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At least 37 records · Page 2

Theoretical description of spectral line profiles of parent molecules in cometary comae

The present overview of cometary spectral-line profiles obtainable through advancements in high-resolution spectroscopic studies, which allow the retrieval of coma kinematic properties from velocity-resolved spectral-line profiles, incorporates the most important gas dynamic processes into an outflow model which is tailored to the interpretation of spectroscopic observations of parent molecules. The model is then used to study the influence on parent-molecule spectral line profile formation of the field-of-view, the expansion velocity, the kinetic temperature, and the anisotropic outflow distributions.

Hu, Hong-Yao↗

Formation of spectral lines in planetary atmospheres. I - Theory for cloudy atmospheres: Application to Venus.

The theory of the formation of spectral lines in a cloudy planetary atmosphere is studied in detail. It is shown that models based upon homogeneous, isotropically scattering atmospheres cannot be used to reproduce observed spectroscopic features of phase effect and the shape of spectral lines for weak and strong bands. The theory must, therefore, be developed using an inhomogeneous (gravitational) model of a planetary atmosphere, accurately incorporating all the physical processes of radiative transfer. Such a model of the lower Venus atmosphere, consistent with our present knowledge, is constructed. The results discussed in this article demonstrate the effects of the parameters that describe the atmospheric model on the spectroscopic features of spectral line profile and phase effect, at visible and near infrared wavelengths. This information enables us to develop a comprehensive theory of line formation in a Venus atmosphere.

Hunt, G. E.↗

Comparison of second-order spectral line widths formulae

Frequently used second-order spectral line width formulae from the projector operator and kinetic theory methods have not been formally compared previously. Here it is shown that a systematic second-order expansion of the projection operator expression including initial correlations agrees with the second-order kinetic theory result. The agreement assumes a common approximation in the projector operator method that introduces a screened radiator–perturber interaction to account for neglected electron–electron correlations. On the other hand, it is shown that the usual width expression from the projection operator approach neglecting initial correlations differs from kinetic theory. The differences, however, are at least third order in the radiator–perturber interaction. The comparisons suggest using the more compact width expression from kinetic theory, which includes initial correlations and a systematic screening of the radiator–perturber interactions, as the starting point for second-order width calculations.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Quantitative laboratory spectra and spectral line parameters for the nu2 and nu4 bands of PH3 applicable to spectral radiative models of the atmosphere of Jupiter

Quantitative laboratory PH3 absorption spectra were obtained in the 800-1350/cm region, at approximately 0.05/cm resolution, with gas amounts corresponding to observed PH3 absorptions in the atmosphere of Jupiter. A compilation of spectral line positions, intensities and ground state energies has been generated for the nu2 and nu4 bands of PH3. Line-by-line calculations have been compared with the experimental spectra.

Goldman, A.↗