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NASA NTRS2002

Rationalizing Burned Carbon with Carbon Monoxide Exported from South America

We present several estimates cross-checking the fluxes of carbon to the atmosphere from burning, comparing models that are based on simple land-surface parameterizations and atmospheric transport dynamics. Both estimates made by NASA Ames and USP modeling techniques are quite high compared to some detailed satellite/land-use studies of emissions. The flux of carbon liberated to the atmosphere via biomass burning is important for several reasons. This flux is a fundamental statistic for the parameterization of the large-scale flux of gases controlling the reactive greenhouse gases methane and ozone. Similarly, it is central to the estimation of the translocation of nitrogen and pyrodenitrification in the tropics. Thirdly, CO2 emitted from rainforest clearing contributes directly to carbon lost from the rainforest system as it contributes to greenhouse gas forcing. While CO2 from pasturage, agriculture, etc, is considered to be reabsorbed seasonally, and so "off budget" for the carbon cycle, it must also be accounted. CO2 anomalies related to daily weather and interannual climatic variation are strong enough to perturb our scientific perception of long-term carbon storage trends. We compare fluxes deduced from land-use statistics (originally, W.M. Hao) and from satellite hot pixels (A. Setzer) with atmospheric fluxes determined by the mesoscale/continental scale models RAMS and MM5, and point to some new work with highly resolved global models (the NASA Data Assimilation Office's GEOS4). Our simulations are tied to events, so that measured tracers like CO tie the models directly to the burning and meteorology of a specific period. We point out a particular sensitivity in estimates based on CO, and indicate how analysis of CO2 along with other biomass-burning tracers may lead to an improved multi-species estimator of carbon burned.

Chatfield, R.↗
NASA NTRS2011

Titan's Aerosol and Condensation Cloud Properties in the Far-IR Between 2005 and 2010

Analyses of far-IR spectra between 20 and 560 cm(exp -1) (500 to 18 micron) recorded by the Cassini Composite Infrared Spectrometer (CIRS) yield the spectral dependence and the vertical distribution of Titan's photochemical aerosol and ice clouds. Titan's aerosol appears to be well mixed between the surface and an altitude of 300 km, with a spectral shape that does not change with latitude or time. The aerosol exhibits an extremely broad emission feature with a spectral peak at 140 cm(exp -1) (71 micron), which is not evident in laboratory simulated Titan aerosols (tholin). This low- energy aerosol emission feature may arise from low-energy molecules such as polycyclic aromatic hydrocarbons and/or nitrogenated aromatics. Unlike the vertically well-mixed aerosol, Titan's condensate clouds are located in highly restricted altitudes in the lower stratosphere, ranging between 60 and 100 km at low and moderate latitudes, to between 150 and 165 km at high northern latitudes during northern winter. Such clouds are located at altitudes where nitrile vapors are expected to condense and appear to be dominated by HCN and HC3N, which are the two most abundant nitriles in Titan's atmosphere. Associated with this ice cloud is a broad emission feature that spectrally peaks near 160 cm(exp -1) (62.5 micron). This ice composite appears to chemically change with altitude and latitude, probably as a result of differences in vapor abundance and condensation temperature, and the ice cloud appears to be global in extent. Both CIRS and the Huygens Descent Imager and Spectral Radiometer (DISR) show evidence of cloud layering in Titan's lower stratosphere. The 15 km difference in cloud altitude indicated by the two instruments suggests a difference in ice composition. CIRS also indicates a second ice cloud that exists at isolated latitudes and is consistent with hydrocarbon condensation above the tropopause. This cloud exhibits an emission feature that spectrally peaks near 80 cm(exp -1) (125 micron), possibly due to C2H6 ice or dominated by an ethane-acetylene composite ice, given that CzH6 then C2H2 are the two most abundant hydrocarbons next to methane in Titan's atmosphere.

