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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 361 records · Page 20

A laser flash photolysis-resonance fluorescence kinetics study of the reaction Cl/2P/ + CH4 yields CH3 + HCl

The technique of laser flash photolysis-resonance fluorescence is employed to study the kinetics of the reaction Cl(2P) + CH4 yields CH3 + HCl over the temperature range 221-375 K. At temperatures less than or equal to 241 K the apparent bimolecular rate constant is found to be dependent upon the identity of the chemically inert gases in the reaction mixture. For Cl2/CH4/He reaction mixtures (total pressure = 50 torr) different bimolecular rate constants are measured at low and high methane concentrations. For Cl2/CH4/CCl/He and Cl2/CH4/Ar reaction mixtures, the bimolecular rate constant is independent of methane concentration, being approximately equal to the rate constant measured at low methane concentrations for Cl2/CH4/He mixtures. These rate constants are in good agreement with previous results obtained using the discharge flow-resonance fluorescence and competitive chlorination techniques. At 298 K the measured bimolecular rate constant is independent of the identity of the chemically inert gases in the reaction mixture and in good agreement with all previous investigations. The low-temperature results obtained in this investigation and all previous investigations can be rationalized in terms of a model which assumes that the Cl(2P 1/2) state reacts with CH4 much faster than the Cl(2P 3/2) state. Extrapolation of this model to higher temperatures, however, is not straightforward.

Ravishankara, A. R.↗

Daylight spectra of individual lightning flashes in the 370-690 nm region

An optical multichannel analyzer slit spectrometer coupled to a minicomputer was used to record lightning spectra. This is the first successful application of a slit spectrometer to the study of individual lightning flashes and it was accomplished in the daytime. Over 300 spectra were obtained in 1978 and 1979 and are correlated with other experiments in the Thunderstorm Research International Program (TRIP). The spectra duplicate previously published nighttime data but reveal for the first time the relative intensity of H-alpha (656.3 nm) and H-beta (486.1 nm) emissions above their daytime absorption features. These are the characteristic Fraunhofer C and F lines in the solar spectrum. This result suggests that the observation of lightning from space may be accomplished by monitoring the hydrogen emissions from lightning which occur on earth, or on other planets with hydrogen in their atmospheres, such as Jupiter and Venus where lightning recently has been reported.

Orville, R. E.↗

The thermonuclear-flash model for X-ray burst sources - A new tool for observing neutron stars

The helium-flash model for X-ray burst sources, in which matter is presumed to accrete onto the surface of a neutron star, is discussed. Attention is given to the accretion process, nuclear burning, X-ray emission, and the energy released by convection as well as by radiative diffusion near the surface. The rise times of observed bursts, their spectral evolution, and the properties of the spectrally soft X-ray transients are considered. Problems in interpreting the continuum spectra are discussed, along with problems in the detection and measurement of line features in the spectra. Also considered are the ratio of time-averaged persistent luminosity to time-averaged burst luminosity, peak burst luminosities, and the possibility of detecting binary membership for burst sources.

Joss, P. C.↗

Lightning source locations from VHF radiation data for a flash at Kennedy Space Center

Three dimensional locations are presented for the VHF (30-50 MHz) radiation sources generated by a three-stroke lightning flash at the Kennedy Space Center. The locations were obtained by calculating the difference in time of arrival (DTOA) of radiated pulses at four ground stations. A computer-implemented multiple time series analysis was used in calculating DTOA data. The locations of the approximately 48,000 sequential VHF sources are compared with wide band electric-field records to provide a better understanding of the physics of lightning discharge.

Rustan, P. L.↗

Thermodynamic performance testing of the orbiter flash evaporator system

System level testing of the space shuttle orbiter's development flash evaporator system (FES) was performed in a thermal vacuum chamber capable of simulating ambient ascent, orbital, and entry temperature and pressure profiles. The test article included the evaporator assembly, high load and topping exhaust duct and nozzle assemblies, and feedwater supply assembly. Steady state and transient heat load, water pressure/temperature and ambient pressure/temperature profiles were imposed by especially designed supporting test hardware. Testing in 1978 verified evaporator and duct heater thermal design, determined FES performance boundaries, and assessed topping evaporator plume characteristics. Testing in 1979 combined the FES with the other systems in the orbiter active thermal control subsystem (ATCS). The FES met or exceeded all nominal and contingency performance requirements during operation with the integrated ATCS. During both tests stability problems were encountered during steady state operations which resulted in subsequent design changes to the water spray nozzle and valve plate assemblies.

