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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 361 records · Page 20

Hydrogen titanate nanotubes for dye sensitized solar cells applications: Experimental and theoretical study

Highlights: • Photoelectrode made of Hydrogen titanate nanotubes from H{sub 2}Ti{sub 3}O{sub 7}. • Solar cell efficiency enhancement from 5.95% to 7.63%. • Increase of Voc due to a decrease in the work function on HTNT. • Increase of Jsc due to an increase of the specific area of HTNT. - Abstract: The existent research literature of Dye Sensitized Solar Cells (DSSC) is mainly focused on the dye but there are very few studies focused in the semiconductor. Here, we present the performance of hydrogen titanate nanotubes (HTNT), showing an enhancement of the solar cell efficiency from 5.95% to 7.63%, respect to anatase as photoelectrode. This enhancement could be explained in terms of open-circuit voltage, directly associated to the value of the HTNT band gap (E{sub g} = 3.3 eV), the relative position of the edge conduction band; and the increase of the short-circuit current, directly associated to the enhancement of the specific area of the photoelectrode. All these characteristics are in very good concordance with our theoretical modelling of the system, based on First Principles calculations. We expect that this system could be further characterized, utilizing different dyes or absorbers, in order to evaluate the potential use of hydrogen titanate nanotubes for solar cell applications.

14 SOLAR ENERGY↗

Cyber Attack Resilient HVDC System (CARDS) (Final Scientific/Technical Report)

This report summarizes the activities conducted under the DOE-OE funded project DE-OE0000824, where ABB Inc. (ABB), in collaboration with University of Illinois at Urbana-Champaign (UIUC), Bonneville Power Administration (BPA), Argonne National Laboratories (ANL), and University of Idaho (UI) pursued the development of a system of defense for High Voltage Direct Current transmission systems against cyber-attacks (CARDS). An HVDC substation with CARDS features will be more capable of mitigating cyber-attacks especially those that seek to control or interrupt the power flow in the HVDC line. It empowers existing HVDC intelligent electronic devices to collaborate in identifying and blocking malicious intents to trip HVDC AC circuit breakers, block thyristor valves, misconfigure devices settings, even though the commands and the measurements comply with correct syntax. The CARDS functions utilize the physics of electromagnetic AC and DC systems, electric power engineering principles, and state estimation to bring more in-depth cyber defense closer to the protected HVDC substation devices. With the aim of advancing the state of the art, the team proceeded to develop a demonstrable system against cyber-attacks in an HVDC substation environment, via functional upgrades to existing firmware of commercial off-the-shelf HVDC station devices, and/or embedded hardware, without the need for additional instrumentation nor new instrumentation technologies. It is to ensure that the solutions resulting from the project will support the HVDC devices currently installed in the US electricity delivery infrastructure.

24 POWER TRANSMISSION AND DISTRIBUTION↗

Soft Magnetic Properties of Hf{sub x}Co{sub 100−x} Thin Films

Hf{sub x}Co{sub 100−x} thin films (in the atomic weight range of x = 30–36) were growth on Si (100) substrates by direct current (DC) magnetron sputtering method. Thin films produced with atomic compositions in this context depicted the amorphous structure. The films revealed soft magnetic properties and thus exhibited very low hysteresis along the hard-axis direction. Magnetic measurements indicated that Hf{sub 35}Co{sub 65} thin film has the maximum saturation magnetization (1491 emu cm{sup −3}) at 300 K. Additionally, magnetization measurements show an increase in saturation magnetization value from 981 to 1491 emu cm{sup −3} when the value of x varies between 30 and 35. The influence of varying sputtering pressure and film composition on soft magnetic properties are investigated and discussed in the present paper.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

Detection of electric current pulses by a fibre-optic sensor using spun fibre

We have studied distinctive features of the response of a fibre-optic current sensor with a spun-fibre sensing loop to short current pulses. It has been shown theoretically that, in a reflective interferometer, the polarisation mode dispersion (PMD) in the sensing spun fibre has no effect on the pulsed output signal of the sensor, in contrast to the PMD in a connecting fibre line. The response of the current sensor to a rectangular pulse has linear edges and its duration is determined by the relationship between the current pulse duration and the light propagation time in the spun fibre. The transition from a linear edge to the maximum sensor response is not accompanied by any transient process. The maximum response amplitude corresponds to the response to an equivalent direct current at a current pulse duration exceeding the light propagation time in the spun fibre. The present calculation results and experimental data agree well for current pulses longer than 300 ns at a light propagation time in the spun fibre of ∼1 μs. (fibre-optic sensors)

