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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 361 records · Page 20
All sourcesNASA NTRSDOE OSTI
DOE OSTI2024

PHIL Interface Design for Use With a Voltage-Regulated Amplifier

Power hardware-in-the-loop (PHIL) has emerged as a leading strategy to thoroughly assess the impact of proprietary inverter controls on a specific power system. The development of a PHIL test bed typically involves an inverter under test, a power amplifier, controllable DC supply, and a digital real-time simulator (DRTS) to simulate the power system under study. As a result of PHIL nonidealities, a form of digital compensation within the DRTS is used, which is commonly referred to as a PHIL interface. Many existing methods use legacy power amplifiers that do not contain internal voltage regulation. These existing interface methods are based around a voltage regulator within the DRTS and do not consider the interaction with the controls in newer amplifiers. In this study, a three-step approach of PHIL interface development for modern power amplifiers with built-in voltage regulation is introduced and is validated in hardware with a 30-kW grid-following inverter.

DRTS↗
DOE OSTI2022

Solid-State Transformer and Hybrid Transformer With Integrated Energy Storage in Active Distribution Grids: Technical and Economic Comparison, Dispatch, and Control

Solid-state transformer (SST) and hybrid transformer (HT) are promising alternatives to the line-frequency transformer (LFT) in smart grids. The SST features medium-frequency isolation, full controllability for voltage regulation, reactive power compensation, and the capability of battery energy storage system (BESS) integration with multiport configuration. The HT has a partially-rated converter for fractional controllability and can integrate a small BESS. Fast grid-edge voltage fluctuations from increased solar photovoltaic (PV) and electric vehicle (EV) penetration are difficult to manage for mechanical load tap changers. Hence, along with the trend towards more BESS in the grid, the controllability and the storage integration capability of the SST and HT are of strong interest. However, a review of literature shows existing SST and HT research is mostly at converter level, while system-level assessments are scarce. Assessing technical and economic impacts is critical to understanding the benefits and role of the SST and HT to guide future research, which is presented for the first time in this article. Experimental results from medium-voltage (MV) SST and MV HT prototypes are shown to confirm equipment-level feasibility, where the voltage controllability waveforms of a MV HT prototype are reported for the first time. Comparative simulations are performed on a modified IEEE 34-bus system. Here, a grid-model-less decentralized grid-edge voltage control method and a day-ahead BESS dispatch method are proposed for the SST and HT. The simulations show that the SST and HT with integrated storage can host more PV, achieve peak shaving, mitigate voltage fluctuation and reverse power flow, and support energy arbitrage for operational cost reduction, as compared to the LFT. Moreover, comprehensive analyses of net present value (NPV) and internal rate of return (IRR) are performed under different installed PV capacities, HT’s partial converter ratings, and BESS capacities. Sensitivities to future cost reductions of the PV and BESS are studied. Although the NPV and IRR are currently negative, 60% capital cost reduction or 150% revenue increase will make the SST and HT economically viable in the use case studied.

14 SOLAR ENERGY↗
DOE OSTI2021

Compact, All-PM Fiber Integrated and Alignment-Free Ultrafast Yb:Fiber NALM Laser With Sub-Femtosecond Timing Jitter

We report a simple and compact design of a dispersion compensated mode-locked Yb:fiber oscillator based on a nonlinear amplifying loop mirror (NALM). The fully polarization maintaining (PM) fiber integrated laser features a chirped fiber Bragg grating (CFBG) for dispersion compensation and a fiber integrated compact non-reciprocal phase bias device, which is alignment-free. The main design parameters were determined by numerically simulating the pulse evolution in the oscillator and by analyzing their impact on the laser performance. Experimentally, we achieved an 88 fs compressed pulse duration with sub-fs timing jitter at 54 MHz repetition rate and 51 mW of output power with 5.5×10 -5 [20 Hz, 1 MHz] integrated relative intensity noise (RIN). Furthermore, we demonstrate tight phase-locking of the laser's carrier-envelope offset frequency ( fceo ) to a stable radio frequency (RF) reference and of one frequency comb tooth to a stable optical reference at 291 THz.

