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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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NASA NTRS2006

Frictional Ignition Testing of Composite Materials

The space flight community has been investigating lightweight composite materials for use in propellant tanks for both liquid and gaseous oxygen for space flight vehicles. The use of these materials presents some risks pertaining to ignition and burning hazards in the presence of oxygen. Through hazard analysis process, some ignition mechanisms have been identified as being potentially credible. One of the ignition mechanisms was reciprocal friction; however, test data do not exist that could be used to clear or fail these types of materials as "oxygen compatible" for the reciprocal friction ignition mechanism. Therefore, testing was performed at White Sands Test Facility (WSTF) to provide data to evaluate this ignition mechanism. This paper presents the test system, approach, data results, and findings of the reciprocal friction testing performed on composite sample materials being considered for propellant tanks.

Peralta, Steve↗

NASA NTRS1998

Thermophotovoltaic Energy Conversion Development Program

Completely integrated thermophotovoltaic (TPV) power sources in the range of 100 to 500 watts are being developed. The technical approach taken in this project focuses on optimizing the integrated performance of the primary subsystems in order to yield high energy conversion efficiency and cost effectiveness. An important aspect of the approach is the use of a narrow band fibrous emitter radiating to a bandgap matched photovoltaic array to minimize thermal and optical recuperation requirements, as well as the non-recoverable heat losses. For the prototype system, fibrous ytterbia emitters radiating in a narrow band centered at 980 nm are matched with high efficiency silicon photoconverters. The integrated system includes a dielectric stack filter for optical energy recovery and a ceramic recuperator for thermal energy recovery. The prototype TPV system uses a rapid mix distributed fuel delivery system with controlled feeding of the fuel and heated air into a flame at the surface of the emitter. This makes it possible to operate at air preheat temperatures well above the auto-ignition temperature of the fuel thereby substantially increasing the system efficiency. The system has been operated with air preheat temperatures up to 1367 K and has produced a uniform narrow band radiation over the surface of the emitter with this approach. The design of the system is described and test data for the system and some of the key components are presented. The results from a system model, which show the impact of various parameters on system performance, are also discussed.

Shukla, Kailash↗

NASA NTRS1977

Symposium on Combustion /International/, 16th, Massachusetts Institute of Technology, Cambridge, Mass., August 15-20, 1976, Proceedings

Aspects of combustion technology in power systems are considered, taking into account a combustion in large boilers, the control of over-all thermal efficiency of combustion heating systems, a comparison of mathematical models of the radiative behavior of a large-scale experimental furnace, a concentric multiannular swirl burner, and the effects of water introduction on diesel engine combustion and emissions. Attention is also given to combustion and related processes in energy production from coal, spray and droplet combustion, soot formation and growth, the kinetics of elementary reactions, flame structure and chemistry, propellant ignition and combustion, fire and explosion research, mathematical modeling, high output combustion systems, turbulent flames and combustion, and ignition, optical, and electrical properties.

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NASA NTRS1963

Apollo-Lunar Orbital Rendezvous Technique

The film shows artists rendition of the spacecrafts, boosters, and flight of the Apollo lunar missions. The Apollo spacecraft will consist of three modules: the manned Command Module; the Service Module, which contains propulsion systems; and the Lunar Excursion Module (LEM) to carry astronauts to the moon and back to the Command and Service Modules. The spacecraft will be launched via a three-stage Saturn booster. The first stage will provide 7.5 million pounds of thrust from five F-1 engines for liftoff and initial powered flight. The second stage will develop 1 million pounds of thrust from five J-2 engines to boost the spacecraft almost into Earth orbit. Immediately after ignition of the second stage, the Launch Escape System will be jettisoned. A single J-2 engine in the S4B stage will provide 200,000 pounds of thrust to place the spacecraft in an earth parking orbit. It also will be used to propel the spacecraft into a translunar trajectory, then it will separate from the Apollo Modules. Onboard propulsion systems will be used to insert the spacecraft into lunar orbit. Two astronauts will enter the LEM, which will separate from the command and service modules. The LEM will go into elliptical orbit and prepare for landing. The LEM will lift off of the Moon's surface to return to the Command and Service Modules, and most likely be left in lunar orbit. After leaving the Moon's orbit, and shortly before entering Earth's orbit, the Service Module will be ejected. The Command Module will be oriented for reentry into the Earth's atmosphere. A drogue parachute will deploy at approximately 50,000 feet, followed by the main parachute system for touchdown.