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

Optical current generation in graphene: CEP control vs. ω + 2 ω control

The injection of directional currents in solids with strong optical fields has attracted tremendous attention as a route to realize ultrafast electronics based on the quantum-mechanical nature of electrons at femto- to attosecond timescales. Such currents are usually the result of an asymmetric population distribution imprinted by the temporal symmetry of the driving field. Here we compare two experimental schemes that allow control over the amplitude and direction of light-field-driven currents excited in graphene. Both schemes rely on shaping the incident laser field with one parameter only: either the carrier-envelope phase (CEP) of a single laser pulse or the relative phase between pulses oscillating at angular frequencies ω and 2ω, both for comparable laser parameters. We observe that the efficiency in generating a current via two-color-control exceeds that of CEP control by more than two orders of magnitude (7 nA vs. 18 pA), as the ω + 2ω field exhibits significantly more asymmetry in its temporal shape. We support this finding with numerical simulations that clearly show that two-color current control in graphene is superior, even down to single-cycle pulse durations. We expect our results to be relevant to experimentally access fundamental properties of any solid at ultrafast timescales, as well as for the emerging field of petahertz electronics.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

Further Development of Crack Growth Detection Techniques for US Test and Research Reactors

One of the key issues facing Light Water Reactors (LWRs) in extending lifetimes beyond 60 years is characterizing the combined effect of irradiation and water chemistry on material degradation and failure. Irradiation Assisted Stress Corrosion Cracking (IASCC), in which a crack propagates in a susceptible material under stress in an aggressive environment, is a mechanism of particular concern. Full understanding of IASCC depends on real time crack growth data acquired under relevant irradiation conditions. Techniques to measure crack growth in actively loaded samples under irradiation have been developed outside the US - at the Halden Boiling Water Reactor, for example. Several types of IASCC tests have also been deployed at the MITR, including passively loaded crack growth measurements and actively loaded slow strain rate tests. However, there is not currently a facility available in the US to measure crack growth on actively loaded, pre-cracked specimens in LWR irradiation environments. A joint program between the Idaho National Laboratory (INL) and the Massachusetts Institute of Technology (MIT) Nuclear Reactor Laboratory (NRL) is currently underway to develop and demonstrate such a capability for US test and research reactors. Based on the Halden design, the samples will be loaded using miniature high pressure bellows and a compact loading mechanism, with crack length measured in real time using the switched Direct Current Potential Drop (DCPD) method. The basic design and initial mechanical testing of the load system and implementation of the DCPD method have been previously reported. This paper presents the results of initial autoclave testing at INL and the adaptation of the design for use in the high pressure, high temperature water loop at the MITR 6 MW research reactor, where an initial demonstration is planned in mid-2015. Materials considerations for the high pressure bellows are addressed. Design modifications to the loading mechanism required by the size constraints of the MITR water loop are described. The safety case for operation of the high pressure gas-driven bellows mechanism is also presented. Key issues are the design and response of systems to limit gas flow in the event of a high pressure gas leak in the in-core autoclave. Integrity of the autoclave must be maintained and reactivity effects due to voiding of the loop coolant must be shown to be within the reactor technical specifications. The technical development of the crack growth monitor for application in the INL Advanced Test Reactor or the MITR can act as a template for adaptation of this technology in other reactors. (authors)

21 SPECIFIC NUCLEAR REACTORS AND ASSOCIATED PLANTS↗

Alternating Current Photovoltaic Effect

It is well known that the photovoltaic effect produces a direct current (DC) under solar illumination owing to the directional separation of light-excited charge carriers at the p–n junction, with holes flowing to the p-side and electrons flowing to the n-side. In this study, we found that apart from the DC generated by the conventional p–n photovoltaic effect, there is another new type of photovoltaic effect that generates alternating current (AC) in the nonequilibrium states when the illumination light periodically shines at the junction/interface of materials. The peak current of AC at high switching frequency can be much higher than that from DC. The AC cannot be explained by the established mechanisms for conventional photovoltaics; instead, it is suggested to be a result of the relative shift and realignment between the quasi-Fermi levels of the semiconductors adjacent to the junction/interface under the nonequilibrium conditions, which results in electron flow in the external circuit back and forth to balance the potential difference between two electrodes. By virtue of this effect, the device can work as a high-performance broadband photodetector with extremely high sensitivity under zero bias; it can also work as a remote power source providing extra power output in addition to the conventional photovoltaic effect.

36 MATERIALS SCIENCE↗

Photochemically‐Driven CO 2 Release Using a Metastable‐State Photoacid for Energy Efficient Direct Air Capture

Abstract One of the grand challenges underlying current direct air capture (DAC) technologies relates to the intensive energy cost for sorbent regeneration and CO 2 release, making the massive scale (GtCO 2 /year) deployment required to have a positive impact on climate change economically unfeasible. This challenge underscores the critical need to develop new DAC processes with substantially reduced regeneration energies. Here, we report a photochemically‐driven approach for CO 2 release by exploiting the unique properties of an indazole metastable‐state photoacid (mPAH). Our measurements on simulated and amino acid‐based DAC systems revealed the potential of mPAH to be used for CO 2 release cycles by regulating pH changes and associated isomers driven by light. Upon irradiating with moderate intensity light, a ≈55 % and ≈68 % to ≈78 % conversion of total inorganic carbon to CO 2 was found for the simulated and amino acid‐based DAC systems, respectively. Our results confirm the feasibility of on‐demand CO 2 release under ambient conditions using light instead of heat, thereby providing an energy efficient pathway for the regeneration of DAC sorbents.

