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This presentation provides an overview of primary fuel cells, regenerative fuel cells, and water electrolyzers as well as how the local environment influences the designs and operations of these systems.
Attention is given to topics of advanced concepts, hydrogen-oxygen fuel cells and electrolyzers, nickel electrodes, and advanced rechargeable batteries. Papers are presented on human exploration mission studies, advanced rechargeable sodium batteries with novel cathodes, advanced double-layer capacitors, recent advances in solid-polymer electrolyte fuel cell technology with low platinum loading electrodes, electrocatalysts for oxygen electrodes in fuel cells and water electrolyzers for space applications, and the corrosion testing of candidates for the alkaline fuel cell cathode. Other papers are on a structural comparison of nickel electodes and precursor phases, the application of electrochemical impedance spectroscopy for characterizing the degradation of Ni(OH)2/NiOOH electrodes, advances in lightweight nickel electrode technology, multimission nickel-hydrogen battery cell for the 1990s, a sodium-sulfur battery flight experiment definition study, and advances in ambient-temperature secondary lithium cells.
Duty cycle of switched, constant current circuit controlled by pressure sensor provides oxygen at a constant pressure from a cell which electrolyzes water, eliminating possibility of cell damage by excessive oxygen demand.
A feasibility study has been conducted for a NASA Kennedy Space Center liquid hydrogen/liquid oxygen production facility using solar cell arrays as the power source for electrolysis. The 100 MW output of the facility would be split into 67.6 and 32 MW portions for electrolysis and liquefaction, respectively. The solar cell array would cover 1.65 sq miles, and would be made up of 249 modular 400-kW arrays. Hydrogen and oxygen are generated at either dispersed or centralized water electrolyzers. The yearly hydrogen output is projected to be 5.76 million lbs, with 8 times that much oxygen; these fuel volumes can support approximately 18 Space Shuttle launches/year.
Two propulsion systems have been selected for the space station: O/H rockets for high thrust applications and the multipropellant resistojets for low thrust needs. These thruster systems integrate very well with the fluid systems on the station. Both thrusters will utilize waste fluids as their source of propellant. The O/H rocket will be fueled by electrolyzed water and the resistojets will use stored waste gases from the environmental control system and the various laboratories. This paper presents the results of experimental efforts with O/H and resistojet thrusters to determine their performance and life capability.
Two propulsion systems have been selected for the space station: gaseous H/O rockets for high thrust applications and the multipropellant resistojets for low thrust needs. These two thruster systems integrate very well with the fluid systems on the space station, utilizing waste fluids as their source of propellant. The H/O rocket will be fueled by electrolyzed water and the resistojets will use waste gases collected from the environmental control system and the various laboratories. The results are presented of experimental efforts with H/O and resistojet thrusters to determine their performance and life capability, as well as results of studies to determine the availability of water and waste gases.
Two propulsion systems have been selected for the Space Station: O/H rockets for high thrust applications and the multipropellant resistojets for low thrust needs. These thruster systems integrate very well with the fluid systems on the station. Both thrusters will utilize waste fluids as their source of propellant. The O/H rocket will be fueled by electrolyzed water and the resistojets will use stored waste gases from the environmental control system and the various laboratories. This paper presents the results of experimental efforts with O/H and resistojet thrusters to determine their performance and life capability.
The U.S. Space Station Freedom Manned Base (SSFMB) propulsion system is a gaseous hydrogen/oxygen-based system for primary reboost, attitude control, and station contingencies using electrolyzed water as a propellant. A secondary propulsion reboost system employs multipropellant resistojets which utilize the various waste gases generated during normal station operations. The hydrogen/oxygen propulsion system is comprised of several modules which contain thrusters, propellant storage tanks, regulation subsystems, water electrolysis units, electronic controls, and fluid plumbing. The resistojet system is comprised of one module containing the resistojets, regulators, electronic controls, and fluid plumbing. The waste gas propellant storage takes place in the Fluid Management System.
The suitability of using the electrical energy from the Space Station's Electrical Power System (EPS) during the periods of peak solar insolation which is currently not specifically allocated (unscheduled power) to produce propulsion propellants, gaseous hydrogen, and oxygen by electrolyzing water is investigated. Reboost propellant requirements are emphasized, but the results are more generally relevant because the balance of recurring propellant requirements are an order of magnitude smaller and the nonrecurring requirements are not significant on an average basis.
Viewgraphs on SPE regenerative hydrogen/oxygen fuel cells for extraterrestrial surface and microgravity applications are presented. Topics covered include: hydrogen-oxygen regenerative fuel cell energy storage system; electrochemical cell reactions; SPE cell voltage stability; passive water removal SPE fuel cell; fuel cell performance; SPE water electrolyzers; hydrophobic oxygen phase separator; hydrophilic/electrochemical hydrogen phase separator; and unitized regenerative fuel cell.