47 OTHER INSTRUMENTATION↗
DOE OSTI2021

Optimization of Source Material for in-situ Arsenic Doping via Vapor Transport Deposition of CdTe Films

In-situ doping of CdTe/CdSeTe films with arsenic is performed using pre-doped source material prepared by high pressure Bridgman (HPB) melt growth. Arsenic level in the source material is varied from 1018-1020 cm-3. Correspondingly, dopant incorporation in the films prepared using vapor transport deposition (VTD) varied from 3x1017 cm-3–1x1018cm-3. In this range, dopant activation is found to inversely correlate with the dopant incorporation, suggesting compensation. The results from this study indicate film properties can be adjusted by source material.

41 EE - Solar Energy Technologies Office (EE-4S)↗
DOE OSTI2022

Hybrid Functional Calculations for Antimony Doping in CdTe

CdTe-based solar cells are leading thin-film photovoltaic technology, with efficiencies over 22%, but still much lower than the theoretical maximum of 29%. Further improvements will rely on increasing the open-circuit voltage Voc, which, in turn, depends on carrier density and lifetime. Using hybrid density functional calculations, we investigate Sb doping of CdTe, focusing on its limitation as shallow acceptor and the formation of compensating AX center. Paying special attention to supercell size and effects of spin-orbit coupling, we predict an ionization energy of 116 meV in the dilute limit, much closer to recent experimental value of 103 meV from temperature-dependent Hall measurements in bulk single crystals, and in contrast to much larger values from previous calculations. We also find that the Sb-related AX centers are not major compensation centers in Sb-doped CdTe.

14 SOLAR ENERGY↗
DOE OSTI2022

Design, Fabrication, and Testing of a 1.9 m Long, 16.5 mm Period NbTi Superconducting Undulator for the Advanced Photon Source Upgrade

Superconducting undulator (SCU) technology has been in use at the Advanced Photon Source since 2013. Due to the successful and reliable operation of the existing SCUs, the Advanced Photon Source upgrade project has decided to expand the use of NbTi-based SCUs. The first new magnets to be designed and fabricated are 1.9 m long with a period length of 16.5 mm. NbTi superconductor is used for coil winding and there are four separate coils wound on the mandrel to produce the main undulator field along with end compensation and distributed dipole compensation. The magnetic design, fabrication details, assembly, and testing are described in detail.

NbTi.↗
DOE OSTI2023

Net Load Forecasting With Disaggregated Behind-the-Meter PV Generation

As worldwide use of residential photovoltaic (PV) systems grows, system operators and utilities will need to transition from forecasting pure demand to forecasting net load with behind-the-meter (BTM) PV generation. However, PV generation can be difficult to predict and the measurements of PV generation from BTM residential systems are often invisible behind a measurement of the net load, making net load forecasting challenging. This paper proposes a novel two-stage framework for net load forecasting in areas with limited observability and high BTM PV generation. First, the profiles of observable customers are used to disaggregate the net load measurements into the pure load and PV generation. Then, separate models are used to forecast the PV generation and pure load individually, and the results are combined for a net load forecast. Further, this paper also proposes a compensator for correcting the error of the net load forecast, using historical forecast errors of the PV generation, pure load, and net load. The proposed framework is tested through two case studies for areas with high BTM PV penetration and less than 10% observable customers. The two-stage forecasting model is compared to two benchmark methods - a time series forecasting model, and a model that forecasts the net load directly using historical net load measurements. Results show that the proposed disaggregation-forecasting framework reduces the error of the net load forecast compared to both benchmark models. In addition, when the net load forecast error is periodic, the compensator can correct the error to improve the forecast accuracy.

14 SOLAR ENERGY↗
DOE OSTI2025

Spike-Free Adaptive Sliding Mode Control: Application to Permanent Magnet Synchronous Motors

A new methodology for adaptive sliding mode control (ASMC) has been widely used to improve the control performance in various systems. This method exhibits several advantages, including low sliding mode control (SMC) chattering, no knowledge of the system disturbance bound, and no overestimation of the control gain. Despite its advantages, this method can be hampered by the spike phenomenon, slow control gain convergence, and difficulty in achieving optimal performance under varying disturbances. Consequently, this article proposes a spike-free ASMC method with a disturbance observer (DOB) to address these problems. Previous ASMC methods have been analyzed via simulations to verify the aforementioned problems. Here, this analysis highlights the need for disturbance compensation and improvements in the SMC gain adaptation law. Therefore, a DOB is designed to mitigate the spike phenomenon by compensating for disturbances. Subsequently, an SMC gain adaptation law based on disturbance error estimation is designed to eliminate the spike phenomenon completely. The proposed adaptation law makes the SMC gain to converge to a slightly higher value than the disturbance estimation error. Consequently, the proposed method not only eliminates the spike phenomenon, but also ensures optimal performance under varying disturbances. The performance of the proposed method is experimen tally validated through a comparative study.

