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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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NASA NTRS1970

Meteor research program

An overview of research on radio and radar meteors accomplished during the past decade is presented, and the work of the past year is highlighted. Velocity distribution and mass flux data are obtained for meteors in the range 10 to 0.0001 g, the size believed to be the principal hazard to space missions. The physical characteristics of mass, structure and density, luminosity, and ablation are briefly described, and the formulation of a theory for interactions of ionization and excitation during collision of atomic particles is mentioned. Five classes of meteoroids are identified, including the two of iron and stone meteorites. Stream meteors associated with known comets are Classes A or C, and parent comets of Class B streams are not observed. Class A meteoroids are identified with the core of a cometary nucleus, Class C with less dense surface of the nucleus after sublimation of ices, and Class B with less dense cores of smaller cometary nuclei. Atmospheric meteor phenomena associated with winds and gravity waves, density and temperature, atomic oxygen, and meteor rate changes are mentioned.

Southworth, R. B.↗
NASA NTRS1988

Plasma contactors for use with electodynamic tethers for power generation

Plasma contactors are proposed as a means of making good electrical contact between biased surfaces such as found at the ends of an electrodynamic tether and the space environment. The plasma contactor emits a plasma cloud which facilitates the electrical connection. The physics of this plasma cloud is investigated for contactors used as electron collectors. The central question addressed is whether the electrons collected by a plasma contactor come from the far field or by ionization of local neutral gas. This question is important because the system implications are different for the two mechanisms. It is shown that contactor clouds in space will consist of a spherical core possibly containing a shock wave. Outside of the core the cloud will expand anisotropically across the magnetic field leading to a turbulent cigar shape structure along the field. This outer region is itself divided into two regions by the ion response to the electric field. A two-dimensional theory for the outer regions of the cloud is developed. The current voltage characteristic of an Argon plasma contactor cloud is estimated for several ion currents in the range of 1 to 100 Amperes. It is suggested that the major source of collected electrons comes by ionization of neutral gas while collection of electrons from the far field is relatively small.

Hastings, D. E.↗
NASA NTRS1995

Measurements of electric fields in the solar wind: Interpretation difficulties

The traditionally measured electric fields in the solar wind plasma (about 1-10 mV/m) are not the natural, primordial ones but are the result of plasma-vehicle interaction. The theory of this interaction is not complete now and current interpretation of the measurements can fail. The state of fully ionized plasma depends on the entropy of the creating source and on the process in which plasma is involved. The increasing twofold of a moving volume in the solar wind (with energy transfer across its surface which is comparable with its whole internal energy) is a more rapid process than the relaxation for the pressure. The presumptive source of the solar wind creation - the induction electric field of the solar origin - has very low entropy. The state of plasma must be very far from the state of thermodynamic equilibrium. The internal energy of plasma can be contained mainly in plasma waves, resonant plasma oscillations, and electric currents. The primordial microscopic oscillating electric fields could be about 1 V/m. It can be checked by special measurements, not ruining the natural plasma state. The tool should be a dielectrical microelectroscope outside the distortion zone of the spacecraft, having been observed from the latter.