Hydrogen-oxygen fuel cells have been shown, in several NASA and contractor studies, to be an enabling technology for providing electrical power for lunar bases, outposts, and vehicles. The fuel cell, in conjunction with similar electrolysis cells, comprises a closed regenerative energy storage system, commonly referred to as a regenerative fuel cell (RFC). For stationary applications, energy densities of 1,000 watt-hours per kilograms an order of magnitude over the best rechargeable batteries, have been projected. In this RFC, the coupled fuel cell and electrolyzer act as an ultra-light battery. Electrical energy from solar arrays 'charges' the system by electrolyzing water into hydrogen and oxygen. When an electrical load is applied, the fuel cell reacts the hydrogen and oxygen to 'discharge' usable power. Several concepts for utilizing RFC's, with varying degrees of integration, have been proposed, including both primary and backup roles. For mobile power needs, such as rovers, an effective configuration may be to have only the fuel cell located on the vehicle, and to use a central electrolysis 'gas station'. Two fuel cell technologies are prime candidates for lunar power system concepts: alkaline electrolyte and proton exchange membrane. Alkaline fuel cells have been developed to a mature production power unit in NASA's Space Shuttle Orbiter. Recent advances in materials offer to significantly improve durability to the level needed for extended lunar operations. Proton exchange membrane fuel cells are receiving considerable support for hydrospace and terrestrial transportation applications. This technology promises durability, simplicity, and flexibility.
System for revitalizing breathing air in enclosed environment converts carbon dioxide and water to oxygen and methane. Chemical conversions take place in reactor module containing solid-metal-cathode water electrolyzer integrated with Sabatier reactor. According to design estimates, fully developed version of system sized to maintain breathable air for four persons, occupies 67 percent less volume, weighs 60 percent less, and consumes 3.4 percent less power than system of same capacity in which electrolyzer and Sabatier reactor are distinct components. Although oxygen primary desired end product in system originally contemplated, product methane also of value in industrial version of system.
The cost of access to space beyond low Earth orbit can be lowered if vehicles can refuel in orbit. The power requirements for a propellant depot that electrolyzes water and stores cryogenic oxygen and hydrogen can be met using technology developed for space solar power. A propellant depot is described that will be deployed in a 400 km circular equatorial orbit, receive tanks of water launched into a lower orbit from Earth by gun launch or reusable launch vehicle, convert the water to liquid hydrogen and oxygen, and store up to 500 metric tonnes of cryogenic propellants. Orbital maneuvering vehicles will transfer the Earth-launched propellant tanks from the lower orbit to the depot orbit. The propellant stored in the depot can support transportation from low Earth orbit to geostationary Earth orbit, the Moon, LaGrange points, Mars, etc. The propellant tanks on the depot are modified versions of those used in the Delta IV-Heavy launch vehicle. The tanks are configured in an in-line gravity-gradient configuration to minimize drag and settle the propellant. Temperatures can be maintained by body-mounted radiators; these will also provide some shielding against orbital debris. Power is supplied by a pair of solar arrays mounted perpendicular to the orbital plane, which rotate once per orbit to track the Sun. The majority of the power will be used to run the electrolysis system. Technology needed for an orbiting propellant depot can be tested and demonstrated in the near-term on the ground, on a Shuttle-deployed free-flyer, and on the International Space Station. Further along, an orbital depot can be deployed that stores liquid hydrogen and oxygen launched from Earth, to be followed by a full conversion and storage depot.
The cost of access to space beyond low Earth orbit can be lowered if vehicles can refuel in orbit. The power requirements for a propellant depot that electrolyzes water and stores cryogenic oxygen and hydrogen can be met using technology developed for space solar power. A propellant depot is described that will be deployed in a 400 km circular equatorial orbit, receive tanks of water launched into a lower orbit from Earth by gun launch or reusable launch vehicle, convert the water to liquid hydrogen and oxygen, and store Lip to 500 metric tonnes of cryogenic propellants. The propellant stored in the depot can support transportation from low Earth orbit to geostationary Earth orbit, the Moon, LaGrange points, Mars, etc. The tanks are configured in an inline gravity-gradient configuration to minimize drag and settle the propellant. Temperatures can be maintained by body-mounted radiators; these will also provide some shielding against orbital debris. Power is supplied by a pair of solar arrays mounted perpendicular to the orbital plane, which rotate once per orbit to track the Sun. In the longer term, cryogenic propellant production technology can be applied to a larger LEO depot, as well as to the use of lunar water resources at a similar depot elsewhere.
