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Results for “splitting methods”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 37 records · Page 2
All sourcesNASA NTRSDOE OSTI
DOE OSTI2022

Methods for making bifunctional porous non-noble metal phosphide catalyst for overall water splitting, electrodes for overall water splitting, and methods for electrocatalytic water splitting

A method of manufacturing a bifunctional electrocatalyst for overall water splitting comprising oxygen evolution reaction (OER) and hydrogen evolution reaction (HER) by growing electrocatalyst comprising primarily metallic phosphides on a three-dimensional substrate by: immersing the substrate in an iron nitrate solution to form a once disposed substrate; subjecting the once disposed substrate to thermal phosphidation with phosphorus powder under inert gas to grow metal phosphides thereupon and form a once subjected substrate; cooling the once subjected substrate to form a cooled, once subjected substrate; immersing the cooled, once subjected substrate in an iron nitrate solution to form a twice disposed substrate; and subjecting the twice disposed substrate to thermal phosphidation with phosphorus powder under inert gas to provide an electrode comprising the bifunctional electrocatalyst on the three-dimensional substrate.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2023

Bifunctional porous non-noble metal phosphide catalyst for overall water splitting and methods of making and using same

A method of electrocatalytic water splitting by providing an anode and a cathode; and utilizing the anode and the cathode for alkaline water electrolysis. Each of the anode and the cathode comprises a uniform distribution of a bifunctional electrocatalyst comprising metallic phosphides on a conductive substrate. The metallic phosphides comprise arion phosphide (FeP) and dinickel phosphide (Ni 2 P). The bifunctional electrocatalyst promotes hydrogen evolution reaction (HER) at the cathode, and oxygen evolution reaction (OER) at the anode.

Ren, Zhifeng↗
NASA NTRS1989

A basic limitation of the split window method for SST retrievals when applied to a wide range of water vapor conditions

The split window method for retrieving sea surface temperatures (SST) from satellite-based observations is evaluated from radiative transfer calculations, and shown to have an inherent limitation that arises from a linear assumption in the correction scheme. This general limitation leads to significant errors (of several degrees in some cases) in the retrieved SST; the theoretical basis for the error is examined.

Hagan, Denise E.↗
DOE OSTI2022

System and method for torque split arbitration

A method for torque split arbitration in a vehicle includes identifying at least one route characteristic of a portion of a route being traversed by the vehicle. The method further includes determining a target torque split based on the at least one route characteristics. The method further includes generating a first output torque demand that corresponds to a product of a first portion of a target torque demand to be provided by a first propulsion unit and a ratio of a total propulsion system torque demand and the target torque demand. The method further includes generating a second output torque demand based on the first output torque demand.

Aggoune, Karim↗
NASA NTRS1982

Conservative supra-characteristics method for splitting the hyperbolic systems of gasdynamics for real and perfect gases

A conservative flux difference splitting is presented for the hyperbolic systems of gasdynamics. The stable robust method is suitable for wide application in a variety of schemes, explicit or implicit, iterative or direct, for marching in either time or space. The splitting is modeled on the local quasi one dimensional characteristics system for multi-dimensional flow similar to Chakravarthy's nonconservative split coefficient matrix method; but, as the result of maintaining global conservation, the method is able to capture sharp shocks correctly. The embedded characteristics formulation is cast in a primitive variable the volumetric internal energy (rather than the pressure) that is effective for treating real as well as perfect gases. Finally the relationship of the splitting to characteristics boundary conditions is discussed and the associated conservative matrix formulation for a computed blown wall boundary condition is developed as an example. The theoretical development employs and extends the notion of Roe of constructing stable upwind difference formulae by sending split simple one sided flux difference pieces to appropriate mesh sites. The developments are also believed to have the potential for aiding in the analysis of both existing and new conservative difference schemes.

