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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 361 records · Page 20

Maximizing the Proppant Carrying and Viscoelastic Properties of the Bakken Hypersaline-Produced Water with High-Viscosity Friction Reducers for Sustainable Applications

Summary The development and production of unconventional reservoirs, such as the Bakken Formation, have become a resolved mystery for operators in North America since the arrival and advancement of horizontal drilling and hydraulic fracturing technologies. As a result, unconventional reservoir assets became the central focus of the oil and gas industry at the state, national, and global levels. The produced water from these activities in the Bakken Formation have high salt contents (110,000–350,000 ppm) total dissolve solids (TDS) and can pose significant challenges to the environment if not treated. Deep injection into disposal wells is the routine method used to get rid of the Bakken produced water. However, there have been some concerns that unrestrained injections, in addition to polluting the groundwater, could potentially lead to seismic activities either at the time of injection or in the near future. To diminish the environmental impacts that may be associated with induced seismicity, including the reduction of the costs of water acquisition, the produced water can be treated and reused in the hydraulic fracturing processes. Also, the treated water could be used for irrigation purposes, for power generation, and coal mining operations. The issues of waste water and residual oil high in TDS are challenges yet to be effectively addressed despite preceding research and studies on advancing produced water technologies. The goal of this study is to explore all applicable ways by which the produced water from the Bakken Formation can serve as a replacement base fluid for use with polymers like the high-viscosity friction reducers (HVFRs) to create hydraulic fracturing fluids that can be stable with reservoir conditions and also be able to minimize environmental impacts and cost of operations. Experimental investigations using the high-salinity produced water from the Bakken Formation with HVFRs were carried out. The studies included a base case that served as a bench mark for comparing the effectiveness of the other scenarios. The results indicate that the Bakken hyper-saline produced water can withstand effect of heavy metals, salinity, hardness and remain stable through different shear rates (66–330 s−1) when treated with higher dosages [4–8 gal/1,000 gal (gpt)] of HVFRs. Filtration and dilution were the only methods used on the Bakken Formation produced wate for this research

Engineering↗

A Scaling Study of Microbially-Enhanced Methane Production From Coal (Mecbm): Optimizing Nutrient Delivery For Maximized Methane Production

Microbially-enhanced coalbed methane (MECBM) recovery is a novel method to stimulate gas production in CBM reservoirs. We first develop suitable nutrient recipes for native coals from sites each in the Illinois Basin and in the San Juan Basin. The optimal concentrations for statistically significant parameters are identified and the methane yields at laboratory scale are obtained (Part I & II). We then demonstrate the importance of replicating truly in-situ conditions for bio- gasification studies by investigating methane productivity in a core holder simulating in-situ conditions. Based on the experimental results, the resulting gas production correlates positively with the permeability of the samples. We examine the deliverability of engineered microbial solutions to promote coal bioconversion in coals and demonstrate that greater than milli-darcy permeability is required under in-situ stress conditions (Part III). This constraint is supplemented by imaging and a fractal-based characterization approach to evaluate changes in the physical properties of coal due to bio-gasification. High resolution SEM imaging is used to observe swelling of the coal matrix with sub-micron wide continuous pores observed to persist even after microbial treatment (IV). We explore the potential of generating, propping-open and sustaining the functionality of hydraulic fractures in coal using different fracturing fluids (Part V). The alteration of the nano-pore structure due to MECBM treatment is examined by using small angle X-ray scattering (SAXS) to define the in-situ porosity evolution as a proxy to infer permeability evolution (Part VI). Coupled hydro-mechanical and bio-gasification modeling is applied to determine the effectiveness of nutrient delivery by hydraulic fracturing and its field implementation. Compared with both the unstimulated and hydro-shear-dilated cases of the natural fracture network, hydraulic fracturing demonstrates a significant improvement to enhance nutrient delivery. A preliminary analysis of field-scale methane yield is completed with consideration of the combined influence of permeability evolution, solute transport and microbial growth (Part VII). Developing nutrient solutions for Illinois Basin and San Juan Basin (Task 2): To enhance methane release from coal through bio-gasification, suitable nutrient solutions are needed to stimulate microbial activities toward coal depolymerization and conversion to biogas. Specific for bituminous coal in the Illinois basin, a nutrient recipe that can be used to enhance coal bio- gasification in situ is developed. Based on our previous experience working with Illinois coal and the characteristics of the formation water and the indigenous microbial community, four parameters, Fe powder, methanol, ethanol, and trace minerals are optimized through using a Box-Behnken design. The optimal condition predicted by the models is: Fe-powder at 74 mM, methanol at 97.91 mM, ethanol at 100 mM, and trace minerals at 100%. Under these conditions, the predicted methane yield and content is 1,417.35 ft 3 /ton and 80.7%, respectively. These results are then validated by experimental studies. In addition, each added component is evaluated in terms of its contribution to methane generated. Specifically, the role of coal in the bio-gasification process is studied against two other solid materials. Experimental data from different solid matrices prove that coal is indeed degraded by the studied microbial community.