An overview of space solar power studies performed at the Boeing Company under contract with NASA will be presented. The major concepts to be presented are: 1. Power Plug in Orbit: this is a spacecraft that collects solar energy and distributes it to users in space using directed radio frequency or optical energy. Our concept uses solar arrays having the same dimensions as ISS arrays, but are assumed to be more efficient. If radiofrequency wavelengths are used, it will necessitate that the receiving satellite be equipped with a rectifying antenna (rectenna). For optical wavelengths, the solar arrays on the receiving satellite will collect the power. 2. Mars Clipper I Power Explorer: this is a solar electric Mars transfer vehicle to support human missions. A near-term precursor could be a high-power radar mapping spacecraft with self-transport capability. Advanced solar electric power systems and electric propulsion technology constitute viable elements for conducting human Mars missions that are roughly comparable in performance to similar missions utilizing alternative high thrust systems, with the one exception being their inability to achieve short Earth-Mars trip times. 3. Alternative Architectures: this task involves investigating alternatives to the traditional solar power satellite (SPS) to supply commercial power from space for use on Earth. Four concepts were studied: two using photovoltaic power generation, and two using solar dynamic power generation, with microwave and laser power transmission alternatives considered for each. All four architectures use geostationary orbit. 4. Cryogenic Propellant Depot in Earth Orbit: this concept uses large solar arrays (producing perhaps 600 kW) to electrolyze water launched from Earth, liquefy the resulting hydrogen and oxygen gases, and store them until needed by spacecraft. 5. Beam-Powered Lunar Polar Rover: a lunar rover powered by a microwave or laser beam can explore permanently shadowed craters near the lunar poles to search for water ice and other frozen volatiles. Near such craters are mountain peaks and highlands that are in near permanent sunlight. Power can be beamed from a collector on a sunlit mountain or crater rim to a rover inside a crater. Near-term applications of space solar power technology can therefore pave the way toward large-scale commercial power from space.
Over its life the International Space Station (ISS) has received gas (nitrogen, oxygen, and air) from various sources. Nitrogen and oxygen are used in the cabin to maintain total pressure and oxygen partial pressures within the cabin. Plumbed nitrogen is also required to support on-board experiments and medical equipment. Additionally, plumbed oxygen is required to support medical equipment as well as emergency masks and most importantly EVA support. Gas are supplied to ISS with various methods and vehicles. Vehicles like the Progress and ATV deliver nitrogen (both as a pure gas and as air) and oxygen via direct releases into the cabin. An additional source of nitrogen and oxygen is via tanks on the ISS Airlock. The Airlock nitrogen and oxygen tanks can deliver to various users via pressurized systems that run throughout the ISS except for the Russian segment. Metabolic oxygen is mainly supplied via cabin release from the Elektron and Oxygen Generator Assembly (OGA), which are water electrolyzers. As a backup system, oxygen candles (Solid Fuel Oxygen Generators-SFOGs) supply oxygen to the cabin as well. In the past, a major source of nitrogen and oxygen has come from the Shuttle via both direct delivery to the cabin as well as to recharge the ISS Airlock tanks. To replace the Shuttle capability to recharge the ISS Airlock tanks, a new system was developed called Nitrogen/Oxygen Recharge System (NORS). NIORS consists of high pressure (7000 psi) tanks which recharge the ISS Airlock tanks via a blowdown fill for both nitrogen and oxygen. NORS tanks can be brought up on most logistics vehicles such as the HTV, COTS, and ATV. A proper balance must be maintained to insure sufficient gas resources are available on-orbit so that all users have the required gases via the proper delivery method (cabin and/or plumbed).
In-Situ Resource Utilization (ISRU) seeks to make human space exploration feasible; by using available resources from a planet or the moon to produce consumables, parts, and structures that otherwise would be brought from Earth. Producing these in situ reduces the mass of such that must be launched and doing so allows more payload mass' for each mission. The production of oxygen from lunar regolith, for life support and propellant, is one of the tasks being studied under ISRU. NASA is currently funding three processes that have shown technical merit for the production of oxygen from regolith: Molten Salt Electrolysis, Hydrogen Reduction of Ilmenite, and Carbothermal Reduction. The ISRU program is currently developing system models of, the , abovementioned processes to: (1) help NASA in the evaluation process to select the most cost-effective and efficient process for further prototype development, (2) identify key parameters, (3) optimize the oxygen production process, (4) provide estimates on energy and power requirements, mass and volume.of the system, oxygen production rate, mass of regolith required, mass of consumables, and other important parameters, and (5) integrate into the overall end-to-end ISRU system model, which could be integrated with mission architecture models. The oxygen production system model is divided into modules that represent unit operations (e.g., reactor, water electrolyzer, heat exchanger). Each module is modeled theoretically using Excel and Visual Basic for Applications (VBA), and will be validated using experimental data from on-going laboratory work. This modularity (plug-n-play) feature of each unit operation allows the use of the same model on different oxygen production systems simulations resulting in comparable results. In this presentation, preliminary results for mass, power, volume will be presented along with brief description of the oxygen production system model.
This NIAC (NASA Advanced Innovative Concepts) work will focus on Mars and will build on previous efforts at analyzing atmospheric mining at Earth and the outer solar system. Spacecraft systems concepts will be evaluated and traded, to assess feasibility. However the study will primarily examine the architecture and associated missions to explore the closure, constraints and critical parameters through sensitivity studies. The Mars atmosphere consists of 95.5 percent CO2 gas which can be converted to methane fuel (CH4) and Oxidizer (O2) for chemical rocket propulsion, if hydrogen is transported from electrolyzed water on the Mars surface or from Earth. By using a highly elliptical Mars Molniya style orbit, the CO2 atmosphere can be scooped, ram-compressed and stored while the spacecraft dips into the Mars atmosphere at periapsis. Successive orbits result in additional scooping of CO2 gas, which also serves to aerobrake the spacecraft, resulting in a decaying Molniya orbit.