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Interannual variations of ozone - Interpretation of 4 years of satellite observations of total ozone

Observations show that the monthly zonal mean total ozone between 1978 and 1982 varies by as much as 5 percent with respect to the 4-year average. These variations have been analyzed with the aid of a two-dimensional chemistry transport model. Observed temperatures and meridional stream functions, calculated from data, were used as inputs for the model. Deviations of the model-calculated total ozone from the 4-year mean were compared with the observed variations. It is shown that a substantial part of the observed variability of total ozone is reproduced by the model, despite uncertainties in the heating rates and without any special attempts to obtain consistent eddy diffusion or otherwise to tune the model. Results indicate that the temperature dependence of the ozone gas phase chemistry plays a negligible role in explaining the observed interannual variations in total ozone. A large part of the variability can be explained by the year-to-year differences in the transport circulation. The variability of the diabatic circulation is shown to be largely independent of the ozone fluctuations and to be a consequence of the observed temperature variations.

Schneider, Hans R.↗

A New Method of Deriving Time-Averaged Tropospheric Column Ozone over the Tropics Using Total Ozone Mapping Spectrometer (TOMS) Radiances: Intercomparison and Analysis Using TRACE A Data

Error analysis of archived total 03 from total ozone mapping spectrometer (TOMS) (version 6) presented. Daily total 03 maps for the tropics, from the period October 6-21, 1992, are derived from TOMS radiances following correction for these errors. These daily maps, averaged together, show a wavelike feature, which is observed in all latitude bands, underlying sharp peaks which occur at different longitudes depending on the latitude. The wave pattern is used to derive both time-averaged stratospheric and tropospheric 03 fields. The nature of the wave pattern (stratospheric or tropospheric) cannot be determined with certainty due to missing data (no Pacific sondes, no lower stratospheric Stratospheric Aerosol and Gas Experiment (SAGE) ozone for 18 months after the Mt. Pinatubo eruption) and significant uncertainties in the corroborative satellite record in the lower stratosphere (solar backscattered ultraviolet (SBUV), microwave limb sounder (MLS)). However, the time- averaged tropospheric ozone field, based on the assumption that the wave feature is stratospheric, agrees within 10% with ultraviolet differential absorption laser Transport and Atmospheric Chemistry near the Equator-Atlantic) (TRACE A) 03 measurements from the DC-8 and with ozonesonde measurements over Brazzaville, Congo, Ascension Island, and Natal, Brazil, for the period October 6-21, 1992. The derived background (nonpolluted) Indian Ocean tropospheric ozone amount, 26 Dobson units (DU), agrees with the cleanest African ozonesonde profiles for September-October 1992. The assumption of a totally tropospheric wave (flat stratosphere) gives 38 DU above the western Indian Ocean and 15-40% disagreements with the sondes. Tropospheric column 03 is high from South America to Africa, owing to interaction of dynamics with biomass burning emissions. Comparison with fire distributions from advanced very high resolution radiometer (AVHHR) during October 1992 suggests that tropospheric 03 produced from biomass burning in South America and Africa dominates the 03 budget in the tropical southern hemisphere during the study period.

