element abundances that are similar to carbonaceous chondrite meteorites. Hydrated silicate-rich IDPs are thought to derive from asteroids based on their mineralogy and low atmospheric entry velocities estimated from peak temperatures reached during atmospheric entry. Anhydrous IDPs are typically aggregates of 0.1 - approx. 1 micron Mg-rich olivine and pyroxene, amorphous silicates (GEMS), Fe, Nisulfides and rare spinel and oxides bound together by carbonaceous material. These IDPs are often argued to derive from comets based on compositional similarities and high atmospheric entry velocities that imply high eccentricity orbits. Infrared spectra obtained from anhydrous IDPs closely match remote IR spectra obtained from comets. The most primitive (anhydrous) IDPs appear to have escaped the parent-body thermal and aqueous alteration that has affected meteorites. These samples thus consist entirely of grains that formed in the ancient solar nebula and pre-solar interstellar and circumstellar environments. Isotopic studies of IDPs have identified silicate stardust grains that formed in the outflows of red giant and asymptotic giant branch stars and supernovae]. These stardust grains include both amorphous and crystalline silicates. The organic matter in these samples also exhibits highly anomalous H, C, and N isotopic compositions that are consistent with formation in low temperature environments at the outermost regions of the solar nebula or presolar cold molecular cloud. The scientific frontiers for these samples include working toward a better understanding of the origins of the solar system amorphous and crystalline grains in IDPs and the very challenging task of determining the chemical composition of sub-micron organic grains. Laboratory studies of ancient and present-day dust in the Solar System thus reveal in exquisite detail the chemistry, mineralogy and isotopic properties of materials that derive from a range of astrophysical environments. These studies are an important complement to astronomical observations that help to place the laboratory observations into broader context.

Messenger, Scott↗

NASA NTRS1999

An ET Origin for Stratospheric Particles Collected during the 1998 Leonids Meteor Shower

On 17 November 1998, a helium-filled weather balloon was launched into tfle strato- sphere, equipped with a xerogel microparticle collector. The three-hour flight was designed to sample the dust environment in the stratosphere during the Leonid meteor shower, and possibly to capture Leonid meteoroids. Environmental Scanning Election Microscope analyses of the returned collectors revealed the capture of a -30-pm particle. with a smooth, multigranular shape, and partially melted, translucent rims; similar to known Antarctic micrometeorites. Energy-dispersive X-ray Mass Spectroscopy shows en- riched concentrations of the non-volatile elements, Mg, Al, and Fe. The particle possesses a high magnesium to iron ratio of 2.96, similar to that observed in 1998 Leonids meteors (Borovicka, et al. 1999) and sharply higher than the ratio expected for typical material from the earth's crust. A statistical nearest-neighbor analysis of the abundance ratios Mg/Si, Al/Si, and Fe/Si demonstrates that the particle is most similar in composition to cosmic spherules captured during airplane flights throucrh the stratosphere. The mineralogical class is consistent with a stony (S) type of silicates. olivine [(Mg, Fe)2SiO4] and pyroxene [(Mg,Fe)SiO3]-or oxides, herecynite [(Fe,Mg) Al2O4]. Attribution to the debris stream of the Leonids' parent body, comet Tempel-Tuttle, would make it the first such material from beyond the orbit of Uranus positively identified on Earth.

Noever, David A.↗

NASA NTRS1988

The spectral properties of interplanetary dust particles

The observed spectral and mineralogical properties of interplanetary dust particles (IDP) allows the conclusion that: (1) the majority of IDP infrared spectra are dominated by olivine, pyroxene, or layer lattice silicate minerals, (2) to the first order the emission spectra of comets Halley and Kohoutek can be matched by mixtures of these IDP infrared types, implying that comets contain mixtures of these different crystalline silicates and may vary from comet to comet and perhaps even within a single comet, (3) do not expect to observe a single 20 micron feature in cometary spectra, (4) carbonaceous materials dominate the visible spectra properties of the IDPs even though the mass in these particles consists primarily of silicates, and (5) the particle characteristics summarized need to be properly accounted for in future cometary emission models.

