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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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NASA NTRS1987

The interstellar medium toward SN 1987A

High-resolution spectra of SN 1987A obtained with the IUE satellite show absorption features from the disk and halo of the Galaxy and the LMC. A rich variety of elements and ionization states is found, including allowed resonance lines of abundant elements with ionization states ranging from C I and O I to Al III, Si IV, and C IV. The Si IV and C IV absorption at LMC velocities is unusually strong toward the supernova as compared to most other stars in the LMC and SMC. The origin of these lines is discussed.

Dupree, A. K.↗
NASA NTRS1990

Implications of abundance measurements of the intracluster medium

The potential implications of future measurements of the heavy-element abundances in intracluster gas are considered in the framework of the cold-dark-matter scenario of structure formation in the early universe (Blumenthal et al., 1984). Particular attention is given to the correlation between the M(gas)/M(stellar) ratio and the gas temperature in groups and clusters of galaxies found by Jones et al. (1989) and its relationship to the efficiency of galaxy formation. Quantitative predictions for the correlation between Fe abundance and gas temperature are presented in graphs and discussed in detail.

Forman, W.↗
NASA NTRS1979

Infrared and optical measurements of the ionized gas in K3-50

Results are reported for optical, near-IR, and mid-IR spectrophotometry of the compact H II region K3-50A. The emission-line observations imply an electron density of about 100,000 per cu cm; the consistency of density measurements in the optical, IR, and radio sources suggests that the optical counterpart of K3-50A is a reflection nebula. Previous measurements of the anomalous extinction law in K3-50A are confirmed, this law is extended out to B-alpha at 4 microns, and a 9-micron optical depth of about 2.5 is obtained. Elemental abundances are derived from measurements of emission lines of several dominant ions of the same element and found to be in close agreement (50%) with mean cosmic abundances. Individual ionic ratios are compared with model H II region calculations to determine the nature of the ionizing radiation. It is concluded that if nongray UV dust absorption does not modify the spectrum appreciably, the radiation temperature can be associated with a stellar surface temperature of about 37,000 K, corresponding to an O6 supergiant.

Lester, D. F.↗
NASA NTRS1979

The origin of metal clasts in the Bencubbin meteoritic breccia

The Bencubbin meteorite is a shock-welded breccia consisting of a diverse collection of metal and silicate clasts. Several types of evidence suggest that the metal clasts in Bencubbin retain chemical abundances that were established during condensation. The Cr, Ni, P and trace element abundances are consistent with condensation calculations and are much closer to the predicted compositions of metal condensates than the CM metal particles. In addition, petrographic and chemical evidence strongly suggest that the breccia components were incorporated as solid clasts within the breccia prior to a shock heating event of very short duration, which did not produce significant metamorphic effects.

Newsom, H. E.↗
NASA NTRS2004

Interstellar Dust Models Consistent with Extinction, Emission, and Abundance Constraints

We present new interstellar dust models which have been derived by simultaneously fitting the far ultraviolet to near infrared extinction, the diffuse infrared emission, and, unlike previous models, the elemental abundances in dust for the diffuse interstellar medium. We found that dust models consisting of a mixture of spherical graphite and silicate grains, polycyclic aromatic hydrocarbon (PAH) molecules, in addition to porous composite particles containing silicate, organic refractory, and water ice, provide an improved .t to the UV-to-infrared extinction and infrared emission measurements, while consuming the amounts of elements well within the uncertainties of adopted interstellar abundances, including B star abundances. These models are a signi.cant improvement over the recent Li & Draine (2001, ApJ, 554, 778) model which requires an excessive amount of silicon to be locked up in dust: 48 ppm (atoms per million of H atoms), considerably more than the solar abundance of 34 ppm or the B star abundance of 19 ppm.

Zubko, Viktor↗
NASA NTRS1972

Comparative petrology of Apollo 16 sample 68415 and Apollo 14 samples 14276 and 14310.

Petrographic and electron microprobe studies of Apollo 16 igneous rock 68415 and Apollo 14 rocks 14276 and 14310 show that all three samples differ from the mare basalts and are characterized by plagioclase as the first liquidus phase and by the abundance of plagioclase which is in part cumulate in origin. Major and minor element abundances and isotopic data prohibit the derivation of rocks like any of these samples from one another by magmatic fractionation during their crystallization. They could have originated by partial melting of an old, more Al-rich source material without isotopic equilibration with the residuum, by complete melting of three independent sources, or by contamination with old radiogenic material. The existence of such feldspathic basalts indicates that the generation of Al-rich magmas may have been an important and widespread lunar process.

