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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 361 records · Page 20

STABILITY TESTS OF MONOPROPELLANTS EXPOSED TO FLAMES AND RIFLE FIRE

Tests of the stability of several monopropellants under the effects of impact and heat were conducted in order to assess the potential hazard in a propellant storage area from major fires and enemy attack. Hydrazine, hydrazine nitrate solution, n-propyl nitrate, and ethylene oxide were all tested in one-gallon aluminum containers (half of them filled to 25% and half to 95% capacity) by being subjected to oil bonfires and wood bonfires, and 20-mm incendiary, 20mm high explosive incendiary, and .30-caliber rifle fire. Aviation gasoline was tested in the same manner, for comparison. In the bonfire tests, all four monopropellants generally gave explosion intensities equivalent to one another regardless of the type of bonfire (oil or wood) or the amount of liquid in the test container. Occasionally, however, with hydrazine, hydrazine nitrate solution, and n-propyl nitrate, anomalous results occurred: there was either (a) no explosion or (b) an explosion of above average intensity. Ethylene oxide more nearly approximated the behavior of aviation gasoline than did the other monopropellants. In the rifle-fire tests, n-propyl nitrate appeared to be most shock- sensitive since it was exploded by all three types of ammunition. Hydrazine and hydrazine nitrate solution were exploded by the high-explosive ammunition, but not by the incendiary or .30-dber ammunition. Ethylene oxide was not exploded by any of the gunfire, but the liquid was ignited by both incendiary and high-explosive incendiary ammunition.

FIRING↗

Oxygen-hydrogen injector performance and compatibility with ablative chambers

An experimental investigation was conducted to develop a high-thrust, high-performance, concentric tube injector element for use with near liquid hydrogen and liquid oxygen propellants. A parallel tube coaxial injector yielded 98 percent theoretical characteristic exhaust velocity efficiency. Installation of swirlers in the oxidizer tube improved performance but caused high ablative erosion near the injector. Film cooling significantly reduced ablative erosion near the injector but did not completely alleviate gouging adjacent to each outer injection element.

Wanhainen, J. P.↗

A feasibility study of developing toroidal tanks for a spinning spacecraft

A study was made to determine the feasibility of developing toroidal propellant tanks for a bipropellant (N204/MMH) propulsion system to be used in a proposed advanced Pioneer spin-stabilized vehicle intended for a Jupiter-orbiter and possibly a Saturn-orbiter mission. The rationale for considering the use of two toroidal tanks rather than the proposed use of four spherical tanks includes the belief that a more symmetrical distribution of propellant mass and a smaller variation in the position of the vehicle center-of-mass during propellant consumption would result, reducing requirements for attitude-control propellants, for balance weight, and for other weights associated with the dynamics of the spinning spacecraft. Results lead to the conclusion that a toroidal tank containing an effective, passive surface tension propellant acquisition device could be fabricated with available manufacturing methods and could be used interchangeably for either fuel or oxidizer.

Anderson, J. E.↗

Development of ASCENT Propellant Thrusters and Propulsion Systems

Since the 1960s, hydrazine technology has dominated the market of propulsion technology by providing reliable performance on a wide variety of spacecraft. Efforts to replace hydrazine with a higher-performance and safer alternative have engaged numerous emerging technologies in the industry to mature. ASCENT propellant, also known as AF-M315E, is an example of one such green propellant. Initially developed to provide a safer handling environment than hydrazine, ASCENT offers higher overall performance than a hydrazine equivalent by creating more heat during ignition. The next generation of propulsion technology, based on ASCENT propellant, produces a higher impulse and energy density, expanding the realm of applicable missions from LEO to GEO and beyond. Building on a strong background in small satellite technology and expertise in thermal and oxidation resistant materials, Plasma Processes began several thruster programs for variety of small satellite applications using ASCENT-based technology. Plasma Processes’ background expertise in thermal and oxidation resistant materials provides the necessary foundation to create ASCENT-based technology hardware.