Sandford, Scott A.↗

NASA NTRS1988

The spectral properties of collected interplanetary dust particles

Sandford, S. A.↗

NASA NTRS2015

Interstellar and Solar System Organic Matter Preserved in Interplanetary Dust

Interplanetary dust particles (IDPs) collected in the Earth's stratosphere derive from collisions among asteroids and by the disruption and outgassing of short‐period comets. Chondritic porous (CP) IDPs are among the most primitive Solar System materials. CP‐IDPs have been linked to cometary parent bodies by their mineralogy, textures, C‐content, and dynamical histories. CP‐IDPs are fragile, fine‐grained (less than um) assemblages of anhydrous amorphous and crystalline silicates, oxides and sulfides bound together by abundant carbonaceous material. Ancient silicate, oxide, and SiC stardust grains exhibiting highly anomalous isotopic compositions are abundant in CP‐IDPs, constituting 0.01 - 1 % of the mass of the particles. The organic matter in CP‐IDPs is isotopically anomalous, with enrichments in D/H reaching 50x the terrestrial SMOW value and 15N/14N ratios up to 3x terrestrial standard compositions. These anomalies are indicative of low T (10‐100 K) mass fractionation in cold molecular cloud or the outermost reaches of the protosolar disk. The organic matter shows distinct morphologies, including sub‐um globules, bubbly textures, featureless, and with mineral inclusions. Infrared spectroscopy and mass spectrometry studies of organic matter in IDPs reveals diverse species including aliphatic and aromatic compounds. The organic matter with the highest isotopic anomalies appears to be richer in aliphatic compounds. These materials also bear similarities and differences with primitive, isotopically anomalous organic matter in carbonaceous chondrite meteorites. The diversity of the organic chemistry, morphology, and isotopic properties in IDPs and meteorites reflects variable preservation of interstellar/primordial components and Solar System processing. One unifying feature is the presence of sub‐um isotopically anomalous organic globules among all primitive materials, including IDPs, meteorites, and comet Wild‐2 samples returned by the Stardust mission.

Messenger, Scott↗

DOE OSTI2021

Search for meteoritic GEMS II: Comparison of inclusions in amorphous silicates from the Paris chondrite and from anhydrous chondritic interplanetary dust particles

Amorphous silicates containing abundant nano-inclusions have been reported in the Paris CM chondrite (Leroux et al., 2015). They have chemical and morphological similarities to glass with embedded metal and sulfides (GEMS) found in interplanetary dust particles (IDPs) and micrometeorites believed to originate from comets. We used scanning transmission electron microscopy (STEM) with energy-dispersive X-ray spectroscopy (EDS) and nanodiffraction to study the chemistry and mineralogy of these inclusions in order to understand the origin of the GEMS-like material in Paris and its possible relationships to other materials found in primitive chondritic materials including IDP GEMS. EDS and diffraction analyses indicate compositional and mineralogical differences between the nanophase inclusions in cometary GEMS and Paris GEMS-like material. Metal inclusions are notably absent within Paris amorphous silicate. Ni-rich sulfides, including pentlandite, are common in even the least altered matrix material of Paris, while they are absent in GEMS-bearing IDPs and Ultracarbonaceous Antarctic Micrometeorites (UCAMMs). From examination of the inclusions, we cannot yet confirm or refute the possibility that GEMS-like material in Paris is related to cometary GEMS. The distinct compositions and mineralogy of the Paris material may be due to aqueous alteration of cometary GEMS precursors, but they may also denote an independent origin for meteoritic GEMS-like assemblages.

58 GEOSCIENCES↗

NASA NTRS2015

Presolar Materials in a Giant Cluster IDP of Probable Cometary Origin

Chondritic porous interplanetary dust particles (CP-IDPs) have been linked to comets by their fragile structure, primitive mineralogy, dynamics, and abundant interstellar materials. But differences have emerged between 'cometary' CP-IDPs and comet 81P/Wild 2 Stardust Mission samples. Particles resembling Ca-Al-rich inclusions (CAIs), chondrules, and amoeboid olivine aggregates (AOAs) in Wild 2 samples are rare in CP-IDPs. Unlike IDPs, presolar materials are scarce in Wild 2 samples. These differences may be due to selection effects, such as destruction of fine grained (presolar) components during the 6 km/s aerogel impact collection of Wild 2 samples. Large refractory grains observed in Wild 2 samples are also unlikely to be found in most (less than 30 micrometers) IDPs. Presolar materials provide a measure of primitive-ness of meteorites and IDPs. Organic matter in IDPs and chondrites shows H and N isotopic anomalies attributed to low-T interstellar or protosolar disk chemistry, where the largest anomalies occur in the most primitive samples. Presolar silicates are abundant in meteorites with low levels of aqueous alteration (Acfer 094 approximately 200 ppm) and scarce in altered chondrites (e.g. Semarkona approximately 20 ppm). Presolar silicates in minimally altered CP-IDPs range from approximately 400 ppm to 15,000 ppm, possibly reflecting variable levels of destruction in the solar nebula or statistical variations due to small sample sizes. Here we present preliminary isotopic and mineralogical studies of a very large CP-IDP. The goals of this study are to more accurately determine the abundances of presolar components of CP-IDP material for comparison with comet Wild 2 samples and meteorites. The large mass of this IDP presents a unique opportunity to accurately determine the abundance of pre-solar grains in a likely cometary sample.

