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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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All sourcesNASA NTRSDOE OSTI
NASA NTRS1999

Single Bubble Sonoluminescence in Low Gravity and Optical Radiation Pressure Positioning of the Bubble

Several groups of researchers have demonstrated that high frequency sound in water may be used to cause the regular repeated compression and luminescence of a small bubble of gas in a flask. The phenomenon is known as single bubble sonoluminescence (SBSL). It is potentially important because light emitted by the bubble appears to be associated with a significant concentration of energy within the volume of the bubble. Unfortunately, the detailed physical mechanisms causing the radiation of light by oscillating bubbles are poorly understood and there is some evidence that carrying out experiments in a weightless environment may provide helpful clues. In addition, the radiation pressure of laser beams on the bubble may provide a way of simulating weightless experiments in the laboratory. The standard model of SBSL attributes the light emission to heating within the bubble by a spherically imploding shock wave to achieve temperatures of 50,000 K or greater. In an alternative model, the emission is attributed to the impact of a jet of water which is required to span the bubble and the formation of the jet is linked to the buoyancy of the bubble. The coupling between buoyancy and jet formation is a consequence of the displacement of the bubble from a velocity node (pressure antinode) of the standing acoustic wave that drives the radial bubble oscillations. One objective of this grant is to understand SBSL emission in reduced buoyancy on KC-135 parabolic flights. To optimize the design of those experiments and for other reasons which will help resolve the role of buoyancy, laboratory experiments are planned in simulated low gravity in which the radiation pressure of laser light will be used to position the bubble at the acoustic velocity node of the ultrasonic standing wave. Laser light will also be used to push the bubble away from the velocity node, increasing the effective buoyancy. The original experiments on the optical levitation and radiation pressure on bubbles in water by Unger and Marston noted above were carried out using a continuous wave (CW) beam of an Argon laser. For lateral stability the beam had a intensity minimum along its axis. Calculations of the optical radiation force on an SBSL bubble indicate that ion laser technology is a poor choice for providing the magnitude of the average optical radiation force required. Consequently it is necessary to examine various diode-pumped solid state laser technologies. The approach for this part of the research will be to achieve optical levitation of a quiescent bubble based on contemporary laser technology and then to strobe the laser synchronously with the SBSL bubble oscillations.

Thiessen, D. B.↗
DOE OSTI2022

Sugar loading is not required for phloem sap flow in maize plants

We report phloem transport of photoassimilates from leaves to non-photosynthetic organs, such as the root and shoot apices and reproductive organs, is crucial to plant growth and yield. For nearly 90 years, evidence has been generally consistent with the theory of a pressure-flow mechanism of phloem transport. Central to this hypothesis is the loading of osmolytes, principally sugars, into the phloem to generate the osmotic pressure that propels bulk flow. Here we used genetic and light manipulations to test whether sugar import into the phloem is required as the driving force for phloem sap flow. Using carbon-11 radiotracer, we show that a maize sucrose transporter1 (sut1) loss-of-function mutant has severely reduced export of carbon from photosynthetic leaves (only ~4% of the wild type level). Yet, the mutant remarkably maintains phloem pressure at ~100% and sap flow speeds at ~50–75% of those of wild type. Potassium (K+) abundance in the phloem was elevated in sut1 mutant leaves. Fluid dynamic modelling supports the conclusion that increased K+ loading compensated for decreased sucrose loading to maintain phloem pressure, and thereby maintained phloem transport via the pressure-flow mechanism. Furthermore, these results suggest that sap flow and transport of other phloem-mobile nutrients and signalling molecules could be regulated independently of sugar loading into the phloem, potentially influencing carbon–nutrient homoeostasis and the distribution of signalling molecules in plants encountering different environmental conditions.

36 MATERIALS SCIENCE↗
NASA NTRS2007

Design, Fabrication and Performance of Open Source Generation I and II Compliant Hydrodynamic Gas Foil Bearings

Foil gas bearings are self-acting hydrodynamic bearings made from sheet metal foils comprised of at least two layers. The innermost top foil layer traps a gas pressure film that supports a load while a layer or layers underneath provide an elastic foundation. Foil bearings are used in many lightly loaded, high-speed turbo-machines such as compressors used for aircraft pressurization, and small micro-turbines. Foil gas bearings provide a means to eliminate the oil system leading to reduced weight and enhanced temperature capability. The general lack of familiarity of the foil bearing design and manufacturing process has hindered their widespread dissemination. This paper reviews the publicly available literature to demonstrate the design, fabrication and performance testing of both first and second generation bump style foil bearings. It is anticipated that this paper may serve as an effective starting point for new development activities employing foil bearing technology.

