Search NASA⌕ Search

SEARCH · Search NASA

Results for “thermodynamic coupling”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 37 records · Page 2
All sourcesNASA NTRSDOE OSTI
NASA NTRS1990

Equilibrium Statistical Thermodynamics of a Many-Particle System Coupled to an External Scalar Field

The equilibrium thermodynamics of a many-particle assembly in the presence of an external scalar field is examined. Two types of scalar coupling are considered: an external field coupled to the particle density and an external scalar field coupled to the energy density. It is shown that the broken translational and rotational invariance of the system due to the external field is reflected in the macroscopic physics by loss of the usual extensivity property of the system and by means of anisotropy in the response of the system to changes in the system lengths or to the system shape. In addition, the assumptions used in local equilibrium analyses are shown to be incorrect in principle. Nonlocal effects due to the external field must be included in the determination of the equation of state. Simple model calculations for a system in an external gravitational field and an externally imposed temperature field are presented as illustrations.

Salvino, R. E.↗
NASA NTRS1989

Climatic equilibrium of the atmospheric convective boundary layer over a tropical ocean

A radiative-convective boundary layer model was developed by coupling a thermodynamic model of a partially mixed convective boundary layer (CBL) with a radiation model, and energy balance constraints were used to study coupled boundary layer (CBL) equilibrium over three timescales (about 1 day, about 10 days, and more than 100 days). It is shown that the variation in cloud top decreases with greater coupling to the atmosphere and the ocean. The slope of the latent heat flux with increasing SST decreases with more tropospheric coupling, and reverses sign with a coupled ocean.

Ridgway, W.↗
NASA NTRS1999

Energetics and kinetics of the prebiotic synthesis of simple organic acids and amino acids with the FeS-H2S/FeS2 redox couple as reductant

The thermodynamics of the FeS-H2S/FeS2 redox couple and a select number of reactions critical to the synthesis of simple carboxylic acids and amino acids have been evaluated as a function of temperature. This thermodynamic evaluation shows that the reducing power of the FeS-H2S/FeS2 redox couple decreases drastically with temperature. By contrast the equilibria describing the reduction of CO2 and the formation of simple carboxylic acids and amino acids require an increasingly higher reducing power with temperature. Given these two opposite trends, the thermodynamic driving force for CO2 reduction and amino acid formation with the FeS-H2S/FeS2 redox couple as reductant diminishes with increasing temperature. An evaluation of the mechanism of CO2 reduction by the FeS-H2S/FeS2 couple suggests that the electron transfer from pyrrhotite to CO2 is hindered by a high activation energy, even though the overall reaction is thermodynamically favorable. By comparison the electron transfer from pyrrhotite to either CS2, CO, or HCOOH are far more facile. This theoretical analysis explains the results of experimental work by Keefe et al. (1995), Heinen and Lauwers (1996) and Huber and Wachtershauser (1997). The implication is that a reaction sequence involving the reduction of CO2 with the FeS-H2S/FeS2 couple as reductant is unlikely to initiate a proposed prebiotic carbon fixation cycle (Wachtershauser, 1988b; 1990b, 1990a, 1992, 1993).

Non-NASA Center↗
NASA NTRS1983

Numerical simulation of the Weddell Sea pack ice

In order to determine the degree to which a coupled dynamic thermodynamic model can reproduce the seasonal cycle of the Antarctic Sea ice in the Weddell Sea, a series of two-year simulations of the Weddell Sea ice pack were carried out. The simulations employed Hibler's (1979) model and used a one-day time step on an 18 x 15 grid with a resolution of 222 km. Daily atmospheric data from 1979 were used to drive the simulations. The simulations yielded a seasonal cycle of ice with maximum and minimum extents close to that observed. Except for portions of the western Weddell, the advance of the ice is found to be primarily thermodynamic in nature, while the rapid decay depends critically on the presence of both leads and lateral ice advection. In early summer the ice motion causes a residual tongue of ice to extend eastward from the Antarctic Peninsula in agreement with observations. Mean ice thicknesses are consistent with observations, as are the mean drift rates of about 5 km/day.

Hibler, W. D., III↗
NASA NTRS1991

Effect of microstructure and composition on the improvement of n-type SiGe/GaP material

Experimental and theoretical work has been conducted at the Jet Propulsion Laboratory to improve the thermoelectric properties of n-type SiGe materials. Particular emphasis has been placed upon the understanding of the differences in dopant solid solubilities when multidoping with both Ga and P instead of P alone, as in standard SiGe alloys. A set of various experimental techniques for obtaining heavily doped hot-pressed samples coupled with thermodynamic theoretical considerations was used to relate microstructure and composition to electrical and thermal transport properties. Application of these results to high-temperature heat treatments of several SiGe/GaP samples achieved substantial improvements of the thermoelectric figure of merit Z, with average values close to 1 x 10-3K-1 over the 600-1000 C temperature range. A set of systematic anneals on heavily doped SiGe/GaP materials is reported in an attempt to consistently reproduce the optimized thermoelectric properties.

