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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 37 records · Page 2

Growth of single-crystal gallium nitride

Use of ultrahigh purity ammonia prevents oxygen contamination of GaN during growth, making it possible to grow the GaN at temperatures as high as 825 degrees C, at which point single crystal wafers are deposited on /0001/-oriented sapphire surfaces.

Clough, R.↗

The satellite ferrimagnetic power limiter

To limit the 4080-mc local oscillator signal power input to the beat oscillator modulator of the Telstar satellite communications repeater, a subsidiary absorption limiter was used which consisted of an optically polished sphere of single-crystal yttrium iron garnet (YIG), placed in a resonant transmission cavity between the amplified 4080-mc output of the traveling-wave tube and the BO modulator input. The limiter holds the output power nearly constant above a given input threshold; below this threshold the YIG is linear and introduces only a small loss. The threshold is determined, for a given sample at a given frequency, by the external magnetic bias field. Temperature compensation over the desired range was obtained by orienting the crystal with the dc magnetic field along a [100] or “hard” axis. The total weight of the limiter package, including the bias magnet and cavity, is 13 ounces.

YTTRIUM-IRON GARNET /YIG/ CRYSTAL↗

Improved method of dicing integrated circuit wafers into chips

Method employing a pressure chamber is used for dicing semiconductor single-crystal wafers, containing integrated circuits, into small chips along pre-scribed lines. Uniform bending of the scribed wafer over the convex surface of a perforated hemisphere, breaks it cleanly into individual chips without damaging the circuits.

Litant, I.↗

Improved reflective coating for integrating spheres

Inorganic salts or oxide material is transparent in single-crystal form, has high refractive index, smooth cleavage, and chemical stability, is stable to radiations of interest, partially soluble and easily dispersed in liquid for spraying, and readily dried /cured/ with reasonable cohesion and adhesion, and has good mechanical stability.

Stuart, J. W.↗

Photoemissive coating

Polystyrene coating is applied to holographic storage tube substrate via glow discharge polymerization in an inert environment. After deposition of styrene coating, antimony and then cesium are added to produce photoemissive layer. Technique is utilized in preparing perfectly organized polymeric films useful as single-crystal membranes.

Gange, R. A.↗

Ordering Effects in NbC and TaC

By means of transmission electron microscopy and electron diffraction, evidence has been obtained for the existence of long range carbon atom ordering in single-crystal niobium carbide that has a carbon-to-metal ratio close to the integral composition Nb6C5. The ordering, which gives rise to superlattice and domain structures similar to those observed in V6C5, appears, however, only in samples that have been cooled slowly through the order-disorder temperature of 1025 C. In TaC of similar composition, the ordering, although present, remains very imperfect even after the crystals are subjected to the same thermal treatment. The results are interpreted in terms of the electronic structure of the transition metal carbides as it is currently understood, and their relevance to the mechanical properties of NbC and TaC are discussed.

Venables, J. D.↗

Thermally restorable optical degradation effects in heat-treated Cu2S-CdS crystal heterojunctions.

We have shown that heat treatment alone does not produce appreciable degradation of the short-circuit current in Cu2S-CdS single-crystal photovoltaic heterojunctions. The degradation, which has been commonly observed, is the result of optically induced effects in the heat-treated cell, subsequent to the heat treatment. These optically induced effects can be correlated with photochemical changes induced in single crystals of CdS:Cd:Cu in which the density of Cu acceptors exceeds the density of excess-Cd donors. Major conclusions about the mechanism of the photovoltaic effect and heat-treatment processes can be drawn.

Kanev, S. K.↗

Inorganic photochromic and cathodochromic recording materials.

Discussion of studies at RCA Laboratories of the properties of rare-earth-doped CaF2, transition-metal-doped SrTiO3 and iron- or sulfur-doped sodalite as photochromic materials which change color during light or electron beam exposures. Particular attention is given to their photochromic characteristics in single-crystal and powder forms and to their cathodochromic properties in powder form. Details are given on the photochromic mechanisms, spectra, optical density, thermal decay rates, and coloring and bleaching efficiency of their single crystals and on the diffuse reflectance spectra, saturated photochromic contrast ratio, switching and erase sensitivities, and cathodochromic excitation of their photochromic powders. The many attractive characteristics of these materials when used in display storage systems are indicated.

Duncan, R. C., Jr.↗

Petrology of basaltic and monomineralic soil fragments from the Sea of Fertility.

Basaltic and monomineralic fragments from the 150-425 micron size fractions of the Luna 16 core obtained from the Sea of Fertility were studied by optical petrographic, electron microprobe, and single-crystal X-ray diffraction techniques. Three textural varieties were identified in the basalts (intersertal, subophitic, and recrystallized). These textures, the assemblages, and individual mineral compositions (especially pyroxenes) indicate that these basalts crystallized under conditions very similar to those from Apollo 11. The pyroxenes have slightly lower Ti/Al (atomic) ratios than the Apollo 11 pyroxenes. We interpret the presence of octahedral Al as being due to the low TiO2/Al2O3 (weight %) ratio in the bulk rock. All observations made on the fine-grained basalt fragments are consistent with a rapid, near-surface, one-stage crystallization history.

Bence, A. E.↗

Apollo 14 inverted pigeonites - Possible samples of lunar plutonic rocks.

Analysis of 'inverted pigeonites' found in Apollo 14 samples 14082 and 14083 (a polymict breccia, the 'white rock') by a combination of optical, electron probe, and single-crystal X-ray diffraction techniques. These 'inverted pigeonites' are regarded as samples of plutonic rocks that have been blasted out of the Imbrium Basin. It is also concluded that lunar pigeonites will invert to orthopyroxenes, given sufficiently slow cooling histories even in very anhydrous environments.

Papike, J. J.↗