Prediction of Structural Damping for Future Saturn Flights
Predictions of structural damping of future AAP cluster Saturn 4B flights
Jones, W. E., Jr.↗
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A study of X-ray emission from galactic and extragalactic sources with emphasis on soft and ultra-soft wavelengths
A Black Brant VC rocket was used to scan the Coma and Virgo clusters in order to measure structure in the X-ray sources. The rocket also made measurements of soft X-ray spectra, soft X-ray background flux during a 50 deg scan of the sky, soft X-rays from De Voucoulers 50, set limits to the energy dependence of soft X-ray background spectra, and the flux of solar 584 A radiation resonantly scattered by interstellar He flowing through the solar system.
Bowyer, C. S.↗
The LAMAR: A high throughput X-ray astronomy facility for a moderate cost mission
The performance of a large area modular array of reflectors (LAMAR) is considered in several hypothetical observations relevant to: (1) cosmology, the X-ray background, and large scale structure of the universe; (2) clusters of galaxies and their evolution; (3) quasars and other active galactic nuclei; (4) compact objects in our galaxy; (5) stellar coronae; and (6) energy input to the interstellar medium.
Gorenstein, P.↗
Recognition and characterization of hierarchical interstellar structure. I - Correlation function
The problem of the quantitative description of multiscale structure in interstellar cloud complexes and gravitational collapse calculations is considered, emphasizing the recognition and characterization of hierarchical fragmentation structure. The response of the two-point correlation function to a variety of analytical models for density structure is discussed for simple clustering of pointlike clouds to more complex models involving clouds with a distribution of sizes and densities and hierarchical substructure. By expressing the density distribution as the superposition of individual clouds, it is shown that the correlation function generates two types of terms: those involving each cloud's density convolved with itself and those involving pairs of different clouds. Major distortion of the correlation function are introduced by the presence of any image features with size scales a significant fraction of the image size.
Houlahan, Padraig↗
High-velocity interstellar gas in the lines of sight to the Wolf-Rayet stars HD 97152 and HD 96548
The interstellar medium was studied in the direction to the WR stars HD 96548 and HD 97152, and the results are reported. New observational data on the UV spectra of several field stars near both these WR stars are presented. The high-velocity gas seen in the spectra of these stars suggests that the detected expanding interstellar gas structure consists of two OB cluster supershells. The presence of high-velocity absorption components in one of five field star spectra in the direction of the more isolated WR star HD 96548 suggests that this expanding gas does not originate from the optical ring nebula RCW 58 surrounding HD 96548, as previously believed, but instead indicates the detection of a previously unknown expanding interstellar shell in this line of sight.
Nichols-Bohlin, Joy↗
A Correlated Ab Initio Study of Linear Carbon-Chain Radicals C(sub n)H (n=2-7)
Linear carbon-chain radicals C(sub n) H for n = 2-7 have been studied with correlation consistent valence and core-valence basis sets and the coupled cluster method RCCSD(T). Equilibrium structures, rotational constants, and dipole moments are reported and compared with available experimental data. The ground state of the even-n series changes from 2Sigma(+) to 2Pi as the chain is extended. For C4H, the 2Sigma(+) state was found to lie only 72 cm(exp -1) below the 2Pi state in the estimated complete basis set limit for valence correlation. The C2H(-) and C3H(-) anions have also been characterized.
Woon, David E.↗
Surfing the High Density Universe
The central theme of the proposed research is to link what we know about galaxy clusters and large-scale structure in the local Universe at z less than 0.1 to what we know about the original fluctuations that led to this structure as observed in the cosmic microwave background. The simple-minded approach to this question (the kind I always take) is to took at structure in the regime 0.1 less than z less than 1000. We have a unique resource to help us in this task in the form of the VLA FIRST radio survey in which, to date, we have completed mapping nearly 5000 deg2 of the northern sky to a 20 cm flux density limit of 1.0 mJy. The 435,000 radio sources detected all have positions accurate to better than 1. As this report is written, we are obtaining the next - 1000 deg 2 of data; the goal of the survey is to complete the full 10,000 deg 2 to be covered in the Sloan Digital Sky Survey.
