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At least 37 records · Page 2

Composition of the earth's upper mantle. I - Siderophile trace elements in ultramafic nodules

The considered investigation is concerned with a reexamination of the question of the distribution of siderophile elements in the earth's upper mantle, taking into account a more unified data base which is now available. A comprehensive suite of ultramafic inclusions was collected as part of the Basaltic Volcanism Study Project and has been analyzed by instrument neutron activation analysis for major, minor, and some lithophile trace elements. In addition, 18 of these rocks and the important sheared garnet lherzolite PHN 1611 have been analyzed by means of radiochemical neutron activation analysis for 7 siderophile elements (Au, Ge, Ir, Ni, Os, Pd, and Re) and 9 volatile elements (Ag, Bi, Cd, In, Sb, Se, Te, Tl, and Zn). The siderophile element data reveal interesting inter-element correlations, which were not apparent from the compiled abundance tables of Ringwood and Kesson (1976) and Chou (1978).

Morgan, J. W.↗

Composition of the earth's upper mantle. II - Volatile trace elements in ultramafic xenoliths

Radiochemical neutron activation analysis was used to determine the nine volatile elements Ag, Bi, Cd, In, Sb, Se, Te, Tl, and Zn in 19 ultramafic rocks, consisting mainly of spinel and garnet lherzolites. A sheared garnet lherzolite, PHN 1611, may approximate undepleted mantle material and tends to have a higher volatile element content than the depleted mantle material represented by spinel lherzolites. Comparisons of continental basalts with PHN 1611 and of oceanic ridge basalts with spinel lherzolites show similar basalt: source material partition factors for eight of the nine volatile elements, Sb being the exception. The strong depletion of Te and Se in the mantle, relative to lithophile elements of similar volatility, suggests that 97% of the earth's S, Se and Te may be in the outer core.

Morgan, J. W.↗

Metamorphosed ultramafic rocks in east Greenland

The compositional and mineralogical characteristics of Archean ultramafic rocks in Kangerdlugssuaq Fjord are summarized: the first provides information important to understanding the primary character of the rock suite, whereas the latter provides data necessary to determine the conditions of their equilibrium during the latest metamorphism. This information will be of value in determining the affinity of the suite to similar Archean rocks in other areas of the North Atlantic craton.

Kays, M. A.↗

Abundance and distribution of ultramafic microbreccia in Moses Rock Dike: Quantitative application of AIS data

Moses Rock dike is a Tertiary diatreme containing serpentinized ultramafic microbreccia (SUM). Field evidence indicates the SUM was emplaced first followed by breccias derived from the Permian strata exposed in the walls of the diatreme and finally by complex breccias containing basement and mantle derived rocks. SUM is found primarily dispersed throughout the matrix of the diatreme. Moses Rock dike was examined with Airborne Imaging Spectrometer (AIS) to map the distribution and excess of SUM in the matrix and to better understand the nature of the eruption which formed this explosive volcanic feature. AIS data was calibrated by dividing the suite of AIS data by data from an internal standard area and then multiplying this relative reflectance data by the absolute bidirectional reflectance of a selected sample from the standard area which was measured in the lab. From the calibrated AIS data the minerals serpentine, gypsum, and illite as well as desert varnish and the lithologies SUM and other sandstones were identified. SUM distribution and abundance in the matrix of the diatreme were examined in detail and two distinct styles of SUM dispersion were observed. The two styles are discussed in detail.

Mustard, John F.↗

Abundance and distribution of ultramafic microbreccia in Moses Rock dike - Quantitative application of mapping spectroscopy

Data from the Airborne Imaging Spectrometer were used to map the distribution and abundance of the serpentized ultramafic microbreccia (SUM) component in the Moses Rock dike, which is a Tertiary diatreme located on the Colorado Plateau in Utah. The geologic setting and composition of Moses Rock dike are discussed together with its texture and the relationship to the bedrock of surface materials. These observations along with laboratory spectroscopic data are used to interpret surface mineralogy of the dike and the surrounding regions from the imaging spectometer data. The spatial distribution and the abundance of the primary surface components were calculated using a nonlinear model for the mixing of spectra from multicomponent surfaces. The derived SUM distribution and abundance data support McGetchin's (1968) model for the emplacement of Moses Rock dike as a fluidized system.

Mustard, John F.↗

Spectral-compositional variations in the constituent minerals of mafic and ultramafic assemblages and remote sensing implications

Chemical compositions of the constituent minerals of 13 mafic and ultramafic assemblages containing from one to five mineral components were analyzed with an electron microprobe, and the compositions were correlated with the reflectance spectra of the samples to determine the spectral-compositional relationships of these assemblages. Results indicate that, as more components are added to a mixture, the quality and quantity of compositional information which can be derived from spectral analysis diminishes. It is shown that opaque minerals (such as magnetite for terrestrial occurrences and ilmenite in lunar assemblages) influence reflectance spectra out of proportion to their abundances, reducing overall reflectance and band depths of mafic silicates in small dispersed amounts.