Anderson, Carrie↗
NASA NTRS2020

On the Role of Trend and Variability of Hydroxyl Radical (OH) in the Global Methane Budget

Decadal trends and interannual variations in the hydroxyl radical (OH), while poorly constrained at present, are critical for understanding the observed evolution of atmospheric methane (CH4). Through analyzing the OH fields simulated by the model ensemble of the Chemistry-Climate Model Initiative (CCMI), we find (1) the negative OH anomalies during the El Niño years mainly corresponding to the enhanced carbon monoxide (CO) emissions from biomass burning and (2) a positive OH trend during 1980-2010 dominated by the elevated primary production and the reduced loss of OH due to decreasing CO after 2000. Both two-box model inversions and variational 4D inversions suggest that ignoring the negative anomaly of OH during the El Niño years leads to a large overestimation of the increase in global CH4 emissions by up to10±3Tg yr-1to match the observed CH4 increase over these years. Not accounting for the increasing OH trends given by the CCMI models leads to an underestimation of the CH4 emission increase by 23±9Tg yr-1from 1986 to 2010. The variational inversion estimated CH4 emissions show that the tropical regions contribute most to the uncertainties related to OH. This study highlights the significant impact of climate and chemical feedbacks related to OH on the top-down estimates of the global CH4 budget.

Hydroxyl radical (OH)↗
NASA NTRS1986

A model of the spatial and temporal variation of the Uranus thermal structure

Seasonal variability of the temperature structure of Uranus is modeled for all latitudes in the .0004 to 2 bar pressure range in anticipation of the Voyager encounter in January 1986. Atmospheric heating in the model results on the one hand from an internal heat source and, on the other hand, from absorption of solar energy by methane and by non-conservative aerosols located between the 0.5 and 2 bar levels. Various cases for the behavior of the internal heat flux are investigated, such as constant with latitude or constrained to yield a time-averaged thermal emission independent of latitude. Meridional transport of heat in the stably stratified atmosphere is not taken into account. The results indicate that the Voyager encounter time, very small north-south temperature asymmetry should be expected. Moreover, the northern hemisphere, although not illuminated, should emit as much energy (within one percent) as the southern hemisphere at this date. At a given latitude, extreme temperatures are reached at the equinoxes. At the poles, seasonal amplitudes of about 10 K in the upper stratosphere and 6 K at the 0.6 bar level are predicted, and the variation with time of the emission to space is found to be at most 20 percent. The atmosphere of Uranus appears to be characterized by very long radiative response times (mainly due to its cold temperature) which inhibit the large seasonal variations that one could otherwise expect in view of the high obliquity of the planet and its long orbital period.

Bezard, B.↗
NASA NTRS2011

A Model Study of the Impact of Source Gas Changes on the Stratosphere for 1850-2100

The long term stratospheric impacts due to emissions of CO2, CH4, N2O, and ozone depleting substances (ODSs) are investigated using an updated version of the Goddard two-dimensional (2D) model. Perturbation simulations with the ODSs, CO2, CH4, and N2O varied individually are performed to isolate the relative roles of these gases in driving stratospheric changes over the 1850-2100 time period. We also show comparisons with observations and the God- 40 dard Earth Observing System chemistry-climate model simulations for the time period 1970-2100 to illustrate that the 2D model captures the basic processes responsible for longterm stratospheric change. The 2D simulations indicate that prior to 1940, the 45 ozone increases due to CO2 and CH4 loading outpace the ozone losses due to increasing N2O and carbon tetrachloride (CCl4) emissions, so that ozone reaches a broad maximum during the 1920s-1930s. This preceeds the significant ozone depletion during approx. 1960-2050 driven by the ODS loading. During the latter half of the 21st century as ODS emissions diminish, CO2, N2O, and CH4 loading will all have significant impacts on global total ozone based on the IPCC AIB (medium) scenario, with CO2 having the largest individual effect. Sensitivity tests illustrate that due to the strong chemical interaction between methane and chlorine, the CH4 impact on total ozone becomes significantly more positive with larger ODS loading. The model simulations also show that changes in stratospheric temperature, Brewer-Dobson circulation (BDC), and age of air during 1850-2100 are controlled mainly by the CO2 and ODS loading. The simulated acceleration of the BDC causes the age of air to decrease by approx. 1 year from 1860-2100. The corresponding photochemical lifetimes of N2O, CFCl3, CF2Cl2, and CCl4 decrease by 11-13% during 1960-2100 due to the acceleration of the BDC, with much smaller lifetime changes 4%) caused by changes in the photochemical loss rates.

