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NASA NTRS1987

Petrology and geochemistry of alkali gabbronorites from lunar breccia 67975

Detailed results of petrologic and compositional studies of three clasts found in thin sections of the Apollo 16 lunar breccia 67975 and of four clasts extracted from the breccia (for instrumental neutron activation analysis) prior to thin sectioning are reported. The alkali gabbronorites of the breccia form two distinct subgroups, magnesian and ferroan. The magnesian gabbronorites are composed of bytownitic plagioclase, hypersthene, augite, a silica mineral, and trace Ba-rich K-feldspar. The ferroan gabbronorites are composed of ternary plagioclase, pigeonite, augite, Ba-rich K-feldspar, and a silica mineral. Trace minerals in both subgroups are apatite, REE-rich whitlockite, and zircon. The magnesian and ferroan alkali gabbronorites appear to have formed by progressive differentiation of the same, or closely related, parent REE-rich magmas.

James, Odette B.↗
NASA NTRS1987

The lunar regolith - Chemistry and petrology of Luna 24 grain size fractions

Chemical data obtained by instrumental neutron activation analysis are reported for 30 elements in eight lunar soil size fractions from 370 to less than 2 microns, as well as petrology for five size fractions down to 40-10 microns in two Luna 24 soils. While the compositions of coarser fractions are similar to each other, they differ from the fractions smaller than 10 microns; these become increasingly feldspathic and enriched in large ion lithophile elements (LILE) with decreasing grain size. The high concentrations of the Ni, Au and Ir meteoritic indicator elements in these finer fractions are consistent with comminution by meteoritic impact. Size distributions, petrology and LILE patterns indicate that Luna 24 soils are less reworked than most lunar soils.

Laul, J. C.↗
NASA NTRS1987

Diverse eucritic pebbles in the Vaca Muerta mesosiderite

Seven 5-cm basaltic pebbles from the Vaca Muerta mesosiderite were studied by neutron activation and electron microprobe analysis, and three additional pebbles were studied petrographically. The cumulate pebbles had low REE concentrations and high Eu/Sm ratios, indicating the absence of intercumulus liquid. Siderophile interelement ratios were similar to those found in Vaca Muerta metal except for anomalously low Ir concentrations. The presence of 20 percent impact-melt breccias among the pebbles and 35-40 percent melt breccias among the mesosiderite whole-rocks suggests that the mesosiderites were more extensively impact melted than the howardites. Three alternative models to explain this greater proportion of impact-melted material among the mesosiderites are proposed.

Rubin, Alan E.↗
NASA NTRS1987

Ru, Re, Os, Pt and Au in iron meteorites

Neutron activation analysis is used to ascertain the proportions of Ru, Re, Os, and Pt refractory siderophiles, and moderately volatile Au, in 41 iron meteorites. The Ni-element trends defined for groups IID and IIIF support a magmatic origin; in addition, the results obtained for groups IAB and IIICD contrast with trends observed in magmatic groups, where the Ru and Pt slopes are substantially less steep. In group IIIAB, at Ni concentrations above 90 mg/g, the steep decrease of Re, Os, and Ir with Ni levels off, and the interelement ratios exhibit considerable scatter. These observations may be explained in terms of the contamination of the residual molten core with small amounts of late primitive melts draining from the mantle.

Pernicka, Ernst↗
NASA NTRS1987

Nuclear techniques in studies of condensed matter

Nuclear techniques have played an important role in the studies of materials over the past several decades. For example, X-ray diffraction, neutron diffraction, neutron activation, and particle- or photon-induced X-ray emission techniques have been used extensively for the elucidation of structural and compositional details of materials. Several new techniques have been developed recently. Four such techniques are briefly reviewed which have great potential in the study and development of new materials. Of these four, Mossbauer spectroscopy, muon spin rotation, and positron annihilation spectroscopy techniques exploit their great sensitivity to the local atomic environments in the test materials. Interest in synchrotron radiation, on the other hand, stems from its special properties, such as high intensity, high degree of polarization, and high monochromaticity. It is hoped that this brief review will stimulate interest in the exploitation of these newer techniques for the development of improved materials.