Cloutis, Edward A.↗

Origin of high-Ti lunar ultramafic glasses

A series of high pressure melting experiments were performed on a synthetic analog of the Apollo 14 Black Glass. At 15 kb and 1400 C, olivine is the liquidus phase. At 25 kb and 1450 C, orthopyroxene and Cr-spinel crystallize. A multiple saturation point with olivine + orthopyroxene + spinel on the liquidus occurs at 20 kb and 1440 C. It was proposed that the high-Ti ultramafic glass evolved from a low-Ti Green Glass generated deep in the lunar interior that assimilated shallow-level, late stage cumulates of magma ocean differentiation. Heat for assimilation is provided by superheat of the low-Ti magma and melts high-Ca pyroxene and ilmenite cumulates at a depth of 100 km. This model is a variant of that proposed by Hubbard and Minear and rejected by Ringwood and Kesson.

Wagner, T. P.↗

Asteroidal Differentiation Processes Deduced from Ultramafic Achondrite Ureilite Meteorites

Ureilites are the second largest achondrite group. They are ultramafic achondrites that have experienced igneous processing whilst retaining some degree of nebula-derived chemical heterogeneity. They differ from other achondrites in that they contain abundant carbon and their oxygen isotope compositions are very heterogeneous and similar to those of the carbonaceous chondrite anhydrous mineral line. Their carbonaceous nature and some compositional characteristics indicative of nebular origin suggest that they are primitive materials that form a link between nebular processes and early periods of planetesimal accretion. However, despite numerous studies, the exact origin of ureilites remains unclear. Current opinion is that they represent the residual mantle of an asteroid that underwent silicate and Fe-Ni-S partial melting and melt removal. Recent studies of short-lived chronometers indicate that the parent asteroid of the ureilites differentiated very early in the history of the Solar System. Therefore, they contain important information about processes that formed small rocky planetesimals in the early Solar System. In effect, they form a bridge between nebula processes and differentiation in small planetesimals prior to accretion into larger planets and so a correct interpretation of ureilite petrogenesis is essential for understanding this critical step.

Downes, Hilary↗

Vesta Evolution from Surface Mineralogy: Mafic and Ultramafic Mineral Distribution

Vesta is the only intact, differentiated, rocky protoplanet and it is the parent body of HED meterorites. Howardite, eucrite and diogenite (HED) meteorites represent regolith, basaltic-crust, lower-crust and possibly ultramafic-mantle samples of asteroid Vesta. Only a few of these meteorites, the orthopyroxene-rich diogenites, contain olivine, a mineral that is a major component of the mantles of differentiated bodies, including Vesta. The HED parent body experienced complex igneous processes that are not yet fully understood and olivine and diogenite distribution is a key measurement to understand Vesta evolution. Here we report on the distribution of olivine and its constraints on vestan evolution models.

DeSanctis, M. C.↗

Apatite geochemistry as a tool for understanding the petrogenesis of layered mafic-ultramafic rocks in the Bushveld Complex, South Africa

The sources of the magmas that formed the Rustenburg Layered Suite of the Bushveld Complex in South Africa remain debated, despite decades of research. Vertical and lateral variation in bulk rock and mineral separate Sr-Nd isotopic compositions, which generally indicate enriched sources, demonstrate that the layered sequence was formed by the emplacement of multiple batches of magma, crucially resulting in episodes of PGE-Cr-V mineralisation. The Lu-Hf isotope compositions of zircon are, however, at odds with the bulk rock Sr-Nd isotopic heterogeneity as they show near homogeneous compositions throughout the layered sequence (εHf (2.06 Ga) =−8). This lack of variation in Hf isotope composition has been attributed to deep, continental lithospheric mantle-related and/or crustal contamination of plume-derived Bushveld magmas. In this study, we analysed the major, trace element and Sr-Nd isotope geochemistry of apatite in the Rustenburg Layered Suite. Apatite occurs as an intercumulus mineral in the lowermost regions and a cumulus mineral in the uppermost regions of the layered sequence and can therefore be used to test existing models for the isotopic disequilibrium between bulk rock Sr-Nd and zircon Hf isotopic compositions. Apatite is largely chlorapatite in the lowermost regions and fluorapatite in the uppermost regions of the layered sequence. The Merensky Reef is unusual in that it comprises both chlorapatite and fluorapatite. Apatite throughout the layered sequence is generally unzoned and shows no evidence of late-stage alteration. Trace element data show that apatite is enriched in L/HREE, with common negative Eu-Sr anomalies. These trace element signatures are consistent with a magmatic origin for the apatite grains, with prior, or concurrent, plagioclase crystallization from the same melt. Variability in in situ Sr and Nd isotope compositions of apatite is recorded throughout the layered sequence with εNd (2.06 Ga) compositions varying between −2.5 and − 10.2 and initial 87 Sr/ 86 Sr compositions varying between 0.7079 and 0.7103 (for the Marikana dikes only). The variability in Sr-Nd isotope compositions of apatite is consistent with the bulk rock (and mineral separate) variation in Sr-Nd isotope compositions, suggesting apatite preserves primary magmatic compositions in the Rustenburg Layered Suite.

Apatite↗

The Kenna ureilite - An ultramafic rock with evidence for igneous, metamorphic, and shock origin

Ureilites are a rare group of achondrites. They are composed mainly of olivine and pigeonite in a matrix of carbonaceous material, including graphite, lonsdaleite, diamond, and metal. In most respects Kenna is a typical ureilite with the requisite mineralogical and chemical properties of the group. Differences of the Kenna ureilite from previously studied ureilites are related to a greater density, the occurrence of exceedingly minute quantities of feldspar, and a very strong elongation lineation of the silicate minerals. A description is presented of a study which indicates a complex history for Kenna, including igneous, mild metamorphic, and shock processes.

Berkley, J. L.↗