Chertkov, A. D.↗
NASA NTRS1994

Explosions of infalling comets in Jupiter's atmosphere

In view of the expected collision of comet Shoemaker-Levy 9 (1993e) with Jupiter in 1994 July, we calculate basic properties of the initial interaction for a simplified Jovian atmosphere. The comet is expected to impact Jupiter at 60 km/sec and at an angle of 45 deg to the zenith. The shock wave generated by the bolide should be optically thick once it has penetrated to an atmospheric density approximately 10(exp -6) gr/cm(exp 3), and we calculate the post-shock conditions assuming local thermodynamic equilibrium (LTE) for shock velocities v(sub sh) in the range 10 to 60 km/sec and preshock densities rho(sub a) = 10(exp -6) to 10(exp -2) gr/cm(exp 3). Our shock calculations include molecular hydrogen, atomic hydrogen, ionized hydrogen, neutral helium, and singly ionized helium. Even at the highest shock velocity, the gas is only partially ionized and the postshock temperature rises with preshock density in order to maintain the ionization. The value of the effective shock adiabatic index gamma(sub sh) varies from 1.17 (at low v(sub sh) and rho(sub a) to 1.40 (at high v(sub sh) and rho(sub a). The ablation rate is limited by the radiative flux that reaches the bolide surface. We argue that the ablated gas does not efficiently transfer its kinetic energy to the atmosphere, and it ultimately slows in a similar fashion to the comet material. As the bolide initially falls through the atmosphere, the character of the shock emission changes. At rho(sub a) approximately 10(exp -8) gr/cm (exp 3), the gas is optically thin and we expect line emission; in the optical spectrum, Balmer emission is expected from the shocked atmosphere and low-ionization metal lines from ablated cometary material. At rho(sub a) approximately 10(exp -6) gr/m(exp 3), the shocked gas is optically thick and the shock front near the bolide produces a blackbody spectrum. The temperature is favorable for ultraviolet (1000 to 3000 A) emission and the luminosity may be approximately 5 x 10(exp 23) ergs/sec for approximately 0.6 sec for a bolide 1 km in radius. At rho(sub a) approximately 10(exp -4) gr/cm(exp 3), the bolide has passed below the ultraviolet photosphere. The shock front emits considerable ionizing radiation, but it is absorbed in a narrow preshock region. The bolometric correction for the optical luminosity is large and we expect a 3000 to 8000 A luminosity of approximately 3 x 10(exp 23) ergs/sec for approximately 1 sec. The optical emission is strongly peaked in the vicinity of the bolide. The bolide does have a somewhat less luminous, optically thick trail extending greater than or equal to 10 km, but the radiation is characterized by a temperature of 4000 to 5000 K. From the fragmentation model of Chyba, Thomas, & Zahnle (1993), the bolide deposits most of its kinetic energy at rho(sub a) approximately 10(exp -3) gr/cm(exp 3) and this is the effective explosion site. The shock wave from such an explosion can move up about one density scale height. We examine the breakout of the shock front from the Jovian atmosphere and find that the shock acceleration in the decreasing density region is slow, so that the energy flux in the shock front is small. Higher velocities might be generated by shock acceleration along the channel left by the bolide if the shock motion can occur before the channel closes off as a result of radiative cooling. Hot gas created by the explosion ultimately rises due to buoyancy on a timescale of a minute. The luminosity is highest when the bubble first rises into the optically thin part of the atmosphere and may be approximately 1 x 10(exp 25) ergs/sec in the near-infrared. Roughly 1% of the initial bolide energy may be radiated in this way; the rest of the energy is lost to sound waves from the initial explosion and to work done by the bubble on the surrounding atmosphere.

Chevalier, Roger A.↗
NASA NTRS1978

Strange doings on Io

Some unusual properties of Io are discussed, and possible explanations for these are considered. The properties discussed include Io's ability to modify radio waves emitted by Jupiter in the decametric band, the satellite's ionosphere and sodium cloud, its extraordinary brightness, and the presence of ionized sulfur just inside the satellite's orbit. Io's ability to modulate Jovian decametric radio emission is explained on the basis of the hypothesis that the satellite conducts electricity and interacts with Jupiter's magnetic field. Characteristics of the sodium cloud are reviewed, and the probable mechanism responsible for this cloud is outlined. It is concluded that the only plausible explanation for the brightness of Io is the presence of cat's-eye-type reflectors, possibly composed of crystalline deposits, on the satellite's surface.

