Optical absorption in transparent materials during 1.5 MeV electron irradiation
Optical absorption in transparent materials during 1.5 MeV electron irradiation
Gagosz, R. M.↗
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Colorless Polyimide Films for Thermal-Control Coatings
Series of six essentially colorless aromatic polyimide films synthesized and characterized with objective of obtaining maximum optical transparency for applications in space; optical transparency requirement for high-performance polymeric films used in second-surface mirror coatings on thermal-control systems. Films remain more transparent than commercial film after ultraviolet and electron irradiation. Increased transparency and enhanced solubility of optically transparent polyimides makes them viable candidates for use in thermal-control coatings.
St. Clair, Anne K.↗
High-Energy Radiation and Solar Cell Shields
High energy electron radiation effect on optical transmission of transparent materials for solar cell shields
TRANSPARENT MATERIAL↗
Limits on the streaming and escape of electrons in thermal models for solar hard X-ray emission
Upper limits on the number of fast electrons streaming through and escaping from a plasma whose electrons have been heated to approximately 100 billion K and confined by a collisionless ion-acoustic thermal conduction front are determined. It is shown that such a front is fairly transparent to fast electrons with velocities much larger than the thermal velocity because the anisotropic ion-acoustic waves cannot scatter them, making them collisionless on a scale much larger than the thickness of the front. The collisionless analog of the collisional thermoelectric field is derived self-consistently and shown to offer a significant impediment to fast electrons because they must climb over a larger potential barrier than in the collisional case. The only factors limiting the escape of electrons able to surmount this barrier are their rate of production and the requirement that they carry less heat flux than the maximum heat flux allowable. The rate of production is determined for the case of a Maxwellian whose tail is being filled collisionally.
Smith, D. F.↗
Graphene Transparent Conductive Electrodes for Next- Generation Microshutter Arrays
Graphene is a single atomic layer of graphite. It is optically transparent and has high electron mobility, and thus has great potential to make transparent conductive electrodes. This invention contributes towards the development of graphene transparent conductive electrodes for next-generation microshutter arrays. The original design for the electrodes of the next generation of microshutters uses indium-tin-oxide (ITO) as the electrode material. ITO is widely used in NASA flight missions. The optical transparency of ITO is limited, and the material is brittle. Also, ITO has been getting more expensive in recent years. The objective of the invention is to develop a graphene transparent conductive electrode that will replace ITO. An exfoliation procedure was developed to make graphene out of graphite crystals. In addition, large areas of single-layer graphene were produced using low-pressure chemical vapor deposition (LPCVD) with high optical transparency. A special graphene transport procedure was developed for transferring graphene from copper substrates to arbitrary substrates. The concept is to grow large-size graphene sheets using the LPCVD system through chemical reaction, transfer the graphene film to a substrate, dope graphene to reduce the sheet resistance, and pattern the film to the dimension of the electrodes in the microshutter array. Graphene transparent conductive electrodes are expected to have a transparency of 97.7%. This covers the electromagnetic spectrum from UV to IR. In comparison, ITO electrodes currently used in microshutter arrays have 85% transparency in mid-IR, and suffer from dramatic transparency drop at a wavelength of near-IR or shorter. Thus, graphene also has potential application as transparent conductive electrodes for Schottky photodiodes in the UV region.
Li, Mary↗
Polyimides from a methylene-bridged dianhydride
High-molecular weight, high-temperature, highly optically transparent films suitable for electronic and aerospace applications were prepared based on a novel methylene-bridged dianhydride 3,3-prime bis(3,4-dicarboxyphenoxy) diphenylmethane dianhydride (PDMDA). All films had lower dielectric constants and significantly higher optical transparency than the commercial Kapton H film, with air-cured films having slightly higher dielectric constants and lower optical transparency than vacuum films, due to oxidative cross-linking.
Boston, Harold G.↗
Polyimides Made From 3,5-Diaminobenzotrifluoride
Polyimides synthesized from 3,5-diaminobenzotrifluoride (DABTF). One monomer of major importance in preparing these high-temperature polymers is 1,3-phenylenediamine (mPDA). Fluorinated polyimides exhibit characteristics potentially attractive for aerospace and electronic applications. Includes optical transparency, solubility in common polar solvents, enhanced thermo-oxidative stability, low dielectric constants, and high glass-transition temperatures. Polyimides also used to form free-standing films, coatings, and moldings.