DellaCorte, Christopher↗
DOE OSTI2025

Security-by-Design: Light Water Small Modular Reactor

The growing demand for nuclear power is increasing pressure to find solutions to cost prohibitive requirements of both construction and security. Offsite response has been proposed as an option to reduce costs associated with training and maintaining an onsite response force. A previous report explored this option and revealed that security could be provided at the required level, but cost savings was not a result of this methodology. An offsite response strategy required costly active and passive delay barriers to provide sufficient time for responders to muster and deploy to a site in time to interrupt a determined and well-equipped adversary. Also, contrary to the hypothesis, the number of responders required for this strategy exceeded that needed for an onsite response force, as the adversaries could avail themselves of advantageous positions within the facility to repel arriving responders. This report builds upon the previous evaluation by using the same hypothetical light water small modular reactor (LWSMR) facility model, but this time an onsite response strategy was assessed. The goal of this analysis was to show that an onsite response strategy could be implemented effectively at a cost point that removes barriers within the industry at this critical time of growth and development. The assessment of the facility design and response strategy was completed through modeling using Scribe3D© and subsequent scenario analysis over the course of a two-day tabletop exercise. Subject matter experts in nuclear security, nuclear facility design, and response strategy and tactics contributed to the effort to ensure accurate representation of hypothetical scenarios. Several adaptations were made to the layout of the LWSMR based on lessons learned during the first day of scenario analysis. The subsequent design evaluated on the second day proved to provide a robust response posture against a large and well-trained adversary force. This report details the process of the analysis and compares the cost of the final facility design with that of the LWSMR model used for evaluation of offsite response. Ultimately, the results of this effort indicate that, when implemented correctly, an onsite response strategy is the best option from a security and cost perspective.

22 GENERAL STUDIES OF NUCLEAR REACTORS↗
NASA NTRS2002

Sonoluminescence in Space: The Critical Role of Buoyancy in Stability and Emission Mechanisms

Sonoluminescence is the term used to describe the emission of light from a violently collapsing bubble. Sonoluminescence ("light from sound") is the result of extremely nonlinear pulsations of gas/vapor bubbles in liquids when subject to sufficiently high amplitude acoustic pressures. In a single collapse, a bubble's volume can be compressed more than a thousand-fold in the span of less than a microsecond. Even the simplest consideration of the thermodynamics yields pressures on the order of 10,000 ATM, and temperatures of at least 10,000K. On the face of things, it is not surprising that light should be emitted from such an extreme process. Since 1990 (the year that Gaitan discovered light from a single bubble) there has been a tremendous amount of experimental and theoretical research in stable, single-bubble sonoluminescence (SBSL), yet there remain at least four unexplained phenomena associated with SBSL in 1g: the light emission mechanism itself, the existence of anisotropies in the emitted light, the disappearance of the bubble at some critical acoustic pressure, and the appearance of quasiperiodic and chaotic oscillations in the flash timing. Gravity, in the context of the buoyant force, is implicated in all four of these. We are developing KC-135 experiments probing the effect of gravity on single bubble sonoluminescence. By determining the stability boundaries experimentally in microgravity, and measuring not only light emission but mechanical bubble response, we will be able to directly test the predictions of existing theories.

Thomas, Charles R.↗
DOE OSTI2025

Pressure effects on lithium anode/nickel-manganese-cobalt oxide cathode pouch cells through fixture design

Applying external pressure to a pouch cell results in improved performance, implicating systems-level design of batteries. Here, different formats and amounts of external pressure to Li-Li x Ni 0.8 Mn 0.1 Co 0.1 O 2 (Li-NMC811) pouch cells were studied under lean electrolyte conditions. Due to the more uniform lithium plating/stripping, a constant gap fixture that retains the distance of the frame during cycling performed greater than a constant pressure fixture that retains applied pressure to the cell. In addition, the use of flexible foam in a constant gap fixture revealed enhanced cycle life at 10 psi; however, at 30 psi, the use of a rigid plate extended cycle life to over 250 cycles, while the foam severely shortened cycle life. This discrepancy with pressure was proven to be driven by stress distribution on cell components. The failure mechanisms and the effects of pressure fixture design on cell components were unveiled, shedding light on improving high-energy battery performance through at-scale fixture design.