Green Propellant↗

Main Chamber and Preburner Injector Technology

This document reports the experimental and analytical research carried out at the Penn State Propulsion Engineering Research Center in support of NASA's plan to develop advanced technologies for future single stage to orbit (SSTO) propulsion systems. The focus of the work is on understanding specific technical issues related to bi-propellant and tri-propellant thrusters. The experiments concentrate on both cold flow demonstrations and hot-fire uni-element tests to demonstrate concepts that can be incorporated into hardware design and development. The analysis is CFD-based and is intended to support the design and interpretation of the experiments and to extrapolate findings to full-scale designs. The research is divided into five main categories that impact various SSTO development scenarios. The first category focuses on RP-1/gaseous hydrogen (GH2)/gaseous oxygen (GO2) tri-propellant combustion with specific emphasis on understanding the benefits of hydrogen addition to RP-1/oxygen combustion and in developing innovative injector technology. The second category investigates liquid oxygen (LOX)/GH2 combustion at main chamber near stoichiometric conditions to improve understanding of existing LOX/GH2 rocket systems. The third and fourth categories investigate the technical issues related with oxidizer-rich and fuel-rich propulsive concepts, issues that are necessary for developing the full-flow engine cycle. Here, injector technology issues for both LOX/GH2 and LOX/RP-1 propellants are examined. The last category, also related to the full-flow engine cycle, examines injector technology needs for GO2/GH2 propellant combustion at near-stoichiometric conditions for main chamber application.

Santoro, Robert J.↗

Low-thrust Isp sensitivity study

A comparison of the cooling requirements and attainable specific impulse performance of engines in the 445 to 4448N thrust class utilizing LOX/RP-1, LOX/Hydrogen and LOX/Methane propellants is presented. The unique design requirements for the regenerative cooling of low-thrust engines operating at high pressures (up to 6894 kPa) were explored analytically by comparing single cooling with the fuel and the oxidizer, and dual cooling with both the fuel and the oxidizer. The effects of coolant channel geometry, chamber length, and contraction ratio on the ability to provide proper cooling were evaluated, as was the resulting specific impulse. The results show that larger contraction ratios and smaller channels are highly desirable for certain propellant combinations.

Schoenman, L.↗

NASA Gateway Refueling Architecture and Concept of Operation

The Lunar Gateway is a deep space orbiting outpost being developed by NASA in partnership with ESA and other domestic and international partners. It is a critical component of NASA’s Artemis program supporting long-term human exploration of the moon and is designed to be refueled, requiring the on-orbit transfer of propellants. The first two modules of Gateway to be launched will be the Power and Propulsion Element (PPE) and the Habitation and Logistics Outpost (HALO). The PPE contains the bipropellant chemical and electrical propulsion systems that will provide attitude control and orbit raising capability for Gateway. The reaction control system (RCS) utilizes monomethylhydrazine (MMH) and mixed oxides of nitrogen-3 (MON-3) as the fuel and oxidizer, respectively. Helium is used as a pressurant. The Advanced Electric Propulsion Systems (AEPS) and Busek hall thrusters that comprise the solar electric propulsion (SEP) system use xenon as the propellent. The ESPRIT Refueling Module, provided by ESA, will supply the propellant refueling function to Gateway’s propulsion systems. On-orbit refueling is a complex, technically challenging operation that is key to enabling sustainable crewed Lunar and Martian exploration. Numerous systems may be involved in the refueling operation. Also numerous systems are required to enable the successful ability for Gateway to refuel such as, SEP, RCS, Structure & Mechanisms (S&M), Guidance, Navigation and Control (GNC), Thermal, Software, Vehicle System Manager (VSM), Flight Ops, Extra Vehicular Robotics (EVR), Communication and Tracking (C&T), Avionics, and more. This paper will detail the design architecture, concept of operations, and challenges associated with the Gateway refueling system. The methodologies used in Gateway will be compared to those implemented in OSAM-1 and the best practices documented by AIAA and CONFERS (Consortium For Execution Of Rendezvous And Servicing Operations).