42 ENGINEERING↗
DOE OSTI2019

Reduced Common-Mode Voltage PWM Scheme for Full-SiC Three-Level Uninterruptible Power Supply With Small DC-Link Capacitors

In this article, a pulsewidth modulation (PWM) scheme for three-level full-SiC uninterruptible power supplies is developed to achieve a high power density. Two key passive components are selected for size reduction of the ac-ac stage: common-mode (CM) EMI filter, and dc-link capacitors. To reduce the CM noise, a new vector combination is proposed based on synchronous switching among three-phases. The proposed combinations align CM voltage (CMV) to be a single pulse per switching period. Owing to the simple shape, CMV cancellation between a three-level rectifier and inverter can be maximally utilized. A transition between the three combinations can control the drift of neutral point voltage. An equivalent carrier-based implementation is developed. Second, a simple algorithm to compensate neutral point voltage fluctuation is proposed both for differential mode (DM) and CM output voltage. Low-order harmonics on three-phase currents and an additional high-frequency CM noise by misaligned switching instant can be eliminated. The proposed compensation can be implemented by a simple correction on carrier slopes and injected zero-sequence voltage. The proposed PWM scheme is verified with 20-kW full-SiC UPS switching at 60 kHz with 140 μF dc-link capacitors.

42 ENGINEERING↗
DOE OSTI2022

Power Decoupling Method for Voltage Source Inverters Using Grid Voltage Modulated Direct Power Control in Unbalanced System

The grid voltage modulated direct power control (GVM-DPC) is a novel power regulation method for grid-connected voltage source inverters (VSI). However, interactions between real and reactive powers still exist in GVM-DPC under unbalanced grid voltage condition, which may deteriorate its transient performance. Here, this article proposes a power decoupling method for GVM-DPC-based VSI in unbalanced systems based on the dynamic feedforward power compensation strategy, which can reduce the coupling magnitudes of real and reactive powers in the transient stages. First, the power coupling mechanism of positive and negative sequence real and reactive powers of VSI under the unbalanced voltage condition is analyzed. Then, the power coupling magnitudes (PCM) are derived according to relationships among the positive sequence components of real power, reactive power and point of common coupling (PCC) voltages. Next, the PCM are compensated into the GVM-DPC for the better decoupling performance. Furthermore, a stability analysis of the proposed control system is studied based on the impedance model, and a comparison with the traditional power decoupling method based on virtual impedance is conducted to show the superiority of the proposed method. Finally, simulations, hardware-in-loop test and experiment are conducted to validate the effectiveness of the proposed method.

42 ENGINEERING↗
DOE OSTI2023

Secrecy Analysis of Uplink IM-OFDMA Systems in the Presence of IQ Imbalance

This article introduces the secrecy analysis of the index modulation-based orthogonal frequency division multiple access (IM-OFDMA) schemes by considering the in-phase and quadrature imbalance (IQI) presence at the users' RF front ends. In particular, by assuming the existence of an eavesdropper, the secrecy performance of the considered uplink multiple-access system is investigated through the strictly positive secrecy capacity and secrecy outage probability, and closed-form expressions are derived for both quantities. Moreover, the secrecy performance is conducted regarding IQI compensation based on a preamble-based estimation method. Further, analysis of the impact of the different parameters of IM-OFDMA, IQI, and estimation method is included via analytical and simulation-based results. In conclusion, the results reveal that IM-OFDMA is more reliable in secrecy performance than OFDMA, regardless of whether IQI is present. Also, IQI compensation can lead to a better secrecy performance compared to the case of no IQI.

