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At least 37 records · Page 2

Functioning of inorganic/organic battery separators in silver-zinc cells

The results of three experimental studies related to the inorganic/organic battery separator operating mechanism are described: saponification of the plasticizer, resistivity of the simulated separators, and zincate diffusion through the separators. The inorganic/organic separator appears to be a particular example of a general class of ionic conducting films composed of inorganic fillers and/or substrates bonded together by an organic polymer containing an incompatible plasticizer that may be leached by the electrolyte. The I/O separator functions as a microporous film of varying tortuosity with essentially no specific chemical inhibition to zincate diffusion.

Philipp, W. H.↗

Effect of microstructure on Na/+/ diffusion in beta alumina

The effect of microstructural features, such as grain size and orientation, on sodium ion diffusion in polycrystalline beta alumina is investigated; the ionic solid is suitable for use in high-energy and power density batteries. Two types of hot-pressed polycrystalline samples are studied, one with grains highly oriented in the direction normal to the pressing direction, the other with significantly less preferred orientation normal to the pressing direction. Results of the experimental assessments indicate that grain size and diffusion path tortuosity have little effect on diffusion kinetics, while grain boundary type and grain aspect ratio are important factors in determining the diffusion rate.

Sarian, S.↗

Electromagnetic fields radiated from a lightning return stroke - Application of an exact solution to Maxwell's equations

A solution is presented for the electromagnetic fields radiated by an arbitrarily oriented current filament over a conducting ground plane in the case where the current propagates along the filament at the speed of light, and this solution is interpreted in terms of radiation from lightning return strokes. The solution is exact in the fullest sense; no mathematical approximations are made, and the governing differential equations and boundary conditions are satisfied. The solution has the additional attribute of being specified in closed form in terms of elementary functions. This solution is discussed from the point of view of deducing lightning current wave forms from measurements of the electromagnetic fields and understanding the effects of channel tortuosity on the radiated fields. In addition, it is compared with two approximate solutions, the traditional moment approximation and the Fraunhofer approximation, and a set of criteria describing their applicability are presented and interpreted.

D M Le Vine↗

Search for selective ion diffusion through membranes

The diffusion rates of several ions through some membranes developed as battery separators were measured. The ions investigated were Li(+), Rb(+), Cl(-), and So4. The members were crosslinked polyvinyl alcohol, crosslinked polyacrylic acid, a copolymer of the two, crosslinked calcium polyacrylate, cellulose, and several microporous polyphenylene oxide based films. No true specificity for diffusion of any of these ions was found for any of the membranes. But the calcium polyacrylate membrane was found to exhibit ion exchange with the diffusing ions giving rise to the leaching of the calcium ion and low reproducibility. These findings contrast earlier work where the calcium polyacrylate membrane did show specificity to the diffusion of the copper ion. In general, Fick's law appeared to be obeyed. Except for the microporous membranes, the coefficients for ion diffusion through the membranes were comparable with their values in water. For the microporous membranes, the values found for the coefficients were much less, due to the tortuosity of the micropores.

May, C. E.↗

Effect of structure on current and potential distributions in porous electrode

Porous electrodes generally contain constricted macropores and localized micropores. The effects of the macropore constrictions on the resistance of a capillary were studied and an analytical model was developed for predicting the current distribution in a constricted macropore which directly includes constriction effects and does not require an empirical tortuosity parameter. The current and concentration distributions in localized micropores were also investigated and it was shown that the microporous area is fully accessible to charge and mass transfer processes. From these analyses it was concluded that the micropores primarily affect the kinetics of the interfacial processes by contributing to the interfacial area, while the macropores impose ohmic and mass transport limitations through the volume of the porous electrode.

Lanzi, Oscar↗

Frequency response of electrochemical cells

The main objective was to examine the feasibility of using frequency response techniques (1) as a tool in destructive physical analysis of batteries, particularly for estimating electrode structural parameters such as specific area, porosity, and tortuosity and (2) as a non-destructive testing technique for obtaining information such as state of charge and acceptability for space flight. The phenomena that contribute to the frequency response of an electrode include: (1) double layer capacitance; (2) Faradaic reaction resistance; (3) mass transfer of Warburg impedance; and (4) ohmic solution resistance. Nickel cadmium cells were investigated in solutions of KOH. A significant amount of data was acquired. Quantitative data analysis, using the developed software, is planned for the future.