Premadasa, Uvinduni I.↗

Inclusion of ion orbit loss and intrinsic rotation in plasma fluid rotation theory

The preferential ion orbit loss of counter-current directed ions leaves a predominantly co-current ion distribution in the thermalized ions flowing outward through the plasma edge of tokamak plasmas, constituting a co-current intrinsic rotation. A methodology for representing this essentially kinetic phenomenon in plasma fluid theory is described and combined with a previously developed methodology of treating ion orbit particle and energy losses in fluid theory to provide a complete treatment of ion orbit loss in plasma fluid rotation theory.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Synchronverter-based Control of Multi-Port Autonomous Reconfigurable Solar Plants (MARS)

Control of integrated photovoltaic (PV) plants with energy storage systems (ESSs) has become an important research and development topic in recent times. In this context, a Multi-port Autonomous Reconfigurable Solar (MARS) plant that integrates PV and ESS to alternating current transmission grid and high-voltage direct current (HVdc) link is studied in this paper. With penetration of power electronic based resources in the grid, the grid’s capability to recover from frequency or voltage disturbances are reduced. Therefore, one of the vital objectives of any new grid integrated power electronic resource is to provide advanced control functions like voltage and frequency support to the grid during disturbances. In this research work, a detailed implementation of a synchronverter-based control algorithm of MARS is presented. The proposed control algorithm and the MARS control architecture are evaluated through simulations on PSCAD/EMTDC simulation platform to showcase the performance in different operating conditions. In addition, they are evaluated in Opal-RT offline simulation models which can also be used to perform control-hardware-in-the-loop (cHIL) tests.

Marthi, Phani Ratna Vanamali↗

Resistive-Aware Linear Approximations for Solving the Optimal Power Flow Problem for Distribution Networks

Although notable progress has been made to solve the Alternate Current (AC) Optimal Power Flow (OPF), the Direct Current (DC) and Decoupled OPF approximations are still preferable in broad scenarios of practical interest. These approximations typically assume that the resistive nature of the lines in the power system is negligible. This work discusses modifications of these assumptions and presents new approximations of the DC and Decoupled OPF in light of distribution systems, in which line resistances may not be negligible. The Enhanced DC (EDC) OPF and Coupled OPF (COPF) approximations are introduced and assessed, presenting favorable results compared to their classic counterparts.

Moutis, Panayiotis↗

Virtual Synchronous Generator Control of Multi-port Autonomous Reconfigurable Solar Plants (MARS)

Multi-port autonomous reconfigurable solar power plant (MARS) is an integrated concept for integration of solar photovoltaic (PV) and energy storage systems (ESS) to transmission alternating current (ac) grid and high-voltage direct current (HVdc) links. The integrated development incorporates advanced control methods to provide enhanced grid ancillary services such as fast frequency responses and dynamic voltage support. In this paper, the virtual synchronous generator (VSG) control algorithm of MARS is discussed. The proposed VSG-based control enables enhanced synthetic inertial response and flexible frequency response characteristics of hybrid PV and ESS power plants in accordance with grid ancillary service requirements. Multi-port power electronics interface allows controlled emergency power support from MARS to local transmission ac grid and remote grid through the HVdc link. The performance of VSG control is validated using a reduced-order model of MARS in Simulink. Methods for estimating grid ancillary service capabilities of MARS are also discussed.

Pan, Jiuping↗

Generation of longitudinal current by a transverse electromagnetic field in classical and quantum plasmas

A distribution function for collisionless plasma is derived from the Vlasov kinetic equation in the quadratic approximation with respect to the electromagnetic field. Formulas for calculation of the electric current at an arbitrary temperature (arbitrary degree of degeneration of the electron gas) are deduced. The case of small wavenumbers is considered. It is shown that nonlinearity leads to the generation of an electric current directed along the wave vector. This longitudinal current is orthogonal to the classical transverse current, well known in the linear theory. A distribution function for collisionless quantum plasma is derived from the kinetic equation with the Wigner integral in the quadratic approximation with respect to the vector potential. Formulas for calculation of the electric current at an arbitrary temperature are deduced. The case of small wavenumbers is considered. It is shown that, at small values of the wavenumber, the value of the longitudinal current for quantum plasma coincides with that for classical plasma. The dimensionless currents in quantum and classical plasmas are compared graphically.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