Messenger, S.↗

NASA NTRS1991

Constraints on the Parent Bodies of Collected Interplanetary Dust Particles

Samples of Interplanetary Dust Particles (IDPs) have now been collected from the stratosphere, from the Earth's ocean beds, and from the ice caps of Greenland and Antarctica. The most likely candidates for the sources of these particles are comets and asteroids. Comparison of the infrared spectra, elemental compositions, and mineralogy of the collected dust with atmospheric entry models and data obtained from cometary probes and telescopic observations has provided important constraints on the possible sources of the various types of collected dust. These constraints lead to the following conclusions. First, most of the deep sea, Greenland, and Antarctic spherules larger than 100 microns are derived from asteroids. Second, the stratospheric IDPs dominated by hydrated layer-lattice silicate minerals are also most likely derived from asteroids. Finally, the stratospheric IDPs dominated by the anhydrous minerals olivine and pyroxene are most likely from comets. The consequences of these parent body assignments are discussed.

Sandford, S. A.↗

NASA NTRS1984

Mineralogical-petrological characterization of near-earth asteroids

The mineralogy and petrology of 17 near-earth asteroids are characterized using reflectance spectroscopy with ground-based telescopes. Assuming the surfaces are composed of cosmically abundant materials, the presence of certain mineralogical species can be determined from diagnostic absorption features and spectral characteristics which have been studied under known laboratory conditions and understood in terms of crystal-field theory. With one possible exception, the surface composition of near-earth asteroids consists of common rock-forming minerals such as olivine, pyroxene, and phyllosilicates. Opaque components are present but cannot be mineralogically identified with existing experimental data. The spectrum of 2201 Oljato cannot be interpreted in terms of common rock-forming minerals and is examined for cometary features because its high orbital eccentricity suggests a possible relation to comets, but no common cometary features are identified. The predominance of mafic silicate absorption features in spectra of near-earth asteroids (compared to the majority of main-belt asteroids) may be a primary compositional feature or may be the signature of relatively fresher asteroid material.

Mcfadden, L. A.↗

NASA NTRS1989

Vega-Giotto flyby missions and cometary cosmogony

The most important implication of the Vega/Giotto flyby missions to Halley's Comet for cometary cosmogony is the opportunity to absorb the results of the in-situ measurements as made onboard the spacecrafts. Unfortunately the exploration of ejecta form the nucleus was unable to provide an unambiguous definition of the chemical-mineralogical nature of the nucleus: it failed to provide information comparable to that which was expected from a sample return mission. However, the obtained results are significant enough to affect and redirect cosmogonical thinking. Accordingly, the understanding of the cometary-matter dichotomy is modified as deduced from the distiction of water-dominated volitiles and silicate-based non-volitiles. Organic carbon compounds emerge as a major constituent of cometary nuclei. Presently, it is likely that the revision of Whipple's classic concept of the icy conglomerate cannot be avoided. Affected by the Vega/Giotto flyby missions to Hally's Comet, cometary cosmogony seems to enter a new conceptual period. The results of the in-situ measurements (mass spectrometric, UV spectroscopic, and IR spectroscopic) appear to be of basic importance. A chemical explanation is employed to explain the occurrence inside the nuclei of the variety of species, as inferred from the mass spectrometric data, to predict the results of the processes possibly involved. A cosmochemical factor is postulated to operate behind the observed cometary phenomena. The chemistry of the interstellar medium, covering the circumstellar and interstellar dust, advances cometary cosmogony.