Thomas, Daniel L.↗

A system for mapping sources of VHF and electric field pulses from in-cloud lightning at KSC

The literature concerning VHF radiation and wideband electric fields from in-cloud lightning is reviewed. VHF location systems give impressive radio images of lightning in clouds with high spatial and temporal resolution. Using systems based on long and short baseline time-or-arrival and interferometry, workers have detected VHF sources that move at speeds of 10(exp 5) to 10(exp 8) m/s. The more slowly moving sources appear to be associated with channel formation but the physical basis for the higher speeds is not clear. In contrast, wideband electric fields are directly related to physical parameters such as current and tortuosity. A long baseline system is described to measure simultaneously VHF radiation and wideband electric fields at five stations at Kennedy Space Center. All signals are detected over remote, isolated ground planes with fiber optics for data transmission. The modification of this system to map rapidly varying dE/dt pulses is discussed.

Thomson, Ewen M.↗

Surface reaction and pore diffusion in flow-tube reactors

The interaction of gas diffusion with surface reaction in porous solids is discussed and applied specifically to heterogeneous rate measurements in flow-tube reactors. External diffusion to the outer surface of a reactive solid, internal diffusion within the pores, surface reaction, and laminar flow are considered. A procedure is developed to correct observed surface rate constants for the interaction of these processes. Measured surface areas and bulk densities are used to construct a semiempirical model for porous diffusion in vapor-formed HNO3-H2O ices which are used to simulate polar stratospheric cloud surfaces. The model is tested experimentally by varying the thickness of these ices from about 15 to 120 microns. The results are consistent with the model predictions and show that the HNO3-H2O ices used are highly porous, and the internal surface must be considered in calculating kinetic parameters from observed loss rates. The best fit of the data yields a tortuosity factor of 3.3 +/-1.1 for the ice substrates.

Keyser, Leon F.↗

Influence of the vapor flux on temperature, density, and abundance distributions in a multicomponent, porous, icy body

We calculated the vapor flux of the icy components in the surface layer of a porous, short-period, Jupiter-class comet, in order to investigate the relationship of the observed relative molecular abundances in the coma with those in the nucleus. The model assumes a body containing one major ice component (H20) and up to three minor components of higher volatility (e.g., CO, CO2, CH3OH). The body's porous structure is modeled as a bundle of tubes with a given tortuosity and initially a constant pore diameter. The mass and energy equations for the different volatiles are solved simultaneously under appropiate boundary conditions. Heat is conducted by the matrix and carried by the vapors. The one-dimensional model includes radially inward and outward flowing vapor within the body, complete depletion of less volatile ices in outer layers, and recondensation of vapor in deeper, coller layers. As a result, we obtain the temperature and abundance distribution in the nucleus and the gas flux into the interior and into the coma for each of the volatiles at various positions in the orbit. The ratio of the gas flux of minor volatiles to that of H2) in the coma varies by several orders of magnitude throughout the orbit. Thus, the relative abundances of species observed in the coma are in most cases not the same as those in the nucleus. Results also indicate that it will be impossible to determine the relative abundances of ices more volatile than water from samples taken a few meters below the surface during a comet rendezvous mission. We made calculations for a wide range of different parameters, such as porosity, pore radius, and thermal conductivity of the matrix. To introduce the model we present typical results for a dust-free comet.

Benkhoff, J.↗

Lightweight Ceramics for Aeroacoustic Applications

The use of a HTP (High Temperature Performance) ceramic foam for aeroacoustic applications is investigated. HTP ceramic foam is a composition of silica and alumina fibers developed by LMMS. This foam is a lightweight high-temperature fibrous bulk material with small pore size, ultra high porosity, and good strength. It can be used as a broadband noise absorber at both room and high temperature (up to 1800 F). The investigation included an acoustic assessment as well as material development, and environmental and structural evaluations. The results show that the HTP ceramic foam provides good broadband noise absorbing capability and adequate strength when incorporating the HTP ceramic foam system into a honeycomb sandwich structure. On the other hand, the material is sensitive to Skydrol and requires further improvements. Good progress has been made in the impedance model development. A relationship between HTP foam density, flow resistance, and tortuosity will be established in the near future. Additional effort is needed to investigate the coupling effects between face sheet and HTP foam material.