42 ENGINEERING↗
DOE OSTI2020

A substantial role of soil erosion in the land carbon sink and its future changes

Realistic representation of land carbon sink in climate models is vital for predicting carbon climate feedbacks in a changing world. Although soil erosion that removes land organic carbon has increased substantially since the onset of agriculture, it is rarely included in the current generation of climate models. Using an Earth system model with soil erosion represented, we estimated that on average soil erosion displaces 5% of newly fixed land organic carbon downslope annually in the continental US. In the lower Mississippi river basin and the Cascades, the fraction can be as large as 40%. About 12% of the eroded organic carbon is eventually exported to inland waters, which is equal to 14% of the simulated net carbon gain by terrestrial ecosystems. By comparing the eroded organic carbon export to rivers with the particulate organic carbon export to oceans, we demonstrated that a large fraction of the carbon export to rivers could have been mineralized in inland waters. Importantly, with a direct comparison of eroded and exported soil organic carbon and land net carbon uptake, we found that Earth system models that ignore soil erosion likely offset the erosional carbon loss by increasing heterotrophic respiration implicitly. But as soil erosion and heterotrophic respiration respond differently to a warming climate, this unrealistic compensation would lead to biased predictions of future land carbon sink.

Tan, Zeli↗
DOE OSTI2024

Photosynthetic responses of switchgrass to light and CO 2 under different precipitation treatments

Switchgrass ( Panicum virgatum L .) is a prominent bioenergy crop with robust resilience to environmental stresses. However, our knowledge regarding how precipitation changes affect switchgrass photosynthesis and its responses to light and CO 2 remains limited. To address this knowledge gap, we conducted a field precipitation experiment with five different treatments, including −50%, −33%, 0%, +33%, and +50% of ambient precipitation. To determine the responses of leaf photosynthesis to CO 2 concentration and light, we measured leaf net photosynthesis of switchgrass under different CO 2 concentrations and light levels in 2020 and 2021 for each of the five precipitation treatments. We first evaluated four light and CO 2 response models (i.e., rectangular hyperbola model, nonrectangular hyperbola model, exponential model, and the modified rectangular hyperbola model) using the measurements in the ambient precipitation treatment. Based on the fitting criteria, we selected the nonrectangular hyperbola model as the optimal model and applied it to all precipitation treatments, and estimated model parameters. Overall, the model fit field measurements well for the light and CO 2 response curves. Precipitation change did not influence the maximum net photosynthetic rate ( P max ) but influenced other model parameters including quantum yield ( α ), convexity ( θ ), dark respiration ( Rd ), light compensation point ( LCP ), and saturated light point ( LSP ). Specifically, the mean P max of five precipitation treatments was 17.6 μmol CO 2 m −2 s −1 , and the ambient treatment tended to have a higher P max . The +33% treatment had the highest α , and the ambient treatment had lower θ and LCP , higher Rd , and relatively lower LSP . Furthermore, precipitation significantly influenced all model parameters of CO 2 response. The ambient treatment had the highest P max , largest α , and lowest θ , R d , and CO 2 compensation point LCP . Overall, this study improved our understanding of how switchgrass leaf photosynthesis responds to diverse environmental factors, providing valuable insights for accurately modeling switchgrass ecophysiology and productivity.

09 BIOMASS FUELS↗
DOE OSTI2024

Pressure Transducer Measurement Variability in Deep Wells Screened Across the Water Table

Abstract Automated water level measurements collected using vented pressure transducers in deep wells screened across the water table may exhibit a greater response to barometric pressure changes than the true water level. The cause was hypothesized to be disequilibrium in barometric pressure between the wellbores and land surface due to air exchange with the deep vadose zone. In this study, vented and nonvented pressure transducers were installed and operated simultaneously in two deep wells screened across the water table. A vent tube open to the atmosphere at land surface allowed for barometric compensation of the vented transducers. Two nonvented transducers were installed in each well, one submerged in the water and one above the water surface. The difference in readings allowed for barometric compensation. Manual measurements were also collected. It was confirmed that measurements from the vented transducers exhibited greater variability in response to barometric pressure changes than the nonvented transducers and manual measurements. Comparison of the downhole barometric pressure measurements to values from a nearby meteorology station showed the response in the wells to changes in barometric pressure was time‐lagged and attenuated. Thus, the reference pressure from land surface supplied to the vented transducers was not representative of the air pressure within the wells. This caused fluctuations of the transducer readings in response to barometric pressure changes to be greater than the true water level change. This issue can be resolved by the use of nonvented pressure transducers.

