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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 37 records · Page 2
All sourcesNASA NTRSDOE OSTI
DOE OSTI2016

Energy production advantage of independent subcell connection for multijunction photovoltaics

Abstract Increasing the number of subcells in a multijunction or “spectrum splitting” photovoltaic improves efficiency under the standard AM 1.5D design spectrum, but it can lower efficiency under spectra that differ from the standard if the subcells are connected electrically in series. Using atmospheric data and the SMARTS multiple scattering and absorption model, we simulated sunny day spectra over 1 year for five locations in the United States and determined the annual energy production of spectrum splitting ensembles with 2–20 subcells connected electrically in series or independently. While electrically independent subcells have a small efficiency advantage over series‐connected ensembles under the AM 1.5D design spectrum, they have a pronounced energy production advantage under realistic spectra over 1 year. Simulated energy production increased with subcell number for the electrically independent ensembles, but it peaked at 8–10 subcells for those connected in series. Electrically independent ensembles with 20 subcells produce up to 27% more energy annually than the series‐connected 20‐subcell ensemble. This energy production advantage persists when clouds are accounted for.

14 SOLAR ENERGY↗
DOE OSTI2017

Design of photovoltaics for modules with 50% efficiency

Abstract We describe a spectrum splitting solar module design approach using ensembles of 2–20 subcells with bandgaps optimized for the AM 1.5D spectrum. Device physics calculations and experimental data determine radiative efficiency parameters for III ‐V compound semiconductor subcells and enable modification of conventional detailed balance calculations to predict module efficiency while retaining computational speed for a wide search of the design space. Accounting for nonideal absorption and recombination rates due to realistic material imperfections allows us to identify the minimum subcell quantity, quality, electrical connection configuration, and concentration required for 50% module efficiency with realistic optical losses and modeled contact resistance losses. We predict a module efficiency of 50% or greater will be possible with 7–10 electrically independent subcells in a spectral splitting optic at 300–500 suns concentration, assuming a 90% optical efficiency and 98% electrical efficiency, provided the subcells can achieve an average external radiative efficiency of 3–5% and a short circuit current that is at least 90% of the ideal. In examining spectrum splitting solar cells with both series‐connected and electrically independent subcells, we identify a new design trade‐off independent of the challenges of fabricating optimal bandgap combinations. Series‐connected ensembles, having a single set of electrical contacts, are less sensitive to lumped series resistance losses than ensembles where each subcells are contacted independently. By contrast, ensembles with electrically independent subcells can achieve lower radiative losses when the subcells are designed for good optical confinement. Distributing electrically independent subcells in a concentrating receiver module allows flexibility in subcell selection and fabrication, and can achieve ultra‐high efficiency with conventional III ‐V cell technology.

Warmann, Emily C.↗
DOE OSTI2014

Colored ultrathin hybrid photovoltaics with high quantum efficiency

Most current solar panels are fabricated via complex processes using expensive semiconductor materials, and they are rigid and heavy with a dull, black appearance. As a result of their non-aesthetic appearance and weight, they are primarily installed on rooftops to minimize their negative impact on building appearance. The large surfaces and interiors of modern buildings are not efficiently utilized for potential electric power generation. Here, we introduce dual-function solar cells based on ultrathin dopant-free amorphous silicon embedded in an optical cavity that not only efficiently extract the photogenerated carriers but also display distinctive colors with the desired angle-insensitive appearances. Light-energy-harvesting colored signage is demonstrated. Furthermore, a cascaded photovoltaics scheme based on tunable spectrum splitting can be employed to increase power efficiency by absorbing a broader band of light energy. Furthermore, this study pioneers a new approach to architecturally compatible and decorative thin-film photovoltaics.

14 SOLAR ENERGY↗
DOE OSTI2018

Transmissive microfluidic active cooling for concentrator photovoltaics

We present the design, fabrication, characterization, and field testing of transmissive active cooling for use in a point-focus spectrum-splitting hybrid concentrator photovoltaics/thermal (CPV/T) system. Seven parallel-path 100 μm thick microchannels are made using polydimethylsiloxane and attached to a CPV module containing a 6 × 6 array of 5.5 mm transmissive CPV cells on a sapphire substrate. Water is flowed through the microchannels to actively cool the CPV cells. The total transmittance of the CPV module reduces by 5.2% with the addition of the active cooling microchannels, relative to the module transmission with no microchannels. The peak cell temperature is measured as 69 °C with a thermal resistance of 9.35 K/W at 157 suns, well below the 110 °C maximum allowed temperature. A maximum flowrate of 16.7 g/s is achieved from a 13 psi pressure drop across the microchannels and manifold assembly. The flow characteristics within each microfluidic channel show maximum fluid velocity of 4.3 m/s (Re = 953) with a calculated convection coefficient of 1.7 × 10 4 W/m 2 K (Nu = 5.36). The CPV/T module and cooling system performance was validated during week-long outdoor tests under varying solar conditions up to 250 suns using a 2.7 m 2 parabolic dish collector mounted to a two-axis tracking system.