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NASA NTRS1999

Edge-Flames in Von Karman Swirling Flows

Classical understanding of diffusion flames dictates that they, unlike the premixed flames, do not possess a characteristic propagation velocity and are constrained by stoichiometric requirements at the flame surface. However, it has been commonly observed that when local extinction occurs within a diffusion flame sheet, the edges that are formed propagate with distinct speeds. In general, the propagation speed of these edges depend on their geometrical shape (concave, convex, or straight) among other factors. Recently, Buckmaster investigated the dynamics of straight diffusion flame edges separating burning and quenched regions using simplified one-dimensional models. He showed that these flame edges can have positive, negative, or zero velocity depending on the Damkoehler number of the equilibrium diffusion flame that support them. It was also shown that this unsteady flame-edge behavior is intrinsically linked to S-curve behavior of the diffusion flame with varying Damkoehler number. When the system Damkoehler number lies between the extinction and ignition limits, flame edges can propagate as an "ignition wave" or as a "failure wave," and for a critical Damkoehler number remain as a stationary flame-edge. We have extend Buckmaster's 1-d model to more general edge-flame configurations where the edges appear as "flame holes" or as "flame disks". These two configurations along with the straight-edge case cover the entire range of possible edge-flame geometry observable in planar diffusion-flame sheets. A generalized map of edge-flame propagation velocities as a function of the system Damkoehler number and the edge-flame radius is presented. Experimentally we show that edge flames can be created using diffusion flames embedded in von Karman boundary layers. In a von Karman boundary layer, the flow is generated by spinning a solid (fuel) disk in a quiescent ambient gas. Under normal gravity we were able to produce "flame disks" over a range of fuel-disk rotational velocities varying from 0 to 20 revolutions per second, by orienting the burning surface of the fuel disk facing downward.

Nayagam, Vedha↗

NASA NTRSDate not supplied

The Influence of Chemical Descriptors on the Reactivity of Potential Hypergolic Fuels With Hydrogen Peroxide

The state-of-the-art for storable hypergolic bipropellant systems is monomethylhydrazine (MMH) and mixed oxides of nitrogen (MON). While MMH and MON provide fast and highly reliable hypergolic ignition with excellent propulsive performance, they suffer from safety concerns impacting their production, cost, and supply to various test and launch facilities. In contrast, identifying and demonstrating low-toxicity fuels hypergolic with rocket grade hydrogen peroxide (H2O2) has been challenging with long ignition delay (IDT) and low propulsive performance affecting their deployment in flight systems. This work describes a preliminary observational study to assess the effects of molecular descriptors suspected to predict the reactivity and hypergolicity of compounds within the same chemical class (i.e., thioamide). The approach centered on evaluating functional groups, electrostatic potential, number of carbons, dipole moment, and adiabatic ionization energy. Thiourea is hypergolic with 89.2 wt.% H2O2 (minimum IDT of 21.9 ms) and was selected as a core fuel to study the reactivity of derived fuels with different functionalities. Additionally, the chemical properties were calculated with the Gaussian16 suite. The results showed that group substitution and generally increased number of carbons on thiourea increases IDT. It was observed that a more positively charged sulfur atom in the thioamide does not increase the reactivity towards H2O2. The dipole moment analysis revealed an overall trend of decreasing IDT due to increasing dipole moment. Finally, a lower adiabatic ionization energy related to increased IDTs for most cases. Additional chemical classes comprising a wider range of functionalities and electrophilic attributes are being investigated in on-going work.