Kwan, H. W.↗

Geometrical Effects on the Electromagnetic Radiation from Lightning Return Strokes

The Los Alamos National Laboratory (LANL) Sferic Array has recorded electric-field-change waveforms simultaneously at several stations surrounding the ground-strike points of numerous return strokes in cloud-to-ground lightning flashes. Such data are available from the five-station sub-networks in both Florida and New Mexico. With these data it has been possible for the first time to compare the waveforms radiated in different directions by a given stroke. Such comparisons are of interest to assess both the effects of channel geometry on the fine structure of subsequent-stroke radiation fields and the role of branches in the more jagged appearance of first-stroke waveforms. This paper presents multiple-station, time-domain waveforms with a 200 Hz to 500 kHz pass-band from both first and subsequent return strokes at ranges generally between 100 and 200 km. The differences among waveforms of the same stroke received at stations in different directions from the lightning channel are often obvious. These differences are illustrated and interpreted in the context of channel tortuosity and branches.

Willett, John C.↗

Evolution and Transport of Water in the Upper Regolith of Mars

Long standing theoretical predictions [1-3], as well as recent spacecraft observations [4] indicate that large quantities of ice is present in the high latitudes upper decimeters to meters of the Martian regolith. At shallower depths and warmer locations small amounts of H2O, either adsorbed or free, may be present transiently. An understanding of the evolution of water based on theoretical and experimental considerations of the processes operating at the Martian environment is required. In particular, the porosity, diffusivity, and permeability of soils and their effect on water vapor transport under Mars-like conditions have been estimated, but experimental validation of such models is lacking. Goal: Three related mechanisms may affect water transport in the upper Martian regolith. 1) diffusion along a concentration gradient under isobaric conditions, 2) diffusion along a thermal gradient, which may give rise to a concentration gradient as ice sublimes or molecules desorb from the regolith, and 3) hydraulic flow, or mass motion in response to a pressure gradient. Our combined theoretical and experimental investigation seeks to disentangle these mechanisms and determine which process(es) are dominant in the upper regolith over various timescales. A detailed one-dimensional model of the upper regolith is being created which incorporates water adsorption/ desorption, condensation, porosity, diffusivity, and permeability effects. Certain factors such as diffusivity are difficult to determine theoretically due to the wide range of intrinsic grain properties such as particle sizes, shapes, packing densities, and emergent properties such as tortuosity. An experiment is being designed which will allow us to more accurately determine diffusivity, permeability, and water desorption isotherms for regolith simulants.

Hudson, T. L.↗

The narrow pulse approximation and long length scale determination in xenon gas diffusion NMR studies of model porous media

We report a systematic study of xenon gas diffusion NMR in simple model porous media, random packs of mono-sized glass beads, and focus on three specific areas peculiar to gas-phase diffusion. These topics are: (i) diffusion of spins on the order of the pore dimensions during the application of the diffusion encoding gradient pulses in a PGSE experiment (breakdown of the narrow pulse approximation and imperfect background gradient cancellation), (ii) the ability to derive long length scale structural information, and (iii) effects of finite sample size. We find that the time-dependent diffusion coefficient, D(t), of the imbibed xenon gas at short diffusion times in small beads is significantly affected by the gas pressure. In particular, as expected, we find smaller deviations between measured D(t) and theoretical predictions as the gas pressure is increased, resulting from reduced diffusion during the application of the gradient pulse. The deviations are then completely removed when water D(t) is observed in the same samples. The use of gas also allows us to probe D(t) over a wide range of length scales and observe the long time asymptotic limit which is proportional to the inverse tortuosity of the sample, as well as the diffusion distance where this limit takes effect (approximately 1-1.5 bead diameters). The Pade approximation can be used as a reference for expected xenon D(t) data between the short and the long time limits, allowing us to explore deviations from the expected behavior at intermediate times as a result of finite sample size effects. Finally, the application of the Pade interpolation between the long and the short time asymptotic limits yields a fitted length scale (the Pade length), which is found to be approximately 0.13b for all bead packs, where b is the bead diameter. c. 2002 Elsevier Sciences (USA).