Kim, J. H.↗

Highlights of TOMS Version 9 Total Ozone Algorithm

The fundamental basis of TOMS total ozone algorithm was developed some 45 years ago by Dave and Mateer. It was designed to estimate total ozone from satellite measurements of the backscattered UV radiances at few discrete wavelengths in the Huggins ozone absorption band (310-340 nm). Over the years, as the need for higher accuracy in measuring total ozone from space has increased, several improvements to the basic algorithms have been made. They include: better correction for the effects of aerosols and clouds, an improved method to account for the variation in shape of ozone profiles with season, latitude, and total ozone, and a multi-wavelength correction for remaining profile shape errors. These improvements have made it possible to retrieve total ozone with just 3 spectral channels of moderate spectral resolution (approx. 1 nm) with accuracy comparable to state-of-the-art spectral fitting algorithms like DOAS that require high spectral resolution measurements at large number of wavelengths. One of the deficiencies of the TOMS algorithm has been that it doesn't provide an error estimate. This is a particular problem in high latitudes when the profile shape errors become significant and vary with latitude, season, total ozone, and instrument viewing geometry. The primary objective of the TOMS V9 algorithm is to account for these effects in estimating the error bars. This is done by a straightforward implementation of the Rodgers optimum estimation method using a priori ozone profiles and their error covariances matrices constructed using Aura MLS and ozonesonde data. The algorithm produces a vertical ozone profile that contains 1-2.5 pieces of information (degrees of freedom of signal) depending upon solar zenith angle (SZA). The profile is integrated to obtain the total column. We provide information that shows the altitude range in which the profile is best determined by the measurements. One can use this information in data assimilation and analysis. A side benefit of this algorithm is that it is considerably simpler than the present algorithm that uses a database of 1512 profiles to retrieve total ozone. These profiles are tedious to construct and modify. Though conceptually similar to the SBUV V8 algorithm that was developed about a decade ago, the SBUV and TOMS V9 algorithms differ in detail. The TOMS algorithm uses 3 wavelengths to retrieve the profile while the SBUV algorithm uses 6-9 wavelengths, so TOMS provides less profile information. However both algorithms have comparable total ozone information and TOMS V9 can be easily adapted to use additional wavelengths from instruments like GOME, OMI and OMPS to provide better profile information at smaller SZAs. The other significant difference between the two algorithms is that while the SBUV algorithm has been optimized for deriving monthly zonal means by making an appropriate choice of the a priori error covariance matrix, the TOMS algorithm has been optimized for tracking short-term variability using month and latitude dependent covariance matrices.

Bhartia, Pawan↗

Highlights from a Decade of OMI-TOMS Total Ozone Observations on EOS Aura

Total ozone measurements from OMI have been instrumental in meeting Aura science objectives. In the last decade, OMI has extended the length of the TOMS total ozone record to over 35 years to monitor stratospheric ozone recovery. OMI-TOMS total ozone measurements have also been combined synergistically with measurements from other Aura instruments and MLS in particular, which provides vertically resolved information that complements the total O3 mapping capability of OMI. With this combined approach, the EOS Aura platform has produced more accurate and detailed measurements of tropospheric ozone. This has led in turn to greater understanding of the sources and transport of tropospheric ozone as well as its radiative forcing effect. The combined use of OMI and MLS data was also vital to the analysis of the severe Arctic ozone depletion event of 2011. The quality of OMI-TOMS total O3 data used in these studies is the result of several factors: a mature and well-validated algorithm, the striking stability of the OMI instrument, and OMI's hyperspectral capabilities used to derive cloud pressures. The latter has changed how we think about the effects of clouds on total ozone retrievals. We will discuss the evolution of the operational V8.5 algorithm and provide an overview and motivation for V9. After reviewing results and developments of the past decade, we finally highlight how ozone observations from EOS Aura are playing an important role in new ozone mapping missions.

Ozone↗

Estimation of errors in the TOMS total ozone measurement during the Antarctica ozone campaign of August/September 1987

The Total Ozone Mapping Spectrometer (TOMS) instrument on the Nimbus-7 satellite provides the primary source of total ozone data for the study of total ozone in the polar regions of the earth. There are two types of instrument related errors: a slowly developing drift in the instrument calibration since the launch of the instrument in October 1978 and an increase in the measurement noise beginning April, 1984. It is estimated that by October 1987, the accumulated error in the TOMS total ozone measurement due to instrument drift is about 6 m-atm-cm. The sign of the error is such that the TOMS is slightly overpredicting the long-term decrease of the Antarctica ozone. The increase in the measurement noise is more difficult to quantify, affecting some measurements by as much as 10 D.U. and others not at all. A detailed analysis of this error and its potential impact on the studies of total ozone from TOMS will be provided. There are three categories of algorithmic errors: (1) error due the unusual shape of the ozone profile in the ozone hole; (2) error caused by very low atmospheric temperatures in the ozone hole affecting the ozone absorption cross-sections at the TOMS wavelengths; and (3) errors resulting from occasionally thick stratospheric clouds that sometimes reach to 20 km in the ozone hole.

Bhartia, P. K.↗

Total ozone during the 88-89 Northern Hemisphere winter

Total ozone values measured by the Total Ozone Mapping Spectrometer during January, February, and March 1989 are analyzed. During this period, polar total ozone values did not reveal clear depletions, although average winter total ozone values indicate that a 2-6 percent ozone reduction has occurred in northern mid to high latitudes over the last 10 years. Rapid total ozone increases were seen during mid-February, resulting from a wave 2 major stratospheric warming. In order to track polar air over the warming period, total ozone trends are further analyzed using Ertel's potential vorticity.