Fleming, E. L.↗
NASA NTRS2001

Suppression of Low Strain Rate Nonpremixed Flames by an Agent

The agent concentration required to achieve the suppression of low strain rate nonpremixed flames is an important consideration for fire protection in a microgravity environment such as a space platform. Currently, there is a lack of understanding of the structure and extinction of low strain rate (<20 s(exp -1)) nonpremixed flames. The exception to this statement is the study by Maruta et al., who reported measurements of low strain rate suppression of methane-air diffusion flames with N2 added to the fuel stream under microgravity conditions. They found that the nitrogen concentration required to achieve extinction increased as the strain rate decreased until a critical value was obtained. As the strain rate was further decreased, the required N2 concentration decreased. This phenomenon was termed "turning point" behavior and was attributed to radiation-induced nonpremixed flame extinction. In terms of fire safety, a critical agent concentration assuring suppression under all flow conditions represents a fundamental limit for nonpremixed flames. Counterflow flames are a convenient configuration for control of the flame strain rate. In high and moderately strained near-extinction nonpremixed flames, analysis of flame structure typically neglects radiant energy loss because the flames are nonluminous and the hot gas species are confined to a thin reaction zone. In counterflowing CH4-air flames, for example, radiative heat loss fractions ranging from 1 to 6 percent have been predicted and measured. The objective of this study is to investigate the impact of radiative emission, flame strain, agent addition, and buoyancy on the structure and extinction of low strain rate nonpremixed flames through measurements and comparison with flame simulations. The suppression effectiveness of a number of suppressants (N2, CO2, or CF3Br) was considered as they were added to either the fuel or oxidizer streams of low strain rate methane-air diffusion flames.

Hamins, A.↗
NASA NTRS1995

Organic Molecules in Oxygen-Rich Circumstellar Envelopes: Methanol and Hydrocarbons

The existence of anomalously high abundances of gaseous CH4 has been invoked to explain the unexpectedly high abundances of the carbon-bearing molecules HCN and H2CO in the outflows from O-rich red giants. We have modelled the chemistry that proceeds in the outer envelope when CH4 is injected from the inner envelope. We find that photolysis by the interstellar radiation field drives an ion-neutral chemistry which produces several organic molecules. The calculated abundances of CH3OH, C2H and C2 can be comparable to those calculated for H2CO and HCN. Species such as C2H4, C2H2 and CH3CN can also be abundant. A search for CH3OH and C2H in several O-rich outflows known to exhibit strong HCN emission is needed. As it derives entirely from the CH4 photochain, is insensitive to the envelope temperature distribution, and has accessible transitions at millimetre wavelengths, the detection of the C2H radical would provide further indirect support for the presence of the hypothesized methane.

Charnley, S. B.↗
NASA NTRS1981

Latitudinal variations in Jovian stratospheric temperature

Ground-based observations of Jupiter show that the planet's stratospheric and tropospheric thermal emission are anticorrelated. The observations can possibly be explained by latitudinal variations in cloud altitude. These variations cause differential stratospheric heating by sunlight which is reflected off the clouds and then absorbed within the stratosphere by visible and near-infrared bands of methane.

Cess, R. D.↗
NASA NTRS1985

Combustion efficiency of a premixed continuous flow combustor

Exhaust gas temperature, velocity, and composition measurements at various radial locations at the combustor exit are presented for a swirling-flow continuous combustor of a confined concentric jet configuration operating on premixed propane or methane and air. The main objective of the study is to determine the effect of fuel substitution and of changes in outer flow swirl conditions on the combustor performance. It is found that there is no difference in observed properties for propane and methane firing; the use of either of the fuels results in nearly the same exit temperature and velocity profiles and the same efficiency for a given operating condition. A mechanism for combustion is proposed which explains qualitatively the changes in efficiency and pollutant emissions observed with changing swirl.

Anand, M. S.↗
NASA NTRS1988

Ozone reduction in the 1980's - A model simulation of anthropogenic and solar perturbations

An interpretation of global ozone changes deduced from satellite data obtained since 1979 is presented, based on two-dimensional model simulations. The study shows that a depletion in total ozone of the order of 2 percent and a reduction in ozone density near 40 km of 7 to 12 percent over the 1979-1986 period are consistent with the observed increase in trace gas densities (chlorofluorocarbons, methane, nitrous oxide, carbon dioxide) and the simultaneous decrease in solar activity during this period. The model also suggests that ozone variations of solar and anthropogenic origins between 1979 and 1986 were of similar magnitude but that the ozone response to trace gas emissions increases substantially with latitude while the solar signal in ozone is present lower in the atmosphere and is nearly independent of latitude.