St. Clair, Terry L.↗
Multi-junction Thin-film Solar Cells on Flexible Substrates for Space Power
The ultimate objective of the thin-film program at NASA GRC is development of a 20 percent AM0 thin-film device technology with high power/weight ratio. Several approaches are outlined to improve overall device efficiency and power/weight ratio. One approach involves the use of very lightweight flexible substrates such as polyimides (i.e., Kapton(Trademark)) or metal foil. Also, a compound semiconductor tandem device structure that can meet this objective is proposed and simulated using Analysis of Microelectronic and Photonic Structures (AMPS). AMPS modeling of current devices in tandem format indicate that AM0 efficiencies near 20 percent can be achieved. And with improvements in materials, efficiencies approaching 25 percent are achievable. Several important technical issues need to be resolved to realize these complex devices: development of a wide bandgap material with good electronic properties, development of transparent contacts, and targeting a 2-terminal device structure (with more complicated processing and tunnel junction) or 4-terminal device. Recent progress in the NASA GRC program is outlined.
Hepp, Aloysius F.↗
Measurements of the UV and VUV transmission of optical materials during high energy electron irradiation
An experimental program was conducted in which the optical transmission of several transparent materials was measured during high energy electron irradiation. These experiments were conducted using the Dynamitron electron accelerator as a continuous source of 1.5 MeV electrons and the LINAC electron accelerator as a pulsed source of 5-7 MeV electrons. The experimental program consisted of three major portions. The first portion, the optical transmission of fused silica, BeO, MgF2, and LiF was measured at vacuum ultraviolet wavelengths in the range 1550-2000 A during ambient temperature, 1.5 MeV electron irradiation at ionizing dose rates to 0.5 Mrad/sec. In the second portion of the program, the optical transmission of fused silica and BeO was measured in the range 2000-3000 A during high dose rate, elevated temperature 1.5 MeV electron irradiation. In particular, accurate measurements of the optical transmission were made at ionizing dose rates as high as 10 Mrad/sec. In the final portion of the program, the optical transmission of fused silica and BeO was measured in the wavelength range 2000-3000 A during pulsed 5 and 7 MeV electron irradiation from the LINAC accelerator. The maximum time averaged ionizing dose rate was limited to 0.75 Mrad/sec due to accelerator limitations.
Palma, G. E.↗
The Influence of Surface Coatings on Exo-Electron Emission During Fatigue
A survey of exo-electron emission literature has shown that the mechanism of exo-emission phenomena has yet to be ascertained. Also, there is probably no unique mechanism that will apply to all the exo-emission observations reported. For exo-emission to occur, trapping centers must first be formed to store electrons. Once such centers are formed, they can be made to give up their trapped electrons by the stimulation of light or oxygen. Future investigations will employ light-transparent films for collecting exo-electrons. Also, a carefully controlled experiment is necessary to detect the emission of exo-electrons from the surface of fatiguing metals. Investigations will include high-vacuum fatigue tests, autoradiography, and solid state collector experiments, and will provide a basis for future research on semiconductor layer collection.
COATING↗
Analysis of the ionosphere-plasmasphere transport of superthermal electrons. I - Transport in the plasmasphere
Analytical solutions are developed for the kinetic equation which describes the transport of superthermal electrons in the terrestrial plasmasphere, together with a relationship which makes it possible to calculate the transparency of the plasmasphere to these electrons. In addition, analytic expressions are presented for the heating rate of the thermal plasma due to the passage of these superthermal electrons through the plasmasphere.
Khazanov, George V.↗
Woven electron emitters for high reliability.
Woven and knitted electron emitters noting reliability, mechanical stability, transparency and efficiency
EMITTER↗
Carrier surface generation and recombination effects in photoconduction of HgI2 single crystals
Dc photoconductivity characteristics of HgI2 single crystals have been measured in the range of 1.75-2.75 eV, using CuI as a transparent electrical contact. Hole and electron photocurrents could be separately measured by applying different voltage polarities to the illuminated electrode. It is shown that charge carrier generation near the surface is highly extrinsic, as displayed by differences in the hole and electron photogeneration spectra. Analysis of the photoconductivity versus voltage characteristics indicates that the hole and electron bulk trapping times satisfy greater than 70 and 3 microsec, respectively. The hole and electron surface recombination velocities were 1.0 x 10 to the 4th cm/s and 8 x 10 to the 5th cm/s, respectively.