14 SOLAR ENERGY↗
DOE OSTI2021

A transmissive concentrator photovoltaic module with cells directly cooled by silicone oil for solar cogeneration systems

Hybrid concentrator photovoltaic-thermal systems can cogenerate electricity and heat by beam-splitting incoming concentrated light onto photovoltaic cells and a thermal receiver to increase total conversion efficiency and potentially reduce system cost. To demonstrate this, we have designed and prototyped a transmissive spectrum-splitting concentrator photovoltaic module that maximizes solar energy conversion by utilizing the entire solar spectrum. Visible light is collected using infrared-transmissive triple-junction photovoltaic cells to achieve an in-band module efficiency of 43.3% for light of wavelength λ < 873 nm, while 44.2% of out-of-band light with λ > 873 nm is transmitted through for collection by a thermal receiver. During testing on a dual-axis tracked parabolic concentrator dish at up to 166 suns, cell temperatures were maintained at 119 °C or below via a novel active cooling method. This cooling system strictly flows silicone oil directly across both sides of the cells, without inhibiting optical transmission, as verified through experimentation and simulation. The module was validated outdoors for 572 sun·hrs, and achieved a maximum thermal receiver temperature of 180 °C. 86.1% of incident solar power is collected at 166 suns average concentration collectively among the electrical, cooling, and thermal receiver subsystems. The remaining 13.9% is lost to mirror reflectivity, dish shadowing, receiver reflection, and thermal losses. The ability to directly cool the cells with an inert silicone oil offers the potential for reduced system cost relative to previous transmissive hybrid concentrator photovoltaic-thermal systems, including microfluidic-cooled designs. This solar cogeneration capability is valuable in a wide range of commercial and industrial applications.

14 SOLAR ENERGY↗
DOE OSTI2024

Transmissive concentrated photovoltaic module with cooling system

A spectrum splitting, transmissive concentrating photovoltaic (tCPV) module is proposed and designed for a hybrid photovoltaic-solar thermal (PV/T) system. The system may be able to fully utilize the full spectrum of incoming sunlight. By utilizing III-V triple junction solar cells with bandgaps of approximately 2.1 eV, 1.7 eV, and 1.4 eV in the module, ultraviolet (UV) and visible light (in-band light) are absorbed and converted to electricity, while infrared (IR) light (out-of-band light) passes through and is captured by a solar thermal receiver and stored as heat. The stored heat energy may be dispatched as electricity or process heat as needed. The tCPV module may have an overall power conversion efficiency exceeding 43.5% for above bandgap (in-band) light under a standard AM1.5D solar spectrum with an average concentration ratio of 400 suns. Passive and/or active cooling methods may be used to keep cells below 110° C. while transmitting >75% of out-of-band light to the thermal receiver, which may attain thermal energy capture at temperatures as high as 500° C. or more. A transparent active cooling system may improve the CPV module efficiency by about 1% (absolute) relative to a passive cooling system by reducing the maximum cell working temperature by about 16° C.

Escarra, Matthew David↗
DOE OSTI2018

Tandem luminescent solar concentrators based on engineered quantum dots

Luminescent solar concentrators (LSCs) can serve as large-area sunlight collectors for terrestrial and space-based photovoltaics. Due to their high emission efficiencies and readily tunable emission and absorption spectra, colloidal quantum dots have emerged as a new and promising type of LSC fluorophore. Spectral tunability of the quantum dots also facilitates the realization of stacked multilayered LSCs, where enhanced performance is obtained through spectral splitting of incident sunlight, as in multijunction photovoltaics. Here, we demonstrate a large-area (>230 cm 2 ) tandem LSC based on two types of nearly reabsorption-free quantum dots spectrally tuned for optimal solar-spectrum splitting. This prototype device exhibits a high optical quantum efficiency of 6.4% for sunlight illumination and solar-to-electrical power conversion efficiency of 3.1%. In conclusion, the efficiency gains due to the tandem architecture over single-layer devices quickly increase with increasing LSC size and can reach more than 100% in structures with window sizes of more than 2,500 cm 2 .