Propellant↗

NASA NTRS2009

Evaluation of an Interferometric Sensor for In-Space Detection of Gas Leaks

Space mission planning often involves long-term storage of volatile liquids or high-pressure gases. These may include cryogenic fuels and oxidizers, high-pressure gases, and life-support-critical consumables. The risk associated with the storage of fluids and gases in space systems has long been an issue and the ability to retain these fluids is often tied to mission success. A leak in the storage or distribution system can cause many different problems, including a simple, but mission endangering, loss of inventory or, in severe cases, unbalanced thrust loads on a flight vehicle. Cryogenic propellants are especially difficult to store, especially over a long duration. The propellant can boil off and be lost through the insulating walls of the tank or simple thermal cycling of the fittings, valves, and propellant feed lines may unseat seals allowing the fluid to escape. Current NASA missions call for long-duration in-space storage of propellants, oxidizers, and life support supplies. Leaks of a scale detectable through a pressure drop in the storage tank are often catastrophic and have long been the focus of ground-based mitigation efforts where redundant systems are often employed. However, there is presently no technology available for detecting and monitoring low-level, but still mission-endangering, gas leaks in space. Standard in-space gas detection methods either have a very limited pressure range over which they operate effectively or are limited to certain gases. Mass spectrometer systems are able to perform the detection tasks, but their size, mass and use of high voltage, which could potentially lead to an arc that ignites a combustible propellent, severely limit their usefulness in a space system. In this paper, we present results from testing of the light-based interferometric gas monitoring and leak detection sensor shown in Fig. 1. The output of the sensor is an interference fringe pattern that is a function of the gas density, and commensurate index of refraction, in the sample region. Changes in the density of gas cause the interference fringes to move across a photodiode detector, providing a temporal history of the leak. The sensor is fiber coupled and constructed from solid optics, allowing for placement almost anywhere on the spacecraft. It is also advantageous in that it consumes very little power and does not introduce an ignition source. Data are presented demonstrating the capability of the sensor to measure density variations in different gas species. In addition, the transient response of the sensor in vacuum is demonstrated. These data extend and improve upon the results previously presented by the authors in Ref. [1].

Polzin, Kurt A.↗

NASA NTRS2009

Gauging Systems Monitor Cryogenic Liquids

Rocket fuel needs to stay cool - super cool, in fact. The ability to store gas propellants like liquid hydrogen and oxygen at cryogenic temperatures (below -243 F) is crucial for space missions in order to reduce their volumes and allow their storage in smaller (and therefore, less costly) tanks. The Agency has used these cryogenic fluids for vehicle propellants, reactants, and life support systems since 1962 with the Centaur upper stage rocket, which was powered with liquid oxygen and liquid hydrogen. During proposed long-duration missions, super-cooled fluids will also be used in space power systems, spaceports, and lunar habitation systems. In the next generation of launch vehicles, gaseous propellants will be cooled to and stored for extended periods at even colder temperatures than currently employed via a process called densification. Densification sub-cools liquids to temperatures even closer to absolute zero (-459 F), increasing the fluid s density and shrinking its volume beyond common cryogenics. Sub-cooling cryogenic liquid hydrogen, for instance, from 20 K (-423 F) to 15 K (-432.4 F) reduces its mass by 10 percent. These densified liquid gases can provide more cost savings from reduced payload volume. In order to benefit from this cost savings, the Agency is working with private industry to prevent evaporation, leakage, and other inadvertent loss of liquids and gases in payloads - requiring new cryogenic systems to prevent 98 percent (or more) of boil-off loss. Boil-off occurs when cryogenic or densified liquids evaporate, and is a concern during launch pad holds. Accurate sensing of propellants aboard space vehicles is also critical for proper engine shutdown and re-ignition after launch, and zero boil-off fuel systems are also in development for the Altair lunar lander.

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NASA NTRS2012

Analysis and Derivation of Allocations for Fiber Contaminants in Liquid Bipropellant Systems

An analysis was performed to identify the engineering rationale for the existing particulate limits in MSFC-SPEC-164, Cleanliness of Components for Use in Oxygen, Fuel, and Pneumatic Systems, determine the applicability of this rationale to fibers, identify potential risks that may result from fiber contamination in liquid oxygen/fuel bipropellant systems, and bound each of these risks. The objective of this analysis was to determine whether fiber contamination exceeding the established quantitative limits for particulate can be tolerated in these systems and, if so, to derive and recommend quantitative allocations for fibers beyond the limits established for other particulate. Knowledge gaps were identified that limit a complete understanding of the risk of promoted ignition from an accumulation of fibers in a gaseous oxygen system.