Goody, R.↗
NASA NTRS2021

A NICER View of the Massive Pulsar PSR J0740+6620 Informed by Radio Timing and XMM-Newton Spectroscopy

We report on Bayesian estimation of the radius, mass, and hot surface regions of the massive millisecond pulsar PSR J0740+6620, conditional on pulse-profile modeling of Neutron Star Interior Composition Explorer X-ray Timing Instrument event data. We condition on informative pulsar mass, distance, and orbital inclination priors derived from the joint North American Nanohertz Observatory for Gravitational Waves and Canadian Hydrogen Intensity Mapping Experiment/Pulsar wideband radio timing measurements of Fonseca et al. We use XMM-Newton European Photon Imaging Camera spectroscopic event data to inform our X-ray likelihood function. The prior support of the pulsar radius is truncated at 16 km to ensure coverage of current dense matter models. We assume conservative priors on instrument calibration uncertainty. We constrain the equatorial radius and mass of PSR J0740+6620 to be-+12.390.981.30km and-+2.0720.0660.067Me respectively, each reported as the posterior credible interval bounded by the 16% and 84% quantiles, conditional on surface hot regions that are non-overlapping spherical caps of fully ionized hydrogen atmosphere with uniform effective temperature; a posteriori, the temperature is=-+TlogK5.99100.060.05([])for each hot region. All software for the X-ray modeling framework is open-source and all data, model, and sample information is publicly available, including analysis notebooks and model modules in the Python language. Our marginal likelihood function of mass and equatorial radius is proportional to the marginal joint posterior density of those parameters(within the prior support)and can thus be computed from the posterior samples.

Millisecond pulsars↗
NASA NTRS1995

Observations of the impact of starbursts on the interstellar medium in dwarf galaxies

Dwarf galaxies play a crucial role in our understanding of the formation and evolution of galaxies, and the concept of supernova-driven mass outflows is a vital ingredient in theories of the structure and evolution of dwarf galaxies. Despite the theoretical importance of these outflows, there is a very limited amount of direct observational evidence for their existence. We have therefore begun a detailed multi-wave-band search for outflows in dwarf (M(sub B) greater than or = -18) galaxies with extensive recent or ongoing centrally concentrated star formation. We report the first results of this search in the present paper. Observations of the ionized gas in dwarf amorphous galaxies with centrally concentrated populations of massive stars provide evidence for the large-scale expansion of their expansion of their ionized interstellar media. Fabry-Perot H alpha images reveal the presence of kiloparsec-scale 'superbubbles' and filaments which tend to be oriented along the galaxy minor axis. These structures are comparable in size to the chracteristic optical sizes of the galaxies, and dominate the morphology of the galaxies at low surface brightness in H alpha. Since expanding structure of this size and velocity are not observed in all low-mass galaxies with recent or ongoing star formation, we suggest that we are witnessing transient events that likely have a relatively low 'duty cycle' in such galaxies. That is, we argue that the particular galaxies in the present paper have had significantly elevated star formation rates over the past 10(exp 7)-10(exp 8) yr (i.e., these are starburst or young poststarburst systems). This interpretation is consistent with the optical colors and emission-line properties of these galaxies.

