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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 361 records · Page 20

Cyanide and isocyanide abundances in the cold, dark cloud TMC-1

Cold, dark molecular clouds are particularly useful for the study of interstellar chemistry because their physical parameters are better understood than those of heterogeneous, complex giant molecular clouds. Another advantage is their relatively small distance from the solar system. The present investigaation has the objective to provide accurate abundance ratios for several cyanides and isocyanides in order to constrain models of dark cloud chemistry. The relative abundances of such related species can be particularly useful for the study of chemical processes. The cloud TMC-1 considered in the current study has a remarkably high abundance of acetylene and polyacetylene derivatives. Data at 3 mm, corresponding to the J = 1 to 0 transitions of HCN, H(C-13)N, HN(C-13), HC(N-15), and H(N-15)C were obtained.

Irvine, W. M.↗

Tribology theory versus experiment

Tribology, the study of friction and wear of materials, has achieved a new interest because of the need for energy conservation. Fundamental understanding of this field is very complex and requires a knowledge of solid-state physics, material science, chemistry, and mechanical engineering. This paper is meant to be didactic in nature and outlines some of the considerations needed for a tribology research program. The approach is first to present a simple model, a field emission tip in contact with a flat surface, in order to elucidate important considerations, such as contact area, mechanical deformations, and interfacial bonding. Then examples from illustrative experiments are presented. Finally, the current status of physical theories concerning interfacial bonding are presented.

Ferrante, John↗

Near-term lander experiments for growing plants on Mars: requirements for information on chemical and physical properties of Mars regolith

In order to support humans for long-duration missions to Mars, bioregenerative Advanced Life Support (ALS) systems have been proposed that would use higher plants as the primary candidates for photosynthesis. Hydroponic technologies have been suggested as the primary method of plant production in ALS systems, but the use of Mars regolith as a plant growth medium may have several advantages over hydroponic systems. The advantages for using Mars regolith include the likely bioavailability of plant-essential ions, mechanical support for plants, and easy access of the material once on the surface. We propose that plant biology experiments must be included in near-term Mars lander missions in order to begin defining the optimum approach for growing plants on Mars. Second, we discuss a range of soil chemistry and soil physics tests that must be conducted prior to, or in concert with, a plant biology experiment in order to properly interpret the results of plant growth studies in Mars regolith. The recommended chemical tests include measurements on soil pH, electrical conductivity and soluble salts, redox potential, bioavailability of essential plant nutrients, and bioavailability of phytotoxic elements. In addition, a future plant growth experiment should include procedures for determining the buffering and leaching requirements of Mars regolith prior to planting. Soil physical tests useful for plant biology studies in Mars regolith include bulk density, particle size distribution, porosity, water retention, and hydraulic conductivity.

NASA Center JSC↗

The carbon chemistry of the moon.

The analysis of lunar samples has shown that the carbon chemistry of the moon is entirely different from the carbon chemistry of the earth. Lunar carbon chemistry is more closely related to cosmic physics than to conventional organic chemistry. Sources of carbon on the moon are considered, giving attention to meteorites and the solar wind. The approaches used in the analysis of the samples are discussed, taking into account the method of gas chromatography employed and procedures used by bioscience investigators in the study of the lunar fines. The presence of indigenous methane and carbide in the lunar fines was established. Reactions and processes taking place on the lunar surface are discussed.

Eglinton, G.↗

Laboratory Astrophysics in the United States

Laboratory astrophysics is a strong and vibrant field in the US with its primary national representation as a full Division of the American Astronomical Society (AAS). Laboratory Astrophysics is also represented in other major scientific societies such as the Astrochemistry subdivision of the American Chemical Society (ACS), the High Energy Density Laboratory Astrophysics (HEDLA) and the Division of Astrophysics (DAP) of the American Physical Society (APS) to cite a few. Laboratory Astrophysics and Astrochemistry is also well represented in federal agencies such as the National Aeronautics and Space Administration (NASA) and the National Science Foundation (NSF) where research programs are fully dedicated to the support of laboratory astrophysics research. Laboratory Astrophysics is also well represented in the Academic arena where Physics, Astronomy and/or Chemistry Departments in many universities host a laboratory Astrophysics or Astrochemistry curriculum. The increasing recognition of the field of laboratory astrophysics has been recently reinforced by its inclusion into the recommendations of the two most recent Decadal Surveys of the National Academy of Sciences (NAS). I will discuss and present the many aspects and representations of Laboratory Astrophysics in the US and summarize the current efforts in the field.