Lowrey, N. M↗

NASA NTRS2006

Ignition Characterization Test Results for the LO2/Ethanol Propellant Combination

A series of contracts were issued by the Marshall Space Flight Center (MSFC) of the National Aeronautics and Space Administration (NASA) under the auspices of the Exploration Systems Mission Directorate to develop and expand the maturity of candidate technologies considered to be important for future space exploration. One such technology was to determine the viability of incorporating non-toxic propellants for Reaction Control Subsystems (RCS). Contract NAS8-01109 was issued to Aerojet to develop a dual thrust Reaction Control Engine (RCE) that utilized liquid oxygen and ethanol as the propellants. The dual thrust RCE incorporated a primary thrust level of 870 lbf, and a vernier thrust level of 10 - 30 lbf. The preferred RCS approach for the dual thrust RCE was to utilize pressure-fed liquid oxygen (LOX) and ethanol propellants; however, previous dual thrust feasibility testing incorporated GOX/Ethanol igniters as opposed to LOX/Ethanol igniters in the design. GOX/Ethanol was easier to ignite, but this combination had system design implications of providing GOX for the igniters. A LOX/Ethanol igniter was desired; however, extensive LOX/Ethanol ignition data over the anticipated operating range for the dual thrust RCE did not exist. Therefore, Aerojet designed and tested a workhorse LOX igniter to determine LOX/Ethanol ignition characteristics as part of a risk mitigation effort for the dual thrust RCE design. LOX, encompassing potential two-phase flow conditions anticipated being present in real mission applications. A workhorse igniter was designed to accommodate the hll LOX design flowrate, as well as a reduced GOX flowrate. It was reasoned that the initial LOX flow through the igniter would flash to GOX due to the latent heat stored in the hardware, causing a reduced oxygen flowrate because of a choked, or sonic, flow condition through the injection elements. As LOX flow continued, the hardware would chill-in, with the injected oxygen flow transitioning from cold GOX through two-phase flow to subcooled LOX. permitted oxygen state points to be determined in the igniter oxidizer manifold, and gas-side igniter chamber thermocouples provided chamber thermal profile characteristics. The cold flow chamber pressure (P(sub c)) for each test was determined and coupled with the igniter chamber diameter (D(sub c)) to calculate the characteristic quench parameter (P(sub c) x D(sub c)), which was plotted as a function of core mixture ratio, m. Ignition limits were determined over a broad range of valve inlet conditions, and ignition was demonstrated with oxygen inlet conditions that ranged from subcooled 210 R LOX to 486 R GOX. Once ignited at cold GOX conditions, combustion was continuous as the hardware chilled in and the core mixture ratio transitioned from values near 1.0 to over 12.5. Pulsing is required in typical RCS engines; therefore, the workhorse igniter was pulse tested to verify the ability to provide the required ignition for a pulsing RCE. The minimum electrical pulse width (EPW) of the dual thrust RCE was 0.080 seconds.

Popp, Christopher G.↗

NASA NTRS1989

Thermodynamic and fluid mechanic analysis of rapid pressurization in a dead-end tube

Three models have been applied to very rapid compression of oxygen in a dead-ended tube. Pressures as high as 41 MPa (6000 psi) leading to peak temperatures of 1400 K are predicted. These temperatures are well in excess of the autoignition temperature (750 K) of teflon, a frequently used material for lining hoses employed in oxygen service. These findings are in accord with experiments that have resulted in ignition and combustion of the teflon, leading to the combustion of the stainless steel braiding and catastrophic failure. The system analyzed was representative of a capped off-high-pressure oxygen line, which could be part of a larger system. Pressurization of the larger system would lead to compression in the dead-end line, and possible ignition of the teflon liner. The model consists of a large plenum containing oxygen at the desired pressure (500 to 6000 psi). The plenum is connected via a fast acting valve to a stainless steel tube 2 cm inside diameter. Opening times are on the order of 15 ms. Downstream of the valve is an orifice sized to increase filling times to around 100 ms. The total length from the valve to the dead-end is 150 cm. The distance from the valve to the orifice is 95 cm. The models describe the fluid mechanics and thermodynamics of the flow, and do not include any combustion phenomena. A purely thermodynamic model assumes filling to be complete upstream of the orifice before any gas passes through the orifice. This simplification is reasonable based on experiment and computer modeling. Results show that peak temperatures as high as 4800 K can result from recompression of the gas after expanding through the orifice. An approximate transient model without an orifice was developed assuming an isentropic compression process. An analytical solution was obtained. Results indicated that fill times can be considerably shorter than valve opening times. The third model was a finite difference, 1-D transient compressible flow model. Results from the code show the recompression effect but predict much lower peak temperatures than the thermodynamic model.