14 SOLAR ENERGY↗
DOE OSTI2015

The unnatural composite Higgs

Composite Higgs models can trivially satisfy precision-electroweak and flavour constraints by simply having a large spontaneous symmetry breaking scale, f ≳ 10 TeV. This produces a ‘split’ spectrum, where the strong sector resonances have masses greater than 10 TeV and are separated from the pseudo Nambu-Goldstone bosons, which remain near the electroweak scale. Even though a tuning of order 10 –4 is required to obtain the observed Higgs boson mass, the big hierarchy problem remains mostly solved. Intriguingly, models with a fully-composite right-handed top quark also exhibit improved gauge coupling unification. By restricting ourselves to models which preserve these features we find that the symmetry breaking scale cannot be arbitrarily raised, leading to an upper bound f ≲ 100-1000 TeV. This implies that the resonances may be accessible at future colliders, or indirectly via rare-decay experiments. Dark matter is identified with a pseudo Nambu-Goldstone boson, and we show that the smallest coset space containing a stable, scalar singlet and an unbroken SU(5) symmetry is SU(7)/SU(6) × U(1). The colour-triplet pseudo Nambu-Goldstone boson also contained in this coset space is metastable due to a residual symmetry. Furthermore, it can decay via a displaced vertex when produced at colliders, leading to a distinctive signal of unnaturalness.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗
DOE OSTI2016

Asymptotic Representation for the Eigenvalues of a Non-selfadjoint Operator Governing the Dynamics of an Energy Harvesting Model

We consider a well known model of a piezoelectric energy harvester. The harvester is designed as a beam with a piezoceramic layer attached to its top face (unimorph configuration). A pair of thin perfectly conductive electrodes is covering the top and the bottom faces of the piezoceramic layer. These electrodes are connected to a resistive load. The model is governed by a system consisting of two equations. The first of them is the equation of the Euler–Bernoulli model for the transverse vibrations of the beam and the second one represents the Kirchhoff’s law for the electric circuit. Both equations are coupled due to the direct and converse piezoelectric effects. The boundary conditions for the beam equations are of clamped-free type. We represent the system as a single operator evolution equation in a Hilbert space. The dynamics generator of this system is a non-selfadjoint operator with compact resolvent. Our main result is an explicit asymptotic formula for the eigenvalues of this generator, i.e., we perform the modal analysis for electrically loaded (not short-circuit) system. We show that the spectrum splits into an infinite sequence of stable eigenvalues that approaches a vertical line in the left half plane and possibly of a finite number of unstable eigenvalues. This paper is the first in a series of three works. In the second one we will prove that the generalized eigenvectors of the dynamics generator form a Riesz basis (and, moreover, a Bari basis) in the energy space. In the third paper we will apply the results of the first two to control problems for this model.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗
DOE OSTI2014

Magnetic interaction in oxygenated alpha Fe-phthalocyanines

Alpha iron phthalocyanines (α-FePc) oxygenated at low temperatures were investigated with the help of {sup 57}Fe Mössbauer spectroscopy, magnetization measurements (SQUID) and X-ray diffractometry (XRD). Mössbauer spectroscopy revealed that upon oxygenation of α-FePc, new species were formed which could be associated with Fe{sup III}Pc oxygen adducts. Unexpectedly, magnetically split spectrum of oxygenated α-FePc was observed below 20 K. In-field Mössbauer spectra in a 5 T external magnetic field at 5K and magnetization measurements indicate antiferromagnetic coupling in oxygenated α-FePc.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
DOE OSTI2016

Transmissive concentrator multijunction solar cells with over 47% in-band power conversion efficiency

Transmissive concentrator multijunction (TCMJ) solar cells with over 47% in-band power conversion efficiency (PCE) have been designed and realized. These TCMJ solar cells have been characterized under 1 sun and concentrated 500 sun solar spectra, showing that the PCE for in-band light (photon energies above the cell’s lowest bandgap) can reach up to 47.6% (29.5% for the full solar spectrum). Temperature coefficients of electrical parameters (V oc , J sc , FF) have been derived from measurements within the temperature range of 20°C to 130°C, showing linear variations versus temperature change. Here, optical measurements demonstrate that the cells show 76.5% solar-weighted optical transmission for the out-of-band light (photon energy below the cell’s lowest bandgap). This TCMJ solar cell exhibits promising spectrum splitting capability, which has potential for use in hybrid photovoltaic-solar thermal applications.

14 SOLAR ENERGY↗