Laboratory Astrophysics↗

Hierarchies of Models: Toward Understanding Planetary Nebulae

Stars like our sun (initial masses between 0.8 to 8 solar masses) end their lives as swollen red giants surrounded by cool extended atmospheres. The nuclear reactions in their cores create carbon, nitrogen and oxygen, which are transported by convection to the outer envelope of the stellar atmosphere. As the star finally collapses to become a white dwarf, this envelope is expelled from the star to form a planetary nebula (PN) rich in organic molecules. The physics, dynamics, and chemistry of these nebulae are poorly understood and have implications not only for our understanding of the stellar life cycle but also for organic astrochemistry and the creation of prebiotic molecules in interstellar space. We are working toward generating three-dimensional models of planetary nebulae (PNe), which include the size, orientation, shape, expansion rate and mass distribution of the nebula. Such a reconstruction of a PN is a challenging problem for several reasons. First, the data consist of images obtained over time from the Hubble Space Telescope (HST) and spectra obtained from Kitt Peak National Observatory (KPNO) and Cerro Tololo Inter-American Observatory (CTIO). These images are of course taken from a single viewpoint in space, which amounts to a very challenging tomographic reconstruction. Second, the fact that we have two disparate and orthogonal data types requires that we utilize a method that allows these data to be used together to obtain a solution. To address these first two challenges we employ Bayesian model estimation using a parameterized physical model that incorporates much prior information about the known physics of the PN. In our previous works we have found that the forward problem of the comprehensive model is extremely time consuming. To address this challenge, we explore the use of a set of hierarchical models, which allow us to estimate increasingly more detailed sets of model parameters. These hierarchical models of increasing complexity are akin to scientific theories of increasing sophistication, with each new model/theory being a refinement of a previous one by either incorporating additional prior information or by introducing a new set of parameters to model an entirely new phenomenon. We apply these models to both a simulated and a real ellipsoidal PN to initially estimate the position, angular size, and orientation of the nebula as a two-dimensional object and use these estimates to later examine its three-dimensional properties. The efficiency/accuracy tradeoffs of the techniques are studied to determine the advantages and disadvantages of employing a set of hierarchical models over a single comprehensive model.

Knuth, Kevin H.↗

Hierarchies of Models: Toward Understanding Planetary Nebulae

Stars like our sun (initial masses between 0.8 to 8 solar masses) end their lives as swollen red giants surrounded by cool extended atmospheres. The nuclear reactions in their cores create carbon, nitrogen and oxygen, which are transported by convection to the outer envelope of the stellar atmosphere. As the star finally collapses to become a white dwarf, this envelope is expelled from the star to form a planetary nebula (PN) rich in organic molecules. The physics, dynamics, and chemistry of these nebulae are poorly understood and have implications not only for our understanding of the stellar life cycle but also for organic astrochemistry and the creation of prebiotic molecules in interstellar space. We are working toward generating three-dimensional models of planetary nebulae (PNe), which include the size, orientation, shape, expansion rate and mass distribution of the nebula. Such a reconstruction of a PN is a challenging problem for several reasons. First, the data consist of images obtained over time from the Hubble Space Telescope (HST) and spectra obtained from Kitt Peak National Observatory (KPNO) and Cerro Tololo Inter-American Observatory (CTIO). These images are of course taken from a single viewpoint in space, which amounts to a very challenging tomographic reconstruction. Second, the fact that we have two disparate and orthogonal data types requires that we utilize a method that allows these data to be used together to obtain a solution. To address these first two challenges we employ Bayesian model estimation using a parameterized physical model that incorporates much prior information about the known physics of the PN. In our previous works we have found that the forward problem of the comprehensive model is extremely time consuming. To address this challenge, we explore the use of a set of hierarchical models, which allow us to estimate increasingly more detailed sets of model parameters. These hierarchical models of increasing complexity are akin to scientific theories of increasing sophistication, with each new model/theory being a refinement of a previous one by either incorporating additional prior information or by introducing a new set of parameters to model an entirely new phenomenon. We apply these models to both a simulated and a real ellipsoidal PN to initially estimate the position, angular size, and orientation of the nebula as a two-dimensional object and use these estimates to later examine its three-dimensional properties. The efficiency/accuracy tradeoffs of the techniques are studied to determine the advantages and disadvantages of employing a set of hierarchical models over a single comprehensive model.

Knuth, Kevin H.↗

Imaging experiment - The Viking Lander.

The Viking Lander Imaging System will consist of two identical facsimile cameras. Each camera has a high-resolution mode with an instantaneous field of view of 0.04 deg, and survey and color modes with instantaneous fields of view of 0.12 deg. Cameras are positioned one meter apart to provide stereoscopic coverage of the near-field. The Imaging Experiment will provide important information about the morphology, composition, and origin of the Martian surface and atmospheric features. In addition, lander pictures will provide supporting information for other experiments in biology, organic chemistry, meteorology, and physical properties.

Mutch, T. A.↗

Photochemical processes in the inner coma

Models for the inner-coma chemistry of comets are reviewed. The physics relevant to the coma's chemistry is summarized, and the interaction of solar radiation with the coma is described, along with photolytic and chemical processes. The formation and destruction of several observed species are traced through a chemical reaction network, and model results are compared with observations. The species considered include CN, C2, C3, NH2, CH, CO, CO(+), OH, H2O, HCO, C2H4, and C2H3. The models most consistent with observations are shown to indicate that only trace amounts (2% in all) of molecules bearing CN, C2, C3, and NH2 can be present in the nucleus of a comet.

