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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 37 records · Page 2

The pinhole interface for IMS/MS

An important supplementary technique for ion mobility spectrometry (IMS) is mass spectrometry (MS). A mass spectrometer coupled to an ion mobility spectrometer (IMS/MS) can provide significant information on the composition of the ions contributing to an ion mobility peak. On the other hand, the interpretation of IMS/MS results requires knowledge of processes which can occur at the pinhole interface. When the ion composition is a mixture of ion clusters, the observed cluster distribution may not be an accurate representation of the ion clusters in the IMS. Depending on the buffer gas, lower clusters can form by equilibrating with reduced concentrations in the continuum regime of the expansion and larger clusters can form by collisional stabilization in the cooled jet stream. Besides water, nitrogen molecules can also add to the ion clusters. Even though nitrogen is non-polar, this addition is made possible by an ion-induced dipole interaction between the ion and molecule.

Spangler, Glenn E.↗

Orbit crowding of molecular gas at a bar-spiral arm transition zone in M83

The southwestern bar-spiral arm transition zone in M83 is been studied in CO, H-alpha, H I, red light, and the radio continuum. A massive molecular gas complex in the heart of the transition zone is composed or two principal components which have the morphology and kinematics expected from orbit crowding, where gas on highly elliptical orbits form the bar region converges with gas on more circular orbits from the spiral arm region. Three mechanisms for the origin of the orbit crowding are investigated, and it is proposed that the crowding is due primarily to density wave streaming motions caused by the bar and spiral arms. The inner CO component is partially coincident with a region of highly polarized radio continuum emission which precedes the H-alpha spiral arm by 15-25 arcsec, indicating that it lies on or just downstream from a shock front. This suggests that the bar gas approaching the transition zone is shocked and explains the ridge of dense gas seen upstream from the spiral arm.

Kenney, Jeffrey D. P.↗

A projection method for particle resampling

Particle discretizations of partial differential equations are advantageous for high-dimensional kinetic models in phase-space due to their better scalability than continuum approaches with respect to dimension. Complex processes collectively referred to as particle noise hamper long time simulations with particle methods. One approach to address this problem is particle mesh adaptivity, or remapping, known as particle resampling and remeshing. Here, this work introduces a resampling method that projects particles to and from a (finite element) function space. The method is simple, using standard sparse linear algebra and finite element techniques, and it preserves all moments up to the order of a polynomial represented exactly by the continuum function space. It is distinguished from most other mesh-based methods in that new particle positions and number are decoupled from the mesh, allowing particle and continuum meshes to be adapted relatively independently. While this work is developed with structured particle and continuum phase-space grids on 1X + 1V Vlasov-Poisson models of Landau damping and two-stream instability, the method is well-suited to unstructured grids. Stable long time dynamics are demonstrated up to time T = 500. Reproducibility artifacts and data are publicly available.

Kinetic methods↗

Algorithm for Computing Particle/Surface Interactions

An algorithm has been devised for predicting the behaviors of sparsely spatially distributed particles impinging on a solid surface in a rarefied atmosphere. Under the stated conditions, prior particle-transport models in which (1) dense distributions of particles are treated as continuum fluids; or (2) sparse distributions of particles are considered to be suspended in and to diffuse through fluid streams are not valid.

Hughes, David W.↗

Pore-Scale Modeling of Electrokinetics in Geomaterials

Pore-scale finite-volume continuum models of electrokinetic processes are used to predict the Debye lengths, velocity, and potential profiles for two-dimensional arrays of circles, ellipses and squares with different orientations. The pore-scale continuum model solves the coupled Navier–Stokes, Poisson, and Nernst–Planck equations to characterize the electro-osmotic pressure and streaming potentials developed on the application of an external voltage and pressure difference, respectively. Here, this model is used to predict the macroscale permeabilities of geomaterials via the widely used Carmen–Kozeny equation and through the electrokinetic coupling coefficients. The permeability results for a two-dimensional X-ray tomography-derived sand microstructure are within the same order of magnitude as the experimentally calculated values. The effect of the particle aspect ratio and orientation on the electrokinetic coupling coefficients and subsequently the electrical and hydraulic tortuosity of the porous media has been determined. These calculations suggest a highly tortuous geomaterial can be efficient for applications like decontamination and desalination.