McDonald, John P.↗
DOE OSTI2020

Thermal Properties of Sodium Borosilicate Glasses as a Function of Sulfur Content

SO3 additions, up to 3.0 wt%, were systematically investigated for effects on the physical properties of sodium borosilicate glass melted in air, with a sulfur-free composition of 50SiO2-10Al2O3-12B2O3-21Na2O-7CaO (wt%). Solubility measurements, using electron microscopy chemical analysis, determined the maximum loading to be ~1.5 wt% SO3. It was found that sulfur (here as sulfate) in this glass increased the glass transition temperature, thermal diffusivity, heat capacity, and thermal conductivity, and decreased the mass density. Structural analysis, performed with Raman spectroscopy, indicated that the borosilicate network polymerized with sulfur additions, presumably due to Na2O being required to charge compensate the ionic SO42- additions, thus becoming unavailable to form non-bridging oxygen in the silicate network. It is postulated that this increased crosslinking of the borosilicate backbone lead to a structure with higher dimensionality and average bond energy. This increased the mean free paths and vibration frequency of the phonons, which resulted in the observed increase in thermal properties.

Thermal properties, Borosilicate glass, Sulfur sol↗
DOE OSTI2021

Effects of Al:Si and (Al+Na):Si Ratios on the Properties of the International Simple Glass, Part II: Structure

High-alumina containing high-level waste (HLW) will be vitrified at the Waste Treatment Plant at the Hanford Site. The resulting glasses, high in alumina, will have distinct composition-structure-property (C-S-P) relationships compared to previously studied HLW glasses. These C-S-P relationships determine the processability and product durability of glasses and therefore must be understood. The main purpose of this study is to understand the detailed structural changes caused by Al:Si and (Al+Na):Si substitutions in a simplified nuclear waste model glass (ISG, International Simple Glass) by combining experimental structural characterizations and molecular dynamics (MD) simulations. The structures of these two series of glasses were characterized by neutron total scattering and 27Al, 23Na, 29Si, and 11B solid-state nuclear magnetic resonance (NMR) spectroscopy. Additionally, MD simulations were used to generate atomistic structural models of the borosilicate glasses and simulation results were validated by the experimental structural data. Short-range (e.g., bond distance, coordination number, etc.) and medium-range (e.g., oxygen speciation, network connectivity, polyhedral linkages) structural features of the borosilicate glasses were systematically investigated as a function of the degree of substitution. The results show that bond distance and coordination number of the cation-oxygen pairs are relatively insensitive to Al:Si and (Al+Na):Si substitutions with the exception of the B-O pair. Additionally, the Al:Si substitution results in an increase of tri-bridging oxygen species, while (Al+Na):Si substitution creates non-bridging oxygen species. Charge compensator preferences were found for Si-[NBO] (Na+), [3]B-[NBO] (Na+), [4]B (mostly Ca2+), [4]Al (nearly equally split Na+ and Ca2+), and [6]Zr (mostly Ca2+). The network former-BO-network former linkages preferences were also tabulated; Si-O-Al and Al-O-Al were preferred at the expense of lower Si-O-[3]B and [3]B-O-[3]B linkages. These results provide insights on the structural origins of property changes such as glass transition temperature caused by the substitutions, providing a basis for future improvements of theoretical and computer simulation models.

Lu, Xiaonan↗
DOE OSTI2022

Effect of iron redox ratio on the structures of boroaluminosilicate glasses

Iron oxide is commonly found in natural or industrial glass compositions and can exist as ferrous (Fe 2+ ) or ferric (Fe 3+ ) species, with their ratios depending on glass composition, temperature, pressure and the redox reactions during the glass forming process. The iron redox ratio plays an important role on silicate glass structures and consequently various properties. This work aims to study the effect of iron oxide, and particularly the iron redox ratio, on the structures of borosilicate and boroaluminosilicate glasses using molecular dynamics simulations with newly developed iron potential parameters that are compatible with the borosilicate potentials. The results provide detailed cation coordination states of both iron species and the effect of redox ratio on boron coordination and other structural features. Particularly, competition for charge compensating modifier cations (such as Na + ) among the fourfold-coordinated cations such as B 3+ , Al 3+ , and Fe 3+ is investigated by calculating the cation–cation pair distribution functions and coordination preferential ratios. The results show that the trivalent ferric ions, with a shorter Fe–O bond distance and better defined first coordiation shell with mainly four-fold coordination, act as a glass former whereas the divalent ferrous ions mainly play the role of glass modifier. The ferrous/ferric ratio (Fe 2+ /Fe 3+ ) was found to affect the glass chemistry and hence glass properties by regulating the amount of four-coordinated boron, the fraction of non-briding oxygen and other features. Finally, the results are compared with available experimental data to gain insights of the complex structures and charge compensation schemes of the glass system.

36 MATERIALS SCIENCE↗