Lang, Bruno↗

NASA NTRS1987

Cometary evolution: Clues from chondritic interplanetary dust particles

Cometary and interplanetary dust particles (IDP) are compared, and the mineralogical evolution of comet nuclei is discussed. Chondritic IDP have properties consistent with properties expected for cometary dust. The complex and varied mineralogy of these particles may indicate mineral alteration processes that occur in comet nuclei. Depending on the thermal budget of a comet, the upper few meters of nucleus material may maintain temperatures within regimes of hydrocryogenic (200 to 237 K) and low-temperature aqueous (274 to 400 K) alteration. Thus, layer silicates, carbonates, and sulfates may be important components of cometary dust and, correspondingly are common constituents of chondritic IDPs. Alteration of comet starting materials may be a common occurrence, and depends on the specific physical and chemical properties of each individual comet.

Reitmeijer, F. J. M.↗

NASA NTRS1986

Lunar and Planetary Science Conference, 16th, Houston, TX, March 11-15, 1985, Proceedings. Part 2

The present conference presents papers on the criteria, data and implications of pristine lunar glasses, lunar granulities and their precursor anorthositic norites of the early lunar crust, characterization and evidence for early formation in the megaregolith of Apollo 16 regolith breccias, and anorthosite assimilation and the origin of the Mg/Fe-related bimodality of pristine moon rocks in support of the magmasphere hypothesis. Other topics include the mineralogy of Yamato 791073 with reference to crystal fractionation of the howardite parent body, the geology and geomorphology of the Venus surface as revealed by the radar images obtained by Veneras 15 and 16, tidal dissipation in a viscoelastic planet, and cosmogenic neutron-capture-produced nuclides in stony meteorites. Also considered are the first results of hydrous alteration of amorphous silicate smokes, elemental analysis of a comet nucleus by passive gamma ray spectrometry from a penetrator, and uranium series dating of Allan Hills ice.

Ryder, G.↗

NASA NTRS2015

Nebular and Interstellar Materials in a Giant Cluster IDP of Probable Cometary Origin

Comets contain a complex mixture of materials with presolar and Solar System origins. Chondritic porous interplanetary dust particles (CP-IDPs) are associated with comets by their fragile nature, unequilibrated anhydrous mineralogy and high abundances of circumstellar grains and isotopically anomalous organic materials. Comet 81P/Wild 2 samples returned by the Stardust spacecraft contain presolar materials as well as refractory 16O-rich Ca-Al-rich inclusion- (CAI), chondrule-, and AOA-like materials. We are conducting coordinated chemical, mineralogical, and isotopic studies of a giant cluster CP-IDP (U2-20-GCA) to determine the proportions of inner Solar System and interstellar materials. We previously found that this IDP contains abundant presolar silicates (approx. 1,800 ppm) and 15N-rich hotspots [6].

Messenger, S.↗

NASA NTRS1988

Sulfides and oxides in comets

Metal abundances associated with Sun-grazing P/comet Ikeya-Seki 1965f, the mineralogy of chrondritic interplanetary dust particles and cosmochemical affinities of Co, V, Cr, and Ni in extraterrestrial materials and probable vaporization data for nonsilicate minerals are used to evaluate the putative dearth of nonsilicates in short-period comets. It is concluded that sulfides and oxides are common, albeit minor, constituents of these comets. Sulfides and oxides can form in situ during perihelion passage in the nucleus of active short-period comets by sulfidation of Mg, Fe-silicates.

Rietmeijer, Frans J. M.↗

NASA NTRS1989

Electron beam analysis of particulate cometary material

Electron microscopy will be useful for characterization of inorganic dust grains in returned comet nucleus samples. The choice of instrument(s) will depend primarily on the nature of the samples, but ultimately a variety of electron-beam methods could be employed. Scanning and analytical (transmission) electron microscopy are the logical choise for morphological, mineralogical, and bulk chemical analyses of dust grains removed from ices. It may also be possible to examine unmelted ice/dust mixtures using an environmental scanning electron microscope equipped with a cryo-transfer unit and a cold stage. Electron microscopic observations of comet nuclei might include: (1) porosities of dust grains; (2) morphologies and microstructures of individual mineral grains; (3) relative abundances of olivine, pyroxene, and glass; and (4) the presence of phases that might have resulted from aqueous alteration (layer silicates, carbonates, sulfates).

Bradley, John↗