Gancarz, A. J.↗
NASA NTRS1985

Variations in the propagation of UH-nuclei

Calculations of the propagation of UH-nuclei were improved by extending the number of individual nuclides considered, and by using more recent evaluations of the rigidity dependence of the escape length, the possible source composition, and altered cross sections. The effects of using different expressions for the dependence of abundances on first ionization potentials (FIP) are outlined. The sensitivity of the calculated elemental abundances to the various changes made in the propagation assumptions are discussed.

Waddington, C. J.↗
NASA NTRS1987

Volatile inventory of Mars-2: Primordial sources and fractionating processes

The total volatile inventory of Mars has been modeled using meteoritic and presumed primordial abundances in the early solar system. Evidence is presented which indicates that the elemental abundances of the noble gases on Earth and Mars are similar, and their ratios are comparable to those in average carbonaceous chondrites with the exception of xenon and krypton. In order to account for presently observed variations in gas abundances, two primordial sources were used. One was the solar composition similar to the solar wind, and the other of carbonaceous grains that were the source for trace exotic components. For Mars, a model in which the early, high solar EUV flux with continued hydrogen production by differentiation results in mass fractionation of the primordial atmosphere, early depletion of xenon, and later depletion of gases lighter than krypton. The result is that the primordial Mars water inventory may have been on the order of 20 to 30 km if spread over the planet.

Pepin, R. O.↗
NASA NTRS1993

Composition of metal in aubrites - Constraints on core formation

Aubrites are differentiated stone meteorites with small amounts of metal. Study of eight aubrites reveals that Fe,Ni grains occur in a variety of textures, from irregular micron-sized particles to rounded nodules of up to 1.5 cm in diameter. The pattern of siderophile element abundances in the silicates is characteristic of igneous metal segregation (the more siderophilic elements are more depleted). Despite large uncertainties in metal/silicate distribution coefficients, the calculated minimum metal content of the aubrite precursor is not unlike that of enstatite chondrites and suggests that metal segregation was an extensive process in the early magmatic evolution of the aubrite parent body. However, the lack of appreciable fractionation in the trace element signature of the metal suggests that the metal now observed in aubrites did not undergo fractional crystallization in a core. We argue instead that the analyzed metal nodules represent a fraction of the iron-nickel that, during partial melting, was not completely segregated from the silicates.

Casanova, Ignacio↗
NASA NTRS1997

Discovery of Interstellar Hydrogen Fluoride

We report the first detection of interstellar hydrogen fluoride. Using the Long Wavelength Spectrometer of the Infrared Space Observatory (ISO), we have detected the 121.6973 micron J = 2-1 line of HF in absorption toward the far-infrared continuum source Sagittarius B2. The detection is statistically significant at the 13 sigma level. On the basis of our model for the excitation of HF in Sgr B2, the observed line equivalent width of 1.0 nm implies a hydrogen fluoride abundance of about 3 x 10 (exp -10) relative to H, If the elemental abundance of fluorine in Sgr B2 is the same as that in the solar system, then HF accounts for about 2% of the total number of fluorine nuclei. We expect hydrogen fluoride to be the dominant reservoir of gas-phase fluorine in Sgr B2, because it is formed rapidly in exothermic reactions of atomic fluorine with either water or molecular hydrogen; thus, the measured HF abundance suggests a substantial depletion of fluorine onto dust grains. Similar conclusions regarding depletion have previously been reached for the case of chlorine in dense interstellar clouds. We also find evidence at a lower level of statistical significance (about 5 sigma) for an emission feature at the expected position of the 4(sub 32)-4(sub 23) 121.7219 micron line of water. The emission-line equivalent width of 0.5 mm for the water feature is consistent with the water abundance of 5 x 10(exp -6) relative to H, that has been inferred previously from observations of the hot core of Sgr B2.