Singh, Jag J.↗
NASA NTRS1988

Fine-scale traverses in cumulate rocks, Stillwater Complex: A lunar analogue study

The objective was to document finite-scale compositional variations in cumulate rocks from the Stillwater Complex in Montana and to interpret these data in the context of planetary magma fractionation processes such as those operative during the formation of the Earth's Moon. This research problem involved collecting samples in the Stillwater Complex and analyzing them by electron microprobe, X-ray fluorescence (XRF), and instrumental neutron activation analysis (INAA). The electron microprobe is used to determine the compositions of cumulus and intercumulus phases in the rocks, the XRF is used to determine the bulk-rock major element and trace element (Y, Sr, Rb, Zr, Ni, and Cr) abundances, and the INAA lab. is used to determine the trace element (Sc, Co, Cr, Ni, Ta, Hf, U, Th, and the REE) abundances of mineral separates and bulk rocks.

Elthon, Donald↗
NASA NTRS1987

Compositional evidence regarding the origins of rims on Semarkona chondrules

This paper presents results on neutron activation analyses of the interiors and the abraded surfaces of seven chondrules from Semarkona chondrite. The results showed that six of seven chondrule rims have enhanced contents of siderophiles and chalcophiles relative to chondrule interiors, indicating that, during chondrule formation, metal/sulfide melts migrated to the exterior of the chondrule; later reheating caused this material to spread out into fine-grained rim material. For nonvolatile elements, the lithophile and siderophile element abundance patterns in the surfaces are generally similar to those in the corresponding interiors, indicating that the surface and the interior metal might have originated from a single precursor. The volatile to moderately-volatile elements K, As, and Zn tend to be enriched in the surface, compared with other elements of similar mineral affinity.

Grossman, Jeffrey N.↗
NASA NTRS1988

Chondrules and matrix in the Ornans CO3 meteorite - Possible precursor components

Bulk compositions of 17 chondrules and one sample of matrix from CO3 Ornans were determined by instrumental neutron activation analysis. Chondrule precursor components deduced from chondrule compositions are characterized by: (1) common and slightly volatile siderophiles, Cr and chalcophiles, (2) refractory lithophiles and Na, (3) Mn, Si and modal pyroxene, and (4) FeO and olivine. Component 4 may be closely related to matrix material. Precursor components have now been inferred for OC, EH, CV, CM and CO chondrules. An MN- and Si-rich component occurs exclusively among carbonaceous chondrite chondrules. Although there are significant intergroup differences, common to chondrules in all chondrite groups are refractory-lithophile-rich, common-siderophile-rich, and (with the exception of EH) common-lithophile-rich components. This indicates that the siderophile/lithophile and refractory lithophile/common lithophile fractionations recorded in chondrite whole-rocks were established prior to chondrule formation at all nebular locations.

Rubin, Alan E.↗
NASA NTRS1988

Igneous history of the aubrite parent asteroid - Evidence from the Norton County enstatite achondrite

Numerous specimens of the Norton County enstatite achondrite (aubrite) were studied by optical microscopy, electron microprobe, and neutron-activation analysis. Norton County is found to be a fragmental impact breccia, consisting of a clastic matrix made mostly of crushed enstatite, into which are embedded a variety of mineral and lithic clasts of both igneous and impact melt origin. The Norton County precursor materials were igneous rocks, mostly plutonic orthopyroxenites, not grains formed by condensation from the solar nebula. The Mg-silicate-rich aubrite parent body experienced extensive melting and igneous differentiation, causing formation of diverse lithologies including dunites, plutonic orthopyroxenites, plutonic pyroxenites, and plagioclase-silica rocks. The presence of impact melt breccias (the microporphyritic clasts and the diopside-plagioclase-silica clast) of still different compositions further attests to the lithologic diversity of the aubrite parent body.

Okada, Akihiko↗
NASA NTRS1988

Trace element partitioning between taenite and kamacite - Relationship to the cooling rates of iron meteorites

Instrumental neutron activation analysis (INAA) was used to determine Ni, Co, Cu, Ga, As, Au, W, Re and Ir in taenite lamellae isolated by acid dissolution from eight iron meteorites from groups IA, IIIAB and IVA. Taenite is enriched in Ni, Cu, Ga, As, Au, W, Re and Ir relative to kamacite, whereas taenite is depleted in Co. Taenite/kamacite partition ratios in slowly cooled IAB meteorites are farther from unity than those in rapidly cooled IVA meteorites. Taenite/kamacite partition ratios for Cu, Ir, Au and Co may be sensitive cooling rate indicators.