Fleurial, Jean-Pierre↗
NASA NTRS2005

Thermodynamic Models for Aqueous Alteration Coupled with Volume and Pressure Changes in Asteroids

All major classes of chondrites show signs of alteration on their parent bodies (asteroids). The prevalence of oxidation and hydration in alteration pathways implies that water was the major reactant. Sublimation and melting of water ice, generation of gases, formation of aqueous solutions, alteration of primary minerals and glasses and formation of secondary solids in interior parts of asteroids was likely to be driven by heat from the radioactive decay of short-lived radionuclides. Progress of alteration reactions should have affected masses and volumes of solids, and aqueous and gas phases. In turn, pressure evolution should have been controlled by changes in volumes and temperatures, escape processes, and production/ consumption of gases.

Mironenko, M. V.↗
NASA NTRS2005

Development of a Stirling System Dynamic Model With Enhanced Thermodynamics

The Stirling Convertor System Dynamic Model developed at NASA Glenn Research Center is a software model developed from first principles that includes the mechanical and mounting dynamics, the thermodynamics, the linear alternator, and the controller of a free-piston Stirling power convertor, along with the end user load. As such it represents the first detailed modeling tool for fully integrated Stirling convertor-based power systems. The thermodynamics of the model were originally a form of the isothermal Stirling cycle. In some situations it may be desirable to improve the accuracy of the Stirling cycle portion of the model. An option under consideration is to enhance the SDM thermodynamics by coupling the model with Gedeon Associates Sage simulation code. The result will be a model that gives a more accurate prediction of the performance and dynamics of the free-piston Stirling convertor. A method of integrating the Sage simulation code with the System Dynamic Model is described. Results of SDM and Sage simulation are compared to test data. Model parameter estimation and model validation are discussed.

Regan, Timothy F.↗
NASA NTRSDate not supplied

Validation of Ullage Collapse Due to Violent Lateral Slosh

Understanding the coupling between thermodynamics and propellant sloshing is important for cryogenic upper stages, especially during the lift-off phase and in missions including multiple engine restarts, as the fluid dynamic condition of the propellant is mainly influenced by various flight maneuvers. This paper describes the development and validation of a Volume of Fluid (VOF)-based CFD solver, Loci/STREAM-VOF, to the ullage collapse under violent later slosh conditions. Loci/STREAM-VOF is shown to be able to capture detailed slosh dynamics, including slosh frequency, non-linear slosh damping, and violent surface breakup due to forced acceleration. The comparison of surface shape and small drops formed during large amplitude slosh with experimental imagery shows excellent agreement throughout the sloshing period. Comparison of temperature histories in the ullage, at the gas-liquid interface, and inside liquid with the experiment conducted at JAXA also show very good agreement. The simulation points to a stratified temperature field inside the liquid near the interface, critical to the ullage pressure after the collapse. The predicted pressure collapse matches well with the experimental value due to sloshing. Parametric sensitivity studies suggest that high-fidelity Loci/STREM-VOF simulations can play an essential role in predicting the actual thermodynamics of ullage collapse when following the recommended simulation methodology.

H Q Yang↗
NASA NTRSDate not supplied

Validation of Ullage Collapse Due to Lateral Violent Slosh

Understanding the coupling between thermodynamics and propellant sloshing is important for cryogenic upper stages, especially during the lift-off phase and in missions including multiple restarts, as the fluid dynamic condition of the propellant is mainly influenced by various flight maneuvers. As a matter of fact, one of the major technical challenges associated with cryogenic fluid management (CFM) is the phenomenon of ullage gas collapse. This collapse is mainly caused by heat transfer from ullage gas to tank walls and interfacing propellants, which are both at temperatures well below those of this gas. The understanding of this phenomenon is of major importance concerning the next generation of cryogenic propellants. This section presents our assessment of a multi-phase CFD code developed at MSFC, Loci/STREAM-VOF, in predicting ullage thermodynamics and collapse due to violent slosh. The experimental data of Himeno et al. will be used for validation.

H. Q Yang↗
NASA NTRS2022

The Future Intensification of the North Atlantic Winter Storm Track: The Key Role of Dynamic Ocean Coupling

Climate models project an intensification of the wintertime North Atlantic storm track, over its downstream region, by the end of this century. Previous studies have suggested that ocean-atmosphere coupling plays a key role in this intensification, but the precise role of the different components of the coupling has not been explored and quantified. In this paper, using a hierarchy of ocean coupling experiments, we isolate and quantify the respective roles of thermodynamic (changes in surface heat fluxes) and dynamic (changes in ocean heat flux convergence) ocean coupling in the projected intensification of North Atlantic transient eddy kinetic energy (TEKE). We show that dynamic coupling accounts for nearly all of the future TEKE strengthening as it overcomes the much smaller effect of surface heat flux changes to weaken the TEKE. We further show that by reducing the Arctic amplification in the North Atlantic, ocean heat flux convergence increases the meridional temperature gradient aloft, causing a larger eddy growth rate, and resulting in the strengthening of North Atlantic TEKE. Our results stress the importance of better monitoring and investigating the changes in ocean heat transport, for improving climate change adaptation strategies.