25 - ENERGY STORAGE↗
NASA NTRS2011

In-Suit Light Exercise (ISLE) Prebreathe Protocol Peer Review Assessment

The performance of extravehicular activity (EVA) by National Aeronautics and Space Administration astronauts involves the risk of decompression sickness. This risk has been mitigated by the use of oxygen "prebreathe" to effectively wash out tissue nitrogen prior to each EVA. Now that the Space Shuttle Program (SSP) is being retired, high-pressure oxygen will become a limited resource. The In-Suit Light Exercise (ISLE) Prebreathe Protocol offers several potential benefits including its potential to save 6 pounds of oxygen per EVA. At the request of the NASA Engineering and Safety Center, the peer review convened on October 14, 2010. The major recommendation of the Review Committee was that the ISLE protocol was acceptable for operational use as a prebreathe option prior to EVA. The results from the peer review are contained in this document.

Brady, Timothy K.↗
DOE OSTI2020

Probabilistic Risk Assessment of a Light Water Reactor Coupled with a High Temperature Electrolysis Hydrogen Production Plant

Two generic probabilistic risk assessments (PRA) for the addition of a heat extraction system (HES) addition to a light water reactor (LWR) are performed, one for a pressurized water reactor (PWR) and one for a boiling water reactor (BWR). The results investigate the applicability of the potential licensing approaches which do not require a full U.S. Nuclear Regulatory Commission (NRC) licensing review. The PRAs are generic, and some assumptions are made. Many conservative assumptions from a the preliminary PWR PRA report were eliminated using design data for both the HES and the high temperature electrolysis facility (HTEF). The results of the PRA indicate that the 10 CFR 50.59 licensing approach is justified due to the minimal increase in initiating event frequencies for all DBAs, none exceeding 5.6%. The PRA results for CDF and LERF support the use of RG 1.174 as further risk information that supports a change without a full LAR. Further insights provided through hazard analysis and sensitivity studies confirm with high confidence that the safety case for licensing an HES addition and a HTEF sited at 1.0 km from the NPP is strong and that the placement of a HTEF at 0.5 km is a viable case. Site specific information can alter these conclusions.

29 ENERGY PLANNING, POLICY, AND ECONOMY↗
DOE OSTI2022

Simultaneous imaging and diffraction in the dynamic diamond anvil cell

The ability to visualize a sample undergoing a pressure-induced phase transition allows for the determination of kinetic parameters, such as the nucleation and growth rates of the high-pressure phase. For samples that are opaque to visible light (such as metallic systems), it is necessary to rely on x-ray imaging methods for sample visualization. Here, we present an experimental platform developed at beamline P02.2 at the PETRA III synchrotron radiation source, which is capable of performing simultaneous x-ray imaging and diffraction of samples that are dynamically compressed in piezo-driven diamond anvil cells. This setup utilizes a partially coherent monochromatic x-ray beam to perform lensless phase contrast imaging, which can be carried out using either a parallel- or focused-beam configuration. The capabilities of this platform are illustrated by experiments on dynamically compressed Ga and Ar. Melting and solidification were identified based on the observation of solid/liquid phase boundaries in the x-ray images and corresponding changes in the x-ray diffraction patterns collected during the transition, with significant edge enhancement observed in the x-ray images collected using the focused-beam. These results highlight the suitability of this technique for a variety of purposes, including melt curve determination.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
NASA NTRS2011

In-Suit Light Exercise (ISLE) Prebreathe Protocol Peer Review Assessment: Appendices - Part 2

The performance of extravehicular activity (EVA) by National Aeronautics and Space Administration astronauts involves the risk of decompression sickness. This risk has been mitigated by the use of oxygen "prebreathe" to effectively wash out tissue nitrogen prior to each EVA. Now that the Space Shuttle Program (SSP) is being retired, high-pressure oxygen will become a limited resource. The In-Suit Light Exercise (ISLE) Prebreathe Protocol offers several potential benefits including its potential to save 6 pounds of oxygen per EVA. At the request of the NASA Engineering and Safety Center, the peer review convened on October 14, 2010. The major recommendation of the Review Committee was that the ISLE protocol was acceptable for operational use as a prebreathe option prior to EVA. The appendices to Volume I of the report are contained in this document.