Rasmussen, Kaare L.↗
NASA NTRS1988

Possible world-wide middle miocene iridium anomaly and its relationship to periodicity of impacts and extinctions

In a study of one million years of Middle Miocene sediment deposition in ODP Hole 689B in the Weddell Sea near Antarctica, a single iridium (Ir) anomaly of 44 (+ or - 10) x 10 to the 12th gram Ir per gram rock (ppt) was observed in core 6H, section 3, 50 to 60 cm, after background contributions associated with manganese precipitates and clay are subtracted. The ODP Hole 689B is 10,000 km away from another site, DSDP Hole 588B in the Tasman Sea north of New Zealand, where a single Ir anomaly of 144 + or - 7 ppt over a background of 11 ppt was found in an earlier study of 3 million years of deposition. From chemical measurements the latter deposition was thought to be impact-related. Ir measurements were made, following neutron activation, with the Iridium Coincidence Spectrometer. The age vs depth calibration curves given in the DSDP and ODP preliminary reports indicate the ages of the Iranomalies are identical, 11.7 million years, but the absolute and relative uncertainties in the curves are not known. Based on the newest age data the age estimate is 10 million years. As the Ir was deposited at the two sites at about the same time and they are one quarter of the way around the world from each other it seems likely that the deposition was world-wide. The impact of a large asteroid or comet could produce the wide distribution, and this data is supportive of the impact relationship deduced for Deep Sea Drilling Project (DSDP) 588B from the chemical evidence. If the surface densities of Ir at the two sites are representative of the world-wide average, the diameter of a Cl type asteroid containing the necessary Ir would be 3 + or - 1 km, which is large enough to cause world-wide darkness and hence extinctions although the latter point is disputed.

Asaro, F.↗
NASA NTRS1988

Noble metals in mid-ocean ridge volcanism: A significant fractionation of gold with respect to platinum group metals

Hydrothermal precipitates, black smoker particulate, and massive sulphide dredge samples from the Explorer Ridge on the Juan de Fuca Plate and the TAG hydrothermal area on the Mid-Atlantic Ridge were analyzed for selected noble metals including Au, Ir and Pd by radiochemical neutron activation analysis. The preliminary results indicate that gold contents may reach the ppm range although values in the neighborhood of 100 to 200 ppb are more typical. The platinum group elements (PGE) represented by Ir and Pd are typically less than 0.02 ppb and less than 2 ppb respectively. These abundances represent a significant enrichment of gold relative to the PGE in comparison with average noble metal abundances in mid-ocean ridge basalts (MORB). A partial explanation of this distinctive fractionation can be found in the concepts of sulfur-saturation of basic magma in mid-ocean ridge (MOR) settings, and the origin of MOR hydrothermal fluids. Experimental and petrological data suggest that MORBs are sulfur-saturated at the time of magma generation and that an immiscible sulfide component remains in the mantle residue. Hence, MORBs are noble metal-poor, particularly with respect to PGE. Consequently, black smoker fluids can be expected to reflect the low Ir and Pd contents of the rock column. The average Au content of MORB is 1.3 ppb, and so the rock column is not significantly enriched in Au. The generation of fluids which precipitate solids with 200 ppb Au is apparently dependent on highly efficient fluid chemistry to mobilize Au from the rock column, high Au solubility in seawater hydrothermal fluids and efficient precipitation mechanisms to coprecipitate Au on Fe, Zn and Cu sulfides. Significant differences in these parameters appear to be the ultimate cause of the strong Au-PGE fractionation in the MOR setting. It does not appear from the current data base that MOR hydrothermal fluids are significant contributors to the Ir enrichment seen in Cretaceous-Tertiary boundary sediments.

Crocket, James H.↗
NASA NTRS1988

Isotopic investigations in the area of the Tunguska catastrophe in 1908 year

The hypotheses of the annihilation and thermonuclear character of the Tunguska explosion have been tested by measuring inductive Ar-39 radioactivity from K and Ca in rocks and soil under the explosion epicentrum. Ar-39 was not detected though its estimated radioactivity was expected to be 100 times higher than the radio-metrical plant sensitivity. These results testify against the nuclear nature of the Tunguska explosion. The contents of 11 elements in the ultrasmall quantity of matter of the silicate microspherules isolated from catastrophe peat layer at the explosion site were measured by method of neutron activation analysis. It was demonstrated that the enrichment of microspherules by light and volatile elements (Al, Na, Zn, Cs) and the impoverishment by more heavy and hard volatile ones (Fe, Co, Sc). It was shown that the microspherules were not the product of differentiation of the terrestrial soil or of an ordinary meteorite material. It was demonstrated that Pb isotopic content in catastrophe peat layer had more Pb-204, Pb-207, Pb-208 than Pb-206 as compared with Pb isotopic content of other peat layers and common Pb in this area. In the peat column taken at the Ostraya hill area in three nearcatastrophe layers, small increases of isotopic C-13 was determined. Isotopic C effect in the peat layer is confirmed also for the North peatbog. Observed isotopic changes are not accounted for by climatic changes or other physico-chemical reasons. They seem to be related to preservation in the peat of matter resembling carbonaceous chrondrites of the Cl type or more probably of cometary matter enriched much more in volatile elements.