NASA Discipline Life Sciences Technologies↗

The Fractal-based Analysis of the Regulation of Vascular Remodeling in the Quail Chorioallantoic Membrane

Critical to the advancement of space exploration is the safety and well being of astronauts while in space. This study focuses on the second highest of NASA-defined risk categories for human space exploration, cardiovascular alterations. Current research of this problem is being tackled by investigating angiogenesis through vascular remodeling. Angiogenesis is the growth and formation of new blood vessels. Angiogenesis is an important part of maintaining normal development and bodily functions. The loss of control of this process, either insufficient or excessive vascular growth, is considered a common denominator in many diseases, such as cancer, diabetes, and coronary artery disease. Objectives are presently being met by observing the effects of various regulators, like thrombospondin 1 (TSP-1) and a novel vessel tortuosity factor (TF), through the use of the chorioallantoic membrane (CAM) of Japanese quail embryos, which enables the direct optical imaging of 2-dimensional vascular branching trees. Research within the CAM is being performed to deduce numerous methods of regulating vessel growth. This project centers on the ability of a novel vessel regulator to affect angiogenesis. For example, it is hypothesized that the TSP-1 will inhibit the growth of CAM vasculature. Fractal/VESGEN-based techniques and PTV analysis are the methodologies used to investigate vascular differentiation. This tactic is used to quantify results and measure the growth patterns and morphology of blood vessels. The regulatory mechanisms posed by this vessel regulator can be deduced by alterations found within the vasculature patterns of quail embryos.

Smith, Genee S.↗

Variations in the Sea Ice Edge and the Marginal Ice Zone on Different Spatial Scales as Observed from Different Satellite Sensor

The Marginal sea Ice Zone (MIZ) and the sea ice edge are the most dynamic areas of the sea ice cover. Knowledge of the sea ice edge location is vital for routing shipping in the polar regions. The ice edge is the location of recurrent plankton blooms, and is the habitat for a number of animals, including several which are under severe ecological threat. Polar lows are known to preferentially form along the sea ice edge because of induced atmospheric baroclinicity, and the ice edge is also the location of both vertical and horizontal ocean currents driven by thermal and salinity gradients. Finally, sea ice is both a driver and indicator of climate change and monitoring the position of the ice edge accurately over long time periods enables assessment of the impact of global and regional warming near the poles. Several sensors are currently in orbit that can monitor the sea ice edge. These sensors, though, have different spatial resolutions, different limitations, and different repeat frequencies. Satellite passive microwave sensors can monitor the ice edge on a daily or even twice-daily basis, albeit with low spatial resolution - 25 km for the Special Sensor Microwave Imager (SSM/I) or 12.5 km for the Advanced Microwave Scanning Radiometer (AMSR-E). Although special methods exist that allow the detection of the sea ice edge at a quarter of that nominal resolution (PSSM). Visible and infrared data from the Advanced Very High Resolution Radiometer (AVHRR) and from the Moderate Resolution Imaging Spectroradiometer (MODIS) provide daily coverage at 1 km and 250 m, respectively, but the surface observations me limited to cloud-free periods. The Landsat 7 Enhanced Thematic Mapper (ETM+) has a resolution of 15 to 30 m but is limited to cloud-free periods as well, and does not provide daily coverage. Imagery from Synthetic Aperture Radar (SAR) instruments has resolutions of tens of meters to 100 m, and can be used to distinguish open water and sea ice on the basis of surface and volume scattering characteristics. The Canadian RADARSAT C-band SAR provides data that cover the Arctic Ocean and the MIZ every 3 days. A change-point detection approach was utilized to obtain an ice edge estimate from the RADARSAT data The Quickscat scatterometer provides ice edge information with a resolution of a few kilometers on a near-daily basis. During portions of March and April of 2003 a series of aircraft flights were conducted over the ice edge in the Bering Sea carrying the Polarimetric Scanning Radiometer (PSR), which provides spectral coverage identical with the AMSR-E instrument at a resolution of 500 meters. In this study we investigated these different data sets and analyzed differences in their definition of the sea ice edge and the marginal ice zone and how these differences as well as their individual limitations affect the monitoring of the ice edge dynamics. We also examined how the nature of the sea ice edge, including its location, compactness and shape, changes over the seasons. Our approach was based on calculation of distances between ice edges derived from the satellite and aircraft data sets listed above as well as spectral coherence methods and shape parameters such as tortuosity, curvature, and fractional dimension.