Brady, Timothy K.↗
NASA NTRS2019

Using Computational Flow Imaging to Optimize Filtered Rayleigh Scattering Measurements of an Isolator Shock Train

Filtered Rayleigh scattering (FRS) is a laser diagnostic where the intensity of elastically scattered light is measured after it passes through a molecular absorption filter. The filter removes background interference that overwhelms the relatively weak scattering from the gas molecules. However, with a filter, the measured light intensity depends on many of the scattering gas properties, including pressure, density, temperature, and velocity. In this work, CFD simulations of an isolator shock train flow field are input into a physics-based model to predict the values of FRS intensity measurements in a proposed experiment. The goal is to evaluate if a simplistic FRS setup (that utilizes one camera, laser, and absorption filter) can be used to accurately quantify number density despite the fact that the scattered light intensity also depends on other gas properties. It is found that the experimental setup can be optimized such that a linear relationship describes the number density with an average prediction error of 2%. The vast majority of the flow exhibits prediction errors of less than 3%, but small regions of the flow reach up to 11% error. A sensitivity analysis shows that the prediction error increases with the central wavelength of the incident laser light and decreases with the angle between the camera and laser propagation directions. The optimal experimental parameters are chosen based on a compromise between the prediction error, spatial resolution, and the amount of unfiltered light. In the future, the proposed FRS setup will be implemented to acquire new and valuable information on an isolator shock train, a flow field that has been traditionally studied using wall static pressure measurements and path-integrated visualization techniques, such as schlieren and shadowgraphy.

Hunt, Robin L.↗
NASA NTRS1993

Light Spectral Quality Effects on the Growth of Potato (Solanum Tuberosum L.) Nodal Cuttings in Vitro

The effects of light spectral quality on the growth of in vitro nodal cuttings of potato (Solanum tuberosum L.) cultivars Norland, Superior, Kennebec, and Denali were examined. The different light spectra were provided by Vita-Lite fluorescent (VF) (a white light control), blue fluorescent (BF), red fluorescent (RF), low-pressure sodium (LPS), and a combination of low-pressure sodium plus cool-white fluorescent lamps (LPS/CWF). For cultivars, stem lengths after 4 wks were longest under LPS, follow by RF, LPS/CWF, VF, and BF (in descending order). Microscopic studies revealed that cells were shortest when cultured in BF or VF environments, and were longest in RF or LPS lamp environments. The highest number axillary branches occurred on plantlets grown with LPS or LPS/CWF, whereas the lowest number occurred with BF. No leaf or stem edema (callus or gall-like growths) occurred iwth LPS or LPS/cwf lighting, and no edema occurred on cv. Norland plantlets, regardless of lighting. Results suggest that shoot morphologic development of in vitro grown potato plants can be controlled by controlling irradiant spectral quality.

Wilson, Deborah A.↗
DOE OSTI2024

Stimuli‐Responsive Emission from Hybrid Metal Halides

Abstract Stimuli‐responsive photoluminescent (PL) materials have attracted considerable attention in recent years owing to their potential applications in anti‐counterfeiting, information encryption, and sensing. Further investigations of the transformation mechanism and potential applications of stimulus‐responsive PL materials are considerably important. In the current study, an organic–inorganic metal halide, C 9 H 15 N 3 SbCl 5 ([C 9 H 13 N 3 ] 2+ is a 1‐(2‐pyridyl) piperazine cation) is obtained, which exhibits a 0D structure withP‐1 space group. At room temperature, when excited by UV light, the C 9 H 15 N 3 SbCl 5 single crystals exhibit unimodal blue light emission at 405 nm, and grinding or hydrostatic pressure induces double‐peak emissions at 405 and 650 nm. Interestingly, double‐emission samples can be restored to single‐emission samples by short annealing or storage in air for 2 weeks, and this process is reversible. Luminescence response to mechanical stimuli can also be achieved in the presence of hydrochloric acid and water. Spectral analysis and the analysis of the microstructural changes revealed that the structural modifications of the inorganic group play a pivotal role in the response to the stimulus. Finally, a composite film device based on C 9 H 15 N 3 SbCl 5 is prepared to demonstrate the potential of these smart materials in anti‐counterfeiting and sensing applications.

Chemistry↗
DOE OSTI2024

Liquid Structure of Iron and Iron–Nitrogen–Carbon Alloys Within the Cores of Small Terrestrial Bodies

Abstract Nitrogen has been proposed to be stored within planetary cores, but its effects on the structure and density of molten Fe–alloys have not been explored experimentally. Using energy‐dispersive X‐ray diffraction, we determined the structure of Fe–N(–C) liquids at core conditions (1–7 GPa and 1700–1900°C) within a Paris‐Edinburgh press. Variation of N up to 7 wt.% and C up to 1.5 wt.% results in near‐linear changes in Fe–Fe atom distances and structure factor with increasing light element content. We did not observe a significant pressure‐driven structural transition in Fe–N(–C) liquids. We model the expansion of the Fe–Fe bonds using a modified Birch‐Murnaghan equation of state. With this model, we demonstrate that N or C contamination could lead to an overestimation of the Fe–Fe distances of pure Fe. We observe that the incorporation of 1 wt.% N or C into Fe results in a change in Fe–Fe distances that is twice as significant as the effect of 1 GPa. By approximating the change in volume, we infer that N and C incorporated in liquid iron could contribute to the density deficit observed in the cores of terrestrial bodies.