Jaax, J. R.↗

Effects of the Shuttle Orbiter fuselage and elevon on the molecular distribution of water vapor from the flash evaporator system

A concern has arisen regarding the emissive distribution of water molecules from the shuttle orbiter flash evaporator system (FES). The role of the orbiter fuselage and elevon in affecting molecular scattering distributions was nuclear. The effect of these components were evaluated. Molecular distributions of the water vapor effluents from the FE were measured. These data were compared with analytically predicted values and the resulting implications were calculated.

Richmond, R. G.↗

A photochemical study of the kinetics of the reactions of NH2 with phosphine, ethylene, and acetylene using flash photolysis-laser induced fluorescence

The photochemistry of the reactions of NH2 was investigated in an attempt to explain the existence of an abundance of ammonia in the Jovian atmosphere. The production of ammonia reservoirs from the coupling of ammonia with other atmospheric constituents was considered. The rate constants for the reactions of NH2 radicals with phosphine, acetylene, and ethylene were measured. Flash photolysis was used for the production of NH2 radicals and laser induced fluorescence was employed for radical detection. It was determined that the rates of the reactions were too slow to be significant as a source of ammonia reservoirs in the Jovian atmosphere.

Bosco, S. R.↗

Electric fields preceding cloud-to-ground lightning flashes

A detailed analysis is presented of the electric-field variations preceding the first return strokes of 80 cloud-to-ground lightning flashes in nine different storms observed at the NASA Kennedy Space Center during the summers of 1976 and 1977. It is suggested that the electric-field variations can best be characterized as having two sections: preliminary variations and stepped leader. The stepped-leader change begins during a transition period of a few milliseconds marked by characteristic bipolar pulses; the duration of stepped leaders lies most frequently in the 6-20 millisecond range. It is also suggested that there is only one type of stepped leader, not two types (alpha and beta) often referred to in the literature.

Beasley, W.↗

Shuttle orbiter flash evaporator operational flight test performance

The Flash evaporator System (FES is part of the Shuttle Orbiter Active Thermal Control Subsystem. The FES provides total heat rejection for the vehicle Freon Coolant Loops during ascent and entry and supplementary heat rejection during orbital mission phases. This paper reviews the performance of the FES during the first two Shuttle orbital missions (STS-1 and STS-2). A comparison of actual mission performance against design requirements is presented. Mission profiles (including Freon inlet temperature and feedwater pressure transients), control temperature, and heat load variations are evaluated. Anomalies that occurred during STS-2 are discussed along with the procedures conducted, both in-flight and post-flight, to isolate the causes. Finally, the causes of the anomalies and resulting corrective action taken for STS-3 and subsequent flights are presented.

Nason, J. R.↗

Lightning flash density versus altitude and storm structure from observations with UHF- and S-band radars

The UHF-(70.5 cm wavelength) and S-band (10 cm wavelength) radar at NASA/Wallops Island Research Facility in Virginia, U.S.A. have been used to relate lightning activity with altitude and with the reflectivity structure of thunderstorms. Two centers of lightning flash density were found; one between 6 and 8 km altitude and another between 11 and 15 km. Previously announced in STAR as N83-31206

Mazur, V.↗

Correlated observations of three triggered lightning flashes

Three triggered lightning flashes, initiated during the Thunderstorm Research International Program (1981) at Langmuir Laboratory, New Mexico, are examined on the basis of three-dimensional return stroke propagation speeds and peak currents. Nonlinear relationships result between return stroke propagation speed and stroke peak current for 56 strokes, and between return stroke propagation speed and dart leader propagation speed for 32 strokes. Calculated linear correlation coefficients include dart leader propagation speed and ensuing return stroke peak current (32 strokes; r = 0.84); and stroke peak current and interstroke interval (69 strokes; r = 0.57). Earlier natural lightning data do not concur with the weak positive correlation between dart leader propagation speed and interstroke interval. Therefore, application of triggered lightning results to natural lightning phenomena must be made with certain caveats. Mean values are included for the three-dimensional return stroke propagation speed and for the three-dimensional dart leader propagation speed.