Leslie, Ian H.↗

DOE OSTI2025

Design of a High-Pressure Fuel System for Use with Dimethyl Ether

The paper documents the modeling and experimental work on a common rail fuel injection system for Dimethyl Ether, a potential diesel substitute with a low carbon intensity signature. The DME fuel system is deployed on a light duty 2.2L compression ignition engine. The paper describes the injector optimization to shift to higher flows to account for the lower heating value and density of the DME when compared to diesel. The type of the injection system used for the DME application is an advanced rendering of the Common rail noted for a one-piece piston-needle injector construction and a solenoid driven spill valve featuring a pressure balanced poppet. A dedicated high-pressure fuel pump designed to pressurize DME is used. The design results in a fast acting open and close injection event, reduced leakage, with reduced cavitation in the fuel injector volume. Design parameters for system optimization included fill and spill orifices, needle lift, bias spring, and injector hole size. The design model provides good correlation of the instantaneous rates of injection with experiments across a wide range of pressure and injection timings. Proposed performance milestones for the design included similar DME injection duration to the diesel counterpart for same fuel energy injected into the cylinder to retain high engine cycle efficiency. Here, the dedicated DME design provided reduced hydraulic delays of 50%. Tests demonstrated sustained operation at pressures of 1000 bar, with capability to reach 1500bar. Durability tests showed no cavitation-deterioration over a 200-hour test cycle by means of spray imaging and hardware inspection.

De Ojeda, William [WM International Engineering, L↗

NASA NTRS2006

LOX, GOX and Pressure Relief

Oxygen relief systems present a serious fire hazard risk with often severe consequences. This presentation offers a risk management solution strategy which encourages minimizing ignition hazards, maximizing best materials, and utilizing good practices. Additionally, the relief system should be designed for cleanability and ballistic flow. The use of the right metals, softgoods, and lubricants, along with the best assembly techniques, is stressed. Materials should also be tested if data is not available and a full hazard analysis should be conducted in an effort to minimize risk and harm.

McLeod, Ken↗

NASA NTRS1982

Survey of Spaceflight Safety Systems /Survey period: July 1981 June 1982/

Information from the Survey of Spaceflight Safety Systems considered most applicable to present and future spaceflight activities is summarized. Mission reports for the first three Shuttle Orbiter flights discuss all anomalies which occurred and their resolution, such as the solid rocket booster ignition overpressure spike, and thermal tile damage. Two emergency rescue systems for orbiting space stations are proposed: a dish type rescue capsule and a reusable orbit vehicle. Prebreathing and stage decompression are considered as means of protecting astronauts against decompression effects. The Spacelab Space Sled experiments are described, as is a test program on the assembly of large space structures completed in mid-1981. Finally, collision hazards for space missions are estimated, and operational procedures for minimizing these hazards are discussed.

Brown, N. E.↗

NASA NTRS1978

Impact of future fuel properties on aircraft engines and fuel systems

The effect of modifications in hydrocarbon jet fuels specifications on engine performance, component durability and maintenance, and aircraft fuel system performance is discussed. Specific topics covered include: specific fuel consumption; ignition at relight limits; exhaust emissions; combustor liner temperatures; carbon deposition; gum formation in fuel nozzles, erosion and corrosion of turbine blades and vanes; deposits in fuel system heat exchangers; and pumpability and flowability of the fuel. Data that evaluate the ability of current technology aircraft to accept fuel specification changes are presented, and selected technological advances that can reduce the severity of the problems are described and discussed.