Brandie L. Rhodes↗

A study of the effects of solid phase reactions on the thermal degradation and ballistic properties of solid propellants

The thermal stability of perchlorate composite propellants was studied at 135 and 170 C. The experimental efforts were concentrated on determining the importance of heterogeneous oxidizer-fuel reactions in the thermal degradation process. The experimental approach used to elucidate the mechanisms by which the oxidizer fuel composites thermally degrade was divided into two parts: (1) keeping the fuel constant and varying the nature of the oxidizers, and (2) holding the oxidizer constant and varying the fuel components. The fuel component primarily utilized in the first phase was polyethylene. Oxidizers included KClO4, KClO3, NH4ClO4 and NH4ClO4 doped with materials such as chlorate, phosphate and arsenate. In the second phase the oxidizer used was primarily NH4ClO4 while the fuels included saturated and unsaturated polybutadiene prepolymers and a series of bonding agents. Techniques employed in the current study include thermogravimetric measurements, differential thermal analysis, infrared, mass spectrometry, electron microscopy, and appropriate wet chemical analysis.

Schmidt, W. G.↗

Modelling and experimental verification of a water alleviation system for the NASP

One possible low speed propulsion system for the National Aerospace Plane is a liquid air cycle engine (LACE). The LACE system uses the heat sink in the liquid hydrogen propellant to liquefy air in a heat exchanger which is then pumped up to high pressure and used as the oxidizer in a hydrogen liquid air rocket. The inlet airstream must be dehumidified or moisture could freeze on the cryogenic heat exchangers and block them. The main objective of this research has been to develop a computer simulation of the cold tube/antifreeze-spray water alleviation system and to verify the model with experimental data. An experimental facility has been built and humid air tests were conducted on a generic heat exchanger to obtain condensing data for code development. The paper describes the experimental setup, outlines the method of calculation used in the code, and presents comparisons of the calculations and measurements. Cause of discrepancies between the model and data are explained.

Vanfossen, G. James↗

Theoretical performance of liquid hydrogen and liquid fluorine as a rocket propellant

Theoretical values of performance parameters for liquid hydrogen and liquid fluorine as a rocket propellant were calculated on the assumption of equilibrium composition during the expansion process for a wide range of fuel-oxidant and expansion ratios. The parameters included were specific impulse, combustion-chamber temperature, nozzle-exit temperature, equilibrium composition, mean molecular weight, characteristic velocity, coefficient of thrust, ration of nozzle-exit area to throat area, specific heat at constant pressure, coefficient of viscosity, and coefficient of thermal conductivity. The maximum value of specific impulse was 364.6 pound-seconds per pound for a chamber pressure of 300 pounds per square inch absolute (20.41 atm) and an exit pressure of 1 atmosphere.

Gordon, Sanford↗

Theoretical performance of liquid ammonia and liquid fluorine as a rocket propellant

Theoretical values of performance parameters for liquid ammonia and liquid fluorine as a rocket propellant were calculated on the assumption of equilibrium composition during the expansion process for a wide range of fuel-oxidant and expansion ratios. The parameters included were specific impulse, combustion chamber temperature, nozzle-exit temperature, equilibrium composition, mean molecular weight, characteristic velocity, coefficient of thrust, ratio of nozzle-exit area to throat area, specific heat at constant pressure, coefficient of viscosity, and coefficient of thermal conductivity. The maximum value of specific impulse was 311.5 pound-seconds per pound for a chamber pressure of 300 pounds per square inch absolute (20.41 atm) and an exit pressure of 1 atmosphere.

COMBUSTION - ROCKET ENGINES↗

Hybrid fuel formulation and technology development

The objective was to develop an improved hybrid fuel with higher regression rate, a regression rate expression exponent close to 0.5, lower cost, and higher density. The approach was to formulate candidate fuels based on promising concepts, perform thermomechanical analyses to select the most promising candidates, develop laboratory processes to fabricate fuel grains as needed, fabricate fuel grains and test in a small lab-scale motor, select the best candidate, and then scale up and validate performance in a 2500 lbf scale, 11-inch diameter motor. The characteristics of a high performance fuel have been verified in 11-inch motor testing. The advanced fuel exhibits a 15% increase in density over an all hydrocarbon formulation accompanied by a 50% increase in regression rate, which when multiplied by the increase in density yields a 70% increase in fuel mass flow rate; has a significantly lower oxidizer-to-fuel (O/F) ratio requirement at 1.5; has a significantly decreased axial regression rate variation making for more uniform propellant flow throughout motor operation; is very clean burning; extinguishes cleanly and quickly; and burns with a high combustion efficiency.