Marlowe, Amanda T.↗
NASA NTRSDate not supplied

NASA's Moon to Mars Autonomous Habitat Status

NASA is developing a strategy for sending humans to the Mars vicinity, known broadly as the Moon to Mars (M2M) Campaign. A critical part of this campaign is the development of in-space and surface habitation systems capable of substantially extending human presence beyond Low Earth Orbit (LEO). Mars missions feature an in-space transit habitat capable of supporting crews of four on ~850-1200-day missions, including transit to and from Mars and time in Mars orbit. Surface and transit habitats are complex elements which must keep crewmembers healthy and productive in deep-space environments with limited resources, long rescue times in contingency situations, and communication delays; all within constrained mass, volume, and power budgets. These habitats provide crew both living and workspace as well as most of the resources needed to support crew life. For deep space habitats, automation needs to be employed due to latency and for significant amounts of time when the habitats are uncrewed. Automation of systems is possible in space applications, but there are limitations. Outside of the Earth’s (or any) magnetosphere, radiation environments are harsh to both the physical hardware and the software components. Radiation (charged particles and ionizing electromagnetic waves) degrades and damages the hardware and causes single event upsets (SEUs) in software. If the hardware is damaged, data can be lost, or control actions not made. For software, SEUs cause algorithms to result in different solutions, or incorrect commands to be sent out. This means that algorithms and hardware used for deep space systems are different than what is used on Earth. Radiation-tolerant hardware is generations behind the current state-of-the-art hardware. Recent NASA missions, such as James Webb Space Telescope, continue to rely on older technologies such as the RAD750 processor, and the most advanced processors are still single core and less than 1.5 GHz. There have been attempts to use higher performance processors, but these often take multiple mitigation steps to handle the radiation environments, which limits the processing power and/or throughput. Current techniques for radiation mitigation have been redundancies, voting, physical separation of hardware, encasing materials, under-clocking hardware, and more. Some radiation mitigation techniques do provide benefits such as having a redundant system to improve the probability that a system will be available when needed. Autonomous software systems will have fewer interactions with humans on deep space missions and therefore need to be able to handle more off-nominal conditions. Microgravity also complicates the autonomous aspects of the mission because autonomous systems are usually built from known deterministic states, but microgravity causes physical objects to shift and move changing the location an autonomous system placed the object. Not only does the software need to be reliable and deterministic, losing resources due to a software error is not only costly but detrimental to reputation. The combination of having lower performance hardware and having to be able to verify and deterministically run software and an ever-changing environment makes deep space autonomous systems more complicated. Multiple gaps have been identified including verification of autonomous software algorithms (including artificial intelligence and machine learning), higher performance processors (graphics and general purpose), high speed networks (onboard and transmissions), memory, power distribution, data security, and variations from these. These gaps need to be closed for more advanced systems to be deployed and reduce the size, weight, and power impacts on the habitats.

Scott B. Tashakkor↗
NASA NTRSDate not supplied

Center for Isotope Cosmochemistry and Geochronology at NASA Johnson Space Center

Ten years in the making the Center for Isotope Cosmochemistry and Geochronology (CICG) at NASA Johnson Space Center is designed to be a cooperative analytical facility where novel techniques are developed and performed. Our team works collaboratively to operate this integrated lab suite comprising sample preparation, metal-free clean chemistry, and mass spectrometers to measure a wide variety of elements and isotopes in astromaterials. Contamination control is enacted throughout by a positive pressure cascade of HEPA filtered air, weekly surface cleaning and particle counting. Astromaterials processing is performed with application-specific mortar and pestles, heavy liquid separation, a Frantz magnetic separator, as well as hand-picking using optical microscopes in laminar flow boxes. Microsampling is also carried out using a New Wave MicroMill. Elements for isotopic analysis are isolated from acid-digested samples using ion-exchange chromatography. Cross-contamination is minimized with dedicated laminar flow boxes and labware for different purification protocols. Instrumentation includes a ThermoFisher Element XR inductively coupled plasma mass spectrometer (ICP-MS) for quantification of elemental concentrations in dissolved sample solutions. For in situ analysis, a Teledyne Photon Machines Analyte Excite+ laser ablation system is coupled to the Element XR. The ThermoFisher Triton thermal ionization mass spectrometer (TIMS) is used to measure the isotopic composition of elements such as CA, K, Cr, Rb, Sr, Sm, Nd at high precision in processed samples. For a more diverse range of isotopic analyses, CICG houses a Nu Sapphire 1700 multi-collector inductively coupled plasma mass spectrometer (MC-ICP-MS), which is a large geometry instrument with a multi-pole collision cell for interference removal. An Applied Spectra Instruments J200 femto-second laser is planned for install this Fall and will be coupled to the Nu Sapphire 1700. NASA’s Internal Scientist Funding Model (ISFM)supports this facility. Advanced analytical geochemistry techniques are applied to targeted astromaterials to address important problems in planetary sciences, with a longer-term goal of preparing for samples collected and returned by space missions. CICG is open to collaborations on projects that utilize the facility’s unique capabilities and are within its research scope. We are particularly eager to support and share expertise with the next generation of planetary scientists.