Newman, Paul↗

Tropospheric Ozone Pollution from Space: New Views from the TOMS (Total Ozone Mapping Spectrometer) Instrument

New products from the TOMS (Total Ozone Mapping Spectrometer) >satellite instrument can resolve pollution events in tropical and mid-latitudes, Over the past several years, we have developed tropospheric ozone data sets by two methods. The modified-residual technique [Hudson and Thompson, 1998; Thompson and Hudson, 1999] uses v. 7 TOMS total ozone and is applicable to tropical regimes in which the wave-one pattern in total ozone is observed. The TOMSdirect method [Hudson et at., 2000] represents a new algorithm that uses TOMS radiances to extract tropospheric ozone in regions of constant stratospheric ozone and tropospheric ozone displaying high mixing ratios and variability characteristic of pollution, Absorbing aerosols (dust and smoke; Herman et at., 1997 Hsu et al., 1999), a standard TOMS product, provide transport and/or source marker information to interpret tropospheric ozone. For the Nimbus 7/TOMS observing period (1979-1992), modified-residual TTO (tropical tropospheric ozone) appears as two maps/month at I-degree latitude 2-degree longitude resolution at a homepage and digital data are available (20S to 20N) by ftp at http://metosrv2. umd.edu/~tropo/ 14y_data.d. Preliminary modified-residual TTO data from the operational Earth-Probe/TOMS (1996- present) are posted in near-real-time at the same website. Analyses with the new tropospheric ozone and aerosol data are illustrated by the following (I)Signals in tropical tropospheric ozone column and smoke amount during ENSO (El Nino-Southern Oscillation) events, e.g. 1982-1983 and the intense ENSO induced biomass fires of 1997-1998 over the Indonesian region [Thompson et a[, 2000a, Thompson and Hudson, 1999]. (2) Trends in tropospheric ozone and smoke aerosols in various tropical regions (Atlantic, Pacific, Africa, Brazil). No significant trends were found for ozone from1980-1990 [Thompson and Hudson, 19991 although smoke aerosols increased during the period [Hsu et al.,1999]. (3) Temporal and spatial offsets ("paradoxes") in tropical tropospheric ozone and smoke aerosol in regions of greatest tropical biomass burning [Thompson et at., 1996;2000b]. (4) Trans-boundary pollution tracking. With an air parcel (trajectory) model, smoke aerosol and ozone and dust plumes can be tracked across oceans (e.g., Asia to North America; North America to Europe) and national boundaries, e.g. Indonesia to Singapore and Malaysia during the 1997 ENSO fires.

Thompson, Anne M.↗

TOMS observations of total ozone in the 1986 Antarctic spring

Total ozone measurements by the Total Ozone Mapping Spectrometer (TOMS) aboard the Nimbus 7 satellite show the reappearance in 1986 of the extreme springtime Antarctic ozone minimum during September and October.The minimum total ozone amounts descended to 156 Dobson Units; the minimum October average of 185 DU was 27 DU higher than the corresponding average in 1985 and 5 DU less than the 1984 average. This behavior indicates a pause in the downward trend of recent years.

Krueger, A. J.↗

Estimating Uncertainty in Long Term Total Ozone Records from Multiple Sources

Total ozone measurements derived from the TOMS and SBUV backscattered solar UV instrument series cover the period from late 1978 to the present. As the SBUV series of instruments comes to an end, we look to the 10 years of data from the AURA Ozone Monitoring Instrument (OMI) and two years of data from the Ozone Mapping Profiler Suite (OMPS) on board the Suomi National Polar-orbiting Partnership satellite to continue the record. When combining these records to construct a single long-term data set for analysis we must estimate the uncertainty in the record resulting from potential biases and drifts in the individual measurement records. In this study we present a Monte Carlo analysis used to estimate uncertainties in the Merged Ozone Dataset (MOD), constructed from the Version 8.6 SBUV2 series of instruments. We extend this analysis to incorporate OMI and OMPS total ozone data into the record and investigate the impact of multiple overlapping measurements on the estimated error. We also present an updated column ozone trend analysis and compare the size of statistical error (error from variability not explained by our linear regression model) to that from instrument uncertainty.

