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Characterization of Mineralogy Across Vesta

Dawn VIR spectra are characterized by pyroxene absorptions and no clear evidence for abundant other minerals are observed at the scale of the present measurements. Even though Vesta spectra are dominated by pyroxenes, spectral variation at regional and local scales are evident and distinct color units are identified. Although almost all of the surface materials exhibit spectra like those of howardites, some large units can be interpreted to be material richer in diogenite (based on pyroxenes band depths and band centers) and some others like eucrite-rich howardite units. VIR data strongly indicate that the south polar region (Rheasilvia) has its own spectral characteristics, indicating the presence of Mg-pyroxene-rich terrains (diogenite-like), while the equatorial areas have swallower band depths and average band centers at slightly longer wavelengths, consistent with more eucrite rich materials. Vesta surface shows considerable diversity at smaller scales (tens of km), in terms of spectral reflectance and emission, band depths and slopes. Many bright and dark spots are present on Vesta. Dark spots have low reflectance at visible wavelengths and are spectrally characterized by shallower 1 and 2 micron bands with respect the surrounding terrains. Bright materials have high reflectance and are often spectrally characterized by deep pyroxenes absorption bands. Vesta presents complex geology/topography and the mineral distribution is often correlated with geological and topographical structures. Ejecta from large craters have distinct spectral behaviors, and materials exposed in the craters show distinct spectra on floors and rims. VIR reveals the mineralogical variation of Vesta s crustal stratigraphy on local and global scales. Maps of spectral parameters show surface and subsurface unit compositions in their stratigraphic context. The hypothesis that Vesta is the HED parent body is consistent with, and strengthened by, the geologic and spectral context for pyroxene distribution provided by Dawn.

De Sanctis, M. C.↗

Landsat Data Continuity Mission Calibration and Validation

The primary payload for the Landsat Data Continuity Mission (LDCM) is the Operational Land Imager (OLI), being built by Ball Aerospace and Technologies, under contract to NASA. The OLI has spectral bands similar to the Landsat-7 ETM+, minus the thermal band and with two new bands, a 443 nm band and 1375 nm cirrus detection band. On-board calibration systems include two solar diffusers (routine and pristine), a shutter and three sets of internal lamps (routine, backup and pristine). Being a pushbroom opposed to a whiskbroom design of ETM+, the system poses new challenges for characterization and calibration, chief among them being the large focal plane with 75000+ detectors. A comprehensive characterization and calibration plan is in place for the instrument and the data throughout the mission including Ball, NASA and the United States Geological Survey, which will take over operations of LDCM after on-orbit commissioning. Driving radiometric calibration requirements for OLI data include radiance calibration to 5% uncertainty (1 q); reflectance calibration to 3% uncertainty (1 q) and relative (detector-to-detector) calibration to 0.5% (J (r). Driving geometric calibration requirements for OLI include bandto- band registration of 4.5 meters (90% confidence), absolute geodetic accuracy of 65 meters (90% CE) and relative geodetic accuracy of 25 meters (90% CE). Key spectral, spatial and radiometric characterization of the OLI will occur in thermal vacuum at Ball Aerospace. During commissioning the OLI will be characterized and calibrated using celestial (sun, moon, stars) sources and terrestrial sources. The USGS EROS ground processing system will incorporate an image assessment system similar to Landsat-7 for characterization and calibration. This system will have the added benefit that characterization data will be extracted as part of the normal image data processing, so that the characterization data available will be significantly larger than for Landsat-7 ETM+.

