Inelastic molecular collisions
Collision cross sections direct measurement for determining macroscopic reaction rates in inelastic molecular collision processes in gas dynamics
Utterback, N. G.↗
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Photon scattering by argon in the vacuum ultraviolet
Photon scattering by Ar in vacuum UV measured for cross sections
Cairns, R. B.↗
Vacuum-ultraviolet photon production in low- energy collisions between two neutral argon atoms
Vacuum UV photons production during ground state neutral argon atomic collisions, measuring relative cross sections energy dependence
Amme, R. C.↗
Energy transfer in planetary atmospheres - Optical spectroscopic studies Final technical report, 1 Dec. 1970 - 30 Mar. 1971
Laboratory measurement of cross sections for production of electronically excited species observed in atmospheres of planets
Broida, H. P.↗
Vibration study of clamped-free elliptical cylindrical shells
Thin shell isotropic clamped free elliptical cylindrical shells with various cross sectional eccentricities, measuring frequencies and mode shapes by vibration analysis
Pusey, C. G.↗
Dissociative excitation of vacuum ultraviolet emission features by electron impact on molecular gases. I - H2 and O2
Vacuum UV emission features dissociative excitation by electron impact on molecular hydrogen and oxygen, measuring excitation cross sections from threshold to 350 eV
Mumma, M. J.↗
Measurement of differential atomic collision cross sections.
An apparatus for the study of differential angular scattering of atomic projectiles by gas targets is described. The design facilitates system alignment and provides for accurate reproducible location of components. The performance of the instrument is studied for scattering of H+ at 5-25 keV energies by helium and argon targets. Differential cross sections for elastic scattering and charge transfer are presented as well as total charge transfer cross sections. The coefficients for secondary electron ejection by impact of H and H+ on a metal surface are compared.
Fitzwilson, R. L.↗
Excitation of atomic nitrogen by electron impact
Absolute cross sections were measured for the excitation of the N I(1134, 1164, 1168, 1200, 1243, and 1743 A) multiplets by electron impact on atomic nitrogen. The presence of vibrationally excited molecular nitrogen in the discharged gas was confirmed, and its effect on the measurements is discussed. The ratio of the oscillator strengths of the 1200 and 1134 A resonance transitions is presented, as well as the branching ratio for the N I(1311/1164 A) multiplets. Striking differences in the distribution of intensity between the spectra of atomic nitrogen and molecular nitrogen excited by energetic electrons suggest an optical method for measuring the density of atomic nitrogen in the upper atmosphere.
Stone, E. J.↗
The composite scattering model for radar sea return
A composite scattering model, suitable for explaining the behavior of measured scattering cross sections of the ocean surface, is presented. Furthermore, utilizing this scattering model, the spectrums of the small gravity, gravity-capillary, waves will be predicted for MSA/MSC, 13.3 GHz Scatterometer data.
Krishen, K.↗
Comparison of stratospheric ozone destruction by fluorocarbons 11, 12, 21, and 22
Measured photoabsorption cross sections for fluorocarbons (FC) 11, 12, 21, and 22 are presented for the wavelength region from 1740 A to about 2200 A. Solar radiation in this region dissociates these molecules in the stratosphere releasing atomic chlorine which participates in catalytic reactions that destroy ozone. Photolysis by solar UV is the only known loss mechanism for FC11 and FC12. However, FC21, and FC22 also react with OH in the troposphere reducing the amount of ground level releases which reach the stratosphere. Calculations comparing the steady state stratospheric C1X due to equal release rates of fluorocarbons 11, 12, 21, and 22 are presented using a range of OH profiles and eddy diffusion coefficients. These calculations indicate approximately a factor of 20 to 450 less C1X in the stratosphere for FC21 and a factor of 40 to 130 for FC22, compared to an equal release rate of FC11 and FC12.
Robbins, D. E.↗
Spectral studies of SiCl4 + N2O + Ar and SiH4 + Ar mixtures in a shock tube in 160-550 nm range
Gases containing SiO, SiO2, SiH, and Si2 were produced in the reflected-shock region of a shock tube by heating SiCl4 + N2O + Ar and SiH4 + Ar mixtures with shock waves. Spectral absorption characteristics were measured in the 160-550 nm wavelength range and in the 2800-3600 K temperature range and compared to calculated values. The sums of the squares of electronic transition moments at equilibrium separation were derived. It was found that absorption by SiO2 and other known bands of SiO, SiH, and Si2 were too weak to be measured. The cross section of absorption by a continuum, believed due to SiH, varied from 2.5 x 10 to the -17th sq cm at 280 nm to 1.6 x 10 to the -18th sq cm at 440 nm.