TOMS and SBUV↗

An analysis of tropopause pressure and total ozone correlations

A study of the relationship between total ozone and tropopause pressure was carried out using Total Ozone Mapping Spectrometer (TOMS) data and National Meteorological Center (NMC) global analyses. The medium scales generally show correlations greater than 0.6 throughout the middle latitudes of both hemispheres with some regions exceeding 0.8. The areas of highest correlations seem to be associated with the storm track regions of both the Northern and Southern Hemispheres. A detailed spectral analysis is performed for the medium scales on five pairs of time series of area averaged tropopause pressure and total ozone. In middle latitudes, total ozone and tropopause pressure exhibit generally similar distributions in the power spectrum. In the subtropics and tropics the power in ozone drops off more rapidly with increasing frequency than the power in tropopause pressure. Only in the Northern Hemisphere middle latitudes does one find a clear association between increased power in ozone and tropopause pressure and maxima in the coherency spectrum. Results for large scales are more complicated, showing generally positive correlations at middle latitudes.

Schubert, Siegfried D.↗

Periodic analysis of total ozone and its vertical distribution

Both total ozone and vertical distribution ozone data from the period 1957 to 1972 are analyzed. For total ozone, improved monthly zonal means for both hemispheres are computed by weighting individual station monthly means by a factor which compensates for the close grouping of stations in certain regions of latitude bands. Longitudinal variability show maxima in summer in both hemispheres, but, in winter, only in the Northern Hemisphere. The geographical distributions of the long term mean, and the annual, quasibiennial and semiannual waves in total ozone over the Northern Hemisphere are presented. The extratropical amplitude of the annual wave is by far the largest of the three, as much as 120 m atm cm over northern Siberia. There is a tendency for all three waves to have maxima in high latitudes. Monthly means of the vertical distribution of ozone determined from 3 to 8 years of ozonesonde data over North America are presented. Number density is highest in the Arctic near 18 km. The region of maximum number density slopes upward toward 10 N, where the long term mean is 45 x 10 to the 11th power molecules cm/3 near 26 km.

Wilcox, R. W.↗

Dynamical response of the tropical total ozone to sea surface temperature changes

Interannual variations of total ozone in the equatorial region are discussed in terms of the lower-stratospheric dynamical processes associated with sea surface temperature (SST) changes on an El Nino-Southern Oscillation time scale. Tropospheric diabatic heating by the latent heat release in convective systems drives the interannual variations of tropopause height and atmospheric vertical motions. The adiabatic cooling associated with the dynamically forced ascending motion is subject to radiative heating, which further extends the upwelling motion into the stratosphere. SST variations can thus influence total ozone amounts by changing the tropopause height and vertical advection through modulation of tropospheric diabatic heating. Mechanistic relationships that describe total ozone fluctuations through the advection effect and the tropopause effect of SST variations are derived using the equivalent potential temperature. Total ozone fluctuations are estimated using a quantitative formulation of these mechanistic equations together with the observed SST data. These results indicate that the interannual variations of the zonal wave component of equatorial total ozone are governed by the tropopause effect of SST variations. Preliminary investigation suggests that the annual cycle of tropical total ozone is coupled to the tropopause height changes under the influence of the planetary wave-induced lower-stratospheric temperature rather than local SST.

Hasebe, Fumio↗

Recent trends in stratospheric total ozone - Implications of dynamical and El Chichon perturbations

The recently reprocessed Nimbus-7 TOMS total ozone data from 1979 to 1989 are analyzed to assess the global impact of the El Chichon volcanic eruption on stratospheric total ozone. An apparent decrease in total ozone of 5 to 6 percent is present during the winter of 1982-1983 following the eruption of El Chichon. A regression analysis of total ozone with the equatorial zonal wind at 30 mb indicates that response to the quasi-biennial oscillation can explain much of the observed ozone anomaly, and that the total ozone decrease which can be attributed to El Chichon is at most 2 to 4 percent. This study also suggests that the interannual variability caused by the quasi-biennial oscillation and planetary wave activity may introduce apparent seasonal trends in total ozone and temperature in the lower stratosphere, particularly if the length of the data record is not very long. Such trends may affect the assessment of total ozone changes caused by chemical perturbations.