Justin I Simon↗
NASA NTRS2002

Interstellar Antifreeze: Ethylene Glycol

Interstellar ethylene glycol (HOCH2CH2,OH) has been detected in emission toward the Galactic center source Sagittarius B2(N-LMH) by means of several millimeter-wave rotational torsional transitions of its lowest energy conformer. The types and kinds of molecules found to date in interstellar clouds suggest a chemistry that favors aldehydes and their corresponding reduced alcohols-e.g., formaldehyde (H2CO)/methanol (CH3OH), acetaldehyde (CH3CHO)/ethanol (CH3CH2OH). Similarly, ethylene glycol is the reduced alcohol of glycolaldehyde (CH2OHCHO), which has also been detected toward Sgr B2(N-LMH). While there is no consensus as to how any such large complex molecules are formed in the interstellar clouds, atomic hydrogen (H) and carbon monoxide (CO) could form formaldehyde on grain surfaces, but such surface chemistry beyond that point is uncertain. However, laboratory experiments have shown that the gas-phase reaction of atomic hydrogen (H) and solid-phase CO at 10-20 K can produce formaldehyde and methanol and that alcohols and other complex molecules can be synthesized from cometary ice analogs when subject to ionizing radiation at 15 K. Thus, the presence of aldehyde/ reduced alcohol pairs in interstellar clouds implies that such molecules are a product of a low-temperature chemistry on grain surfaces or in grain ice mantles. This work suggests that aldehydes and their corresponding reduced alcohols provide unique observational constraints on the formation of complex interstellar molecules.

Hollis, J. M.↗
NASA NTRS2013

Analytic Theory of Titans Schumann Resonance: Constraints on Ionospheric Conductivity and Buried Water Ocean

This study presents an approximate model for the atypical Schumann resonance in Titan's atmosphere that accounts for the observations of electromagnetic waves and the measurements of atmospheric conductivity performed with the Huygens Atmospheric Structure and Permittivity, Wave and Altimetry (HASI-PWA) instrumentation during the descent of the Huygens Probe through Titan's atmosphere in January 2005. After many years of thorough analyses of the collected data, several arguments enable us to claim that the Extremely Low Frequency (ELF) wave observed at around 36 Hz displays all the characteristics of the second harmonic of a Schumann resonance. On Earth, this phenomenon is well known to be triggered by lightning activity. Given the lack of evidence of any thunderstorm activity on Titan, we proposed in early works a model based on an alternative powering mechanism involving the electric current sheets induced in Titan's ionosphere by the Saturn's magnetospheric plasma flow. The present study is a further step in improving the initial model and corroborating our preliminary assessments. We first develop an analytic theory of the guided modes that appear to be the most suitable for sustaining Schumann resonances in Titan's atmosphere. We then introduce the characteristics of the Huygens electric field measurements in the equations, in order to constrain the physical parameters of the resonating cavity. The latter is assumed to be made of different structures distributed between an upper boundary, presumably made of a succession of thin ionized layers of stratospheric aerosols spread up to 150 km and a lower quasi-perfect conductive surface hidden beneath the non-conductive ground. The inner reflecting boundary is proposed to be a buried water-ammonia ocean lying at a likely depth of 55-80 km below a dielectric icy crust. Such estimate is found to comply with models suggesting that the internal heat could be transferred upwards by thermal conduction of the crust, while convective processes cannot be ruled out.