Park, C.↗
Radar observations of asteroids
Radar observations of asteroids use simple CW waveforms, the transmissions lasting for the duration of the round-trip delay. The echo is received, spectrum-analyzed, and integrated for a similar period. Since radar coherently illuminates the target, the surface scattering properties at radio wavelengths are directly determined as a function of angle and polarization. The distance and radial velocity obtained with radar complement the angular position of the object as determined from telescope measurements. Radar cross sections, scattering law, and radius are given for radar-observed asteroids.
Pettengill, G. H.↗
The ultraviolet dayglow. I - Far UV emissions of N and N2
Far ultraviolet rocket spectra of N I and N2 dayglow emissions have been analyzed by using AE-E photoelectron spectra, laboratory-measured excitation cross sections, and photochemical models of atomic nitrogen. A self-consistent picture of both optically thick and thin emission features is found by using a model in which the principal production mechanism for N I 1200-A and 1493-A photons is photodissociative excitation of N2. The aeronomic data require that 50-70% of the excited 4 P atoms produced dissociatively have velocities within the Doppler core of the ambient nitrogen atoms, contrary to the expectation that those atoms are produced with large excess kinetic energy. The derived atomic nitrogen density has a maximum density of 2.7 x 10 to the 7th per cu cm at 170 km, a value that is within 40% of that from recent models of odd nitrogen photochemistry.
Meier, R. R.↗
Atmospheric emission photometric imaging
A dual-channel video system mounted on a stabilized two-axis gimbal system (mounted on the pallet) with associated optics and data handling electronics described the low light flux observations are required for: (1) investigating ionospheric transport processes by observing Mg+ ions; (2) supporting magnetospheric electron bounce experiments; (3) measuring electron cross sections for selected atmospheric species; (4) detecting small particle contamination; and (5) studying natural auroras.
Mende, S. B.↗
The ionization equilibrium of astrophysically abundant elements
The paper presents new calculations of ionization equilibrium fractions of 11 abundant elements (C, N, O, Ne, Mg, Si, S, Ar, Ca, Fe, Ni) as functions of temperature. Convenient coefficients for fitting the rates of collisional ionization, radiative recombination, and dielectronic recombination are also tabulated. Many of the ionization rates are based on recent experimental measurements of cross sections for collisional ionization and autoionization following inner-shell excitation. These rates are used elsewhere in computations of nonequilibrium ionization, radiative cooling, radiative shock models, and plasma emission diagnostics.
Shull, J. M.↗
Precision ozone vapor pressure measurements
The vapor pressure above liquid ozone has been measured with a high accuracy over a temperature range of 85 to 95 K. At the boiling point of liquid argon (87.3 K) an ozone vapor pressure of 0.0403 Torr was obtained with an accuracy of + or - 0.7 percent. A least square fit of the data provided the Clausius-Clapeyron equation for liquid ozone; a latent heat of 82.7 cal/g was calculated. High-precision vapor pressure data are expected to aid research in atmospheric ozone measurements and in many laboratory ozone studies such as measurements of cross sections and reaction rates.
Hanson, D.↗
Hardware test program for evaluation of baseline range/range rate sensor concept
The test program Phase II effort provides additional design information in terms of range and range rate (R/R) sensor performance when observing and tracking a typical spacecraft target. The target used in the test program was a one-third scale model of the Hubble Space Telescope (HST) available at the MSFC test site where the tests were performed. A modified Bendix millimeter wave radar served as the R/R sensor test bed for evaluation of range and range rate tracking performance, and generation of radar signature characteristics of the spacecraft target. A summary of program test results and conclusions are presented along with detailed description of the Bendix test bed radar with accompaning instrumentation. The MSFC test site and facilities are described. The test procedures used to establish background levels, and the calibration procedures used in the range accuracy tests and RCS (radar cross section) signature measurements, are presented and a condensed version of the daily log kept during the 5 September through 17 September test period is also presented. The test program results are given starting with the RCS signature measurements, then continuing with range measurement accuracy test results and finally the range and range rate tracking accuracy test results.
Pernic, E.↗
CF2 and CFCl fluorescence from VUV excitation of C2F3Cl
The photoexcitation process of C2F3Cl molecule was investigated in the 106 to 230 nm region using synchrotron radiation as a light source. Photoabsorption and fluorescence cross sections were measured and used to determine the fluorescence quantum yield. Fluorescence yield starts to appear at 170 nm and increases to about 2% at 155 nm. The fluorescence spectra were dispersed to identify the emitting species. At the excitation wavelength of 155 nm, the emission system is CFCl (Hermitian conjugate of A - Hermitian conjugate of X), and at 123.9 nm, both the CF2 (Hermitian conjugate of A - Hermitian conjugate of X) and CFCl (Hermitian conjugate of A - Hermitian conjugate of X) systems are observed. The dissociation processes that produced these excited species are discussed.
Nee, J. B.↗