Markham, Brian L.↗

Landsat-8 Sensor Characterization and Calibration

Landsat-8 was launched on 11 February 2013 with two new Earth Imaging sensors to provide a continued data record with the previous Landsats. For Landsat-8, pushbroom technology was adopted, and the reflective bands and thermal bands were split into two instruments. The Operational Land Imager (OLI) is the reflective band sensor and the Thermal Infrared Sensor (TIRS), the thermal. In addition to these fundamental changes, bands were added, spectral bandpasses were refined, dynamic range and data quantization were improved, and numerous other enhancements were implemented. As in previous Landsat missions, the National Aeronautics and Space Administration (NASA) and United States Geological Survey (USGS) cooperated in the development, launch and operation of the Landsat- 8 mission. One key aspect of this cooperation was in the characterization and calibration of the instruments and their data. This Special Issue documents the efforts of the joint USGS and NASA calibration team and affiliates to characterize the new sensors and their data for the benefit of the scientific and application users of the Landsat archive. A key scientific use of Landsat data is to assess changes in the land-use and land cover of the Earth's surface over the now 43-year record. In order to perform these analyses and avoid confusing sensor changes with Earth surface changes, a solid understanding of the sensors' performance, consistent geolocation and radiometry are essential. Particularly with the significant changes in the Landsat-8 sensors relative to previous Landsat missions, this characterization becomes all the more important.

Radiometry↗

Field Characterization of the Mineralogy and Organic Chemistry of Carbonates from the 2010 Arctic Mars Analog Svalbard Expedition by Evolved Gas Analysis

The 2010 Arctic Mars Analog Svalbard Expedition (AMASE) investigated two geologic settings using methodologies and techniques being developed or considered for future Mars missions, such as the Mars Science Laboratory (MSL), ExoMars, and Mars Sample Return. The Sample Analysis at Mars (SAM) [1] instrument suite, which will be on MSL, consists of a quadrupole mass spectrometer (QMS), a gas chromatograph (GC), and a tunable laser mass spectrometer (TLS); all will be applied to analyze gases created by pyrolysis of samples. During AMASE, a Hiden Evolved Gas Analysis-Mass Spectrometer (EGA-MS) system represented the EGA-MS capability of SAM. Another MSL instrument, CheMin, will use x-ray diffraction (XRD) and x-ray fluorescence (XRF) to perform quantitative mineralogical characterization of samples [e.g., 2]. Field-portable versions of CheMin were used during AMASE. AMASE 2010 focused on two sites that represented biotic and abiotic analogs. The abiotic site was the basaltic Sigurdfjell vent complex, which contains Mars-analog carbonate cements including carbonate globules which are excellent analogs for the globules in the ALH84001 martian meteorite [e.g., 3, 4]. The biotic site was the Knorringfjell fossil methane seep, which featured carbonates precipitated in a methane-supported chemosynthetic community [5]. This contribution focuses on EGA-MS analyses of samples from each site, with mineralogy comparisons to CheMin team results. The results give insight into organic content and organic-mineral associations, as well as some constraints on the minerals present.

McAdam, A. C.↗

Derivation of surface properties from Magellan altimetry data

The fit of the Hagfors model to the Magellan altimetry data provides a means to characterize the surface properties of Venus. However, the derived surface properties are only meaningful if the model provides a good representation of the data. The Hagfors model provides a good representation of the data. The Hagfors model is generally a realistic fit to surface scattering properties of a nadir-directed antenna such as the Magellan altimeter; however, some regions of the surface of Venus are poorly described by the existing model, according to the goodness of fit parameter provided on the ARCDR CD-ROMs. Poorly characterized regions need to be identified and fit to new models in order to derive more accurate surface properties for use in inferring the geological processes that affect the surface in those regions. We have compared the goodness of fit of the Hagfors model to the distribution of features across the planet, and preliminary results show a correlation between steep topographic slopes and poor fits to the standard model, as has been noticed by others. In this paper, we investigate possible relations between many classes of features and the ability of the Hagfors model to fit the observed echo profiles. In the regions that are not well characterized by existing models, we calculate new models that compensate for topographic relief in order to derive improved estimates of surface properties. Areas investigated to date span from longitude 315 through 45, at all latitudes covered by Magellan. A survey of those areas yields preliminary results that suggest that topographically high regions are well suited to the current implementation of the Hagfors model. Striking examples of such large-scale good fits are Alpha Regio, the northern edges of Lada Terra, and the southern edge of Ishtar Terra. Other features that are typically well fit are the rims of coronae such as Heng-O and the peaks of volcanos such as Gula Mons. Surprisingly, topographically low regions, such as the ubiquitous plains areas, are modeled poorly in comparison. However, this generalization has has exceptions: Lakshmi Planum is an elevated region that is not well fit compared to the rest of neighboring Ishtar, while the southern parts of topographically low Guinevere Planitia are characterized quite well by the Hagfors model. Features that are candidates for improved models are impact craters, coronae, ridges of significant scale, complex ridged terrains, moderate-sized mountains, and sharp terrain boundaries. These features are chosen because the goodness of fit is likely to be most affected either by departures from normal incidence angles or by sharp changes in terrain type within a single footprint. Most large features that are elevated with respect to their surroundings will suffer from steep slope effects, and smaller coronae and impact craters will probably suffer due to rapid changes in their appearance within a single footprint (10-20 km).