TITAN↗
NASA NTRS2011

Pickup Ion Distributions from Three Dimensional Neutral Exospheres

Pickup ions formed from ionized neutral exospheres in flowing plasmas have phase space distributions that reflect their source's spatial distributions. Phase space distributions of the ions are derived from the Vlasov equation with a delta function source using three.dimensional neutral exospheres. The ExB drift produced by plasma motion picks up the ions while the effects of magnetic field draping, mass loading, wave particle scattering, and Coulomb collisions near a planetary body are ignored. Previously, one.dimensional exospheres were treated, resulting in closed form pickup ion distributions that explicitly depend on the ratio rg/H, where rg is the ion gyroradius and H is the neutral scale height at the exobase. In general, the pickup ion distributions, based on three.dimensional neutral exospheres, cannot be written in closed form, but can be computed numerically. They continue to reflect their source's spatial distributions in an implicit way. These ion distributions and their moments are applied to several bodies, including He(+) and Na(+) at the Moon, H(+2) and CH(+4) at Titan, and H+ at Venus. The best places to use these distributions are upstream of the Moon's surface, the ionopause of Titan, and the bow shock of Venus.

Hartle, R. E.↗
NASA NTRS2012

X-Ray Emission from an Asymmetric Blast Wave and a Massive White Dwarf in the Gamma Ray Emitting Nova V407 CYG

Classical nova events in symbiotic stars, although rare, offer a unique opportunity to probe the interaction between ejecta and a dense environment in stellar explosions. In this work, we use X-ray data obtained with Swift and Suzaku during the recent classical nova outburst in V407 Cyg to explore such an interaction. We find evidence of both equilibrium and non-equilibrium ionization plasmas at the time of peak X-ray brightness, indicating a strong asymmetry in the density of the emitting region. Comparing a simple model to the data, we find that the X-ray evolution is broadly consistent with nova ejecta driving a forward shock into the dense wind of the Mira companion. We detect a highly absorbed soft X-ray component in the spectrum during the first 50 days of the outburst that is consistent with supersoft emission from the nuclear burning white dwarf. The high temperature and short turn off time of this emission component, in addition to the observed breaks in the optical and UV lightcurves, indicate that the white dwarf in the binary is extremely massive. Finally, we explore the connections between the X-ray and GeV-ray evolution, and propose that the gamma ray turn-off is due to the stalling of the forward shock as the ejecta reach the red giant surface.

Nelson, Thomas↗
NASA NTRS2002

Pulse Detonation Rocket MHD Power Experiment

A pulse detonation research engine (MSFC (Marshall Space Flight Center) Model PDRE (Pulse Detonation Rocket Engine) G-2) has been developed for the purpose of examining integrated propulsion and magnetohydrodynamic power generation applications. The engine is based on a rectangular cross-section tube coupled to a converging-diverging nozzle, which is in turn attached to a segmented Faraday channel. As part of the shakedown testing activity, the pressure wave was interrogated along the length of the engine while running on hydrogen/oxygen propellants. Rapid transition to detonation wave propagation was insured through the use of a short Schelkin spiral near the head of the engine. The measured detonation wave velocities were in excess of 2500 m/s in agreement with the theoretical C-J velocity. The engine was first tested in a straight tube configuration without a nozzle, and the time resolved thrust was measured simultaneously with the head-end pressure. Similar measurements were made with the converging-diverging nozzle attached. The time correlation of the thrust and head-end pressure data was found to be excellent. The major purpose of the converging-diverging nozzle was to configure the engine for driving an MHD generator for the direct production of electrical power. Additional tests were therefore necessary in which seed (cesium-hydroxide dissolved in methanol) was directly injected into the engine as a spray. The exhaust plume was then interrogated with a microwave interferometer in an attempt to characterize the plasma conditions, and emission spectroscopy measurements were also acquired. Data reduction efforts indicate that the plasma exhaust is very highly ionized, although there is some uncertainty at this time as to the relative abundance of negative OH ions. The emission spectroscopy data provided some indication of the species in the exhaust as well as a measurement of temperature. A 24-electrode-pair segmented Faraday channel and 0.6 Tesla permanent magnet assembly were then installed on Marshall Space Flight Center's (MSFC's) rectangular channel pulse detonation research engine. Magnetohydrodynamic (MHD) electrical power extraction experiments were carried out for a range of load impedances in which cesium hydroxide seed (dissolved in methanol) was sprayed into the gaseous oxygen/hydrogen propellants. Positive power extraction was obtained, but preliminary analysis of the data indicated that the plasma electrical conductivity is lower than anticipated and the near-electrode voltage drop is not negligible. It is believed that the electrical conductivity is reduced due to a large population of negative OH ions. This occurs because OH has a strong affinity for capturing free electrons. The effect of near-electrode voltage drop is associated with the high surface-to-volume ratio of the channel (1-inch by 1-inch cross-section) where surface effects play a dominant role. As usual for MHD devices, higher performance will require larger scale devices. Overall, the gathered data is extremely valuable from the standpoint of understanding plasma behavior and for developing empirical scaling laws.