Rudey, R. A.↗

NASA NTRS2010

Liquid Oxygen/Liquid Methane Component Technology Development at MSFC

The National Aeronautics & Space Administration (NASA) has identified Liquid Oxygen (LOX)/Liquid Methane (LCH4) as a potential propellant combination for future space vehicles based upon exploration studies. The technology is estimated to have higher performance and lower overall systems mass compared to existing hypergolic propulsion systems. Besides existing in-house risk reduction activities, NASA has solicited from industry their participation on component technologies based on the potential application to the lunar ascent main engine (AME). Contracted and NASA efforts have ranged from valve technologies to engine system testbeds. The application for the AME is anticipated to be an expendable, pressure-fed engine for ascent from the moon at completion of its lunar stay. Additionally, the hardware is expected to provide an abort capability prior to landing, in the event that descent systems malfunction. For the past 4 years, MSFC has been working with the Glenn Research Center and the Johnson Space Center on methane technology development. This paper will focus on efforts specific to MSFC in pursuing ignition, injector performance, chamber material assessments and cryogenic valve technologies. Ignition studies have examined characteristics for torch, spark and microwave systems. Injector testing has yielded insight into combustion performance for shear, swirl and impinging type injectors. The majority of chamber testing has been conducted with ablative and radiatively cooled chambers with planned activities for regenerative and transpiration cooled chambers. Lastly, an effort is underway to examine the long duration exposure issues of cryogenic valve internal components. The paper will summarize the status of these efforts.

Robinson, Joel W.↗

NASA NTRS1998

Propulsion System for Very High Altitude Subsonic Unmanned Aircraft

This paper explains why a spark ignited gasoline engine, intake pressurized with three cascaded stages of turbocharging, was selected to power NASA's contemplated next generation of high altitude atmospheric science aircraft. Beginning with the most urgent science needs (the atmospheric sampling mission) and tracing through the mission requirements which dictate the unique flight regime in which this aircraft has to operate (subsonic flight at greater then 80 kft) we briefly explore the physical problems and constraints, the available technology options and the cost drivers associated with developing a viable propulsion system for this highly specialized aircraft. The paper presents the two available options (the turbojet and the turbocharged spark ignited engine) which are discussed and compared in the context of the flight regime. We then show how the unique nature of the sampling mission, coupled with the economic considerations pursuant to aero engine development, point to the spark ignited engine as the only cost effective solution available. Surprisingly, this solution compares favorably with the turbojet in the flight regime of interest. Finally, some remarks are made about NASA's present state of development, and future plans to flight demonstrate the three stage turbocharged powerplant.

Bents, David J.↗

NASA NTRS2019

Characterization of Propellant Flow and Bias Required to Initiate an Arc Discharge in a Heaterless Hollow Cathode

Heaterless hollow cathodes provide an opportunity to reduce complexity and improve reliability in electric propulsion systems. While removal of the heater has little effect on steady-state operation of a hollow cathode, it has a considerable effect on the ignition process. To successfully integrate a heaterless hollow cathode into a spaceflight electric propulsion system, it will be necessary to establish definitive requirements for the propellant feed and electrical subsystems so that ignition of a plasma discharge can be achieved reliably. The aim of this research was to form a better understanding of these requirements by performing an investigation of the propellant flow and voltage conditions required for the ignition of a plasma arc discharge. This aim was achieved by performing discharge initiation experiments using both a specially designed experimental apparatus and a functional heaterless hollow cathode assembly. It was demonstrated that there is a distinct difference in the voltage required to initiate a plasma discharge between two common electric propulsion propellants, xenon and krypton, which suggests that the developmental testing of heaterless hollow cathodes needs to be performed with the appropriate propellant gas species. Heaterless hollow cathode ignition experiments showed that the keeper orifice diameter has a strong effect on the voltage required to ignite a plasma discharge at a given propellant mass flow rate, while the effect of keeper-cathode separation distance was only strong at flow rates below 25 sccm (Xe).

Ham, Ryan K.↗