01 COAL, LIGNITE, AND PEAT↗

Maximizing REE Recovery in Geothermal Systems

Rare Earth element (REE) concentrations were measure in several on-land geothermal systems, many of which boil due to pressure drop during fluid upflow in geothermal production wells. REE were also measured in several seafloor hydrothermal systems sampled at pressures above the boiling point for comparison to boiled systems. Boiling during production lowers REE concentration in fluids sampled at the well head due to changes in fluid pH and Temperature that occur during boiling that affect the solubility of REE mineral phases. Geochemical calculations using the best available thermodynamic data were preformed to extend the understanding of REE behavior beyond the systems sampled for this study. Our data and modeling show that REE concentration in geothermal fluids is controlled by solubility limits, not by concentration in the source rocks. With the exception of La and Ce, the concentration of most of the REE in geothermal fluids are less than one part per trillion. There are no reasonable scenarios under which co-production of REE from geothermal fluids used to produce energy will contribute to the economic viability of the resource.

15 GEOTHERMAL ENERGY↗

Hybridizing Classifiers and Collection Systems to Maximize Intelligence and Minimize Uncertainty in National Security Data Analytics Applications

There are numerous applications that combine data collected from sensors with machine-learning based classification models to predict the type of event or objects observed. Both the collection of the data itself and the classification models can be tuned for optimal performance, but we hypothesize that additional gains can be realized by jointly assessing both factors together. Through this research, we used a seismic event dataset and two neural network classification models that issued probabilistic predictions on each event to determine whether it was an earthquake or a quarry blast. Real world applications will have constraints on data collection, perhaps in terms of a budget for the number of sensors or on where, when, or how data can be collected. We mimicked such constraints by creating subnetworks of sensors with both size and locational constraints. We compare different methods of determining the set of sensors in each subnetwork in terms of their predictive accuracy and the number of events that they observe overall. Additionally, we take the classifiers into account, treating them both as black-box models and testing out various ways of combining predictions among models and among the set of sensors that observe any given event. We find that comparable overall performance can be seen with less than half the number of sensors in the full network. Additionally, a voting scheme that uses the average confidence across the sensors for a given event shows improved predictive accuracy across nearly all subnetworks. Lastly, locational constraints matter, but sometimes in unintuitive ways, as better-performing sensors may be chosen instead of the ones excluded based on location. This being a short-term research effort, we offer a lengthy discussion on interesting next-steps and ties to other ongoing research efforts that we did not have time to pursue. These include a detailed analysis of the subnetwork performance broken down by event type, specific location, and model confidence. This project also included a Campus Executive research partnership with Texas A&M University. Through this, we worked with a professor and student to study information gain for UAV routing. This was an alternative way of looking at the similar problem space that includes sensor operation for data collection and the resulting benefit to be gained from it. This work is described in an Appendix.

97 MATHEMATICS AND COMPUTING↗

Maximizing the efficiency of plasma-based lepton accelerators

The next generation of particle accelerators will likely rely on compact accelerating structures to achieve very high gradients; one such candidate is accelerators using plasmas for the accelerating structures. Because of the small length scales of these structures, they can also be prone to the beam break-up instability, which would spoil the quality of the beam and leave it unsuitable for many applications. The goal of this project is to develop a framework for understanding the instabilities in plasma accelerators using language from conventional linear accelerator instabilities, such as wake fields and wake functions. During the course of this Phase I, we benchmarked a pseudo-spectral particle-in-cell code to determine its suitability for computing wake functions, and developed a procedure for extracting wake functions from a sequence of simulations using this code.