Lovell, Amy J.↗

Improved Regolith-Landform and Geological Mapping using AIRSAR Data as an Aid to Mineral Exploration in the North-Eastern Goldfields Region, Western Australia

The distinctive contribution of AIRSAR data in characterizing the regolith-landforms in a relatively vegetation free environment are discussed. AIRSAR frame processed data were initially MAF-cleaned to enhance the signal content of the data before geocoding to AMG coordinates. Colors in a three frequency single polarization combination image C-, L- P- bands, and in an enhancement of pedestal height, relate directly to the scale of surface roughness of the various regolith units Examination of the AIRSAR enhancements reveals that in mafic terrain, and to a lesser extent, in felsic terrain, AIRSAR data provides discrimination between the principle geomorphic regimes, relict, erosional and depositional. A multivariate statistical technique called an all-possible subsets calculation was used to examine the degree of polarimetric separation between selected regolith-landforms for all combinations of the nine band AIRSAR radar. An unanticipated aspect of the research was the identification on the AIRSAR imagery of previously unmapped structural features.

Tapley, Ian J.↗

Relation of major volcanic center concentration on Venus to global tectonic patterns

Global analysis of Magellan image data indicates that a major concentration of volcanic centers covering about 40 percent of the surface of Venus occurs between the Beta, Atla, and Themis regions. Associated with this enhanced concentration are geological characteristics commonly interpreted as rifting and mantle upwelling. Interconnected low plains in an annulus around this concentration are characterized by crustal shortening and infrequent volcanic centers that may represent sites of mantle return flow and net downwelling. Together, these observations suggest the existence of relatively simple, large-scale patterns of mantle circulation similar to those associated with concentrations of intraplate volcanism on earth.

Crumpler, L. S.↗

Spectroscopic Properties of Metamorphosed Mafic Rocks: Remote Sensing Applications on Mars

Reflectance spectroscopy in the visible and near-infrared wavelengths, between 420 mn to 2588 nm. was utilized on a suite of hydrothermally metamorphosed mafic rocks from the Smartville complex in the northern Sierra Nevada mountains in California. A detailed data base of 102 samples was compiled in order to distinguish differences in mineralogy, petrology, and degree of metamorphism for remote sensing applications. Study was limited to metaigneous and metasedimentary rocks in an attempt to spectrally characterize terrestrial rocks analogous to the possible surface of Mars, for a better understanding and possible detection of the geologic features on the remote surface. Diagnostic absorption bands of iron, water, and hydroxyl produced the majority of discernible features in this study. Mossbauer spectroscopy was performed in order to determine specific iron sites. The resulting spectral data base along with thin section mineral identification, metamorphic zone, rock type and location were recorded and available for future application and research. Continued exploration of Mars in the advancing years, will further advance our understanding of the geology of Mars. Spectroscopic techniques will undoubtedly be integral parts of these future missions. Work on terrestrial analogs to the Martian surface must continue, in order to produce extensive data bases and broaden our knowledge of spectral features.