Dean, D. L.↗

Mars Ascent Vehicle Hybrid Propulsion Configuration

As part of a Mars Sample Return (MSR) campaign, two Mars Ascent Vehicle (MAV) configurations have been designed in parallel. Each ascent vehicle configuration has a different propulsion system which ultimately leads to two unique vehicle designs. As part of a Preliminary Architecture Assessment (PAA), these vehicle designs were developed to the same level of maturity in order to inform the selection of one of the vehicles as the point of departure design for the campaign. The selection will be made in November 2019. The initial MSR architecture called for a hybrid-based propulsion MAV. This type of propulsion system calls for a solid wax motor that would utilize liquid MON-25 as an oxidizer. Hybrid rocket propulsion allows for more flexibility than traditional solid or liquid propulsion options, and typically benefits from the advantages of both. A hybrid motor can be throttled and shut down easily, and avoids significant risk in manufacturing and handling. On a theoretical level, hybrid motors perform at a higher specific impulse (Isp) than solid motors. The primary disadvantage of hybrid motors comes from additional complexity and significantly less flight heritage and low Technology Readiness Level (TRL). This paper describes the design of the hybrid propulsion configuration. An additional paper will be published describing the design of the solid propulsion configuration1. The hybrid propulsion configuration MAV was developed in 2019 by NASA Marshall Space Flight Center (MSFC) in association with NASA Jet Propulsion Laboratory (JPL). It features a Single Stage to Orbit (SSTO) design with an SP7A solid wax fuel and MON-25 liquid oxidizer. The liquid portion of the vehicle allows for a Liquid Injection Thrust Vector Controller (LITVC) as well as hypergolic propellant additives for ignition. The vehicle was designed to deliver approximately 0.31kg of Martian geological samples to a circular orbit at Mars of 343km at a 25o inclination. Although hybrid propulsion in general has been used on launch vehicles in the past, the integrated vehicle subsystems that operate in conjunction with these propulsion elements do not typically operate in a Martian environment, which in this application can get as cold as -40oC. The PAA advanced the maturity of these subsystems by performing detailed design and analysis on the vehicle with respect to structures and mechanisms, Guidance/Navigation/Control (GNC) systems, avionics, Reaction Control System (RCS), LITVC, thermal environments, and advanced Computational Fluid Dynamics (CFD). This paper will summarize the results of these studies.

Yaghoubi, Darius↗

STS-55 pad abort: Engine 2011 oxidizer preburner augmented spark igniter check valve leak

The STS-55 initial launch attempt of Columbia (OV102) was terminated on KSC launch pad A March 22, 1993 at 9:51 AM E.S.T. due to violation of an ME-3 (Engine 2011) Launch Commit Criteria (LCC) limit exceedance. The event description and timeline are summarized. Propellant loading was initiated on 22 March, 1993 at 1:15 AM EST. All SSME chill parameters and launch commit criteria (LCC) were nominal. At engine start plus 1.44 seconds, a Failure Identification (FID) was posted against Engine 2011 for exceeding the 50 psia Oxidizer Preburner (OPB) purge pressure redline. The engine was shut down at 1.50 seconds followed by Engines 2034 and 2030. All shut down sequences were nominal and the mission was safely aborted. The OPB purge pressure redline violation and the abort profile/overlay for all three engines are depicted. SSME Avionics hardware and software performed nominally during the incident. A review of vehicle data table (VDT) data and controller software logic revealed no failure indications other than the single FID 013-414, OPB purge pressure redline exceeded. Software logic was executed according to requirements and there was no anomalous controller software operation. Immediately following the abort, a Rocketdyne/NASA failure investigation team was assembled. The team successfully isolated the failure cause to the oxidizer preburner augmented spark igniter purge check valve not being fully closed due to contamination. The source of the contaminant was traced to a cut segment from a rubber O-ring which was used in a fine clean tool during valve production prior to 1992. The valve was apparently contaminated during its fabrication in 1985. The valve had performed acceptably on four previous flights of the engine, and SSME flight history shows 780 combined check valve flights without failure. The failure of an Engine 3 (SSME No. 2011) check valve to close was sensed by onboard engine instruments even though all other engine operations were normal. This resulted in an engine shutdown and safe sequential shutdown of all three engines prior to ignition of the solid boosters.