36 MATERIALS SCIENCE↗

The Northern Middle Lobe of Centaurus A: Circumgalactic Gas in a Starburst Wind

We present deep ultraviolet (GALEX), radio continuum (VLA) and H-alpha (Magellan) images of the circumgalactic medium around Centaurus A (NGC5128). We focus on the Northern Middle Lobe (NML), a region extending more than 50kpc beyond the galaxy and known to host a collection of striking phenomena: emission line filaments, recent star formation, disrupted HI/molecular gas streams, and short-lived X-ray clouds. Far UV emission is tightly correlated with H-alpha emission for more than 50kpc, and loosely associated with a filament of X-ray clouds and with the radio continuum emission. The radio emission in the NML region does not appear to be an extension of the inner radio jet (10kpc) or a typical radio lobe. We speculate that the "weather" seen in the NML region is a short-lived phenomenon, caused by an outflow encountering cool gas deposited by one of the recent merger/encounter events which have characterized the history of NGC5128.

Neff, S. G.↗

Physical, resource supply, and biological controls on nutrient processing along the river continuum

Nutrient impairment has led to damages to US surface and groundwater systems in excess of 100 billion dollars per year. Therefore, there is a strong need to develop methods to predict the transport, uptake, and export of nutrients along fluvial networks. We present results that are based on a data-driven mechanistic understanding of three factors that largely control nutrient uptake and export: 1) interactions between transport-related processes (mass transfer to metabolically active zones), 2) resource supply dynamics (nutrient concentration, stoichiometric constraints, etc.), and 3) biological controls (microbial community structure and function). Our results were generated from column experiments conducted along the Jemez River-Rio Grande continuum, which spans four orders of magnitude in mean annual discharge, more than 2000 m in altitude, and more than 500 km of stream longitude. Two resource supply injections were performed on each of the columns, i.e., a nitrate only addition, followed by a stoichiometrically ‘balanced’ 106Carbon:16Nitrogen:1Phosphorus addition. We quantified NO3-N uptake kinetics while constraining three variables: stream order, sediment type and type of injection (N vs stoichiometrically ‘balanced’ C:N:P). Following the laboratory nutrient uptake experiments, the columns were destructively sampled and the contents were homogenized to collect subsamples for DNA sequencing. Amplicon analysis was carried out as described by the Earth Microbiome Protocol for 16s and ITS sequencing.

54 ENVIRONMENTAL SCIENCES↗

Pulsed Electrolysis Promotes Catalyst Activity in Dilute CO 2 Streams

Industrial CO 2 streams vary widely in composition, from pure to as low as 3%, posing challenges for purification or direct conversion. Electrochemical reduction offers a route for converting dilute CO 2 streams but faces severe mass transport limitations. This study demonstrates that pulsed electrolysis effectively overcomes these limitations, enhancing CO 2 electroreduction across variable feed compositions and current densities, particularly at low CO 2 concentrations and high current densities. At 25% CO 2 and 400 mA cm −2 , pulsing improved selectivity from 25.6 to 78.6%, production rate from 13.7 to 21.0 mol m −2 h −1 , and energy productivity from 0.77 to 2.59 mol kWh −1 . A dynamic, multiphysics continuum model confirms a 64% increase in CO 2 concentration within the catalyst layer during pulsing, resolving the transient chemical microenvironment. These findings establish pulsed electrolysis as a viable strategy for converting dilute industrial CO 2 streams into valuable feedstocks, bypassing costly pre-separation.

Orfali, Dania Muhieddine [New York University (NYU↗

Computational model development and validation of fuel dispersal phenomena

As the US nuclear industry is renewing efforts to extend the rod average burnup limits in existing pressurized water reactors, it becomes imperative to investigate the safety implications associated with high burnup fuel fragmentation and the potential dispersal of fragmented fuel into the reactor coolant system. Additionally, as there is a growing interest in transitioning to new nuclear fuel designs to accommodate higher fuel burnup levels, it becomes essential to conduct studies on fuel behavior during design basis accident scenarios, particularly during a postulated loss-of-coolant accident, in order to ensure the safe operation of light-water reactors. The present study develops a computational model to simulate the complex three-phase flow of the fuel dispersal phenomena that occur following a breach in the cladding, when the stream of solid fuel particles and carrier fission gas stream may interact with the surrounding liquid medium. Furthermore, the proposed framework considers the solid phase as discrete Lagrangian particles while the interpenetrating gas–liquid continuum is modeled using a Eulerian framework. The developed simulation framework is validated with experimental results performed in a separate-effect test facility by comparing predicted particle settlement locations with the experimental observations reported in the literature. Key highlights of this study include the interpretation of the high-pressure boundary conditions and the three-phase flow coupling strategy. Also discussed are the gas–liquid hydrodynamics and the behavior of particles as they are transported through the gas and liquid phases.