Graff, Trevor G.↗

Geology of Libya Montes and the Interbasin Plains of Northern Tyrrhena Terra, Mars: Project Introduction and First Year Work Plan

The highland-lowland boundary (HLB) of Mars is interpreted to be a complex tectonic and erosional transition that may hold evidence for past geologic processes and environments. The HLB-abutting margin of the Libya Montes and the interbasin plains of northern Tyrrhena Terra display an exceptional view of the earliest to middle history of Mars that has yet to be fully characterized. This region contains some of the oldest exposed materials on the Martian surface as well as aqueous mineral signatures that may be potential chemical artifacts of early highland formational processes. However, a full understanding of the regions geologic and stratigraphic evolution is remarkably lacking. Some outstanding questions regarding the geologic evolution of Libya Montes and northern Tyrrhena Terra in-clude: Does combining geomorphology and composition advance our understanding of the region s evolution? Can highland materials be subdivided into stratigraphically discrete rock and sediment sequences? What do major physiographic transitions imply about the balanced tectonism, climate change, and erosion? Where is the erosional origin and what is the post-depositional history of channel and plains units? When and in what types of environments did aqueous mineral signatures arise? This abstract introduces the geologic setting, science rationale, and first year work plan of a recently-funded 4-year geologic mapping proposal (project year = calendar year). The objective is to delineate the geologic evolution of Libya Montes and northern Tyrrhena Terra at 1:1M scale using both classical geomorphological and compositional mapping techniques. The funded quadrangles are MTMs 00282, -05282, -10282, 00277, -05277, and -10277.

Skiner, J. A., Jr.↗

Feasibility of Enhanced Geothermal Systems (EGS) Development at Bradys Hot Springs, Nevada

The Bradys EGS project focused on utilizing EGS technology to improve permeability in an existing non-productive well (15-12 ST1, located on BLM land) at Ormat’s Bradys geothermal facility in Churchill County, Nevada. The Bradys geothermal field is located within the Hot Springs Mountains, approximately 50 miles northeast of Reno, NV, along the western boundary of a very large intermontane basin known as the Carson Sink. It is one of several producing geothermal areas in the region; the Desert Peak, Stillwater, Soda Lake, and Salt Wells geothermal projects also lie within the Carson Sink, which is a region of high heat flow characterized by prominent NNE-striking faults that have formed in response to regional extension within the Basin and Range geologic province.

15 GEOTHERMAL ENERGY↗

Comparative global albedo and color maps of the Uranian satellites

The surfaces of the Uranian satellites Ariel, Miranda, Oberon, Titania, and Umbriel are characterized on the basis of Voyager observations. Tables of spectrophotometric data and maps of normal reflectances, green/violet ratios, and possible geological formations are presented and discussed in detail. Variations in albedo are found to be associated with impact features, and it is inferred from color differences that the upper surface of Ariel contains a higher proportion of redder material (tentatively identified as accreted low-albedo meteoritic dust) than those of the other moons.

Buratti, Bonnie J.↗

Biomarkers as tracers for life on early earth and Mars

Biomarkers in geological samples are products derived from biochemical (natural product) precursors by reductive and oxidative processes (e.g., cholestanes from cholesterol). Generally, lipids, pigments and biomembranes are preserved best over longer geological times and labile compounds such as amino acids, sugars, etc. are useful biomarkers for recent times. Thus, the detailed characterization of biomarker compositions permits the assessment of the major contributing species of extinct and/or extant life. In the case of the early Earth, work has progressed to elucidate molecular structure and carbon isotropic signals preserved in ancient sedimentary rocks. In addition, the combination of bacterial biochemistry with the organic geochemistry of contemporary and ancient hydrothermal ecosystems permits the modeling of the nature, behavior and preservation potential of primitive microbial communities. This approach uses combined molecular and isotopic analyses to characterize lipids produced by cultured bacteria (representative of ancient strains) and to test a variety of culture conditions which affect their biosynthesis. On considering Mars, the biomarkers from lipids and biopolymers would be expected to be preserved best if life flourished there during its early history (3.5-4 x 10(9) yr ago). Both oxidized and reduced products would be expected. This is based on the inferred occurrence of hydrothermal activity during that time with the concomitant preservation of biochemically-derived organic matter. Both known biomarkers (i.e., as elucidated for early terrestrial samples and for primitive terrestrial microbiota) and novel, potentially unknown compounds should be characterized.