Pease, Allison [Department of Earth and Environmen↗
DOE OSTI2023

Unraveling H2 chemisorption and physisorption on metal decorated graphene using quantum Monte Carlo

Molecular hydrogen has the potential to significantly reduce the use of carbon dioxide emitting energy processes. However, hydrogen gas storage is a major bottleneck for its large-scale use as current storage methods are energy intensive. Among different storage methods, physisorbing molecular hydrogen at ambient pressure and temperatures is a promising alternative—particularly in light of the advancements in tunable lightweight nanomaterials and high throughput screening methods. Nonetheless, understanding hydrogen adsorption in well-defined nanomaterials remains experimentally challenging and reference information is scarce despite the proliferation of works predicting hydrogen adsorption. We focus on Li, Na, Ca, and K, decorated graphene sheets as substrates for molecular hydrogen adsorption, and compute the most accurate adsorption energies available to date using quantum diffusion Monte Carlo (DMC). Building on our previous insights at the density functional theory (DFT) level, we find that a weak covalent chemisorption of molecular hydrogen, known as Kubas interaction, is feasible on Ca decorated graphene according to DMC, in agreement with DFT. This finding is in contrast to previous DMC predictions of the 4H2/Ca+ gas cluster (without graphene) where chemisorption is not favored. However, we find that the adsorption energy of hydrogen on metal decorated graphene according to a widely used DFT method is not fully consistent with DMC. The reference adsorption energies reported herein can be used to find better work-horse methods for application in large-scale modeling of hydrogen adsorption. Furthermore, the implications of this work affect strategies for finding suitable hydrogen storage materials and high-throughput methods.

Chemistry↗
DOE OSTI2024

X-ray spectroscopic investigation of crystal fields in Ce 2 Rh 1 − x Ir x In 8 heavy fermions

The higher dimensionality in the crystal fields of the Ce 2 M In 8 ( M = Rh , Ir ) compounds and its interplay with hybridization and disorder are key ingredients to understand the complex phase diagrams by this family, which have been explored extensively by macroscopic techniques. Here, we present an investigation of the crystal-electric field schemes of Ce 2 Rh 1 − x Ir x In 8 using x-ray absorption spectroscopy. Our full multiplet calculations for the 4 f 1 configuration of Ce 3 + to describe the temperature-dependent linear dichroism in Ce 2 M In 8 are consistent with a Γ 7 1 = 1 − α 2 · | ∓ 3 2 〉 − | α | · | ± 5 2 〉 ground state containing a predominant | ± 3 / 2 〉 contribution that increases further with x . This enhancement is believed to favor superconductivity in Ce-based heavy fermion materials, observed in previous results in the Ce M In 5 family. Our recent observations shed light on the unexpected emergence of the ambient-pressure superconducting dome in the center of the composition phase diagram and its subsequent suppression on the Ir-rich side due to the early onset of fluctuations associated with the structurally more disordered state, inferred from previous neutron magnetic diffraction experiments. Published by the American Physical Society 2024

Christovam, D. S. (ORCID:0000000250698107)↗
NASA NTRS1972

Some analyses of the variability of atmospheric parameters at low altitudes significant for aircraft propagation

The results are discussed in terms of the meteorological data acquisition procedures necessary to monitor changes in atmospheric parameters to support aircraft flyover noise measurements and aircraft noise certification programs. The data consisted primarily of sequential radiosonde ascents to approximately 5000 ft spaced some half-hour to an hour apart. The weather covered by the data sample was predominantly that of clear skies and calm-to-light surface winds associated with well established high-pressure systems. Under these restrictive weather conditions, the study shows that the largest variabilities in temperature and humidity occur during the early morning hours resulting from the effects of direct solar heating of the surface. These rapid changes apparently do not penetrate above approximately 1000 ft. In the late morning hours, the atmosphere appears to become stabilized so that net changes in temperatures and relative humidities at all levels are insignificant even in time periods exceeding three hours. By noon, however, turbulent fluctuations in surface wind and the wind speed itself increase to levels which would make the microphone recording of acoustic signals in the field difficult.

Chang, D. T.↗