North Atlantic winter storms↗
NASA NTRS1988

The development of flux-split algorithms for flows with non-equilibrium thermodynamics and chemical reactions

A finite-volume method for the numerical computation of flows with nonequilibrium thermodynamics and chemistry is presented. A thermodynamic model is described which simplifies the coupling between the chemistry and thermodynamics and also results in the retention of the homogeneity property of the Euler equations (including all the species continuity and vibrational energy conservation equations). Flux-splitting procedures are developed for the fully coupled equations involving fluid dynamics, chemical production and thermodynamic relaxation processes. New forms of flux-vector split and flux-difference split algorithms are embodied in a fully coupled, implicit, large-block structure, including all the species conservation and energy production equations. Several numerical examples are presented, including high-temperature shock tube and nozzle flows. The methodology is compared to other existing techniques, including spectral and central-differenced procedures, and favorable comparisons are shown regarding accuracy, shock-capturing and convergence rates.

Grossman, B.↗
NASA NTRS1977

Design of closed-cycle MHD generator with nonequilibrium ionization and system

A method is developed to include the nonequilibrium ionization process in the MHD generator duct design equations, and these equations are coupled to the thermodynamic conditions of the closed cycle system. This is used to relate MHD generator size, configuration and gas conditions to the overall thermodynamic efficiency of the system. The system studied consists of an MHD loop (Ar + Cs or He + Cs) topping a steam bottoming plant.

Voshall, R. E.↗
NASA NTRS1988

A note on chimney formation in ice edge regions

This paper investigates a coupled mesoscale ice-ocean system forced by winds and cooling, leading to the phenomenon of 'chimney' formation (i.e., the formation of a rapid deepening of the mixed layer due to a strong surface heat loss) in ice-edge regions. A numerical model, based on Hakkinen's (1987) coupled dynamic-thermodynamic model of an ice-ocean system, was used that included, in addition to wind stirring, the entrainment parameterization. The results are for the most part similar to the results of Hakkinen, indicating the overwhelming relevance of wind mixing, with penetrative convection having additional effects. The model calculations show that the area affected by ice edge upwelling is most prone to entrainment; the convectively induced entrainment is necessary for the production of a chimney.

Hakkinen, Sirpa↗
NASA NTRS1989

Interactions among radiation, convection, and large-scale dynamics in a general circulation model

The effects of radiatively active clouds on the climate simulated by a GCM are studied, focusing on the effects of upper tropospheric stratiform clouds associated with deep cumulus convection and the interactions of these clouds with convection and the large-scale circulation. The isolated effects of atmospheric cloud radiative forcing are analyzed using a model climate of an ocean-covered earth. It is found that the upper tropospheric cloudiness associated with cumulus convection has a powerful influence on both the convection and the large-scale circulation. Consideration is given to the importance of developing a GCM which includes a direct representation of the radiative, thermodynamical, and dynamical couplings between the convection parameterization and the large-scale saturation parameterization.

Randall, David A.↗
NASA NTRS1996

Surface Turbulent Fluxes Over Pack Ice Inferred from TOVS Observations

A one-dimensional, atmospheric boundary layer model is coupled to a thermodynamic ice model to estimate the surface turbulent fluxes over thick sea ice. The principal forcing parameters in this time-dependent model are the air temperature, humidity, and wind speed at a specified level (either at 2 m or at 850 mb) and the downwelling surface radiative fluxes. The free parameters. are the air temperature, humidity, and wind speed profiles below the specified level, the surface skin temperature, the ice temperature profile, and the surface turbulent fluxes. The goal is to determine how well we can estimate the turbulent surface heat and momentum fluxes using forcing parameters from atmospheric temperatures and radiative fluxes retrieved from the TIROS-N Operational Vertical Sounder (TOVS) data. Meteorological observations from the Lead Experiment (LeadEx, April 1992) ice camp are used to validate turbulent fluxes computed with the surface observations and the results are used to compare with estimates based on radio-sonde observations or with estimates based on TOVS data. We find that the TOVS-based estimates of the stress are significantly more accurate than those found with a constant geostrophic drag coefficient, with a root-mean-square error about half as large. This improvement is due to stratification effects included in the boundary layer model. The errors in the sensible heat flux estimates, however, are large compared to the small mean values observed during the field experiment.

Lindsay, R. W.↗