Brasseur, Guy↗
NASA NTRS2018

The GeoCarb Mission: One Tool in the Evolving Understanding of Methane and Carbon Monoxide Budgets

NASA plans to operate an instrument in geostationary orbit over the Americas beginning in 2022. This mission allows a coordinated study of climate-determining carbon species. Prime focus is on CO2 fluxes, but the reactive species CO and CH4 are particularly relevant to IGAC. Measurements of solar-induced fluorescence will describe plant photosynthesis contemporaneous with emissions. To outline the technology: Grating mapping spectrometery, using a single slit and four focal planes set at 0.76, 1.60, 2.07, and 2.32 microns and ~17000 resolving power. Retrieval profiting from the rich heritage of OCO-2, GOSAT, TropOMI, and GOME/SCIAMACHY. Column concentrations of CO2, CH4, and CO, with finest resolution at 3 km x 6 km. A selection of scans allowing appreciable refinement in fluxes of CO2 and CH4. Rapid re-pointing allowing at least one synoptic observation of all North and South America daily, and 3 observations through the day for selected areas.This presentation is an appeal to IGAC community to use GeoCarb to help improve the attribution of fluxes by sector and by geography. Cost constraints allow GeoCarb only limited listed goals. For example, GeoCarb aspires to constrain CH4 emissions for the whole US, closing the ~60% gap between US EPA estimation and 3-d models. Detailed CO measurements should also aid photochemical and aerosol studies. NASA's TEMPO (UV-Vis geostationary) instrument will overlap GeoCarb. Consequently, HCHO, NO2, aerosol, and CO may be intercompared, allowing elucidation of chemical sources and also transformation timescales. We expect that Sentinel-5P's TropOMI will lead the way here; geostationary imaging will allow diurnal views and reduced cloud obscuration of interesting areas. Analysis of current data suggests interesting questions: (a) puzzling XCH4 diel variations in the Amazonian rainforest; (b) time-varying CO/NO2 relationships in urban plumes. We also urge the suite of airborne and small-sat measurements needed to complete the story at fine scales.

Chatfield, Robert B.↗
NASA NTRS2011

Physical Properties and Seasonal Behavior of H2O, HDO, CO2 and Trace Gases on Mars: Quantitative Mapping from Earth-Based Observatories

Since 1997, we have used high-resolution (R greater than 40000) spectrometers on ground based-telescopes to study molecules that have astrobiological significance in Mars' atmosphere. We have used the NASA-IRTF, Keck II, and VLT telescopes in the 1.0-5.0 micron range. The spectrometer is set at a wavelength to detect specific molecules. Spectral/spatial images are produced. Extracts from these images provide column densities centered at latitude/longitude locations (resolution ~400km at sub-Earth point). We have mapped the O2 singlet-Delta emission (a proxy for ozone), HDO, and H2O for seasonal dates throughout the Martian year. Previously undiscovered isotopic bands of CO2 have been identified along with isotopic forms of CO. We are searching for other molecules that have astrobiological importance and have successfully measured methane in Mars' atmosphere.

Novak, Robert E.↗
NASA NTRS2022

Accurate Modeling of Lyα Profiles and their Impact on Photolysis of Terrestrial Planet Atmospheres

Accurately measuring and modeling the Lyα (Lyα; λ1215.67 Å) emission line from low-mass stars is vital for our ability to build predictive high energy stellar spectra, yet interstellar medium (ISM) absorption of this line typically prevents model-measurement comparisons. Lyα also controls the photodissociation of important molecules, like water and methane, in exoplanet atmospheres such that any photochemical models assessing potential biosignatures or atmospheric abundances require accurate Lyα host star flux estimates. Recent observations of three early M and K stars (K3, M0, M1) with exceptionally high radial velocities (>100 km s −1 ) reveal the intrinsic profiles of these types of stars as most of their Lyα flux is shifted away from the geocoronal line core and contamination from the ISM. These observations indicate that previous stellar spectra computed with the PHOENIX atmosphere code have underpredicted the core of Lyα in these types of stars. With these observations, we have been able to better understand the microphysics in the upper atmosphere and improve the predictive capabilities of the PHOENIX atmosphere code. Since these wavelengths drive the photolysis of key molecular species, we also present results analyzing the impact of the resulting changes to the synthetic stellar spectra on observable chemistry in terrestrial planet atmospheres.