Neufeld, David A.↗
NASA NTRS1997

Discovery of Interstellar Hydrogen Fluoride

We report the first detection of interstellar hydrogen fluoride. Using the Long Wavelength Spectrometer of the Infrared Space Observatory (ISO), we have detected the 121.6973 micron J = 2-1 line of HF in absorption toward the far-infrared continuum source Sagittarius B2. The detection is statistically significant at the 13 sigma level. On the basis of our model for the excitation of HF in Sgr B2, the observed line equivalent width of 1.0 nm implies a hydrogen fluoride abundance of approximately 3 x 10(exp -10) relative to H2. If the elemental abundance of fluorine in Sgr B2 is the same as that in the solar system, then HF accounts for approximately 2% of the total number of fluorine nuclei. We expect hydrogen fluoride to be the dominant reservoir of gas-phase fluorine in Sgr B2, because it is formed rapidly in exothermic reactions of atomic fluorine with either water or molecular hydrogen; thus, the measured HF abundance suggests a substantial depletion of fluorine onto dust grains. Similar conclusions regarding depletion have previously been reached for the case of chlorine in dense interstellar clouds. We also find evidence at a lower level of statistical significance (approximately 5 sigma) for an emission feature at the expected position of the 4(sub 32)-4(sub 23) 121.7219 micron line of water. The emission-line equivalent width of 0.5 nm for the water feature is consistent with the water abundance of 5 x 10(exp -6) relative to H2 that has been inferred previously from observations of the hot core of Sgr B2.

Neufeld, David A.↗
NASA NTRS2006

SIMS Studies of Allende Projectiles Fired into Stardust-type Aluminum Foils at 6 km/s

We have explored the feasibility of C-, N-, and O-isotopic measurements by NanoSIMS and of elemental abundance determinations by TOF-SIMS on residues of Allende projectiles that impacted Stardust-type aluminum foils in the laboratory at 6 km/s. These investigations are part of a consortium study aimed at providing the foundation for the characterization of matter associated with micro-craters that were produced during the encounter of the Stardust space probe with comet 81P/Wild 2. Eleven experimental impact craters were studied by NanoSIMS and eighteen by TOF-SIMS. Crater sizes were between 3 and 190 microns. The NanoSIMS measurements have shown that the crater morphology has only a minor effect on spatial resolution and on instrumental mass fractionation. The achievable spatial resolution is always better than 200 nm, and C- and O-isotopic ratios can be measured with a precision of several percent at a scale of several 100 nm, the typical size of presolar grains. This clearly demonstrates that presolar matter, provided it survives the impact into the aluminum foil partly intact, is recognizable even if embedded in material of Solar System origin. TOF-SIMS studies are restricted to materials from the crater rim. The element ratios of the major rockforming elements in the Allende projectiles are well characterized by the TOF-SIMS measurements, indicating that fractionation of those elements during impact can be expected to be negligible. This permits information on the type of impactor material to be obtained. For any more detailed assignments to specific chondrite groups, however, information on the abundances of the light elements, especially C, is crucial.

Hoppe, Peter↗
NASA NTRS1981

Abundance enhancements in cosmic rays produced by collisionless shocks

It is shown that shocks preferentially accelerate partially ionized heavy elements over protons. Within the framework of a previously published model of injection, the spectra of different ion species are calculated from thermal to ultrarelativistic energies. For typical astrophysical parameters, the predicted enhancement is in qualitative agreement with observations for a 10 to the 6th K preshock plasma; ions with Z greater than 10 are enhanced by about an order of magnitude or so. The continuing increase with energy of the heavy-element abundances into the air-shower regime is discussed.

Eichler, D.↗
NASA NTRS1993

Lewis Cliff 87057: A new metal-rich E3 chondrite with similarities to Mt. Egerton, Shallowater and Happy Canyon

The Antarctic meteorites LEW87057, LEW87220, LEW87223, LEW87234, LEW87237, and LEW87285 were described as paired E3 chondrites by Brian Mason (Antarctic Meteorite Newsletters, 12(1) and 15(1,2)). LEW87223 is texturally unusual, containing abundant chondrules and jagged troilite grains which are enclosed in metal. Our INAA data show that the siderophile element abundance in two splits of LEW87223 are higher than the EH range, while chalcophile elements (Cr excepted) are highly depleted. Mineral compositions are unlike those normally found in EH or EL chondrites or aubites, and in some respects resemble those of several anomalous enstatite meteorites such as Shallowater, Mt. Egerton, and Happy Canyon. The bulk and mineral compositions are consistent with the addition of EL chondrite metal to an EL3 chondrite with the removal of sulfides other than troilite which is now Cr-rich. We suggest that this meteorite is an EL3 chondrite into which metal was introduced and sulfides redistributed during an event involving impact melting and brecciation.