Helfand, David J.↗
A correlated ab initio study of linear carbon-chain radicals CnH (n = 2-7)
Linear carbon-chain radicals CnH for n = 2-7 have been studied with correlation consistent valence and core-valence basis sets and the coupled cluster method RCCSD(T). Equilibrium structures, rotational constants, and dipole moments are reported and compared with available experimental data. The ground state of the even-n series changes from 2 sigma+ to 2 pi as the chain is extended. For C4H, the 2 sigma+ state was found to lie only 72 cm-1 below the 2 pi state in the estimated complete basis set limit for valence correlation. The C2H- and C3H- anions have also been characterized.
NASA Discipline Exobiology↗
A Strong Merger Shock in Abell 665
Deep (103 ks) Chandra observations of Abell 665 have revealed rich structures in this merging galaxy cluster, including a strong shock and two cold fronts. The newly discovered shock has a Mach number of M =3.0 +/- 0.6, propagating in front of a cold disrupted cloud. This makes Abell 665 the second cluster, after the Bullet cluster, where a strong merger shock of M is approximately 3 has been detected. The shock velocity from jump conditions is consistent with (2.7 +/- 0.7) × 10(exp 3) km s(exp −1). The new data also reveal a prominent southern cold front with potentially heated gas ahead of it. Abell 665 also hosts a giant radio halo. There is a hint of diffuse radio emission extending to the shock at the north, which needs to be examined with better radio data. This new strong shock provides a great opportunity to study the reacceleration model with the X-ray and radio data combined.
galaxies: clusters: general- galaxies: clisters; i↗
Penetration of Magnetosheath Plasma into Dayside Magnetosphere: 1. Density, Velocity, and Rotation
In this study, we examine a large number of plasma structures (filaments), observed with the Cluster spacecraft during 2 years (2007-2008) in the dayside magnetosphere but consisting of magnetosheath plasma. To reduce the effects observed in the cusp regions and on magnetosphere flanks, we consider these events predominantly inside the narrow cone less than 30 about the subsolar point. Two important features of these filaments are (i) their stable antisunward (earthward) motion inside the magnetosphere, whereas the ambient magnetospheric plasma moves usually in the opposite direction (sunward), and (ii) between these filaments and the magnetopause, there is a region of magnetospheric plasma, which separates these filaments from the magnetosheath. The stable earthward motion of these magnetopause show the possible disconnection of these filaments from the magnetosheath, as suggested earlier by many researchers. The results also show that these events cannot be a result of back-and-forth motions of magnetopause position or surface waves propagating on the magnetopause. Another important feature of these filaments is their rotation about the filament axis, which might be a result of their passage through the velocity shear on magnetopause boundary. After crossing the velocity shear, the filaments get a rotational velocity, which has opposite directions in the noon-dusk and noon-dawn sectors. This rotation velocity may be an important factor, supporting the stability of these filaments and providing their motion into the magnetosphere.
Lyatsky, Wladislaw↗
Exploring Anomalous Photoelectron Angular Distributions in the Photoelectron Spectra of Gd 3 O 3 – : Study of Gd 3 O 2 – and Gd 3 O 3 – Using Photoelectron Spectroscopy and Density Functional Theory Calculations
Anion photoelectron (PE) spectra of lanthanide oxide clusters obtained previously have exhibited anomalous photoelectron angular distributions which were attributed to strong PE–valence electron (PEVE) interactions. Here, to further explore this effect, we have obtained the PE spectra of Gd 3 O 2 – and Gd 3 O 3 – , two clusters that have similarly complex electronic structures but contrasting symmetries. The spectra exhibit manifolds of detachment transitions at similar binding energies in a 0.5 eV window of energy. The electron affinity of Gd 3 O 2 is measured to be 1.29 ± 0.05 eV, and that of Gd 3 O 3 is 1.31 ± 0.05 eV. As seen in previous studies on lanthanide oxide cluster anions in lower than conventional oxidation states, transitions in spectra obtained lower photon energies are more congested than those obtained with higher photon energy, a signature of strong PEVE interactions. While the detachment transitions have predominantly parallel photoelectron angular distributions (PAD), the PAD varies across the manifold of transitions in the PE spectrum of Gd 3 O 3 – in a way that suggests four different subgroups of transitions. Results of calculations on Gd 3 O 2 – suggest kite or V-shape structures with antiferromagnetic coupling between one of the 4f 7 subshells with the two others. Calculations on Gd 3 O 3 – more definitively point to ring structures with a nearly isoenergetic ferromagnetically coupled high spin (24-tet) state and a dectet state in which one of the 4f 7 subshells is antiferromagnetically coupled with the other two. Taking these results as qualitative, we propose that strong mixing between the unperturbed states predicted computationally leads to overlapping transitions with different PADs.