Markus, Thorsten↗

Triamcinolone Acetonide Selectively Inhibits Angiogenesis in Small Blood Vessels and Decreases Vessel Diameter within the Vascular Tree

The steroid triamcinolone acetonide (TA) is a potent anti-angiogenesis drug used to treat retinal vascular diseases that include diabetic retinopathy, vascular occlusions and choroidal neovascularization. To quantify the effects of TA on branching morphology within the angiogenic microvascular tree of the chorioallantoic membrane (CAM) of quail embryos. Increasing concentrations of TA (0-16 ng/ml) were applied topically on embryonic day 7 (E7) to the chorioallantoic membrane (CAM) of quail embryos cultured in Petri dishes, and incubated for an additional 24 or 48 hours until fixation. Binary (black/white) microscopic images of arterial end points were quantified by VESGEN software (for Generational Analysis of Vessel Branching) to obtain major vascular parameters that include vessel diameter (Dv), fractal dimension (Df), tortuosity (Tv) and densities of vessel area, length, number and branch point (Av, Lv, Nv and Brv). For assessment of specific changes in vascular morphology induced by TA, the VESGEN software automatically segmented the vascular tree into branching generations (G1...G10) according to changes in vessel diameter and branching. Vessel density decreased significantly up to 34% as the function of increasing concentration of TA according to Av, Lv, Brv, Nv and Df. TA selectively inhibited the growth of new, small vessels, because Lv decreased from 13.14plus or minus 0.61 cm/cm2 for controls to 8.012 plus or minus 0.82 cm/cm2 at 16 ng TA/ml in smaller branching generations (G7-G10), and for Nv from 473.83 plus or minus 29.85 cm(-)2 to 302.32 plus or minus 33.09 cm-()2. In contrast, vessel diameter (Dv) decreased throughout the vascular tree (G1-G10).

McKay, Terri L.↗

VESGEN Software for Mapping and Quantification of Vascular Regulators

VESsel GENeration (VESGEN) Analysis is an automated software that maps and quantifies effects of vascular regulators on vascular morphology by analyzing important vessel parameters. Quantification parameters include vessel diameter, length, branch points, density, and fractal dimension. For vascular trees, measurements are reported as dependent functions of vessel branching generation. VESGEN maps and quantifies vascular morphological events according to fractal-based vascular branching generation. It also relies on careful imaging of branching and networked vascular form. It was developed as a plug-in for ImageJ (National Institutes of Health, USA). VESGEN uses image-processing concepts of 8-neighbor pixel connectivity, skeleton, and distance map to analyze 2D, black-and-white (binary) images of vascular trees, networks, and tree-network composites. VESGEN maps typically 5 to 12 (or more) generations of vascular branching, starting from a single parent vessel. These generations are tracked and measured for critical vascular parameters that include vessel diameter, length, density and number, and tortuosity per branching generation. The effects of vascular therapeutics and regulators on vascular morphology and branching tested in human clinical or laboratory animal experimental studies are quantified by comparing vascular parameters with control groups. VESGEN provides a user interface to both guide and allow control over the users vascular analysis process. An option is provided to select a morphological tissue type of vascular trees, network or tree-network composites, which determines the general collections of algorithms, intermediate images, and output images and measurements that will be produced.

Parsons-Wingerter, Patricia A.↗

Development of Polyimide Foam for Aircraft Sidewall Applications

In this paper, the use of polyimide foam as a lining in double panel applications is considered. It is being investigated here as a replacement for aircraft grade glass fiber and has a number of attractive functional attributes, not the least of which is its high fire resistance. The test configuration studied here consisted of two 1mm (0.04 in.) thick, flat aluminum panels separated by 12.7 cm (5.0 in.) with a 7.6 cm (3.0 in.) thick layer of foam centered in that space. Random incidence transmission loss measurements were conducted on this buildup, and conventional poro-elastic models were used to predict the performance of the lining material. Results from two densities of foam are considered. The Biot parameters of the foam were determined by a combination of direct measurement (for density, flow resistivity and Young s modulus) and inverse characterization procedures (for porosity, tortuosity, viscous and thermal characteristic length, Poisson s ratio and loss factor). The inverse characterization procedure involved matching normal incidence standing wave tube measurements of absorption coefficient and transmission loss of the isolated foam with finite element predictions. When the foam parameters determined in this way were used to predict the performance of the complete double panel system, reasonable agreement was obtained between the measured transmission loss and predictions made using a commercial statistical energy analysis code.

Silcox, Richard↗