Kolesnikov, E. M.↗
NASA NTRS1988

The reliability of macroscopic identification of lunar coarse fines particles and the petrogenesis of 2-4 mm particles in Apennine Front sample 15243

Particles from the 15243 Apennine Front sample (Station 6) were studied using macroscopic, neutron activation, and petrographic methods. It was found that macroscopic identifications allow for good identification of the particles. It was shown that the Station 6 regolith must consist of a fine-grained, comparatively KREEP-poor material and a coarser component consisting of Apollo 15 KREEP basalts and KREEP-like impact melt fragments.

Ryder, Graham↗
NASA NTRS1988

Cumberland Falls chondritic inclusions. III - Consortium study of relationship to inclusions in Allan Hills 78113 aubrite

The contents of Ag, Au, Bi, Cd, Co, Cs, Ga, In, Rb, Sb, Se, Te, Tl, U, and Zn in large chondritic clasts from the Cumbersand Falls aubrite were determined by radiochemical neutron activation analysis, and the results, together with the results of a mineralogical investigation, were compared with respective data obtained for three primitive inclusions from the ALH A78113 aubrite. The results indicated that the clasts from both aubrite sources constitute a single chondritic suite. The analyses data, together with the results of thermoluminescence data for Cumberland Falls chondritic inclusions and achondritic host, indicate that inclusions in Cumberland Falls and in ALH A78113 aubrite represent a primitive chondrite sample suite whose properties were established during primary nebular accretion and condensation over a broad redox range.

Lipschutz, Michael E.↗
NASA NTRS1989

Chondrules in the Sharps H3 chondrite - Evidence for intergroup compositional differences among ordinary chondrite chondrules

Bulk compositions of 19 chondrules and one matrix-rich sample from H3.4 Sharps were determined by instrumental neutron activation analysis. Samples were characterized petrographically, and mineral compositions were determined by electron microprobe analysis. There is constancy among ordinary chondrite (OC) groups in the compositional interrelationships of different chondrule types; e.g., in H3 as well as L3 and LL3 chondrites, porphyritic chondrules are more refractory than nonporphyritic chondrules. Precursor components of H3 chondrules are closely related to those of LL3 chondrules. The mean Ir/Ni, Ir/Co, and Ir/Au ratios of H3 chondrules differ from the corresponding ratios of LL3 chondrules at the 99, 90, and 79 percent confidence levels, respectively. The ratios in H3 chondrules exceed those in LL3 chondrules by amounts similar to those by which H whole-rocks exceed LL whole-rocks. These data suggest that there are primary systematic differences in bulk composition between H and LL chondrules. These differences support the inference that chondrule formation occurred after major nebular fractionation events had established the observed bulk compositional differences among OC groups.

Rubin, Alan E.↗
NASA NTRS1988

Compositional study of a suite of samples from the 28-t Armanty (Xinjiang) iron meteorite

Neutron activation analysis of 15 samples from widely separated locations on the surface of the 28-t Armanty (Xinjiang) group-IIIE iron meteorite showed no compositional variations attributable to magmatic fractionation processes such as fractional crystallization. The homogeneity contrasts with that observed in the Cape York IIIAB iron, in keeping with the idea that the latter is an exceptional case. From the maximum compositional gradients the radius of the IIIE core is estimated at greater than 1 km. One sample taken from a surface formed by fracture associated with its fall to Earth is slightly anomalous in composition. It is suggested that this region is near the border between two parental gamma crystals and has a high content of minor phases.

Wasson, John T.↗
NASA NTRS1989

Workshop on Analysis of Returned Comet Nucleus Samples

This volume contains abstracts that were accepted by the Program Committee for presentation at the workshop on the analysis of returned comet nucleus samples held in Milpitas, California, January 16 to 18, 1989. The abstracts deal with the nature of cometary ices, cryogenic handling and sampling equipment, origin and composition of samples, and spectroscopic, thermal and chemical processing methods of cometary nuclei. Laboratory simulation experimental results on dust samples are reported. Some results obtained from Halley's comet are also included. Microanalytic techniques for examining trace elements of cometary particles, synchrotron x ray fluorescence and instrument neutron activation analysis (INAA), are presented.

Source record↗