Zhang, Y.↗
NASA NTRS1997

The Complex Stratigraphy of the Highland Crust in the Serenitatis Region of the Moon Inferred from Mineral Fragment Chemistry

Large impact basins are natural drill holes into the Moon, and their ejecta carries unique information about the rock types and stratigraphy of the lunar crust. We have conducted an electron microprobe study of mineral fragments in the poikilitic melt breccias collected from the Taurus Mountains at the Apollo 17 landing site. These breccias are virtually unanimously agreed to be impact melt produced in the Serenitatis impact event. They contain lithic fragments and much more abundant mineral fragments of crustal origin. We have made precise microprobe analyses of minor element abundances in fragments of olivine, pyroxene, and plagioclase to provide new information on the possible source rocks and the crustal stratigraphy in the Serenitatis region. These data were also intended to elucidate the nature of the cryptic geochemical component in breccias such as these with low-K Fra Mauro basalt compositions. We chose the finest-grained (i.e., most rapidly quenched) breccias for study, to avoid reacted and partly assimilated fragments as much as possible. Most of the mineral fragments appear to have been derived from rocks that would fall into the pristine igneous Mg-suite as represented by lithic fragments in the Apollo collection, or reasonable extensions of it. Gabbroic rocks were more abundant in the target stratigraphy than is apparent from the Apollo sample collection. Some pyroxene and plagiociase, but probably not much olivine, could be derived from feldspathic granulites, which are metamorphosed polymict breccias. Some mineral fragments are from previously unknown rocks. These include highly magnesian olivines (up to Fo(sub 94)), possibly volcanic in origin, that exacerbate the difficulty in explaining highly magnesian rocks in the lunar crust. It appears that some part of the lunar interior has an mg*(= 100 x Mg/(Mg/Fe) atomic) greater than the conventional bulk Moon value of 80-84. Other volcanic rocks, including mare basalts, and rapidly- cooled impact melt rocks do not contribute significantly to the fragment population. Nor do ferroan anorthosites contribute more than a tiny part of even the plagiociase fragment population. A few mineral fragments that are consistent with the cryptic low-K Fra Mauro chemical component were found, and these appear to be from gabbroic sources. The mineral fragment populations cannot be mixed in their observed proportions to produce the whole rock composition, because the fragments are more refractory and deficient in Ti, P, and alkalis. A preferential contribution to the melt from a rock similar to sodic ferrogabbro can partly resolve the discrepancy. The population of mineral fragments requires a very diverse population of igenous rocks that are not all related to each other, demonstrating the existence of a complex crust built of numerous separate igneous plutons. Many of these plutons may have crystallized at shallow depths. The chemical composition of the melt breccias, in combination with the mineral fragment data and an understanding of the cratering process, suggests that the deepest crust sampled by the Serenitatis impace (not necessarily the deepest crust) was basaltic in composition, including KREEP and gabbroic rocks like sodic ferrogabbro, and lacking abundant olivine-rich material. These were overlain by Mg-suite rocks of varied types, including norites and troctolites that supplied most of the olivine mineral fragments. Granulities, which are metamorphosed and more feldspathic breccias, were abundant near the surface. Remote sensing indicates that the entire Serenitatis region lacks ferroan anorthosite, consistent with the results of our study.

Ryder, Graham↗
NASA NTRS1999

Interrelationships Between Aerosol Characteristics and Light Scattering During Late-winter in a Eastern Mediterranean Arid Environment

An intensive field campaign involving measurement of various aerosol physical, chemical, and radiative properties was conducted at Sde Boker in the Negev Desert of Israel, from 18 February to 15 March 1997. Nephelometer measurements gave average background scattering coefficient values of about 25 M/m at 550 nm wavelength, but strong dust events caused the value of this parameter to rise up to about 800 M/m Backscattering fractions did not depend on aerosol loading, and generally fell in the range of 0.1 to 0.25, comparable to values reported for marine and Arctic environments. Chemical analysis of the aerosol revealed that, in the coarse size range (2 - 10 micrometer equivalent aerodynamic diameter (EAD)), calcium (Ca) was by far the most abundant element followed by silicon (Si), both of which are indicators for mineral dust. In the fine size fraction (< 2 micrometers EAD), sulfur (S) generally was the dominant element, except during high dust episodes when Ca and Si were again the most abundant. Furthermore, fine black carbon (BC) correlates with S, suggesting that they may have originated from the same sources or source regions. An indication of the short-term effect of aerosol loading on radiative forcing was provided by measurements of global and diffuse solar radiation, which showed that during high turbidity periods (strong dust events) almost all of the solar radiation reaching the area is scattered or absorbed.

Ichoku, C.↗