Lombard, C. K.↗
DOE OSTI2023

Catalyst for water splitting

Methods for producing a carbon-free, PGM-free support for PGM catalyst. The catalytic material comprises PGM metals disposed on a carbon-free support which is catalytic but free of PGM.

Chong, Lina↗
DOE OSTI2020

The geometric theory of charge conservation in particle-in-cell simulations

In recent years, several gauge-symmetric particle-in-cell (PIC) methods have been developed whose simulations of particles and electromagnetic fields exactly conserve charge. While it is rightly observed that these methods’ gauge symmetry gives rise to their charge conservation, this causal relationship has generally been asserted via ad hoc derivations of the associated conservation laws. In this work, we develop a comprehensive theoretical grounding for charge conservation in gauge-symmetric Lagrangian and Hamiltonian PIC algorithms. For Lagrangian variational PIC methods, we apply Noether’s second theorem to demonstrate that gauge symmetry gives rise to a local charge conservation law as an off-shell identity. For Hamiltonian splitting methods, we show that the momentum map establishes their charge conservation laws. We define a new class of algorithms – gauge-compatible splitting methods – that exactly preserve the momentum map associated with a Hamiltonian system’s gauge symmetry – even after time discretization. This class of algorithms affords splitting schemes a decided advantage over alternative Hamiltonian integrators. We apply this general technique to design a novel, explicit, symplectic, gauge-compatible splitting PIC method, whose momentum map yields an exact local charge conservation law. Finally, our study clarifies the appropriate initial conditions for such schemes and examines their symplectic reduction.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗
NASA NTRS1982

Conservative supra-characteristics method for splitting the hyperbolic systems of gasdynamics with computed boundaries for real and perfect gases

Implicit methods developed by Beam and Warming (1978 and Briley and McDonald (1977) make it possible to overcome the hyperbolic stiffness of the conservative compressible Navier-Stokes equations in the fine wall region computational mesh for high Reynold's number flow. Certain difficulties related to the use of these methods could be overcome by employing an approach reported by Roe (1981). In the present investigation Roe's conceptual framework has been adopted for constructing globally conservative finite difference methods. A globally conservative upwind finite difference method (CSCM) consisting of both implicit interior point and boundary point equations is constructed from a new characteristics based flux difference splitting. It is found that the employed upwind eigenvector split scheme which combines fully coupled implicit interior point and boundary point approximations has the desired properties of robust stability and accuracy.

Lombard, C. K.↗
NASA NTRS1989

The solution of the Navier-Stokes equations using Gauss-Seidel line relaxation

The Navier-Stokes equations in an implicit flux-split difference formulation are solved numerically using a Gauss-Seidel line-relaxation procedure. Particular attention is given to the selection of flux-vector splitting method and flux splitting in boundary layers. Results for sample problems involving (1) turbulent supersonic flow over a cone and (2) the viscous hypersonic flow of a chemically reacting gas in thermal nonequilibrium past a blunted cone are presented in extensive graphs and briefly characterized. The present flux-split procedures are shown to provide accurate shear-layer calculations.

Maccormack, Robert W.↗
DOE OSTI2024

Pressure-stabilized fixed-stress iterative solutions of compositional poromechanics

We consider the numerical behavior of the fixed-stress splitting method for coupled poromechanics as undrained regimes are approached. We explain that pressure stability is related to the splitting error of the scheme, not the fact that the discrete saddle point matrix never appears in the fixed-stress approach. This observation reconciles previous results regarding the pressure stability of the splitting method. Using examples of compositional poromechanics with application to geological CO sequestration, we see that solutions obtained using the fixed-stress scheme with a low order finite element-finite volume discretization which is not inherently inf-sup stable can exhibit the same pressure oscillations obtained with the corresponding fully implicit scheme. Moreover, pressure jump stabilization can effectively remove these spurious oscillations in the fixed-stress setting, while also improving the efficiency of the scheme in terms of the number of iterations required at every time step to reach convergence.

42 ENGINEERING↗