Non-NASA Center↗

TPSAS-NF1676L-35628-DND

CHARISMA responds to the Committee on Astrobiology and Planetary Science (CAPS)'s recommendation to study a large/medium-class dedicated space telescope for planetary science. We are nearing the end of the Hubble Space Telescope lifetime, at which point the continuity of solar system UV measurements will be lost. Scientific objectives critically dependent on UV capabilities include studies of exospheric and auroral emissions in planetary atmospheres and plumes. CHARISMA will also revolutionize our understanding of time-dependent phenomena in our solar system currently not supported by programs intended to observe and visit new targets. The time-domain phenomena to be explored by CHARISMA include interaction of planetary magnetospheres with the solar wind, Venus and giant planet atmospheric dynamics, icy satellite geologic activity and surface evolution, cometary evolution, and evolving ring phenomena. CHARISMA also enables a comprehensive survey of the spectral characterization of minor bodies across the solar system, which requires a large time allocation not supported by existing facilities. CHARISMA will examine the benefits of advanced in-Space Assembly (iSA) technologies that enable a 10-m class aperture at New-Frontiers cost. CHARISMA will have the greatest impacts on science objectives particularly sensitive to dynamically evolving phenomena.

C L Young↗

In Situ Measurements of Surface Texture with Virtual Environments Support Science-Driven Human Surface Operations on the Moon and Beyond

Visualization tools enabling real-time scientific analysis are important for supporting future astronaut operations on the lunar surface. Such tools can be built into virtual environments to support scientific investigations, as well as situational awareness, real-time decision making, and efficient communication between astronauts and ground and support systems. Understanding how these tools can be optimized for science is essential for upcoming Artemis missions. In this contribution, we discuss how measurements of surface texture at multiple length scales can greatly enhance in situ science on/of the Moon, and eventually Mars, asteroids, and beyond. Roughness measurements at various wavelengths directly support objectives defined in the Artemis Science Plan, including (O1) “understanding planetary processes,” (O2) “understanding volatile cycles,” and (O3) “interpreting the impact history of the Earth-Moon system” . Key scientific analyses enabled by texture measurements at different length scales include: ● Sub-centimeter scales: Texture measurements can help constrain lava flow crystallinity, lava rheology, emplacement flow dynamics, and cooling histories (O1). Measurements of lacunarity (voids in fractal fill space) can shed light on eruptive volatile content, residence time of migrating volatiles, and near-surface volume available for micro-cold trapping of volatiles (O1, O2). ● Centimeter–meter scales: Texture measurements can be used for the differentiation of individual lava flows, the reconstruction of local stratigraphies and emplacement sequences, characterization of post-emplacement surface modification processes (O1, O3). Derived roughness (polarization) metrics can be used in the detection of water ice and characterization of ice properties (e.g., purity, grade, depth, abundance). ● Hectometer–Kilometer scales: Texture measurements can be used to differentiate major geologic surface units and surface structures (O1), constrain the presence of abundant ground ices (O2), and analyze surface modification and estimate surface age (O3). Real-time measurements of surface texture across these multiple length scales will enable efficient sample identification and scientific investigations by future astronauts. To support these investigations and the objective classification of surface texture, virtual environments employed by astronauts should be able to instantaneously convert raw data into processed data (e.g., digital terrain and elevation models) and derived metrics (e.g., RMS, std, Hurst, CPR) and perform statistical analyses (e.g., PCA, outliers, correlation matrices). Such tools are being developed and tested by the Resource Exploration and Science of our Cosmic Environment (RESOURCE) team, a node of NASA’s Solar System Exploration Research Virtual Institute (SSERVI), and are an excellent example of the powerful synergies of human and robotic ground assets critical in the return of humans to the Moon.

Ariel N. Deutsch↗

High Priority Samples to Characterize the Habitability of Groundwaters and Search for Rock-Hosted Life on Mars with Sample Return

Objective 1.1 of the iMOST sample return objectives is to establish the geologic context, interpret the potential habitability, and evaluate the potential for biosignature preservation in samples from an environment hypothesized to have had elevated potential for Martian life. Here, we describe the strategies required to understand the geologic context and habitability of Martian groundwater aquifers and to search for evidence of life in the Martian subsurface using samples.