Chandra, S.↗

Nimbus-7 total ozone observations of western North Pacific tropical cyclones

The Nimbus-7 Total Ozone Mapping Spectrometer (TOMS) was used to map the distribution of total ozone around western North Pacific tropical cyclones from 1979 to 1982. The strong correlation between total ozone distribution and tropopause height found in the subtropical and midlatitudes made it possible for TOMS to monitor the propagation of upper-tropospheric waves and the mutual adjustment between these waves and tropical cyclones during their interaction. Changes in these total ozone patterns reflect the 3D upper-tropospheric transport processes that are involved in tropical cyclone intensity and intensity and motion changes. The total ozone distributions indicate that: (1) the mean upper-tropospheric circulations associated with western North Pacific and Atlantic tropical cyclones are similar; (2) more intense tropical cyclones have higher tropopauses around their centers; (3) more intense tropical cyclones have higher tropopauses on the anticyclonic-shear side of their outflow jets, which indicate that the more intense tropical cyclones have stronger outflow channels than less intense systems; (4) tropical cyclones that intensify (do not intensify) are within 10 deg (15 deg) latitude of weak (strong) upper-tropospheric troughs that are moderately rich (very rich) in total ozone; and (5) tropical cyclones turn to the left (right) when they move within approximately 15 deg latitude downstream of an ozone-poor (ozone-rich) upper-tropospheric ridge (trough).

Stout, John↗

Observational evidence and dynamical interpretation of the total ozone variations in the equatorial region

The total ozone amount is sensitive to the general circulation changes in the lower stratosphere due to the photochemically inactive nature of ozone there. In the equatorial region, such circulation changes arise from the quasi-biennial oscillation (QBO) of the stratospheric zonal wind and the El Nino/Southern Oscillation (ENSO). In the first half of this study we present observational results of the long-term variations in the equatorial ozone field using the 11 year Total Ozone Mapping Spectrometer (TOMS) data, by paying special attention to the longitudinal structure. In the latter half we try to understand quantitatively these variations by using a simple mechanistic relationship. We hypothesis that the ozone modulating processes are attributable to two dynamical effects, the advection effect and tropopause effect, owing to the strong vertical stratification of ozone existing just above the tropopause. The advection effect comes from the vertical motion which maintains the temperature structure, compensating for the radiative damping. The tropopause effect is associated with the altitude change of the tropopause. The total ozone variations in the tropics is discussed in terms of these two dynamical processes with the aid of mechanistic equations combined with the wind and sea surface temperature (SST) observations. The interactions between tropical and extratropical latitudes are beyond the scope of this study. Photochemical effects are also neglected. Details of this study are given by Shiotani (1992) and Hasebe (1992).

Shiotani, Masato↗

Global Total Ozone Recovery Trends Attributed to Ozone-Depleting Substance (ODS) Changes Derived From Five Merged Ozone Datasets

We report on updated trends using different merged zonal mean total ozone datasets from satellite and ground-based observations for the period from 1979 to 2020. This work is an update of the trends reported in Weber et al. (2018) using the same datasets up to 2016. Merged datasets used in this study include NASA MOD v8.7 and NOAA Cohesive Data (COH) v8.6, both based on data from the series of Solar Backscatter Ultraviolet (SBUV), SBUV-2, and Ozone Mapping and Profiler Suite (OMPS) satellite instruments (1978–present), as well as the Global Ozone Monitoring Experiment (GOME)-type Total Ozone – Essential Climate Variable (GTO-ECV) and GOME-SCIAMACHY-GOME-2 (GSG) merged datasets (both 1995–present), mainly comprising satellite data from GOME, SCIAMACHY, OMI, GOME-2A, GOME-2B, and TROPOMI. The fifth dataset consists of the annual mean zonal mean data from ground-based measurements collected at the World Ozone and Ultraviolet Radiation Data Centre (WOUDC). Trends were determined by applying a multiple linear regression (MLR) to annual mean zonal mean data. The addition of 4 more years consolidated the fact that total ozone is indeed slowly recovering in both hemispheres as a result of phasing out ozone-depleting substances (ODSs) as mandated by the Montreal Protocol. The near-global (60° S–60° N) ODS-related ozone trend of the median of all datasets after 1995 was 0.4 ± 0.2 (2σ) %/decade, which is roughly a third of the decreasing rate of 1.5 ± 0.6 %/decade from 1978 until 1995. The ratio of decline and increase is nearly identical to that of the EESC (equivalent effective stratospheric chlorine or stratospheric halogen) change rates before and after 1995, confirming the success of the Montreal Protocol. The observed total ozone time series are also in very good agreement with the median of 17 chemistry climate models from CCMI-1 (Chemistry-Climate Model Initiative Phase 1) with current ODS and GHG (greenhouse gas) scenarios (REF-C2 scenario). The positive ODS-related trends in the Northern Hemisphere (NH) after 1995 are only obtained with a sufficient number of terms in the MLR accounting properly for dynamical ozone changes (Brewer–Dobson circulation, Arctic Oscillation (AO), and Antarctic Oscillation (AAO)). A standard MLR (limited to solar, Quasi-Biennial Oscillation (QBO), volcanic, and El Niño–Southern Oscillation (ENSO)) leads to zero trends, showing that the small positive ODS-related trends have been balanced by negative trend contributions from atmospheric dynamics, resulting in nearly constant total ozone levels since 2000.