anions↗
Dehydration-Driven Ion Aggregation and the Onset of Gelation in ZnCl2 Solution
A minimal model of ionic aggregation in concentrated ZnCl2 is developed, guided by molecular dynamics simulations with a machine-learned potential. It explicitly incorporates solvent-site depletion, correlated chloride binding, and allows for loops within Zn–Cl clusters. Dehydration drives two coordination-controlled structural changes: a crossover at Z=2 from predominantly isolated Zn-containing species to Cl-bridged clusters and the onset of gelation near Z≈3. The model reproduces the concentration-dependent trends observed in the molecular dynamics simulations with two fitted parameters, while the cluster-size distribution at the highest concentration is consistent with three-dimensional percolation scaling over the accessible range of cluster sizes.
25 ENERGY STORAGE↗
Microcanonical Kinetics of Water-Mediated Proton Transfer in 4ABAH + ·(H 2 O) n = 4–6 Clusters (ABA = Aminobenzoic Acid): A Model System for Size-Dependent Relaxation to Ergodic Behavior
Here, we leverage the unique properties of the 4ABAH + · (H 2 O) n clusters (ABA = 4-aminobenzoic acid, n = 4−6) to quantitatively address how a finite, isolated system evolves into an ergodic condition starting from localized arrangements in configuration space. This system adopts two distinct structural isomers in which water molecules cluster around the cationic centers of its two protomers with widely separated positive charge centers. These isomers arise from excess proton attachment to either the acid (O) or amino (N) group on opposite sides of the benzene ring. Both forms are captured and kinetically trapped using cryogenic ion methods and then selectively vibrationally excited through their mutually exclusive IR bands involving NH and OH stretching fundamentals. Because the IR excitation lies below the water binding energy, the system can evolve to explore slow, rare events that lead to the interconversion between the two isomers. The rates of these intracluster reactions are determined by using a pump−probe scheme involving ∼5 ns IR pump and UV probe lasers. The rates occur on the microsecond time scale, leading to steady state populations of the isomers, thus revealing the cluster size-dependent fractionation between the two species at microcanonical equilibrium. The steady state distributions are correlated with the expected trend in the cluster size-dependent reaction energetics, which are in turn consistent with changes in the relative densities of states of the two species. These results thus provide an unusually clear example in which complex, protic-solvent-mediated chemical transformations are captured within a finite system at a precisely determined internal energy.
Rana, Abhijit [Yale Univ., New Haven, CT (United S↗
Characteristics of luminous structures in the stratosphere above thunderstorms as imaged by low-light video
An experiment was conducted in which an image-intensified, low-light video camera systematically monitored the stratosphere above distant (100-800 km) mesoscale convective systems over the high plains of the central U.S. for 21 nights between 6 July and 27 August 1993. Complex, luminous structures were observed above large thunderstorm clusters on eleven nights, with one storm system (7 July 1993) yielding 248 events in 410 minutes. Their duration ranged from 33 to 283 ms, with an average of 98 ms. The luminous structures, generally not visible to the naked, dark-adapted eye, exhibited on video a wide variety of brightness levels and shapes including streaks, aurora-like curtains, smudges, fountains and jets. The structures were often more than 10 km wide and their upper portions extended to above 50 km msl.