Idone, V. P.↗

Three unusual strokes in a triggered lightning flash

Time-resolved photographic records of three strokes of a triggered lightning flash are examined. These strokes exhibit several examples of novel behavior that include (1) the abrupt transformation of dart leaders to stepped leaders and (2) the partial 'reflection' of dart leader luminosity back up the channel. Both phenomena are associated with an apparent discontinuity in channel characteristics between the natural and artificial (wire) sections of the channel. We estimate the ratio of characteristic impedances for these sections to have an upper bound of about a factor of 3. Analysis of one of the dart leader 'reflections' yields a propagation speed of 9.6 x 10 to the 7th m/s whereas the dart leader and return stroke speeds (two-dimensional) over the same channel section are 1.7 x 10 to the 7th and 13 x 10 to the seventh m/s, respectively. Also, one of the return strokes reveals the occurrence of two distinct waves of luminosity that are separated by only 5 microns and that travel up nearly identical channels that differ only in the channel terminus.

Idone, V. P.↗

Direct-strike lightning photographs, swept-flash attachment patterns, and flight conditions for storm hazards 1982

As part of the NASA Langley Research Center Storm Hazards Program, 241 thunderstorm penetrations were made in 1982 with an F-106B airplane in order to record direct-strike lightning data and the associated flight conditions. During these penetrations, the airplane received 156 direct lightning strikes; in addition, lightning transient data were recorded from 26 nearby lightning flashes. The tests were conducted within 150 nautical miles of Hampton, Virginia, assisted by ground-based weather-radar guidance from the NASA Wallops Flight Facility. The photographs of the lightning attachments taken from two onboard 16-mm color movie cameras and the associated strike attachment patterns are presented. A table of the flight conditions recorded at the time of each lightning event, and a table in which the data are cross-referenced with the previously published lightning electromagnetic waveform data are included.

Zaepfel, K. P.↗

The Space Shuttle Orbiter molecular environment induced by the supplemental flash evaporator system

The water vapor environment of the Space Shuttle Orbiter induced by the supplemental flash evaporator during the on-orbit flight phase has been analyzed based on Space II model predictions and orbital flight measurements. Model data of local density, column density, and return flux are presented. Results of return flux measurements with a mass spectrometer during STS-2 and of direct flux measurements during STS-4 are discussed and compared with model predictions.

Ehlers, H. K. F.↗

Forming Solar-Cell Junctions By Flash Diffusion

Modified fabrication process simultaneously forms front and back junctions of silicon photovoltaic cells. With flash diffusion, junctions formed in 10 to 20 seconds. Cost reductions of 25 to 30 percent expected with modified process. Devices produced have performance equal to or better than cells made by conventional diffusion.

Alexander, Paul, Jr.↗

Laboratory studies of the deposition of alkali sulfate vapors from combustion gases using a flash-evaporation technique

A relatively simple experimental technique is proposed and demonstrated for making measurements of absolute dewpoints and relative deposition rates from flowing combustion gases containing condensible inorganic vapors. The method involves first accumulating condensate on a Pt ribbon target maintained below the dewpoint and then flash-evaporating the condensate into the filament wake, where its alkali content is monitored by alkali-atom emission spectroscopy. The advantages of the method over others are demonstrated; in particular, the method can detect liquid condensate inventories which are small enough to be negligibly influenced by surface runoff produced by gas-side shear stress and liquid condensate surface tension gradients. Illustrative Na2SO4 and K2SO4 deposition rate data and corresponding dewpoint data obtained in a series of alkali-seeded propane/air atmospheric flames are presented and discussed.

Rosner, Daniel E.↗