Huebner, W. F.↗

The role of water in slip casting

Slips and casting are considered in terms of physical and colloidal chemistry. Casting slips are polydisperse suspensions of lyophobic particles in water, whose degree of coagulation is controlled by interaction of flocculating and deflocculating agents. Slip casting rate and viscosity are functions of temperature. Slip rheology and response to deflocculating agents varies significantly as the kinds and amounts of colloid modifiers change. Water is considered as a raw material. Various concepts of water/clay interactions and structures are discussed. Casting is a de-watering operation in which water moves from slip to cast to mold in response to a potential energy termed moisture stress. Drying is an evaporative process from a free water surface.

Mccauley, R. A.↗

Adhesive properties of LARC-CPI, a new semi-crystalline polyimide

As part of an effort on high temperature structural resins for aerospace applications, a new family of polyimides containing carbon and ether connecting groups between aromatic rings were prepared. Several of these polyimides were semicrystalline. One polyimide, designated LARC-CPI, with a glass transition temperature of 222 C and a crystalline melt temperature of 350 C, was evaluated in the form of an adhesive, film, and molding. Unoriented films exhibited excellent resistance to solvents and strong bases and high tensile properties. Compact tension specimens gave very high fracture toughness values. Titanium tensile shear specimens provided exceptional strength under a variety of test conditions. The chemistry and the physical and mechanical properties of LARC-CPI are discussed.

Hergenrother, P. M.↗

Remote sensing of land processes: Sponsored programs of study by the National Aeronautics and Space Administration

The NASA Land Processes Program consists of four interrelated disciplines which support studying the terrestrial geology, ecology, hydrology, and remote sensing science. The first three represent the space based components of classical science disciplines, while the last discipline is the study of the physics, biology, and chemistry of the land surface as it relates to the interaction of electromagnetic energy with the land surface.

Asrar, G.↗

How tethered systems can benefit microgravity research in the Space Station era

The use of a tethered movable orbiting laboratory for microgravity research is examined. The relation between reduced microgravity carriers and acceleration levels, and the effects of acceleration levels on in-orbit experiments are studied. The tuning of the gravity level at a space laboratory by employing a tether is described. The applications of the variable gravity environment to research in fluids and materials sciences, life sciences, separative techniques, and physical and applied chemistry are discussed.

Lavitola, Maria Stella↗

CFD validation for aerodynamic flows - Challenge for the '90's

The process of computational fluid dynamics (CFD) validation is described from two perspectives, numerical error validation and physical model validation. Errors associated with time and space discretization, grid refinement, numerical dissipation, and level of solution convergence, are all possible sources of numerical error. The second aspect of CFD code validation is associated with the governing equations and the physical models, e.g., chemistry and turbulence models. This type of validation requires comparisons with carefully conducted experiments and is the primary aspect of the validation process discussed in this paper. Examples of validation are shown for selected Reynolds-averaged Navier-Stokes codes for conditions from transonic through hypersonic. Since code applications are becoming more complex, it no longer suffices to use data from surface or integral quantities alone to provide the required validation. Flow field surveys and experimental boundary condition measurements are emerging as critical data that must be obtained for CFD code validation. Progress in the overall level of validation is shown to be improving. However, future challenges remain, some of which are enumerated.

Marvin, Joseph G.↗

NASA's supercomputing experience

A brief overview of NASA's recent experience in supercomputing is presented from two perspectives: early systems development and advanced supercomputing applications. NASA's role in supercomputing systems development is illustrated by discussion of activities carried out by the Numerical Aerodynamical Simulation Program. Current capabilities in advanced technology applications are illustrated with examples in turbulence physics, aerodynamics, aerothermodynamics, chemistry, and structural mechanics. Capabilities in science applications are illustrated by examples in astrophysics and atmospheric modeling. Future directions and NASA's new High Performance Computing Program are briefly discussed.

Bailey, F. Ron↗

Supercomputers Of The Future

Report evaluates supercomputer needs of five key disciplines: turbulence physics, aerodynamics, aerothermodynamics, chemistry, and mathematical modeling of human vision. Predicts these fields will require computer speed greater than 10(Sup 18) floating-point operations per second (FLOP's) and memory capacity greater than 10(Sup 15) words. Also, new parallel computer architectures and new structured numerical methods will make necessary speed and capacity available.

Peterson, Victor L.↗

Chemistry and properties of poly(arylene ether benzoxazole)s

Several new poly(arylene ether benzoxazole)s (PAEBs) were prepared by the nucleophilic displacement reaction of activated aromatic difluorides with two novel bis(hydroxyphenyl benzoxazole), using potassium carbonate. The 6F-containing PAEBs exhibited better solubility and higher Tgs than did the 6,6'-bis-(2-(4-hydroxyphenyl)benzoxazole)-derived polymers. Several of the 6,6'bis(2-(4-hydroxyphenyl)benzoxazole)-derived polymers exhibited crystallinity by DSC and wide-angle X-ray diffraction. Unorientated thin film properties of the 6F-containing PAEBs were comparable to those of other 6F-containing PAEBS that were previously reported. The chemistry and the physical and mechanical properties of the above polymers are discussed.

Smith, J. G., Jr.↗