Sarah Peacock↗
NASA NTRS2007

Determination of Combustion Product Radicals in a Hydrocarbon Fueled Rocket Exhaust Plume

The identification of metallic effluent materials in a rocket engine exhaust plume indicates the health of the engine. Since 1989, emission spectroscopy of the plume of the Space Shuttle Main Engine (SSME) has been used for ground testing at NASA's Stennis Space Center (SSC). This technique allows the identification and quantification of alloys from the metallic elements observed in the plume. With the prospect of hydrocarbon-fueled rocket engines, such as Rocket Propellant 1 (RP-1) or methane (CH4) fueled engines being considered for use in future space flight systems, the contributions of intermediate or final combustion products resulting from the hydrocarbon fuels are of great interest. The effect of several diatomic molecular radicals, such as Carbon Dioxide , Carbon Monoxide, Molecular Carbon, Methylene Radical, Cyanide or Cyano Radical, and Nitric Oxide, needs to be identified and the effects of their band systems on the spectral region from 300 nm to 850 nm determined. Hydrocarbon-fueled rocket engines will play a prominent role in future space exploration programs. Although hydrogen fuel provides for higher engine performance, hydrocarbon fuels are denser, safer to handle, and less costly. For hydrocarbon-fueled engines using RP-1 or CH4 , the plume is different from a hydrogen fueled engine due to the presence of several other species, such as CO2, C2, CO, CH, CN, and NO, in the exhaust plume, in addition to the standard H2O and OH. These species occur as intermediate or final combustion products or as a result of mixing of the hot plume with the atmosphere. Exhaust plume emission spectroscopy has emerged as a comprehensive non-intrusive sensing technology which can be applied to a wide variety of engine performance conditions with a high degree of sensitivity and specificity. Stennis Space Center researchers have been in the forefront of advancing experimental techniques and developing theoretical approaches in order to bring this technology to a more mature stage.

Langford, Lester A.↗
NASA NTRS2015

Pulling Results Out of Thin Air: Four Years of Ozone and Greenhouse Gas Measurements by the Alpha Jet Atmospheric Experiment (AJAX)

The Alpha Jet Atmospheric eXperiment (AJAX) has been measuring atmospheric ozone, carbon dioxide, methane and meteorological parameters from near the surface to 8000 m since January 2011. The main goals are to study photochemical ozone production and the impacts of extreme events on western US air quality, provide data to support satellite observations and aid in the quantification of emission sources e.g. wildfires, urban outflow, diary and oil and gas. The aircraft is based at Moffett Field and flies multiple times a month to sample vertical profiles at selected sites in California and Nevada, providing long-term data records at these sites. AJAX is also uniquely positioned to launch with short notice sampling flights in rapid response to extreme events e.g. the 2013 Yosemite Rim fire. This talk will focus on the impacts of vertical transport on surface air quality, and investigation of emission sources from diaries and wildfires.

AJAX↗
NASA NTRS1986

Atmospheric methane sources - Alaskan tundra bogs, an alpine fen, and a subarctic boreal marsh

Methane (CH4) flux measurements from Alaska tundra bogs, an alpine fen, and a subarctic boreal marsh were obtained at field sites ranging from Prudhoe Bay on the coast of the Arctic Ocean to the Alaskan Range south of Fairbanks during August 1984. In the tundra, average CH4 emission rates varied from 4.9 mg CH4 per sq m per day (moist tundra) to 119 mg CH4 per sq m per day (waterlogged tundra). Fluxes averaged 40 mg CH4 per sq m per day from wet tussock meadows in the Brooks Range and 289 mg Ch4 per sq m per day from an alpine fen in the Alaskan Range. The boreal marsh had an average CH4 emission rate of 106 mg CH4 per sq m per day. Significant emissions were detected in tundra areas where peat temperatures were as low as 4 C, and permafrost was only 25 cm below the ground surface. Emission rates from the 17 sites sampled were found to be logarithmically related to water levels at the sites. Extrapolation of the data to an estimate of the total annual CH4 emission from all arctic and boreal wetlands suggests that these ecosystems are a major source of atmospheric CH4 and could account for up to 23 percent of global CH4 emissions from wetlands.