Source record↗

Characterizing Nanophase Materials on Mars: Spectroscopic Studies of Allophane and Imogolite

Allophane is an amorphous or poorly crystalline hydrous aluminosilicate material. Allophane's chemical structure represents a hollow nanosphere, 5-6 nm in diameter with 4-7 large pores in the structure. Identification of allophane and other amorphous and nanophase minerals on Mars has provided clues about the aqueous geochemical environment there. These materials likely represent partially altered or leached basaltic ash and therefore, could represent a geologic marker for where water was present on the Martian surface; as well as indicate regions of climate change, where surface water was not present long enough or sufficiently warm to form clays. Characterization of these materials is important for increasing spectral recognition capabilities using visible/near-infrared (VNIR) and thermal infrared (TIR) spectra of Mars. A suite of synthetic allophane samples was created using a method that has been modified to produce allophane with Fe isomorphically substituted for Al in octahedral coordination. Compositions of the materials range from high-Si allophane (molar Al:Si = 1:2) to protoimogolite (Al:Si = 2:1), with Fe(3+) and Fe(2+) isomorphically substituted for Al from 0-10 mol% of total Al. These compositions span the range observed in natural terrestrial allophanes. Fe K-edge X-ray absorption spectroscopy provided information on the speciation and electrochemical and structural position of Fe in the framework. Fourier transform infrared spectroscopy confirmed syntheses and demonstrated changes in infrared spectroscopic signature with Fe substitution. VNIR reflectance spectra and TIR Thermal infrared emissivity spectra were also collected for direct comparison to Martian data. By increasing spectral recognition capacities of nanophase materials, more accurate estimates can be made on the aqueous geochemical environment of Mars.

Jeute, Thomas↗

Geological Map of the Fredegonde (V-57) Quadrangle, Venus

The area of V-57, the Fredegonde quadrangle (50-75degS, 60-120degE, Fig.1), is located within the eastern portion of Lada Terra within the topographic province of midlands (0-2 km above MPR [1,2]). Midlands form the most abundant portion of the surface of Venus and are characterized by diverse sets of units and structures [3-11]. The area of the Fredegonde quadrangle is in contact with the elevated portion of Lada Terra to the W and with the lowland of Aino Planitia to the NE. The transitions of the mid-lands to the lowlands and highlands are, thus, one of the main themes of the geology within the V-57 quadrangle. The character of the transitions and distribution and sequence of units/structures in the midlands are crucially important in understanding the time and modes of formation of this topographic province. The most prominent features in the map area are linear deformational zones consisting of swarms of grooves and graben and large coronae. The zones characterize the central and NW portions of the map area and represent regionally important, broad (up to 100s km wide) ridges that are 100s m high. Relatively small (100s km across, 100s m deep) equidimensional basins occur between the corona-groove-chains in the west and border the central chain from the east. Here we describe units that make up the surface within the V-57 quadrangle and present a summary of our geological map that shows the areal distribution of the major groups of units.

Ivanov, M. A.↗

Ultrasonic Resonance Techniques for Materials Research

Mechanical resonances are directly related to the physical behavior of a system at the bulk and microscopic levels. In materials science, resonant ultrasound spectroscopy (RUS) has long been a preferred nondestructive method to study mechanical resonances of solids and precisely measure quantitative material properties, namely elasticity. In recent years, advances in computational power and hardware have enabled RUS to be relevant for an increasing range of applications, such as advanced manufacturing. An extension of this technique, nonlinear RUS (NRUS), has been demonstrated to provide unmatched sensitivity to early-stage damage. NRUS was originally developed to probe geologic materials but has become a vital tool in nondestructive evaluation and materials research, offering a powerful means of quantifying and characterizing microstructural nonlinearity in a broad range of materials. This review summarizes recent developments and growth opportunities in RUS and NRUS techniques, modeling, and applications across a wide range of material systems including metals, composites, geomaterials, and explosives.

36 MATERIALS SCIENCE↗