Source record↗

Space shuttle seal material and design development for earth storable propellant systems

The results of a program to investigate and characterize seal materials suitable for space shuttle storable propellant systems are given. Two new elastomeric materials were identified as being potentially superior to existing state-of-the art materials for specific sealing applications. These materials were AF-E-124D and AF-E-411. AF-E-124D is a cured perfluorinated polymer suitable for use with dinitrogen tetroxide oxidizer, and hydrazine base fuels. AF-E-411 is an ethylene propylene terpolymer material for hydrazine base fuel service. Data are presented relative to low and high temperature characteristics as well as propellant exposure effects. Types of data included are: mechanical properties, stress strain curves, friction and wear characteristics, compression set and permeability. Sealing tests with a flat poppet-seal valve were conducted for verification of sealing capability. A bibliography includes over 200 references relating to seal design or materials and presents a concise tabulation of the more useful seal design data sources.

Source record↗

Effect of silicone oil on nozzle heat transfer in solid propellant rockets

The feasibility of reducing heat transfer rates to inert nozzle walls in solid rockets by addition of silicone oil as a propellant ingredient is explored experimentally. A metallized control propellant and its counterpart with 1% silicone oil are fired in a 2 1/2-in. diameter end burning all-metal burner. Pressure-time histories are obtained; temperature-time data at the nozzle throat are obtained in some of the runs. The heat loss by the product gases to the cold inert walls of the nozzle lower the temperature of the gases leading to the condensation of aluminum oxide on the walls. This condensation is used as an index of the heat transfer rate to the nozzle. On a statistical basis it is found that the silicone propellant gives practically no condensation in 70% of the firings contrasted with 21% for its counterpart with no silicone oil in it. The gas temperature at the nozzle throat is experimentally seen to be generally higher with the silicone propellant than with its counterpart; this higher temperature is consistent with a preliminary analysis that is used here to relate the nozzle surface temperature to the heat transfer from the product gases.

Ramohalli, K.↗

Triaxial Swirl Injector Element for Liquid-Fueled Engines

A triaxial injector is a single bi-propellant injection element located at the center of the injector body. The injector element consists of three nested, hydraulic swirl injectors. A small portion of the total fuel is injected through the central hydraulic injector, all of the oxidizer is injected through the middle concentric hydraulic swirl injector, and the balance of the fuel is injected through an outer concentric injection system. The configuration has been shown to provide good flame stabilization and the desired fuel-rich wall boundary condition. The injector design is well suited for preburner applications. Preburner injectors operate at extreme oxygen-to-fuel mass ratios, either very rich or very lean. The goal of a preburner is to create a uniform drive gas for the turbomachinery, while carefully controlling the temperature so as not to stress or damage turbine blades. The triaxial injector concept permits the lean propellant to be sandwiched between two layers of the rich propellant, while the hydraulic atomization characteristics of the swirl injectors promote interpropellant mixing and, ultimately, good combustion efficiency. This innovation is suited to a wide range of liquid oxidizer and liquid fuels, including hydrogen, methane, and kerosene. Prototype testing with the triaxial swirl injector demonstrated excellent injector and combustion chamber thermal compatibility and good combustion performance, both at levels far superior to a pintle injector. Initial testing with the prototype injector demonstrated over 96-percent combustion efficiency. The design showed excellent high -frequency combustion stability characteristics with oxygen and kerosene propellants. Unlike the more conventional pintle injector, there is not a large bluff body that must be cooled. The absence of a protruding center body enhances the thermal durability of the triaxial swirl injector. The hydraulic atomization characteristics of the innovation allow the design to be rapidly scaled from small in-space applications [500-5,000 lbf (2.2 22.2 kN)] to large thrust engine applications [80,000 lbf (356 kN) and beyond]. The triaxial injector is also less sensitive to eccentricities, manufacturing tolerances, and gap width of many traditional coaxial and pintle injector designs. The triaxial-injector injection orifice configuration provides for high injection stiffness. The low parts count and relatively large injector design features are amenable to low-cost production.

Muss, Jeff↗