Total Column Ozone Trends↗

The role of polar stratospheric clouds on total ozone minihole events

Using seven years of data from tha SAM 2 (Stratospheric Aerosol Measurement 2) and TOMS (Total Ozone Mapping Spectrometer) instruments, along with 70 mbar temperatures extracted from an NMC analysis, the effect of the austral spring polar stratospheric clouds (PSC) on the formation of total ozone miniholes is investigated. A total ozone minihole event is designated as the rapid decrease of more than 20 DU of total ozone over a time period of a day and a spatial extent of approximately 1000 by 1000 km. The severe decrease of total ozone during these minihole events could be explained in part by PSC being formed at altitudes of 10 to 24 km and preventing scattered UV radiation from ozone below the cloud from reaching the TOMS instrument. A result of the cloud's opaqueness is that the total ozone retrieval from TOMS data would underestimate the ozone column in the vicinity of the PSC. The approach to investigate the effect of PSC on total ozone was to use SAM 2 aerosol extinction values in conjunction with NMC stratospheric temperatures to determine if PSC are present during total ozone minihole events occurring during August and September, 1979 to 1986. The minihole events during these seven years were divided into two types: type 1, where the minihole region of 24 hour darkness from regions exposed to sunlight, and type 2, where the minihole occurred 5 to 10 degrees north of the terminator. The presence of PSC in a given region was ascertained by a maximum aerosol extinction greater than .006/km occurring with a temperature less than 189 K. It is found that PSC are consistently present with type 2 minihole events. This is contrasted with PSC rarely occurring in the same vicinity of type 2 miniholes. Also observed of that type 1 minihole events have minimum total ozone values which are on the average 3 to 10 DU smaller than type 2 miniholes. It can be concluded that care must be taken when trying to deduce a dynamical explanation of minihole events near the polar terminator and the role of PSC must be accounted for in type 1 minihole formation.

Sabutis, Joseph L.↗

Comparison of recalculated Dobson and TOMS total ozone at Hradec Kralove, Czechoslovakia, 1978-1990

The reevaluated Dobson total ozone data from Hradec Kralove, Czechoslovakia were compared with independent Total Ozone Mapping Spectrophotometer (TOMS) 'version 6' data set. The comparison was performed by means of the parallel daily averages of ground-based and satellite total ozone pairs of the period November 1978 to December 1990. The comparison showed slight differences between both data series. Their average relative difference is 0.48 percent. The similar results have been reached for subsets of direct sun and zenith types of measurements as well. Their relative differences are 0.61 percent and 0.11 percent respectively. These facts indicate not only good mutual relation of both data sources but also reliability and accuracy of the zenith charts of the spectrophotometer No. 74 used at Hradec Kralove. Preliminary assessment of seasonal MU-dependence of the differences between Dobson and TOMS data was made while using total ozones of winter and summer months representing values of MU=2.70-5.20 and MU = 1.12-1.30 respectively. The results did not show systematic underestimation or overestimation of total ozone due to MU-dependence of the instrument at Hradec Kralove in both seasons.

Stanek, Martin↗