Lyons, Walter A.↗
Catastrophic Collapse of Particulate Clouds: Implications From Aggregation Experiments in the USML-1 and USML-2 Glovebox
Experiments with electrostatic aggregation of well-dispersed (nominally, mono-dispersed), freely suspended particles in the United States Microgravity Laboratory (USML) Glovebox have determined that filamentary aggregates are a universal product of grain interactions in relatively dense particulate clouds. Aggregate growth from the experimental particle clouds primarily involves dipole-dipole interactions for nonconducting materials; dipole interactions account for both attraction between grains as well as the cohesive force that maintains the integrity of the filamentary structures. When a cloud undergoes a turbulent-to-quiescent transition after damping of fluid and ballistic grain motions, aggregation occurs almost instantaneously and the cloud is transformed into a population of "heavier" clusters of material with organized electrical structures. This abrupt transformation could initiate catastrophic gravitational collapse of certain regions of particulate clouds, thus controlling the longevity and fate of cloud systems as diverse as protoplanetary dust disks and volcanic eruption plumes.
Marshall, John↗
Numerical experiments on the clustering of galaxies
Consistent and robust growth rates for disturbances which lead to galaxy clustering are obtainable with a precision of 1-2 percent, in numerical experiments that encompass such conditions as expansion, nonexpansion, and parameter variations. The experiments have given attention to the dominant physical processes of gravitational clustering in an expanding universe of conventional matter, and are based on n-body integrations for 100,000 particles responding self-consistently to forces of self-gravitation with periodic boundary conditions. Observed structures of the scale of galaxy clusters and superclusters are most easily described in terms of matter swept away from growing empty regions. The result of this process has a cellular appearance which resembles clustering of the scale of large voids and superclusters.
Miller, R. H.↗
Mixed Valence {Ni 2+ Ni 1+ } Clusters as Models of Acetyl Coenzyme A Synthase Intermediates
Acetyl coenzyme A synthase (ACS) catalyzes the formation and deconstruction of the key biological metabolite, acetyl coenzyme A (acetyl-CoA). The active site of ACS features a {NiNi} cluster bridged to a [Fe4S4] n+ cubane known as the A-cluster. The mechanism by which the A-cluster functions is debated, with few model complexes able to replicate the oxidation states, coordination features, or reactivity proposed in the catalytic cycle. In this work, we isolate the first bimetallic models of two hypothesized intermediates on the paramagnetic pathway of the ACS function. The heteroligated {Ni 2+ Ni 1+ } cluster, [K(12-crown-4) 2 ][1], effectively replicates the coordination number and oxidation state of the proposed “A red ” state of the A-cluster. Addition of carbon monoxide to [1] - allows for isolation of a dinuclear {Ni 2+ Ni 1+ (CO)} complex, [K(12-crown-2) n ][2] (n = 1–2), which bears similarity to the “A NiFeC ” enzyme intermediate. Structural and electronic properties of each cluster are elucidated by X-ray diffraction, nuclear magnetic resonance, cyclic voltammetry, and UV/vis and electron paramagnetic resonance spectroscopies, which are supplemented by density functional theory (DFT) calculations. Calculations indicate that the pseudo-T-shaped geometry of the three-coordinate nickel in [1] – is more stable than the Y-conformation by 22 kcal mol –1 , and that binding of CO to Ni 1+ is barrierless and exergonic by 6 kcal mol –1 . UV/vis absorption spectroscopy on [2] - in conjunction with time-dependent DFT calculations indicates that the square-planar nickel site is involved in electron transfer to the CO π*-orbital. Further, we demonstrate that [2] - promotes thioester synthesis in a reaction analogous to the production of acetyl coenzyme A by ACS.
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
Cluster Analysis of Thermal Icequakes Using the Seismometer to Investigate Ice and Ocean Structure (SIIOS): Implications for Ocean World Seismology
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Angela Marusiak↗