Sebacher, D. I.↗
NASA NTRS2016

Scientific and Technical Assistance for the Deployment of a Flexible Airborne Spectrometer System During C-MAPExp and COMEX: COMEX Version - 1.9T

The COMEX (CO2 and MEthane eXperiment) campaign supports the mission definition of CarbonSat and HyspIRI (Hyperspectral Infrared Imager) by providing representative airborne remote sensing data ‐ MAMAP (Methane Airborne MAPper) for CarbonSat; the Airborne Visual InfraRed Imaging Spectrometer (Classic & Next Generation) AVIRIS‐C/AVIRIS‐NG for HyspIRI ‐ as well as ground-based and airborne in‐situ data. The objectives of the COMEX campaign activities are (see Campaign Implementation Plan (RD‐4)): 1. Investigate spatial/spectral resolution trade‐offs for CH4 anomaly detection and flux inversion by comparison of MAMAP‐derived emission estimates with AVIRIS/AVIRIS‐NG derived data. 2. Evaluate sun‐glint observation geometry on CH4 retrievals for marine sources. 3. Characterize the effect of Surface Spectral Reflectance (SSR) heterogeneity on trace gas retrievals of CO2 and CH4 for medium and low‐resolution spectrometry. 4. Identify benefits from joint SWIR/TIR (ShortWave InfraRed/Thermal InfraRed ) data for trace gas detection and retrieval by comparison of MAMAP and AVIRIS/AVIRIS‐NG NIR/SWIR data with MAKO (Aerospace Corp.)TIR data. The ability to derive emission source strength for a range of strong emitting targets by remote sensing will be evaluated from combined AVIRIS‐NG and MAMAP data, adding significant value to the HyspIRI campaign AVIRIS‐NG dataset. The data will be used to quantify anomalies in atmospheric CO2 and CH4 from strong local greenhouse gas sources e.g. localized industrial complexes, landfills, etc. and to derive CO2 and CH4 emissions estimates from atmospheric gradient measurements. The original campaign concept was developed by University of Bremen and BRI. The COMEX campaign is funded bilaterally by NASA and ESA (European Space Agency). Whereas NASA funds the US part of the project via a contract with Dr. Ira Leifer, BRI (Bubbleology Research International), the contribution of MAMAP to the COMEX campaign is funded by ESA within the COMEX‐E project and NASA with respect to a 50 percent contribution to the flight-related costs of flying MAMAP on a US aircraft. The Data Acquisition Report (RD‐9) describes the instrumentation used, the measurements made by the team during the COMEX campaign in May/June 2014 and August/September 2014 in California, and an initial assessment of the data quality.

Point Sources↗
NASA NTRS2018

The Gas Composition and Deep Cloud Structure of Jupiter's Great Red Spot

We have obtained high-resolution spectra of Jupiter's Great Red Spot (GRS) between 4.6-5.4 microns using telescopes on Mauna Kea to derive gas abundances and to constrain its cloud structure between 0.5-5 bars. We used line profiles of deuterated methane (CH3D) at 4.66 microns to infer the presence of an opaque cloud at 5 plus or minus 1 bars. From thermochemical models, this is almost certainly a water cloud. We also used the strength of Fraunhofer lines in the GRS to obtain the ratio of reflected sunlight to thermal emission. The level of the reflecting layer was constrained to be at 570 plus or minus 30 millibars based on fitting strong NH3 lines at 5.32 microns. We identify this layer as an ammonia cloud based on the temperature where gaseous NH3 condenses. We found evidence for a strongly absorbing but not totally opaque cloud layer at pressures deeper than 1.3 bars by combining Cassini/CIRS (Composite Infrared Spectrometer) spectra of the GRS at 7.18 microns with ground-based spectra at 5 microns. This is consistent with the predicted level of an NH4SH cloud. We also constrained the vertical profile of H2O and NH3. The GRS spectrum is matched by a saturated H2O profile above an opaque water cloud at 5 bars. The pressure of the water cloud constrains Jupiter's O/H ratio to be at least 1.1 times solar. The NH3 mole fraction is 200 plus or minus 50 ppm (parts per million) for pressures between 0.7-5 bars. Its abundance is 40 ppm at the estimated pressure of the reflecting layer. We obtained 0.8 plus or minus 0.2 ppm for PH3, which is a factor of 2 higher than in the warm collar surrounding the GRS. We detected all five naturally occurring isotopes ofgermanium in GeH4 in the GRS. We obtained an average value of 0.35 plus or minus 0.05 ppb (parts per billion) for GeH4. Finally, we measured 0.8 plus or minus 0.2 ppb for CO in the deep atmosphere.

Bjoraker, G. L.↗