Burshtein, Z.↗
Rigid-Rod Polyimides
Experimental polyimides relatively rigid synthesized in effort to exploit some of advantages of rodlike polymers, while alleviating disadvantages. Polymers used to make colorless fibers and transparent films for optical and electronic application.
Chuang, Kathy C.↗
Performance Characterization and Vibration Testing of 30-cm Carbon-Carbon Ion Optics
Carbon-based ion optics have the potential to significantly increase the operable life and power ranges of ion thrusters because of reduced erosion rates compared to molybdenum optics. The development of 15-cm and larger diameter grids has encountered many problems, however, not the least of which is the ability to pass vibration testing. JPL has recently developed a new generation of 30-cm carbon-carbon ion optics in order to address these problems and demonstrate the viability of the technology. Perveance, electron backstreaming, and screen grid transparency data are presented for two sets of optics. Vibration testing was successfully performed on two different sets of ion optics with no damage and the results of those tests are compared to models of grid vibrational behavior. It will be shown that the vibration model is a conservative predictor of grid response and can accurately describe test results. There was no change in grid alignment as a result of vibration testing and a slight improvement, if any change at all, in optics performance.
grids↗
Performance of Titanium Optics on a NASA 30 Cm Ion Thruster
The results of performance tests with two titanium optics sets are presented and compared to those of molybdenum optics. All tests were conducted on a 30 cm ion thruster that was nearly identical to the NASA Solar Electric Propulsion Technology Application Readiness (NSTAR) thruster design. Optics performance tests were conducted over a thruster input power range of 0.5 to 4.6 kW. Optics performance including impingement-limited total voltages, electron backstreaming limits, screen grid ion transparencies, near-field beam current density profiles, beam divergence angles, and beam divergence thrust correction factors were determined throughout this power range. The impingement-limited total voltages for titanium optics were within 10 to 55 V of those for molybdenum optics. Electron backstreaming limit magnitude as a function of peak beam current density for both molybdenum and titanium optics were within a few volts of each other, indicating similar hot grid gaps for these two grid materials during steady-state operation. Beam divergence half-angles at 90 percent of the total beam current and thrust correction factors for both titanium optics sets were within one degree and one percent, respectively, of those for molybdenum optics. When thruster power was increased to 2.3 kW immediately following discharge ignition, the titanium screen grid came into contact with the accelerator grid within five minutes of ignition. Relative to molybdenum, titanium's larger thermal expansion and smaller thermal conductivity likely caused the screen grid to thermally expand more relative to the accelerator grid during startup.
Soulas, George C.↗
Performance Evaluation of 40 cm Ion Optics for the NEXT Ion Engine
The results of performance tests with two 40 cm ion optics sets are presented and compared to those of 30 cm ion optics with similar aperture geometries. The 40 cm ion optics utilized both NSTAR and TAG (Thick-Accelerator-Grid) aperture geometries. All 40 cm ion optics tests were conducted on a NEXT (NASA's Evolutionary Xenon Thruster) laboratory model ion engine. Ion optics performance tests were conducted over a beam current range of 1.20 to 3.52 A and an engine input power range of 1.1 to 6.9 kW. Measured ion optics' performance parameters included near-field radial beam current density profiles, impingement-limited total voltages, electron backstreaming limits, screen grid ion transparencies, beam divergence angles, and start-up transients. Impingement-limited total voltages for 40 cm ion optics with the NSTAR aperture geometry were 60 to 90 V lower than those with the TAG aperture geometry. This difference was speculated to be due to an incomplete burn-in of the TAG ion optics. Electron backstreaming limits for the 40 cm ion optics with the TAG aperture geometry were 8 to 19 V higher than those with the NSTAR aperture geometry due to the thicker accelerator grid of the TAG geometry. Because the NEXT ion engine provided beam flatness parameters that were 40 to 63 percent higher than those of the NSTAR ion engine, the 40 cm ion optics outperformed the 30 cm ion optics.
Soulas, George C.↗
Single-element Electron-transfer Optical Detector System
An optical detector system includes an electrically resistive screen that is substantially transparent to radiation energy having a wavelength of interest. An electron transfer element (e.g., a low work function photoactive material or a carbon nanotube (CNT)-based element) has a first end and a second end with its first end spaced apart from the screen by an evacuated gap. When radiation energy passes through the screen with a bias voltage being applied thereto, transfer of electrons through the electron transfer element is induced from its first to its second end such that a quantity indicative of the electrons transferred can be detected.
Jeffrey D Jordan↗