22 GENERAL STUDIES OF NUCLEAR REACTORS↗

River sinuosity describes a continuum between randomness and ordered growth

River channels are among the most common landscape features on Earth. An essential characteristic of channels is sinuosity: their tendency to take a circuitous path, which is quantified as along-stream length divided by straight-line length. River sinuosity is interpreted as a characteristic that either forms randomly at channel inception or develops over time as meander bends migrate. Studies tend to assume the latter and thus have used river sinuosity as a proxy for both modern and ancient environmental factors including climate, tectonics, vegetation, and geologic structure. But no quantitative criterion for planform expression has distinguished between random, initial sinuosity and that developed by ordered growth through channel migration. This ambiguity calls into question the utility of river sinuosity for understanding Earth’s history. We propose a quantitative framework to reconcile these competing explanations for river sinuosity. Using a coupled analysis of modeled and natural channels, we show that while a majority of observed sinuosity is consistent with randomness and limited channel migration, rivers with sinuosity ≥1.5 likely formed their geometry through sustained, ordered growth due to channel migration. This criterion frames a null hypothesis for river sinuosity that can be applied to evaluate the significance of environmental interpretations in landscapes shaped by rivers. The quantitative link between sinuosity and channel migration further informs strategies for preservation and restoration of riparian habitat and guides predictions of fluvial deposits in the rock record and in remotely sensed environments from the seafloor to planetary surfaces.

58 GEOSCIENCES↗

The holar wind

String theory in AdS 3 with purely NS-NS fluxes and vanishing RR moduli has a continuum of winding string excitations in radial plane wave states. BTZ black holes can emit such strings, which then flow out toward the AdS 3 boundary as a stream of massive quanta, and form a black hole analogue of the solar wind. The winding string sector thus provides a decay channel for the black hole to evaporate without having either to couple the system to an external reservoir or to match the AdS 3 throat onto an asymptotically flat region. We compute the emission amplitude of this “holar wind” in the semi-classical approximation, and consider the associated version of the black hole information paradox.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗

Development of a Boundary Layer Property Interpolation Tool in Support of Orbiter Return To Flight

A new tool was developed to predict the boundary layer quantities required by several physics-based predictive/analytic methods that assess damaged Orbiter tile. This new tool, the Boundary Layer Property Prediction (BLPROP) tool, supplies boundary layer values used in correlations that determine boundary layer transition onset and surface heating-rate augmentation/attenuation factors inside tile gouges (i.e. cavities). BLPROP interpolates through a database of computed solutions and provides boundary layer and wall data (delta, theta, Re(sub theta)/M(sub e), Re(sub theta)/M(sub e), Re(sub theta), P(sub w), and q(sub w)) based on user input surface location and free stream conditions. Surface locations are limited to the Orbiter s windward surface. Constructed using predictions from an inviscid w/boundary-layer method and benchmark viscous CFD, the computed database covers the hypersonic continuum flight regime based on two reference flight trajectories. First-order one-dimensional Lagrange interpolation accounts for Mach number and angle-of-attack variations, whereas non-dimensional normalization accounts for differences between the reference and input Reynolds number. Employing the same computational methods used to construct the database, solutions at other trajectory points taken from previous STS flights were computed: these results validate the BLPROP algorithm. Percentage differences between interpolated and computed values are presented and are used to establish the level of uncertainty of the new tool.

Greene, Francis A.↗

Flow Visualization of Liquid Hydrogen Line Chilldown Tests

We present experimental measurements of wall and fluid temperature during chill-down tests of a warm cryogenic line with liquid hydrogen. Synchronized video and fluid temperature measurements are used to interpret stream temperature profiles versus time. When cold liquid hydrogen starts to flow into the warm line, a sequence of flow regimes, spanning from all-vapor at the outset to bubbly with continuum liquid at the end can be observed at a location far downstream of the cold inlet. In this paper we propose interpretations to the observed flow regimes and fluid temperature histories for two chilldown methods, viz. trickle (i.e. continuous) flow and pulse flow. Calculations of heat flux from the wall to the fluid versus wall temperature indicate the presence of the transition/nucleate boiling regimes only. The present tests, run at typical Reynolds numbers of approx O(10 (exp 5)), are in sharp contrast to similar tests conducted at lower Reynolds numbers where a well-defined film boiling region is observed.