Litchford, Ron J.↗
NASA NTRS2018

Relative Sputtering Rates of FeS, MgS, and Mg Silicates: Implications for ISM Gas Phase Depletions of Rock-Forming Elements

Astronomical measurements of S abundances in the diffuse interstellar medium (ISM) indicate ionized S is a dominant species with little (< 5%) S residing in grains (e.g. Jenkins 2009). This is an enigmatic result, given that abundant Fe-sulfide grains are observed in dust around pre- and post-main sequence stars and are also observed as major components of primitive meteoritic and cometary samples. These disparate observations suggest that the lifetime of sulfide grains in the ISM is short because of destruction processes. Our previous work has shown that FeS and MgS retain their crystallinity and do not amorphize during radiation processing, whereas enstatite and forsterite are readily amorphized. We have extended this study to measure the relative sputtering rates of FeS and MgS compared to enstatite and forsterite. Irradiation of FeS with 4 keV He+ results in preferential sputtering of S and the formation of a thin 2-3 nm, compact Fe metal layer that armors the surface. The zone of S loss extends to a depth of ~8-10 nm below the exposed surface. Despite this S loss, the FeS retains its crystallinity and shows no sign of incipient amorphization. Irradiation of FeS with 5kV Ga+ in a focused ion beam (FIB) instrument resulted in preferential sputtering of S and the formation of a 5-8-nm thick surface layer of nanophase Fe metal. X-ray mapping shows that the zone of S sputtering extends to a depth of nearly 20 nm, but there is no evidence for FeS amorphization, consistent with our previous work. The irradiation experiments show that the relative sputtering rate of FeS and MgS are much higher than olivine or enstatite. Sputtering experiments utilizing 30 kV and 5 kV Ga ions in the FIB produced volume loss in troilite that was ~4X greater than in enstatite or forsterite. The sputter yield under these conditions is such that for every Si atom sputtered from enstatite, ~14 S atoms are sputtered from FeS. We have performed similar sputtering experiments on Fe-bearing niningerite (MgS) and co-existing enstatite from the ALH 84170 EH3 chondrite. MgS also sputters much more rapidly than enstatite with a relative Si:S sputter yield of 1:8. For MgS, sulfur is highly depleted at the surface and the S-depletion zone extends to a depth of ~15 nm (using 5 kV Ga+). There is a corresponding zone of Mg and especially Fe enrichment that extends from 5 to ~10 nm below the surface, respectively. The dominant grain destruction mechanism in the ISM is sputtering from passage of supernova-generated shock waves. This process also results in the amorphization of crystalline silicates in the ISM. Our results indicate that FeS and MgS grains produced in evolved stars and injected into the ISM will be destroyed more rapidly than crystalline silicates. This process may account for the lack of significant depletion of S from the gas phase in the ISM. However, rare nanophase FeS grains occur as inclusions in circumstellar amorphous silicate grains found in comet dust particles analyzed in the laboratory. These results show that a finite amount of S in the ISM is sequestered in solid grains.

SPUTTERING RATES↗