43 PARTICLE ACCELERATORS↗

Maximizing the Use of Ductless Mini-Splits in Homes with Existing Central or Zonal Heating and Cooling Equipment

In the residential retrofit application, ductless mini-split heat pumps (DHP) are often reported to hold high-energy savings potential, depending on the system they are supplementing or replacing. However, of late, there have been a number of studies and analyses indicating these energy savings are not being achieved. The primary goal of this project was to determine the most cost effective (lowest cost for the most energy saved) and persistent (e.g. automated, hard to change, etc.) solution for controlling a ductless heat pump in an existing home with central forced air furnace. Various control strategies were tested at the Pacific Northwest National Laboratory Lab Homes to compare the energy savings between the different energy efficient control strategies. A maximum of 40% energy savings was realized by using the ductless mini-split as the primary heat source with the central air conditioning unit as the secondary source.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

Maximizing Solar and Transportation Synergies

This report considers the technological and market pathways that will enable better use of photovoltaic (PV) electricity as fuel for future transportation demand. Most of the pathways identified will require collaborative research and development (R&D) efforts to improve the capabilities of multiple technologies, including PV, energy storage, vehicles, electrolyzers, electrofuels, and infrastructure. For plug-in electric vehicles (PEVs), technologies that enable wide-scale managed and coordinated charging are among the highest priorities for continued research, development, and deployment in the near term. Furthermore, managed and coordinated charging capabilities are foundational for future vehicle-to-grid (V2G) functionality in the long term. For hydrogen fuel cell electric vehicles (FCEVs), the use of PV electricity for electrolysis provides an opportunity to increase PV deployment. For rail, air, and maritime transportation, the feasibility of increased PV use varies in the near term; opportunities for synergies with solar include the electrification of rail, increased reliability from airport microgrids, and switching from heavy fuel oil to clean maritime electrofuels made from PV-based hydrogen. Over the longer term, battery swap stations for electric airplanes and the co-location of solar with hydrogen fueling stations at shipping ports may enable greater synergies between PV and transportation.

14 SOLAR ENERGY↗

Maximizing Scrap Recycling by Designing Cu Tolerant Steel Compositions

Residual elements from scrap steel recycling, most notably copper, are known to result in hot shortness during thermomechanical processing and casting. As the concentration of copper and other residuals in steel scrap streams increases, Electric Arc Furnace (EAF) scrap recycling heats commonly use pig iron to dilute residuals below current limits. This work focuses on establishing residual element tolerant compositions and concomitant processing windows that can simultaneously mitigate issues from residuals during thermomechanical processing and, if possible, use these residuals to improve properties, yielding a more sustainable steel manufacturing pathway with a substantially smaller carbon footprint.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

Maximizing Uptake of Hygroscopic Hydrogels Through Extreme Swelling-Induced Salt Loading

Hygroscopic hydrogels have emerged as scalable and low-cost materials with the potential of high-performance vapor sorption for atmospheric water harvesting, dehumidification, and passive cooling. Despite extensive research interest aimed at improving hygroscopic hydrogels, devices using these materials still exhibit insufficient performance, partly due to limited water uptake of the hydrogels. In this work, we study the swelling dynamics of hydrogels in aqueous lithium chloride solutions and use this to achieve extreme salt loading of hygroscopic hydrogels. By rationally tuning the salt concentration used for swelling we achieve successful synthesis of hygroscopic hydrogels with high water uptake of 1.76 g/g, 2.53 g/g, 3.80 g/g at relative humidites of 30%, 50%, and 70%, respectively, exceeding previous hydrogels by over 19%. These water uptakes bring the performance of hydrogels within ≈91% of the fundamental limit of commonly used hygroscopic salts, while still avoiding leakage problems common in salt solutions. Furthermore, we elucidate via models the maximum uptake achievable without leakage as a function of the operating relative humidity and hydrogel swelling ratio. The insights from this work can be used to design hygroscopic hydrogels with exceptional performance for a wide variety of sorption applications to tackle global challenges such as water scarcity and energy efficiency.

25 ENERGY STORAGE↗

Maximizing the impact of the Vera Rubin Observatory LSST, and DESI and CMB-S4 experiments in constraining gravity and dark sector physics

The work in this award has addressed our objectives on a number of fronts: Current graduate student Chris Wilson and Bean are determining how cosmic voids can be used to test the properties of gravity, leveraging simulations from DESI collaborator Baojiu Li and refining theoretical Gaussian Streaming Model approaches to predict galaxy dynamics in voids when the cosmology is not GR. This work is still underway, including analyses of the efficacy of void quadrupole correlation statistics and void size functions when studying dark matter halo statistics or the expected galaxy distributions from upcoming galaxy surveys; Current graduate student Yulin Gong, Bean with collaborators are refining techniques to extract out the kinetic Sunyaev Zel’dovich effect from galaxy cluster survey data and CMB temperature anisotropies, with the intent to further ready this pipeline development in readiness for spectroscopic data from DESI and LSST along with CMB-S4 measurements.

79 ASTRONOMY AND ASTROPHYSICS↗