Line chill down↗

High-resolution forbidden Ne II observations of the ionized filaments in the Galactic center

The forbidden Ne II 12.8 micron emission from the central 10 arcsec of the Galaxy has been observed with 1.5 arcsec resolution. The broad lines previously observed in this region are resolved into separate features associated with the filaments and knots of radio continuum emission present. The radial velocity varies rapidly and continuously with position along the filaments, with gradients of up to 30 km/s. The emission along the 'eastern arm' is mapped. The velocities are consistent with streams of gas orbiting about the center. A simple model of gravitationally dominated orbits fits the data; the masses estimated to lie within the orbits suggest the presence of a central mass of about 2.5 million solar. The implications of this model and possible objections to it are considered.

Serabyn, E.↗

Seasonal changes in the drivers of water physico-chemistry variability of a small freshwater tidal river

Where rivers meet the sea, tides can exert a physical and chemical influence on the lower reaches of a river. How tidal dynamics in these tidal river reaches interact with upstream hydrological drivers such as storm rainfall, which ultimately determines the quantity and composition of material transferred from watersheds to estuaries, is currently unknown. We monitored a small freshwater tidal river in the Pacific Northwest, USA in high resolution over one year to evaluate the relative importance of tides versus upstream hydrological flows (i.e., base flow and precipitation events) on basic physico-chemical parameters (pH, dissolved oxygen, turbidity, specific conductivity, and temperature), and how these interactions relate to the downstream estuary. Tidal variability and diurnal cycles (i.e. solar radiation) dominated water physico-chemical variability in the summer, but the influence of these drivers was overshadowed by storm-driven sharp pulses in river physico-chemistry during the remainder of the year. Within such events, we found incidences of counterclockwise hysteresis of pH, counterclockwise hysteresis of dissolved oxygen, and clockwise hysteresis of turbidity, although systematic trends were not observed across events. The dominance of storm rainfall in the river’s physico-chemistry dynamics, and similar pulses of decreased pH observed in adjacent estuarine waters, suggest that the linkage between tidal streams and the broader system is variable throughout the year. High-frequency monitoring of tidal river biogeochemistry is therefore crucial to enable the assessment of how the relative strength of these drivers may change with future sea level rise and altered precipitation patterns to modulate biogeochemical dynamics across the land-ocean-atmosphere continuum.

aquatic↗

The position and size of radio sources associated with solar electron events

The positions and sizes of the sources of type 3 bursts which are associated with interplanetary electron events ( 45 keV) are observed by the 80-MHz Culgoora radioheliograph. The sizes of the responsible electron streams at 0.6 solar radius in the corona are much smaller than the cones of propagation of the electrons in interplanetary space. Many of the type 3 bursts are shown to be accompanied by a type 5 continuum, and it is argued that the observation of a type 3 to 5 radio burst implies an increased spreading of electrons at heights 0.6 solar radius, consistent with the extent of the propagation cone of the electrons in interplanetary space.

Palmer, I. D.↗

Decameter storm radiation. II

The height, size, directivity, and lifetime of decametric storm sources are investigated. The height of the continuum sources is determined from the rotation rate, and the gradient of electron density for the regions of storm origin is computed by assuming that the radiation originates at the plasma frequency. The mean angular size of the sources is found to be quite large (increasing with decreasing frequency), the storm continuum is strongly directive toward the disk center, and east-west asymmetry is observed at decameter wavelengths. Two distinct classes of type III bursts are observed during storms: 'off-fringe' (displaced in position from the continuum source) and 'on-fringe' (coinciding in position with the continuum). A model of the storm region is proposed in which the 'on-fringe' bursts originate in regions of diverging field lines above closed magnetic loops and the 'off-fringe' bursts are excited by energetic electron streams having access to open field lines at the base of the loops.

Gergely, T. E.↗

IUE observations of the peculiar star RX Puppis

The first set of high-dispersion UV observations of RX Pup are presented. Anomalous line profile structure observed in a number of high-excitation emission lines is discussed in context with a model that includes streams and complex mass motions in the system. Anomalies in high-excitation lines suggest dynamic activity in circumstellar material that probably has the form of rings and/or gas streamers between the cool giant and the hot companion. The continuum in low dispersion is fairly flat around 1200-2000 and rises toward longer wavelengths, and cannot be due to a star earlier than A0 II. Alternatively, it may be from an accretion disk. Photoionizing radiation may be due to the presence of an unseen, hot subdwarf with most probable effective temperature 75,000-90,000 K. Alternatively, it may be due to an accretion disk around a secondary with boundary layer temperature about 100,000 K.

Kafatos, M.↗